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By E. H. Baker

Vapour pressures of sulphur have been measured over the temperature range 340-1039°C by means of boiling-point measurements, an internally heated pressure vessel being employed with argon as the pressure medium. The results are expressed satisfactorily by a four-term pressure-temperature relation. At the cited critical temperature of 1040°C the calculated critical pressure is 204 atm. From the pressure-temperature relation and available thermal data for the vapour, the approximate composition of the saturated vapour in terms of the various molecular species has been derived for the critical point

Dec 1, 1971

By C. C. Harris

The use of Alyavdin's equation Y(x,t) = 1-e(-bt) for describing the effect of grinding time on size distribution is discussed. The equation transforms into linear form by expressing it as log-log reciprocal (1 - Y) versus log t. For plotting, specially divided grids are available; Rosin-Rammler or Weibull charts may be used. The data of Herbst and Fuerstenau are especially useful for illustrating the Alyavdin-Weibull chart in two applications: (1) presenting data (which are relatively unaffected by experimental scatter) and comparing them with theoretical predictions, and (2) as a test for the zero-order kinetics production hypothesis. The chart based on the Alyavdin-Weibull equation is suggested as a useful aid in the analysis of kinetic data (/ versus f), though not as a procedure in its own right. Proposed applications are (1) displaying data with excellent clarity, since it avoids the kind of congestion inherent in some other plotting methods, and (2) as a test for assumed kinetic relationships. Sometimes, equation 1 describes the data quite closely, and in these cases the parameter values appear to be related to certain operating conditions.

Dec 1, 1971

By J. H. Chesters

The main, though rarely mentioned advantage, is likely to be the standardisation of best practice and product. In a batch process conditions vary cyclically, but with a continuous process they would, at least ideally, remain the same for long periods of time. The other main advantages of continuous over batch processes are likely to be reduced operating and capital costs, the improved possibilities for automatic control, and more consistent product quality. Recent developments are surveyed for ironmaking and steelmaking with reference to blast furnaces; solid-product and molten-product direct reduction; the trough-type processes of Thring, Worner, the Japanese National Research Institute for Metals and Glinkov; basic-oxygen furnace (LD) variants; spray steelmaking; continuous casting and vacuum degassing; rolling; and coating. Encouragement in the devleopment of continuous processes may be drawn from the way unexpected difficulties, such as trouble with sulphur and refractories, were tackled and overcome to achieve the float glass process

Dec 1, 1971

By S. Y. Ezz

Report of discussion at February, 1971, IMM general meeting (Chairman : M. J. Cahalan, President) of a paper published in Transactions/ Section C (Mineral Processing & Extractive Metallurgy), vol. 79, September, 1970, pp. C226-C233 with contributions by Wild R. and Astier J. on fluidised bed reduction of iron ore fines

Dec 1, 1971

The report of the Annual General Meeting of the Institution of Mining and Metallurgy held on Thursday, 20 May, 1971, in the rooms of the Geological Society of London, Burlington House, Piccadilly, London, W.1, at 4 p.m. (Chairman : M. J. Cahalan, President) includes details of awards and prizes presented to William Justin Kroll, Sir Gordon Colvin Lindesay Clark, John Convey, Evert Hoek, Peter Reginald Dawson and Christopher Michael St. John

Dec 1, 1971

By M. G. Fleming, F. Warner, R. W. Boswell, M. J. Cahalan

The annual dinner of the Institution was held at the Savoy Hotel, London W.C.2, on 22 April, 1971. The President, Mr. M. J. Cahalan, was in the Chair; members and guests numbered 320. The toasts of The Queen and Queen Elizabeth The Queen Mother, Prince Philip The Duke of Edinburgh, The Prince of Wales, and the other Members of the Royal Family were proposed and loyally honoured. R.W. Boswell proposed the toast of the Institution of Mining and Metallurgy, the president responded, Professor M.G. Fleming proposed the toast of the guests and Sir Frederick Warner replied

Dec 1, 1971

By H. L. Shergold, O. Mellgren

The conditions of amine concentration and pH necessary for the concentration of fine haematite particles at the iso-octane-water interface have been determined. Results obtained from the related studies on the effect of pH and dodecylamine concentration on the adsorption density, electrokinetic potential, contact angle and concentration of various amine species in the system are included. A good correlation was obtained between these different variables. Maximum concentration of haematite at the oil-water interface was obtained when the haematite zeta-potential was small or equal to zero

Dec 1, 1971

By D. Newman

Mineral production in the Highlands and Islands of Scotland during the last ten years has been confined to the sporadic production of industrial minerals—for example marble, anorthosite, limestone, talc and silica. From 1962 onwards there has been an upsurge in mineral exploration in the Highlands, increasing in tempo from 1966 onwards due to the efforts of the Institute of Geological Sciences, the Highlands and Islands Development Board, and private and public companies. Geological, chemical and economic aspects of some of the more interesting mineral prospects are discussed: these include anorthosite, feldspar, magnetite, quartzite and brucite marble. Reference is made to a geochemical survey undertaken in the Rosehall district of Sutherland, the results obtained being summarised. Problems that affect the future of mineral exploration in the Highlands are stated.

Dec 1, 1971

By A. Paulin, A. W. D. Hills

The work has shown that packed-bed behaviour can be predicted from the results of single-particle experiments, total reaction times being predicted somewhat more accurately than gas and solid temperatures and gas compositions. A small laboratory packed-bed reactor was built and used to study the decomposition of beds of specially prepared CaCO3 spheres, steps being taken to minimise the effects exerted by the walls of the bed on processes occurring within the bed. Gas and solid temperatures and gas compositions were measured at various points in the bed and compared with theoretical predictions based on kinetic data determined in previous single-particle experiments. The measured solid temperatures and total reaction times agreed remarkably well with the values predicted theoretically. Gas and solid temperatures measured after the reaction had finished at any point in the bed did not agree with the theory. This was because solid temperatures in the bed rose very rapidly once the reaction was completed and the walls of the bed could not be heated at a sufficient rate for their temperatures to rise as rapidly; thus some loss of heat from the bed to the walls was inevitable, and this could not be accounted for in the theory. In addition, the theory did not allow for the conduction of heat within the bed, and this resulted in some further slight discrepancy between the measured and predicted values, particularly after the reaction was completed. Gas compositions measured in the bed were rather scattered, but, even so, they agreed moderately well with the predictions of the theory.

Dec 1, 1971

By B. W. Hester

Report of discussion at January, 1971, general meeting (Chairman: M. J. Cahalan, President) of the paper published in Transactions/Section B (Applied Earth Science), vol. 79, May, 1970, pp. B60-B67, and contributed remarks. Comments were made by Taylor J.T.M., James C.H., Lethbridge R.F. and Heath K.C.G.

Dec 1, 1971

By A. B. Holland-Batt

Two graphical techniques which are commonly used to assess batch separations are analysed in terms of reaction kinetics to provide a more powerful method of evaluation. An alternative and more general approach, based on the selection and application of suitable efficiency criteria, is also presented. The method proposed distinguishes between selection and collection efficiency in flotation and can be used to estimate the degree of liberation in the feed. Two examples are given: table concentration of monazite and ilmenite from a beach sand, and flotation of a pyrite-haematite ore

Dec 1, 1971

By J. A. Franklin, E. Broch, G. Walton

To make the best use of rock core, the mechanical character of the rock should be evaluated concurrently with conventional geological observations. The advent of simple techniques, such as the point load 'nutcracker' test, makes field logging of mechanical properties competitive with sampling and testing in the laboratory

Dec 1, 1971

By M. Rahman, P. C. Kapur

The fixed-time locked-cycle grinding test is employed to simulate the industrial closed grinding circuit on the laboratory scale. A mathematical algorithm for 'cyclewise' computer simulation of the locked-cycle test has been derived and used to study an idealised laboratory-scale model of a closed ball-mill circuit. The agreement between simulated and experimental results is reasonably good, except when the grinding times are relatively long

Dec 1, 1971

By A. D. Read

Selective flocculation was investigated as a possible method of recovering values from mineral slimes which are too finely divided to be treated by conventional mineral processing methods. It has proved possible to flocculate selectively either haematite or a silicate from a stably dispersed mixture by varying the anionic character of the high-molecular-weight, partially hydrolysed polyacrylamide employed. Different separation methods have been developed for hard and soft water media. Electrokinetic and infrared techniques have been employed to elucidate the mechanism whereby selectivity has been attained in the different cases. The following influences on the various selective flocculation parameters have been investigated: (a) the level of the different reagent additions and (b) the shear conditions during and after flocculant addition. A feature of the particular system studied was the high solids content at which it was possible to achieve good selectivity. Probable reasons for this are advanced, and the possibilities and potentialities of the process are discussed.

Dec 1, 1971

By R. R. Liebenberg, M. I. Brittan

The kinetics of the copper segregation process has been investigated. The experimental strategy used to isolate the rate-controlling reaction step is described. This step was found to be the chloridisation of the oxide copper minerals in the ore. The link between the rate of chloridisation and the overall rate of segregation is demonstrated experimentally. The influence on the kinetics of the various parameters in a TORCO system is examined and the implications are discussed

Dec 1, 1971

By H. B. Bell, L. C. Smith

Measurements have been made of the activity of 'FeO' in 'Fe0'-Mn0-Ti02 melts at 1475 degrees C. The results obtained are discussed in terms of ideal mixing of titanates and in terms of a regular solution model. On the basis of the regular solution model activities of Ti02 and MnO in the Fe0-Mn0-Ti02 and Mn0-Ti02 systems have been derived. The data have been shown to be consistent with the liquidus lines in the phase systems. Examples are given of the application of the data to slag-metal equilibria, being used to derive slag-metal data between liquid iron and Fe0-Mn0-Ti02 slags

Dec 1, 1971

By R. Phillips

The low concentration of diamond in workable deposits requires very large samples for grade estimation, and results, even then, may be erratic and difficult to interpret. Although the Poisson probability distribution cannot accurately describe the occurrence of diamond, it is suggested that it gives a better estimate of grade than conventional methods, even from single samples. Examples illustrate the simple calculation required.

Dec 1, 1971

By J. R. Hammond, I. C. Herbert

Report of discussion at October, 1970, IMM general meeting (Chairman: M. J. Cahalan, President) and contributed remarks on the paper published in Transactions/Section C (Mineral Processing & Extractive Metallurgy), vol. 79, June, 1970, pp. C128-36 and introduced by I.C. Herbert. Contributors were von Struve G., on the application of balling discs and the use of basic additives; Young P.A., asking for details of the drying, grinding, balling, induration and specification testing equipment and processes; Davison J. on pellet swelling properties and Carter G.C. on disc operation, refractories and green ball properties.

Dec 1, 1971

By P. C. Kapur

Several empirical and semi-empirical laws of comminution, which describe the relationships between the cumulative grinding energy input and the degree of size reduction of brittle solids, have been rationally derived in the time-domain in a unified manner, starting with an integro-differential equation of grinding kinetics. The analysis leads to and provides explicit interrelationships between the energy-size reduction laws associated with Kick, Rittinger, Holmes, Bond, Charles and others, and gives useful estimates of their relative merits and validity. It is shown that Holmes' expression is, in fact, a solution to the grinding equation; consequently, this classical law is compatible with the modern theory of comminution based on population balance on particulate species

Dec 1, 1971

By C. H. J. Beaven, M. P. Jones

Since the various new techniques of automation and computing have enabled vast numbers of mineralogical observations of relatively small samples to be made cheaply and rapidly, the statistical assessment of these measurements has become of vital importance. Much of the theory and most of the procedures of sampling that are used in the mineral industry are based on Gaussian statistics, but modern measuring techniques show that many mineralogical parameters do not necessarily follow the Gaussian distribution function. Consequently, it has become necessary to examine the application of other, more suitable statistical methods in order to derive the maximum amount of useful information from the examination of mineralogical samples. Some of the errors that can be introduced by the use of incorrect distribution functions are discussed and the value of determining the function that is appropriate to the particular parameter that is being measured is shown. Examples are provided of non-Gaussian distribution functions in mineralogical materials that were encountered during prospecting and during mineral treatment operations: a Canadian uranium ore, a Thai tin ore, and gold ore tailings.

Dec 1, 1971