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By C. J. Ferron

Gold occurrence in operating plant tailings ranges from gold in solution, fine free gold, gold associated with sulphides/arsenides/tellurides and gold occluded within iron oxides or arsenates and silica gangue. This paper briefly presents various alternatives to reprocess gold tailings, with examples. These include the use of centrifugal gravity separators, CIL, magnetic separation, flotation and pressure oxidation.

Jan 1, 1993

By R. R. Pierce, C. E. Semler, K. G. Thomas, R. A. Williams, H. J. . H. Pieterse

This paper highlights the experience and knowledge gained at Barrick Goldstrike Mines Inc. with reference to the pressure oxidation circuit. Particular attention is given to the different linings employed on the autoclaves, flash and condenser vessels. Experience gained during the three years of operation is given. A test program and results are discussed. Quality assurance is highlighted. Barrick Goldstrike is 100% owned by American Barrick Resources Corporation, Toronto, Ontario, Canada.

Jan 1, 1993

By Kathleen A. Altman, Kevin Hegerle

FMC Gold Company start.ea processing ore at their Paradise Peak Mine in 1986. Gold, silver and mercury haye been produced from the Merrill-Crowe milling circuit and from heap leaching. There are three heap leach circuits, Paradise Peak, Ketchup Flat and County Line. The Paradise Peak and Ketchup Flat heap effluent solutions are routed into the zinc precipitation plant which is associated with the mill for recovery of the precious metals. The County Lne hea lech circuit is a stand-alone operation, again with a zinc precipitation recovery circuit. The mill was shut down in May, 1993 due to depletion of ore reserves with the remainder of the heap leach ore due to be placed on the leach pads by late summer of the same year.

Jan 1, 1993

By Charles A. Horne

Grinding mill circuits used for particle size reduction of mineral ores commonly use cyclones as primary classifiers. Typically, several individual cyclones are installed in a cluster (Fig. 1) where they can easily be added or valved-out of operation in order to balance classifier capacity with fluctuations in tonnage and recirculating loads as ore grades and hardness vary.

Jan 1, 1993

By Richard W. Jolk

A pollution control equipment exemption which reduces the fair and equitable taxable value of a mine property is allowed under Nevada Revised Statute (NRS) 361.077 and must be filed in accordance with the filing requirements of NRS 361.155. USMX Nevada Operations annually saves a substantial amount of State property tax dollars by taking advantage of this tax exemption. The State documents received by USMX and the documents filed by USMX are reviewed in this paper. The application filed by USMX exhibits the format and detail used to obtain this tax exemption and the extent to which environmental control equipment may be claimed.

Jan 1, 1993

By Johann Knecht

Due to lower specific investment and operating costs the tendency towards large scale equipment will remain. For the design engineers not only the stresses in the mill structure and manufacturing are of importance but also transportation to and erection on site. A scale up of the design of smaller sized units on the pantograph principle may not always give the best approach to the job in this respect. This paper covers recent developments in the design of large size equipment where the huge dimensions call for designs being different to the well known ball and SAG mill concept with cast conical endwalls. The first part describes the features of the biggest ball mill in the world, whereas the second part provides some details of the largest shell supported SAG mills being currently in the manufacturing process.

Jan 1, 1993

By John Wiebmer

Six industry trends will have significant effect on the way mining equipment is designed and supported in the years ahead: 1. MINING IS MIGRATING TO LESSER DEVELOPED PARTS OF THE WORLD The global recession of the early 1980's drove down commodity prices and intensified cost competition. This caused a fairly dramatic trend in mining away from higher cost operations in developed countries to richer, lower cost deposits in developing countries. Miners operating in lesser developed parts of the world will place higher value on rugged, durable designs that can live in more difficult and sometimes abusive conditions. They need engines and power train systems that are more tolerant of a wide variation in fuel quality and oil specifications. They'll require machines that are simpler to operate, simpler to maintain, simpler to troubleshoot and simpler to repair. And they'll require creative means of support in getting technical information, parts and components to remote operational sites. Mining equipment in the future will be more durable and simple than it is today, and product support will grow in importance as purchasing criterion. 2. THE MINING INDUSTRY IS CONSOLIDATING An intense amount of corporate acquisition and industry consolidation activity is occurring, to the point that today just 50 mining companies account for 55% of the western world non-fuel mineral production. Consolidation will continue, leading in the future to an industry structure weighted heavily toward a few key global mining houses.

Jan 1, 1993

By Stanley A. Bunk, Desmond J. Bruyns

The purpose of roasting gold ores is to release for extraction, typically by cyanidation, the small particles of gold which are surrounded by refractory stone. The roasting simply opens up passages for the penetration of solution into the interior of the ore particles. This is accomplished by the removal by volatilization or formation of volatile oxides of certain constituents such as sulfur, arsenic or antimony. Temperature is an important parameter. High temperatures tend to form a dense iron particle rather than a "spongy" calcine. The dense iron particles result in lower gold recoveries. High temperature can cause melting of some components which also results in gold encapsulation. Roasting of refractory gold ore concentrates has been practiced for decades. Multiple hearth, rotary kiln and muffle reactors were first used for roasting. Fluid bed roasting provided a low capital cost, low maintenance technology with better process control and soon became the favored technology. The first fluid bed concentrate roasters were commissioned in the late 1940's. Early fluid beds were "bubbling" type. Environmental considerations did not significantly impact on the design. Feedstocks were highly exothermic and reaction rates were relatively rapid. Roasting today must compete with other technologies for treatment of refractory ores. Ore bodies which are not

Jan 1, 1993

By Hans von Michaelis

The revolution in development of new technology and practices in the gold mining and metallurgy industry continues unabated despite the ups and downs in the gold price. Some of the new cutting edge technologies are listed in Table 1 overleaf. There is room to discuss just a few of these here, but many more are identified and described in RANDOL (1992). Cutting edge advancements in gold recuperation, can be sorted into three categories. The first category includes fundamental advances that offer major improvement with significant economic benefits. Second would include evolutionary developments that offer smaller, but nonetheless commercially valuable improvements. Finally there are those "advances" that are interesting but of trivial or question­able economic benefit to industry. It is essential to adopt a "systems approach" philosophy towards developing and applying new technology. Practical innovation often comes about as a result of having to solve a problem. Innovation for innovation sake is an ego trip. Environmental management has become an important part of the system and the environmental implications of new processes and practices in the mine and mill have to be carefully considered for potential benefits and/or liabilities.

Jan 1, 1993

By Fred Woodcock, A. R. Laplante

A laboratory technique is presented that uses the Knelson Concentrator and a relatively small sample to predict the amenability of a given gold ore to gravity recovery. The technique applies to develop­mental orebodies as well as retrofitting existing plants. Justification for this approach is discussed. Actual results of the technique applied to existing and prospective circuits are presented and discussed.

Jan 1, 1993

By Michael J. Virnig, Keith E. Weerts

The development of heap leach technology for the treatment of low grade gold and silver ores has led to a boom in gold production in the Western United States in the last 15 years. The heap leaching process consists of stacking the mined ore on a specially prepared leach pad followed by leaching with dilute alkaline cyanide solution. Depending on the nature of the ore, it may require crushing and/or agglomeration prior to stacking on the leach pad. As the dilute alkaline cyanide solution migrates down through the stacked ore, the precious metal values along with a portion of the base metal values present in the ore are dissolved to give a pregnant leach solution which is collected at the base of the stacked ore. The precious metal values are then recovered by zinc precipitation or by adsorption on activated carbon. Once all of the economic metal values have been leached from the ore, the spent heap leach pad, the leached materials, and associated process solutions must be decomissioned. Decommissioning requires that the spent heap leach pad along with the leached materials and process solution be treated to reduce the concentration of the residual cyanide, base metal cyanide complexes, and other anionic metal species to levels where they no longer represent a long tenn liability for the environment and the operator. The levels to which these components must be reduced is dependent upon the applicable water quality standards as determined by the responsible federal, state, and local agencies. As environmental awareness has grown, these standards have become increasingly stringent. A number of treatment options have been developed for the de-toxification of the process residues. These include natural degradation which incorporates bio-degradation, fresh water rinsing, alkaline chlorination, hydrogen peroxide, and sulfur dioxide/air. Each of these options has been reviewed with regard to relative effectiveness, generation of hazardous by­products, reagent handling considerations, relative costs, and time requirements by Denton, Iverson, and Gosling I. As an outgrowth of the program to develop Henkel's guanidine based gold extractants, COGNIS, Inc., the environmental ann of Henkel, has developed the CyanoMet R process for the extraction and concentration of the various cyanide and anionic metal species from the dilute aqueous alkaline solutions generated during the process of detoxifying spent heap leach pads. This paper describes the CyanoMet R process, its application to three different feed solutions, and treatment of the concentrate generated by the process.

Jan 1, 1993

By Steve McIntosh

Restoration of a wetland which was initially disturbed at the turn­of-the-century will be undertaken to compensate for the temporary loss of wetlands associated with future mining operations. The proposed mitigation area exhibits xeric conditions as a result of past dredging and gravel mining operations which had the effect of lowering the flood plain surface and wasting the fine surface sediments. Together these mining activities resulted in complete alteration of the surface and subsurface water systems. Water which had inundated the soil profile, now flows on the basalt bedrock, surfacing only for a relatively short time during high flow periods. The conventional approach to wetland restoration in this type of area is to remove surface material in an attempt to bring the surface nearer to the underground water. These operations would require the removal and redistribution of large quantities of gravel, cobbles and boulders and the attendant destruction of existing wetland areas. Rather than lowering the surface elevation to the water level, the mitigation plan conceptualized for this project involves forcing the water to the surface by creating subsurface ponds behind four impermeable barriers. The barriers will extend vertically from the bedrock to the surface. Surface berms will be constructed along the length of each groundwater barrier to enhance sediment deposition and encourage the development of wetland vegetation. This is the least expensive and least invasive method of creating a wetland which will remain saturated to the requisite degree and for the amount of time required for classification as a wetland as defined by the 1989 Federal Manual for Identifying and Delineating Jurisdictional Wetlands.

Jan 1, 1993

By R. J. Rice, K. F. Denning

Effect of iron on the removal of arsenic, mercury and selenium from gold mining effluents. Arsenic, mercury and selenium are common trace elements in gold tailing effluents that require removal before the water is either recycled or returned to a receiving body. One of the better methods of removal of these elements is the use of iron salts whereby, the metal is trapped on the freshly precipitated hydrolyzed iron oxides either by adsorption or enmeshment of the fine particulate and hence, removed from solution. The metal removal is effected by iron to metal ratio, pH, temperature etc. Pilot plant tests have shown that mercury can be reduced to < 5 ppb Hg, while full scale tests on arsenic and selenium have achieved levels of < 50 ppb As and < 10 ppb Se in well controlled systems.

Jan 1, 1993

By J. R. Dartez

The use of CCD (counter current decantat.io;1) thickeners, or; clarifiers, in the gold mining industry is quite common. Although there are a number of technologies in the industry which utilize these types of tanks, the fundamental requirement is to settle leach tailings and eventually separate gold and silver "values" from the "barren" (no values) solution. The thickener separation process varies depending upon the raw ores found in any specific mine. In mines where rudimentary, rocky ores are most common the settling process is fairly straight-forward and uncomplicated. But, for those mines with complex carbonaceous ores, usually identified by high silting, clay components, the ability to monitor and control the settled materials is quite laborious and costly. The task of monitoring and maintaining control of settled residue in clarifiers and thickeners, of any design, is difficult in any industry, but due to the added desire in the gold mining industry of leaching the values from the liquid slurry, the problem is multiplied. Other common activities taking place in the thickeners are exaggerated internal flow rates, settleable solids activity due to rake movement, and the settling activity generated by flocculents being added to the liquid medium. All of this action within the liquid column causes the continual monitoring of the interfaces within the tank close to impossible.

Jan 1, 1993

By W. D. Gould, . W. Koren, P. Bedard, P .. B. Marchant

Ammonia and nitrate in metallurgical operations arise from several sources: (1) the use of ammonium nitrate based explosives, e.g. ANFO; (2) the use of cyanide for gold extraction which is degraded to ammonia by most cyanide destruction techniques; and (3) the use of nitrogenous reagents in the mill for neutralisation, flotation and extraction. The concentrations of ammonia and nitrate in effluents vary from 10-50 ppm and 25-300 ppm respectjvely. A number of environmental problems are associated with both ammonia and nitrate. Both of these forms of nitrogen can contribute to the eutrophication of receiving waters. Ammonia and organic nitrogen can also cause high dissolved oxygen demands in receiving waters. Ammonia is also toxic to fish, particularly at elevated pH values. Several methods are in use for the removal of ammonia and nitrate from municipal wastewater, industrial effluents and agricultural runoff. To date, no treatment systems have been developed specifically for the removal of nitrogen from mine and mill effluents. This paper will report on some removal techniques that have been tested using actual and synthetic mine effluents.

Jan 1, 1993

By Nancy L. Jackson, Leslie C. Thompson

Acid rock drainage is one of the most complex issues facing regulators and mining companies for management and remediation of mining wastes. All mining waste units, including open pits, underground workings, tailings, waste rock and leached spent ore have the potential to generate acidic leachate based on the acid generation or neutralization potential of the material. This paper uses a case study of the Walker Mine in northern California to give an overview of the available control and mitigation methods. Wetland design is emphasized as a low-cost alternative treatment option for wastewater remediation. The Walker Mine is located on the eastern flank of the Sierra Nevada, 20 miles north of Portola in Plumas County, California. The Walker Mine was an active copper mine between 1915 and 1941. During active mining, tailings were discharged into an area 1 mile west of the site at the confluence of Dolly Creek and Grizzly Creek. In addition, there were two main sources of metal-rich, acid waters impacting Dolly Creek: discharge from the mine tunnel portal, and seepage and surface runoff from waters contacting mine waste downslope from the portal area. A mine portal seal was installed in 1987 which prevented the majority of mine water drainage from further contaminating the area. Minor drainage from the portal and seeps discharge into a holding pond which overflows into Dolly Creek when elevation exceeds 6,200 feet. A site characterization study was performed to evaluate the potential water quality threat to Dolly Creek from mine tunnel discharge and waste rock seeps. Based on the results of this study several remedial options were investigated, both on a design and cost basis, to determine which abatement alternatives could be realistically implemented. The remedial options considered include both in situ containment (landfill, waste pile) or removal (backfilling into underground workings and/or sinkholes) of solid wastes. Waste water remedial options include long-term, seasonal treatment of the portal mine water, or long-term, passive treatment of portal discharge and waste pile leachate.

Jan 1, 1993

By Gary Krix

The Amdel Thickener Interface Gauge (TIG) provides continuous on-line measurement of the level of the liquid/solid interface in thickeners and Counter Current Decantation (CCD) washers. Unlike other interface level measurement systems, the TIG also determines the span of the transition zone. The transition zone is the region between the clear liquid overflow zone and the compressed solids zone. The Thickener Interface Gauge determines the level of the interface by measuring the natural radioactivity of the solids in the thickener tank using an array of up to twelve detectors mounted vertically in a stainless steel probe. All solids contain low levels of natural radioactivity while the liquid phase generally does not. The concentration of natural radioactivity at each level in the thickener therefore depends on the concentration of solids. The radiation emitted by the solids is converted to electrical pulses by the detectors in the probe and the pulse-rate provides an accurate measurement of the density. A typical count-rate profile is presented in Figure 1. The vertical axis indicates the depth in the tank referenced to the surface of the liquid. The horizontal axis indicates the count-rate measured by the TIG probe, this count-rate is proportional to the density and can be used to determine the settling rate. The count-rate at the top of the graph is relatively low, this region corresponds to the clear overflow zone which contains virtually no solids. Moving down the vertical axis the count-rate increases dramatically at the level of the transition zone where the solids content increases with the depth in the tank. In this region the settling conditions of the solid particles change from free settling to compression. Moving further down the vertical axis the count-rate reaches a plateau where the count-rate remains relatively constant although there are often small fluctuations, this region corresponds to the solids compression zone. The liquid/solid interface as measured by the TIG corresponds to the depth at which the count-rate crosses the target count-rate which is generally selected to be midway between the liquid count-rate and the compressed solids count-rate. The length of the TIG probe is selected to cover the typical operating range of the liquid/solid interface in the thickener or washer. If, for example, the minimum bed level is 3.0 metres below the surface of the liquid then the probe length is selected to extend 30 metres below the surface. The TIG probe can include up to twelve detectors and the se are spaced over the measurement range. For small measurement ranges of around one metre 4 to 6 detectors would normally be used while for larger measurement ranges of three metres or more twelve detectors would be supplied.

Jan 1, 1993

By John Neale, Robert Huberts, Tony Pinches

A major R&D programme for the application of bacterial oxidation to the pretreatment of refractory sulphide gold ores was started at Mintek in the early 1980s. This arose from an established expertise base in the bacterial leaching of base-metal sulphide ores. The refractory gold programme has been supported by a number of South African gold-mining companies, but major support has been provided by the Anglo American Corporation of South Africa (AAC) and the AAC Vaal Reefs Exploration and Mining Company Limited · (Vaal Reefs). The Mintek-AAC collaboration has been formalized as a joint-venture technology agreement for the comme;cialization, as well as continued development and improvement, of the bacterial oxidation process (MINBAC). From a process standpoint, bacterial oxidation involves the contacting of slurries of finely ground sulphide concentrate with suitable strains of iron-sulphur oxidizing bacteria, which act as the catalyst to promote sulphide·· oxidation by oxygen from air. Process engineering is simplified in that this reaction is carried out at low temperatures and ambient pressures. The view was taken that the successful development and implementation of the MINBAC technology should be based on parallel R&D aimed at an understanding of the process fundamentals, the process engineering and scale-up requirements, as well as the ancillary requirements for the gold recovery-processes and environmental management. This has represented a major R&D effort at a total cost to date of around US $10 million.

Jan 1, 1993

By Rob Henson, Te-Lin Yau, Darryl Amick

The process industry faces tightening environmental regulations. In order to comply with these mandates, environmentally safe chemicals, such as oxygen and hydrogen perox­ide are becoming attractive oxidants. These oxidants appear benign but must be respected when involved in harsh environments. It is therefore important to address both the safety and suitability of materials selected for these environments. Otherwise, severe prob­lems, such as equipment failure or fire and explosion can occur. Laboratory and field experience will be used to discuss the perfor­mance of titanium, zirconium and Ti-45Nb alloy in piping systems for handling these environ­ments. Sealing methods for piping, pumps and valves of these metals will also be reviewed. For comparison, information on the performance of stainless alloys will be given.

Jan 1, 1993

By Jack Barrett

The oxidants which participate in the bacterially catalyzed oxidation of minerals are dissolved oxygen and some aqueous iron(III) complexes. Speciation studies indicate that these complexes consist of iron (III) -sulfate and iron (III) -arsenate ions. The complexes have different oxidizing powers as indicated by their calculated standard reduction potentials. The thermodynamics of the oxidations of pyrite and arsenopyrite are related to the mechanisms of the reactions. The mechanisms are discussed in terms of primary processes occurring on the mineral surfaces and the secondary reactions of the primary products. The importance of the conclusions to plant operation is discussed.

Jan 1, 1993