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By D. A. Baker, W. J. Mullin, T. P. Philip, P. A. Korpi

Some of you will recall from the last Randol conference held in Cairns, Australia in April 1991 that I shot my mouth off when I declared that I believe that these conferences are covering only a small slice of the overall mining industry pie because the major emphasis is on ore processing. The attendees at these conferences to date have been composed principally of metallurgists, which naturally leads to a preponderance of papers on this important feature, but it is only one of the areas of the mining business.

Jan 1, 1992

By Walter Hoecker

The dissolution of gold in cyanide_ leaching has been we11 published with the genera1 acceptance that gold is oxidised by oxygen and stabilized by complexation with cyanide [1]. The dissolution of gold is essentially an electrochemical process. The rate of the anodic gold dissolution is controlled by the cyanide concentration. - (2) While the cathode reduction of oxygen is controlled by dissolved oxygen concentration - (3) There are a number of factors influencing the concentration of oxygen, and if 1owered substanth.lly will effect the efficiency of the leaching plant. These include: "' salinity "' temperature "'partial pressure "'oxygen consumption rate The use of pure oxygen for· cyanidation is only beneficial if oxygen is rate limiting, Conversely a slurry saturated with air (typically 5 - 8 ppm) may not be enough for maximum leach rate. The diagram below shows the maximum dissolved oxygen levels obtainable with pure oxygen and air. DISSOLVED OXYGEN (MAXIMUM) IN WATER At steady state, the rate of the cathodic reaction must equal the rate of the anodic reaction. Thus the rate of gold dissolution is dependent on both the· cyanide and oxygen concentrations. - (4) Using an average of Do/Den =· 1.5 [2] (where Do and Den are the oxygen and cyanide diffusion coefficients) the table below illustrates the maximum effective oxygen concentrations for given cyanide levels in clean water [3].

Jan 1, 1992

By Cao Changlin, Gong Qian, Hu Jiexue

The thiosulfate, effects copper of concentrations of and ammonia ou the extractlon of gold from sulfide gold concentrate have been studied. The experimental results showed that it is possible to reduce thiosulfate concentration. Above 95% of gold extraction was obtained in O. 2M thiosulfate leaching solution in two hours under the suitable conditions. Therefore, the process of washing residue was simplified, the consumption of thiosulfate and the loss of thiosulfate carried were reduced. by washing residued.

Jan 1, 1992

By H. D. R. Browner, D. A. Marsh

The need for a product dewatering step between the milling/classification and leach/carbon stages of gold plants has traditionally been performed by thickeners. Whether these be the 'conventional' or 'high-rate' types both require considerable initial capital outlay even without provision for standby facilities. In addition, their sensitivity (both mechanically and metallurgically) to changing feed conditions often results in these being considered 'high-risk' items of equipment, requiring a high degree of attention from operating personnel.

Jan 1, 1992

By William R. Bond, Jim V. Rouse, Laura L. Damon

As noted by Damon (1990), "The time that a heap (of gold ore) is on the reusable leach pad is of critical economic importance." The Interim Neutralization Study, conducted by Brohm Mining Corporation (Brohm), at the request of the South Dakota Department of Water and Natural Resources and reported by Damon indicated that improvements could be made in leaching and pointed out the need for a better understanding of the gold ore leach procedures. To provide data on an actual heap, personnel from Brohm and GEOCHEM installed a series of pressure/vacuum lysimeters in an active Brohm heap, and conducted subsequent testwork to evaluate the efficiency of leaching. The objectives of the testwork included efforts to:

Jan 1, 1992

By Abbas Zaidi, Betty L. W. Ou

Wastewaters generated during the extraction of gold from the ore can contain a variety of contaminants such as cyanide, heavy metals and arsenic. Proper management of these wastewaters is therefore necessary to minimize the negative impact of gold mining and milling operations on the environment. The Wastewater Technology Centre (WTC),located in Burlington, Ontario, Canada, has been involved in several studies related to the evaluation of various effluent treatment technologies which are relevant to the treatment and proper management of gold mill effluents. These studies have included bench and pilot scale tests, and the evaluation offull-scale systems. Furthermore, the WTC staff developed protocols for cyanide analysis in gold mill effluents, and a mathematical model for predicting the degradation of cyanide in tailings ponds. The information generated by the WTC staff has been referenced in several reports and papers published over the last ten years (Schmidt et.al. 1982, Simovic & Snodgrass 1989, Whittle et.al. 1989, Zaidi et.al. 1989, Zaidi et.al. 1991). Recently, the WTC has started to develop a micro­computer based expert system for use by decision makers in the gold mining industry and relevant government agencies who are involved in process design, process evaluation, costing, evaluation of the best practicable technology, approval of suggested effluent management systems, and so on. This paper presents some relevant background information and a discussion of the latest version of the expert system being developed by the WTC.

Jan 1, 1992

By Frank Ladwig, Stephen Gos

Tailings and/or wastewater generated from gold extraction plants employing cyanida­ tion must often be treated to remove the cyanides and heavy metals for environmental reasons and/or gold extraction inhibition reasons, due to the presence of heavy metals like copper, which have a detrimen­ tal effect during cyanidation. In recent years, the treatment of effluents contain­ ing cyanides and heavy metals has been widely studied, Among chemical treatment methods, the use of hydrogen peroxide has been universally employed as a viable option. However, in some cases, effluents containing high concentrations of heavy metals and/or solids decompose the hydrogen peroxide, an undesirable side reaction. The addition of stabilizers or other peroxygen compounds together with hydrogen peroxide can, however, considerably reduce the rate of decomposition and thus result in detoxi­ fication costs, which are considerably less than the standard detoxification process using hydrogen peroxide. In some cases, the reaction rate can also be increased, resul­ ting in lower investment costs for new detoxification plants. This paper deals with the results of developmental work performed in the recent past and introduces some new processes with the aim of optimizing reagent consumption and costs.

Jan 1, 1992

By W. Hoecker, S. Watson

The use of oxygen (Goldox™) in gold leaching has emerged as a significant modification in the past nine years. The Goldox™ process was ori gi na 11 y developed by Afrox Ltd ( part of the BOC Group) and is currently used in South Africa, Australia, Canada and the United States. Although a variety of benefits have been observed with oxygen, this paper out 1 i nes the main ones with reference to Australian plant data. The case studies were categorised into the ore type: Oxide, blends and primary ore.

Jan 1, 1992

By Hans von Michaelis

Metallurgists are trained to seek synergisms and to optimize trade-offs in the selection of processes and flowsheets. The subject of my paper and the focus of this entire conference is on synergisms involving more than just metallurgical recovery, but encompassing mining and environmental management too. Operators have always known that by recycling tailings water they could recover some cyanide and lime values or reduce the amount of new flotation reagent additions. The trade-offs have changed at many US mines today where concern about avian mortality necessitates that water in the tailings pond be detoxified. This is just one example of how selection of processes and technology today requires integration of environmental management. MUDDER & GOLDSTONE (1989) showed how cyanide can be recovered from tailings slurries by an acidification­volatilization-reabsorption (A VR) process which was installed in New Zealand, and which in 1992 is being commissioned also at Nerco DeLamar Silver Mine as described by OMOFOMA & HAMPDEN (1992). FRICKER (1990) and FRICKER & OWERS (1992) show how using A VR to recover cyanide from pregnant pulps ahead of gold recovery improves the yield of recoverable cyanide while improving the performance of the gold recovery step and detoxifying the tailings. This is an excellent example of the synergisms that can be achieved ,y applying a "systems approach."

Jan 1, 1992

By Ulf Marklund, Manfred Lindvall

Fighting the challenge of diminishing ore grades, low base metal prices and a changing pattern of ore supply, Boliden has now taken the second generation of the fully­autogenous grinding concept on stream, Using new design and a highly-developed process control system the benefits of conventional two stage autogenous grinding technology are obtained with a wide range of ore types. The APC grinding system has been developed further. A new design of the Boliden Pebble Extractor together with an advanced control strategy make the performance of the APC concept superior to all other grinding systems with any ore quality. The capacity and simplicity of the autogenous grinding concept is equivalent to the best SAG installations but the operational costs are up to 25 % lower than for SAG or other primary ball or rod mill systems. The concept is as flexible as conventional crushing and rod mill installations but investment and operating costs are of the order of 25 % lower. Also, from the metallurgical point of view, the different types of autogenous grinding system outperform all other comminution systems including SAG. From 1989 to 1991 four fully autogenous grinding sections have been installed at various concentrators at the Boliden company. Old crushing plants and rod and pebble grinding circuits have finally been replaced by highly productive and cost-efficient autogenous grinding equipment. Significant savings in operational costs have already been reported. Power consumption and maintenance costs have been reduced significantly. Productivity expressed as milled tonnes per operator has been improved. Metallurgical results have developed favourably.

Jan 1, 1992

By Dennis R. Rice

The Kettle River Joint Venture is 70 percent owned by Echo Bay Minerals Company, a wholly-owned subsidiary of Echo Bay Mines Limited, and 30 percent owned by Crown Resources. Initial announced ore reserves were 700,000 troy ounces of gold contained in three deposits located east and north of Republic, WA., U.S.A. Additional reserves are being proven. Processing of finely ground ore by preaeration-carbon in leach (CIL) circuit was selected followed by cyanide destruction by the INCO Air/SO2 process.

Jan 1, 1992

By James Y. Oldshue, Paul M. Kubera

Ore processing requirements in the gold industry are similar to those in other sectors of the minerals industry. In all cases, the processes revolve around the handling of large volumes of ore slurry, incorporating either physical processing or chemical processing steps which are related to distinct mixing application classes as defined in Table 1. From this standpoint, the complexity of the applications range from the simple (blending, solid suspension, etc.) to the complex (e.g., multi-phase reactor systems). The large volume of material to be processed dictates the large equipment size which is characteristic of this industry, and the often remote locations place a premium on both mechanical and process reliability.

Jan 1, 1992

By G. Henry, S. J. Domvile

Arsenic management practices at the Con Mine in Yellowknife, Northwest Territories have evolved over the last fifty years of operations under changing regulatory, economic and technological conditions and incentives. As a result of a processing upset in the mine' s arsenic trioxide reclamation plant circuit in August 1988, arsenic levels in the mine' s tailings pond rose from 30 to over 100 mg V. At these arsenic levels, water treatment operations were unable to meet water licence discharge criteria and the mine itself was under risk of closure due to limited water storage capacity. Under these internal pressures, the mine initiated its own research initiatives designed to restore water treatment operations. The new process developed from the mine's research, utilized the mine's existing water treatment plant hardware but introduced a pretreatment step involving a discrete sludge recycle and removal system. In February 1989, water treatment operations resumed under the new process.

Jan 1, 1992

By Wolfgang Baum

The selection of roasting technology is a complex task which is primarily dependent on the ore mineralogy. Key roasting parameters are directly linked to mineralogical characteristics of the feed and vary considerably between different ore types even in the same deposit. In addition to sulfide refractoriness, other refractory conditions frequently exist. Together with various mineralogical features of the feed, they may complicate roasting testwork and process design. For most roasting scenarios, the critical economic factors are gold recovery, capital cost and environmental performance. This paper will show how these economic factors are influenced by the mineralogical ore characteristics.

Jan 1, 1992

By Larry Whittle

Gold milling activities generate waste streams containing dissolved metals and cyanide, among other contaminants, that require some form of treatment prior to discharging to the environment. To date, this treatment has involved the destruction of cyanide through natural degradation, chemical oxidation, or a combination of both followed by the precipitation of metal hydroxides. Although these processes have been proven to be capable of achieving. regulatory levels for metals and cyanide, they often generate significant levels of cyanate and, at times, ammonia, that may be toxic to rainbow trout and thus undesirable for regulatory compliance. Tallon Metal Technologies Inc. (Tallon) has developed Vitrokele™, a chelating resin that has the ability to capture metals (including gold), both total and weak acid dissociable cyanide, as well as thiocyanate from both slurries and solutions. The loaded resin is eluted and returned to the recovery circuit while metals and cyanide are recovered from the eluent stream. This process was demonstrated at pilot scale at B.P. Resources' Hope Brook Gold Mine in Newfoundland, and more recently at Canamax's Bell Creek Mine near Timmins, Ontario. The results from these pilot programs showed metal and cyanide recoveries of 99% or more with the concentration of cyanide and metals in the effluent reduced to levels with minimal or no toxicity to rainbow trout. Furthermore, neither cyanate nor ammonia were generated from the process. The loaded resin was effectively stripped and re-introduced to the recovery circuit; cyanide was captured in the eluent stream and made available for recycling to the mill leaching circuit; and metals were captured for re-use, sale or disposal. This paper summarizes the results obtained from the pilot tests at the Bell Creek and Hope Brook Gold mine sites.

Jan 1, 1992

By Thomas M. Goodell, Timothy D. Arnold

Dilute-phase pneumatic conveying has been used in the mining industry since the 1920s. It has primarily been used for the hoisting of coal and salt ores, and as a transportation medium for backfill material. More recently there have been investigations into a wider variety of applications, which this paper addreses. The paper will point out some deficiencies in the system. It 1s not the "champion" of the mining industry, but rather an excellent srste?1 with a variety of applications that may not have been studied m enough detail. The most imaginative applications to the Redpath Pneumatic Conveying System have been initiated by persons needing an innovative application to a specific predicament.

Jan 1, 1992

By C. A. Fleming, C. J. Ferron, E. S. Makande, P. Mason

Several small mines are producing refractory gold concentrates in Zimbabwe and, owing to the small scale of most of these operations, their output is processed in a central custom roaster in Kwekwe. Owing to the wide variations in the feed to the roaster, the efficiency of the old Edwards roaster is deemed unsatisfactory with gold recovery from concentrate as low as 70%, and alternative processes were evaluated to improve this situation. Various processes for oxidizing refractory arsenopyrite/pyrite concentrates to liberate gold prior to cyanidation are known. In practice, only two have to date met with wide industrial acceptance, pressure oxidation and roasting. Owing to the ·high arsenic and antimony levels of some concentrates in Zimbabwe, the only viable roasting alternative would be two-stage air-roasting of concentrates in two reactors, as practiced at Giant Yellowknife, Campbell Red Lake and New Consort. This process, however, creates an arsenic disposal problem, and produces gas of fairly low SO2 content, requiring a large gas handling system for acid production. On the other hand, there are currently four commercial pressure oxidation plants treating refractory gold ores (McLaughlin, Mercur, Getchell and Goldstrike) and three treating concentrates (Sao Bento, Porgera, Campbell). One other concentrate oxidation plant is being constructed (Con), and several more are being considered.

Jan 1, 1992

By David Seymour

Precious metal producing mining companies in the United States, Canada, and South Africa were surveyed on carbon usage practices in the recovery of silver and gold. Responding companies represented CIP/CIL dperations, heap leach operations and combined mill/leach operations. Operational practices and carbon consumption rate measurements are presented, correlating consumption rates with process attributes. Precious metal producing mining companies in the United States, Canada, and South Africa were surveyed on carbon usage practices in the recovery of silver and gold. Responding companies represented CIP/CIL dperations, heap leach operations and combined mill/leach operations. Operational practices and carbon consumption rate measurements are presented, correlating consumption rates with process attributes.

Jan 1, 1992

By J. Jeremy Burden, Bruce S. Brown

A major question in the design and permitting of a tailings storage facility is the quality and quantity of seepage which will occur from the base of the tailings facility into the underlying foundation and groundwater regime. A corollary to this is what liner system, if any, is necessary to protect the groundwater regime from unacceptable contamination. Modern tailings storage facilities are generally designed as drained tailings deposits whereby all free water is removed from the facility by decant, drainage and evaporation. This removes the source of on­going seepage and allows for efficient and timely reclamation of the facilities. Quantifying the residual seepage from the base of the tailings deposit is complicated due to the following factors:

Jan 1, 1992

By Kenneth L. Myers

The net balance of the inflow and outflow of water in a tailings storage facility has major economic implications in any large mining and milling operation. In a net precipitation environment it can control the ultimate size and storage capacity of a facility or dictate the need for an expensive treatment and discharge program. In a net evaporation environment it can control the extent of the water rights acquisitions required for makeup water and dictate the number and size of expensive wells and pumping and delivery systems. The elements considered in a water balance analysis include the anticipated production rate, the water content of the slurry used to deliver the tailings, inflow from precipitation and snowmelt, and losses from evaporation and seepage. The mine can exert significant control over only one of these elements: the production rate. All others are subject to considerable uncertainty from month to month and year to year. The traditional approach is to analyze in a spreadsheet environment by making simplifying assumptions and using monthly mean or "average" values for precipitation inflows and evaporation losses. Often the analysis will be repeated with values subjectively assigned to represent a "wet" year or "dry'' year. The probabilistic approach uses the same basic spreadsheet model in conjunction with a probabilistic simulation add-in program allowing probability distributions to be substituted for any of the deterministic variables. The resulting analysis shows the full range of variation possible for each parameter of interest (i.e., available return water, makeup water required, storage, seepage losses) and estimates the exceedance probabilities for each. The potential uses and advantages of the probabilistic approach are discussed.

Jan 1, 1992