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By Frederick W. DeVries

EPA announced, when they proposed to set a potable-water limit on cyanide, in August, 1990, that they had never encountered cyanide in a :sample of potable water, but they felt this was a sufficiently toxic and common material that it should be covered with a specification. The writer worked with both the American Mining Congress and the Aluminum Association in responding to their proposed spec. of 0.2 ppm max. of "cyanide" in· potable water. Although there are many subcategories of "cyanide", they failed to specify which type they meant.

Jan 1, 1993

By Brian T. Field

Development of cost effective technology for whole ore roasting of refractory gold ores is an important requirement to increase recovery rates as ore grades become more carbonaceous and sulfidic in nature. It is important that the industry focus on the further development of cost effective, environmentally sound technologies to roast this ore. Traditional technologies have centered around bubbling and circulating fluidized beds with and without oxygen enrichment. Fuller Company has developed a process to flash roast refractory ores in its pilot plant with the R&D results, commercial scale up issues, and indicative economics discussed herein.

Jan 1, 1993

By P. R. Bailey

The use of carbon for the recovery of the gold dissolved in cyanide leaching began with a pilot unit at Barberton in 1977. This was quickly followed by larger scale plants at Modderfontein (1978), President Brand (calcine 1980), Western Areas (filter tails 1980) and Beisa (primary ore 1981) and has grown to become the preferred process. There are currently 34 operations that use the carbon in pulp/leach process which accounts for 35 percent of South Africa's gold production. The size of individual plant varies over a wide range.

Jan 1, 1993

By Stephen LaBrooy, David Muir

Gold ores in the geologically more recent rocks are often associated with copper minerals which pose problems of high reagent consumption with conventional cyanidation practice. Many examples exist in northern Australia, Indonesia, Papua­New Guinea, Chile, and Brazil where, despite various treatment options (LaBrooy, 1992), the processing of oxide and transition ores is uneconomic either for copper or gold recovery. Hence, there is a need for a reagent which is selective for gold without leaching copper minerals. The ammonia-cyanide system appears to meet this criterion (Muir et al, 1989; LaBrooy et al, 1991; Costello et al, 1992; Hayes and Corrans, 1992) but it has proven difficult to optimise and apply to a variety of ores due to differences in the mineralogy and reactivity of ores and a lack of understanding of how the system works. Recent work on the mechanism, however, (Muir et al, 1993) has thrown a new light on the problem which should allow better process control. Ammonia­cyanide mixtures behave neither like free cyanide nor free ammonia and too much of either reagent in the mixture is detrimental. The key to the process is understanding how ammonia enhances gold extraction yet inhibits copper extraction in an essentially cyanide environment.

Jan 1, 1993

By A. R. Laplante

In this paper, the performance of the Knelson Concentrator and of the batch and continuous Falcon Concentrators are compared. The units are based on different operating principles, and perform quite differently. The Knelson yields very high free gold recoveries over a wide size range of both the recovered and rejected species. It is less effective in recovering very fine (<15 μm) or very flaky gold, as encountered in flotation feeds, concentrates or tails. It is the preferred unit for gold recovery from grinding circuits. The batch Falcon is effective in the fine range, typically less than 37 μm for gold. Its recovery zone is quickly saturated when there is significant heavies in the feed. It works best as a pre-concentration unit, or when sulphide content is low. The continuous Falcon is a versatile unit which is capable of recovering fine heavies (density down to 5 g/cm 3), especially from coarser gangue.

Jan 1, 1993

By D. W. Dew, D. M. Miller, P. C. van Aswegen

The bacterial oxidation (BIOX®) process for pre-treatment of refractory ores for gold recovery is marketed by BIOMIN Technologies S.A. The process was originally developed by GENMIN who are still providing testwork, design and commissioning assistance to BIOMIN. This process offers an alternative to the more conventional roasting or pressure oxidation techniques with the following advantages: • Greatly reduced capital costs for small to medium size plants. • A relatively flexible and easily controllable process requiring relatively unskilled labour for operation. • Improved gold recovery. • A process that is environmentally friendly. The principal disadvantage of bacterial oxidation is the relatively slow kinetics compared to pressure oxidation and roasting, a plant residence time of 4 to 5 days typically being required to obtain complete liberation of gold from refractory sulphide minerals. Bacterial activity is also slow to recover from disruptions such as air supply failure or contamination by toxic species such as cyanide. Optimum plant performance depends on judicious management and sound training of operators.

Jan 1, 1993

By Bruce W. Cavender

There is a tendency for managers of mining companies to regard the performance of a process plant as essen­tially fixed, with only incremental improvements to be realized by optimizing individual unit operations. However, a number of op­erations management methods are available that will substantially improve plant performance, through both productivity increases and cost reductions. Known collectively as "world-class manufac­turing" techniques, these include total quality control, just-in-time production and inventory management, the systematic develop­ment of innovative plant practices, and progressive management accounting and business control systems. The implementation of these techniques by plant managers and operators will enable the plant's performance to exceed levels that are currently believed to be maximized.

Jan 1, 1993

By Jurgen H. L. Stuve, Rick E. M. Widelski

Any one who has been involved with the mining or the treatment of gold-bearing ores will agree that at the end of the total process, the quantity of gold recovered is never as much as was expected. These short falls are usually explained away by claiming that:- the original evaluation of the ore being mined was inaccurate the plant treatment process is not at its optimum theft is taking place excessive dilution occurs during mining The truth of the matter is that the gold is being "lost". During all the stages of its production, starting from the mining, right through to the smelting process, a certain amount of gold is not recovered. When a newly found gold deposit is being evaluated and the drilling data being analysed, cautionary factors are applied so that the grade is not over-stated. Once the decision has been taken to start mining and development is in progress, the exposed ore is sampled. When Again, when this data is being analysed more safety factors are used to ensure that when a piece of ground is given a block-value, the gold content is not over estimated. mining actually takes place and the ore transported to the plant for treatment, the metallurgical department also introduces certain safety factors when predicting how much gold will be recovered. This shows that the quantity of gold that one expects to finally recover is already a conservative figure. The actual quantity recovered invariably falls short of this figure, in fact, South African gold mines are satisfied when achieving a Mine Call Factor (MCF) of 85%. In the last few years a great deal of work has been carried out to investigate how this unaccounted for gold is lost and what steps can be taken to remedy the situation. Previously mined areas were re-swept using the traditional hand brush method; experiments were carried out with water jets sometimes in conjunction with compressed air and even small portable vacuum cleaners were tried. None of these methods were totally successful in recovering the left over gold but the use of vacuum systems showed the most potential. the In South Africa this has resulted in introduction of high-powered vacuum systems on the gold mines to suck-up this lost gold. These were initially introduced in the mining areas, particularly old areas, to recover any left over ore. The results proved extremely profitable, So much SO that presently, well over 120 suction systems are doing this type of work. This success encouraged plant operators to look at areas of potential loss in the plant itself. This has resulted in an increasing number of machines being supplied to gold plants mainly for clean-up applications with the bonus that the material sucked up invariably contains gold.

Jan 1, 1993

By Ian Mcgaffin

P.T. Kellan Equatorial Mining (KEM) is an Indonesian incorporated company owned 90% by CRA Limited of Australia and 10% by PT. Harita Jayaraya of Indonesia. The Kelian gold mine first commenced production in January 1992 and has produced in excess of 21 tonne of gold (675,000 oz) in its first 18 months of operation. The operation is a large tonnage low grade deposit that accepts a low gold recovery by industry standards due to the partially refractory nature of the orebody.

Jan 1, 1993

By Dennis J. Appelhans

Lac Minerals Bullfrog conducted research and testwork to find an environmentally acceptable alternative to lead for fire assaying. The result of this work was the substitution of bismuth for lead in all fire assaying performed at the Bullfrog Mine. The environmental and economic ramifications of this discovery are highlighted.

Jan 1, 1993

By Gary L. Simmons

Aqueous pressure oxidation at low temperature, although desirable from a process engineering and operations point of view, presents unique problems when temperatures approach 160°C (320°F). In developing the pressure oxidation process for the Lone Tree Mine, elemental sulfur formation and agglomeration with pyrite proved to be a problem. This paper discusses some of the unique mineralogical and chemical characteristics of the Lone Tree sulfide deposit that make it amenable to low temperature pressure oxidation. Problems encountered during pilot plant operation and their solutions are also discussed.

Jan 1, 1993

By Yeonuk Choi, Gus Van Weert

cyanide control in effluents is becoming a critical environmental issue for the gold extraction industry. Silver impregnated carbon removes free cyanide effectively to the ppb level from solution in high throughput columns. By re-calcining the cyanide saturated carbon, the impregnated silver is restored to activity and the cyanide destroyed outside the effluent stream. Many gold mills already have an activation kiln on site, which could make retrofit relatively easy.

Jan 1, 1993

By Eric Jones, Leslie C. Thompson

Biological processes for cyanide detoxification in mine waste are receiving attention as an alternative to conventional chemical treatment options. Some of the advantages of biological treatment include: Low comparative treatment cost * Shorter treatment time * In Situ Treatment * Complete Detoxification - Ends long-term liability - Eliminates in-perpetuity monitoring - Natural Re-Vegetation potential Natural and non-toxic nutrients, by-products and process end-products Hecla Mining chose a bio-neutralization process developed by Pintail Systems, Inc. for cyanide detox in spent are and process solutions from heap leach operations at the Yellow Pine Unit. The Yellow Pine operation is located 50 air miles east of McCall, Idaho, in the Stibnite Mining District. This district is a historic mining district dating back to the early 1900's. During World War II, this district produced a majority of the antimony and tungsten the United States using for the war effort. More recently, the Stibnite district has been known for its gold production. Hecla Mining Company is based in Coeur d'Alene, Idaho, and is a leading domestic producer of precious metals and a major supplier of specialty aggregate and industrial minerals. Pintail Systems, Inc. is a company specializing in the development of biological treatment processes for mine waste remediation. PSI has offices in three states and a laboratory, pilot plant and field office in Aurora, Colorado

Jan 1, 1993

By G. M. Bernard

This paper provides an overview of the various methods and techniques for transporting and stacking ore on heap leach pads. Towards this end, brief discussions of the various methods and techniques important to this process are presented.

Jan 1, 1993

By J. M. W. Mackenzie

Three major developments have dominated the recovery of gold from ores, viz; 1846 Elsner's studies of gold solubility in aerated alkaline cyanide solutions 1887 MacArthur and Forrest's process based on zinc precipitation 1980+ Large scale development of the CIP process The brevity of this list for a metal whose extractive metallurgy has been as widely studied as any metal reflects the fact that the chemistry of the gold recovery process, as opposed to the engineering has seen few significant breakthroughs in over a century of application. to The purpose of this paper is introduce a new chemistry for gold recovery which may, in the future, add significantly to the technology of gold recovery. This new chemistry is based guanidine functionality - (R2R2N) 2 C = N R2 on the In developing the use of the guanidine functionality for the recovery of gold as the aurocyanide anion from leach solutions and pulps, Henkel has, as its objective, the development of an effective gold selective ion exchange resin. As will be seen, the initial investigation of the properties of the guanidine functionality in the solvent form for gold recovery lead to some significant metallurgical developments of their own but, the foremost objective was, and remains, the development of a resin for gold recovery. As a part of this development project, Henkel has entered into association with Mintek, South Africa, and this ongoing association has the potential to develop RIP/RIS technology for the gold industry. More details on Henkel's gold recovery technology and Mintek's role in this programme are given in (1). an The application of ion exchange resins to gold recovery is not new and many reviews have been published on the advantages of this process, and on the current state of the art of gold recovery by ion exchange resins. (2)(3)(4) Widespread application of ion exchange resin based processes for gold recovery has, however, not occurred to date. Fleming and Cromberge (5), described some significant pilot plant RIP trials in South Africa and the partial success of these pilot plant trials held out the tantalising possibility of a breakthrough in gold recovery based on RIP technology. Despite this pioneering work, only two really significant applications of RIP technology for gold recovery exist today. These are the Golden Jubilee Plant in the Eastern Transvaal South Africa and the widespread, although in some respects technically backward, use of ion exchange for gold recovery in the former USSR. There are two main reasons for the current scarcity of RIP and RIS plants used for gold recovery. These are: 1. 2. The perceived problems of engineering RIP plants The lack of a resin having suitable chemistry for both gold loading and gold elution The problems of engineering RIP plants have been largely overcome in the last 25 years. Much of the development in RIP plant design took place in the uranium industry during the rapid expansion of that industry in the mid 1970's. In addition, the development of CIP engineering systems has lead to the development of in-pulp solid extractant based metallurgical plant designs which can, with limited modification, be adopted to RIP. The lack of a resin having suitable chemical properties has almost certainly been the main reason for RIP/RIS not being introduced into the gold industry over the past decade. Attempts to use RIP/RIS have focussed on either conventional we ak base or conventional strong base resins. The weak. base resins have the disadvantage that they

Jan 1, 1993

By Diane Schwegler-Berry, Vincent Castranova, Chang-geng Moe, Jane Y. C. Ma, Mark D. Moore, Joseph K. H. Ma, Carl J. Malanga, Ji-Hee Kane

"Effects of Bisbenzylisoquinoline Alkaloids on Alveolar Macrophages: Correlation between Binding Affinity. Inhibitory Potency and Antifibrotic Potential. CASTRANOVA, V., KANG, J-H., MA. J. K. H., Mo, C-H., MALANGA, L. J., MOORE M. D., SCHWEGLER-BERRY, D.. AND MA. J. Y. C. (1991). Toxicol. Appl. Pharmacol 108, 242-252. The Chinese have conducted extensive studies concerning the medicinal properties of plant products. In this investigation the ability of three bisbenzylisoquinoline alkaloids to inhibit particle-induced activation of alveolar macrophages was evaluated and this inhibitory potential was correlated with the ability of those drugs to bind to membrane components. Tetrandrine. i.e.. an herbal medicine used as an antifibrotic agent in China, was a potent inhibitor of particle-stimulated oxygen consumption, superoxide release, and hydrogen peroxide secretion by alveolar macrophages. Tetrandrine also exhibited substantial binding affinity for membrane lipids and alveolar macrophages. In contrast, tubocurine, an analogue with little antifibrotic potential, exhibited low binding affinity and had little effect on macrophage activation. Methoxyadiantifoline, an alkaloid of unknown antifibrotic potential, exhibited inhibitory and binding properties similar to those of tetrandrine. The data indicate that a strong relationship exists between the antifibrotic potential of these alkaloids and their ability to bind to alveolar macrophages and inhibit particle-induced activation of these phagocytes. These drugs should serve as useful probes to evaluate the role of alveolar macrophages in pulmonary fibrosis. © 1991 Academic Press, Inc.Chronic silicosis is a fibrotic disease resulting from occupational exposure to silica dust. It is manifested initially by an increase in the quantity of pulmonary surfactant (Dethloff et al., 1986). However, in later stages it is characterized by an increase in collagen formation and the development of concentric hyalinized nodular lesions in the lung (Ziskind et al., 1976). Although mechanisms for the progression of silicosis have not yet been completely defined, activation of alveolar macrophages by respirable silica particles is believed to play an important role in the etiology of this disease. Studies from our laboratory have shown that both in vitro and in vivo silica exposures result in a stimulation of macrophage release of reactive products capable of damaging the lung parenchyma (Castranova et al., 1990; Goodman et al., 1990). In addition, exposure of al¬veolar macrophages to silica results in the release of fibrogenic factors which enhance the proliferation of fibroblasts and the synthesis of collagen by these pneumocytes (Leibovich and Ross, 1976; Bitterman et al., 1982, 1983).The bisbenzylisoquinoline alkaloids, which represent the largest group among the iso-quinoline compounds isolated from the plant kingdom, are known to exhibit a broad rangeof pharmacological activities. Tetrandrine, for example, an alkaloid isolated from the root of Stephania tetrandra, has been tested for its antitumor, antihypertensive, and antisilicotic effects (Kupchan and Atland, 1973; Zeng et al., 1985; Yu et al., 1983). It is currently used in China as a treatment for angina, hypertension, and silica-induced pulmonary fibrosis (Li et al., 1981). Several related bisbenzylisoquinoline alkaloids such as methoxyadiantifoline and tubocurine have also been evaluated for medicinal effects. Methoxyadiantifoline has been shown to exhibit effects on the cardiovascular system similar to those reported for tetrandrine (Jia et al., 1988). However, to date, the antifibrotic activity of methoxyadiantifoline has not been evaluated. In contrast to tetrandrine, tubocurine, a structural analogue of this drug, has been reported to be relatively ineffective against fibrosis (Mo et al., 1982)."

Mar 1, 1992

By A. W. Khair, M. Ahmad

"Bit wear has been proven to have a significant effect on respirable dust generation in coal cutting system. The mechanism of bit wear can be adhesion, abrasion. oxidation, or diffusion. depending on cutting conditions. This paper presents a portion of an extensive ongoing series of studies to better understand the principles of bit wear and dust generation. Used bits collected from underground coal mines were analyzed to identify the basic principle of bit wear in coal and rock cutting. Distribution of weight loss and conical height loss of worn bits were studied and bit wear was divided into four stages according to weight loss. Utilizing these worn bits, Laboratory experiments have been carried out to study the effects of bit wear on coal cutting system and respirable dust generation. An Automated Rotary Coal Cutting Simulator was use to perform the experiments. Acoustic emission monitoring is applied to study the effect of bit wear on fracture formation and dust generation. INTRODUCTIONContinuous miners were introduced in the 1950’s and became the major equipment in underground coal production. Now the larger production in the coal industry has increased the demand for continuous miners and their use. It is well known that serious dust problem is also introduced with the use of continuous miners, especially with recent increase in productivity. On the other hand, legal restrictions are made ·more strict by the Mine Health & Safety Administration for the respirable dust generated by the continuous miners to prevent coal workers from incidence of pneumoconiosis. The incidence of pneumoconiosis depends on dust concentration, exposure time, and physical properties of dust. Of them, dust concentration is the best parameter for the assessment of the risk of pneumoconiosis. Although a lot of research work has been done to reduce dust concentration substantially, some areas are still required further investigation to meet the strict regulations. One of the areas is about bit wear and dust generation. In this area, the principles of bit wear and effect of bit wear on dust generation are major concerns."

Mar 1, 1992

By R. L. Grayson

"Compliance standards for respirable dust, which are reduced because of high quart: concentrations, have become an industry-wide problem. Research on the physical and chemical character of quart-classified particles in respirable coal mine dusts indicates that they may exist in intermixed layers or may be coated by clay or coal material. The relative amount of intermixing varies with the coal seam being mined. If most of the quart: particles of a mine dust are ""pure,"" then the dust may have a high fibrogenic risk potential because of truly free silica and the compliance standard should be lowered. lf, however, quart: is locked inside another material matrix, or coated, a reduced compliance standard may not be appropriate.Although much research has been done on coal workers' pneumoconiosis (CWP) over the past decades, the etiologic agents of the disease still have not been pinpointed. The predominant methods of characterizing respirable coal mine dusts were bulk analysis techniques for determination of elemental and mineralogical concentrations, the results of which were used in statistical analyses to determine relationships between dust composition and the occurrence of CWP. These methods are incapable of finding the etiologic agents in the dust primarily because of complicated and confounding physiochemical factors, which may be discovered if the focus of characterization was done on a dust particle level.The SEM/EDXA-based research discussed here shows a significant difference in the number of ""pure"" quartz particles in respirable dusts collected from different mines. Some of the results have been reported previously (Grayson, Andre, and Simonyi, 1988). Concurrent research by other investigators (Wallace et al., 1989) demonstrates an SEM/EDXA-based methodology to pinpoint the location of the ""contaminating"" substance(s ) in a quartz-classified particle. The research of the European Economic Community has also begun analyses on the respirable-dust-particle level (Robock and Bauer, 1988).Since the compensatory and intangible costs of CWP are substantial in the United States, it is important that the etiologic agents be determined and then either controlled or neutralized in a cost-effective way. This line of research is especially important consid-ering the forecasted. near-term growth of coal production and the evolution of high productivity longwall panels (an immediate problem in compliance) and continuous mining sections ( a probable future problem).This need has been accentuated now that nearly all respirable dust samples submitted to MSHA are analyzed for free silica (Tomb, Parobeck, and Gem, 1986). Today a real problem exists in the coal industry, both underground and surface, because of high quartz levels in respirable dusts causing substantially reduced compliance standards (Murphy, 1989).The combined results of the respirable dust particle investigators indicate that conventional bulk sample analyses may not faithfully represent the amount of biologically available or active quartz in all mines with a high level (greater than 5% ) of quartz in the dust For example, some mine dusts might contain predominantly occluded (or coated) quartz particles where bulk analysis would result in anomalously high ""free silica"" measurements. The same result would occur when quartz particles are intermixed substantially with other minerals that can alter the surface of the composite particle away from a quartz-behaving character."

Mar 1, 1992

By Vincent Castranova, Jane Y. C. Ma, Joseph K. H. Ma, Chang-geng Mo, Carl J. Malanga

"A group of bisbenzylisoouinoline alkaloids has been shown to exhibit various degrees of effectiveness in preventing silica-induced fibrosis in animal models [1, 2]. The objective the present study was to characterize the binding of several of these alkaloids to phosphatidylcholine vesicles and rat alveolar macrophages using fluorometric and equilibrium dialysis methods, respectively. The lipid binding affinity of these alkaloids was found to depend upon several structural factors including hydrophobic substitutions, chiral configurations, and double oxygen bridge-restricted conformation of the benzylisoquinoline moieties. Tetrandrine, which is a highly effective agent in preventing fibrosis, showed strong binding to both lipid vesicles and alveolar macrophages. In contrast, certain analogues of tetrandrine such as curine and tubocurine, which have little or no effect on silicosis, exhibited only weak binding to lipid vesicles and almost no binding to cells. The moderate binding affinity of fangchinoline to vesicles and cells corresponded to a moderate effectiveness of the compound as an antifibrogenic agent. Methoxyadiantifoline, an alkaloid of unknown antifibrogenic potential, also exhibited high binding affinities for lipid and cells. In conclusion, the results of these studies indicate that alveolar macrophages exhibit large binding capacities for certain members of this class of bisbenzylisoquinoline alkaloids. A positive correlation was observed between binding affinity to alveolar macrophages and the reported antifibrotic potency of these compounds. These data also suggest that the ability of these drugs to interact with alveolar macrophages may be a key step in inhibition of the progression of silica-induced pulmonary disease.INTRODUCTIONInhalation of crystalline silica is associated with the development of silicosis. This fibrotic disease is characterized by the appearance of concentric hyalinized nodular lesions in the lungs with the progressive development of pulmonary dysfunction [3, 4]. Many theories concerning the etiology of silicosis involve silica-induced activation of alveolar macrophages. Evidence indicates that in vitro silica exposures result in the generation of chemiluminescence, and the release of superoxide and hydrogen peroxide from alveolar macrophages [5]. Activation of alveolar macrophages has also been demonstrated after intratracheal instillation or inhalation of silica [5, 6]. Such excess release of reactive products from pulmonary phagocytes has been associated with damage to the lung parenchyma [7, 8]. In addition, silica exposure results in the release of mediators from alveolar macrophages, which enhance proliferation of fibroblasts and collagen synthesis by these pneumocytes [9-12]."

Mar 1, 1992

By B. K. Cantrell, K. L. Rubow

"Quantifying exposure to diesel exhaust aerosol in an underground coal mine depends on the ability to measure this component of respirable mine aerosol separately from coal dust. Such measurement is complicated by the carbonaceous nature of both the diesel and coal dust particulate that make up the respirable aerosol. Hence, special sampling and analytical techniques must be used to distinguish between these two aerosol components.As part of a continuing study of diesel exhaust aerosol characteristics, the U.S. Bureau of Mines has applied size selective sampling together with gravimetric analysis to separate and measure respirable diesel exhaust and coal dust aerosol concentrations in diesel-equipped underground coal mines. This technique is based on the premise that the diesel portion of the aerosol is predominantly submicrometer and the mineral dust portion is mostly greater than 1 µm in size. In the study, chemical mass balance (CMB) modeling, based on the distribution of chemical elements in aerosol and aerosol source material samples, is used to referee the analysis of diesel exhaust and mineral dust aerosol concentrations from the size selective sampling results.Based on the results of the study, the Bureau, in cooperation with the University of Minnesota and the U.S. Mine Safety and Health Administration (MSHA), have developed a prototype personal diesel exhaust aerosol sampler for underground coal mines. The sampler has three stages: a preclassifier stage to select for respirable aerosol, an inertial impaction stage with an aerodynamic diameter(d) size cut at 0.8 µm to separate diesel aerosol from mineral dust and collect the mineral dust, and a final filtration stage to collect the diesel fraction of the sample. The sampler has been evaluated in both laboratory and field experiments conducted by the Bureau, MSHA, and the Generic Minerals Technology Center for Respirable Dust (GMTC-RD)."

Mar 1, 1992