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By M. G. Zabetakis, T. D. Moore

The use of a partially slotted 6.5-inch-inside-diameter vertical pipe to remove methane from a longwall gob area at a depth of 2,260 feet in the Pocahontas No. 3 coalbed ms investigated. The value of gas removed by such a pipe under free-flow conditions was found to equal the cost of the installation in this case. Approximately 25 percent of the available methane passed through the pipe without the use of an exhauster; an additional 10 percent was removed when an exhauster was employed. The diversion of methane through a vertical slotted pipe to the surface permitted the use of increased mining rates and decreased the ventilation air requirements.

Jan 1, 1972

By J. W. Onuscheck

The oxygen-fuel oil burner lance is a very useful tool at the Monessen B.O.F. It increases the overall flexibility of the operation. An additional 15,000 to 20,000 ingot tons can be produced at a given hot metal supply. It helps overcome sporadic drops in hot metal thermal values and/or supply. It results in increased yield, in particular, on high carbon heats where much yield was lost on reblow triggered slag reactions. The burner has also been adopted as a standard tool to aid burning in new vessel linings. Overall, steelmaking performance has improved with the use of standard preheat practice. Scrap charges up to 50 percent have been used routinely in times of extreme hot metal shortages, but the performance is weak in some categories. Development of a single step oxy-oil process is in progress. In this process, scrap and hot metal are charged as in the normal B.O.F. practice, but fuel oil is fired with the refining oxygen.

Jan 1, 1972

By Martin H. Stanczyk

Ultrafine grinding of the industrial minerals mica, pyrophyllite, talc, marble, barite, and fluorite was accomplished using the Bureau-developed and patented attrition-grinding process. The materials, representing minerals of diverse physical characteristics, were batch ground in a 10-inch-diameter machine using statistically designed experimental test programs. The tests were made to determine large effects of variables such as feed pulp density, grinding medium size, and quantity of the electrical energy consumed during grinding on product particle size and bulk density. In designing the test programs, it was assumed that there was no interaction between the variables. Relatively coarse commercial flotation concentrates of mica, barite, and fluorspar and mine-run products of pyrophyllite, talc, and marble were readily ground into subsieve size ranges. Considering the great amount of particle size reduction obtained, the electrical energy requirements for grinding were very low. In general, the test results indicated that the best conditions for particle size reduction were approached when grinding with the coarser fraction of sand grinding media, the higher-sand-to-mineral weight ratio, and the higher feed pulp density.

Jan 1, 1972

By Keros Cartwright

Distribution of temperature within the lithosphere can be significantly affected by the movement of ground water. Stallman (1960) presented the basic equation for the simultaneous transfer of heat and fluid in a porous medium and first used earth temperatures to determine aquifer permeability. Subsequently, studies of rock and soil temperatures were used to determine the flow of water through clay layers separating aquifers (Bredehoeft and Papadopulos, 1965; and Sorey, 1971), and to locate shallow aquifers (Cartwright, 1968; Birman, 1969). Cartwright (1968) showed that shallow aquifers maintain a nearly constant temperature throughout the year and that heat is exchanged between the aquifer and land surface. These temperature data also suggest that shallow aquifers hydrologically connected to surface-water systems have significantly greater effect on temperature distribution than aquifers in the deep artesian basins. Water wells developed in the shallow glacial and dolomite aquifers to depths of over 122 meters (400 feet) in northern and central Illinois produce water at temperatures very close to the mean annual air temperature. An analysis of the character of the rocks and soils suggests that the tem¬perature gradient should, and does, vary according to changes in thermal conductivity due to changes in lithology. This is because, under conditions of steady and uniform flow of heat from the earth's interior to the surface, a greater temperature gradient is required in poorly conductive rocks than in highly conductive rocks to transmit the same quantity of heat. Based on estimated values of thermal conduc-

Jan 1, 1972

By M. E. Volin, F. H. Erbisch, G. M. Wenberg

Bacterial leaching of copper and uranium is practiced under acidic conditions in environments furnishing sulfur and iron. However, many mineral deposits do not have these conditions; the chalcocite and native copper deposits in Michigan's Upper Peninsula are examples. Species of bacteria and fungi isolated previously from samples taken at the White Pine Copper Co. tailings pond and mine, were screened for solubilization of copper from chalcocite ore and flotation concentrate and from native copper jig concentrate. Certain Penicillium species solubilized significant amounts of copper under neutral to slightly acidic conditions in a carbon and nitrogen-enriched medium. Leaching apparently was accomplished by release of metabolites which chelated with the copper. The copper yield was highly dependent upon the medium composition and the concentration of copper in the source material. The standardized procedures which were developed in an attempt to maximize copper yield in leaching times of three to five days are described. This preliminary research indicates a biological leaching process for copper which is different from those in use, but whether it can be applied economically remains to be determined.

Jan 1, 1972

By Victor F. Hollister, Robert W. Hodder

"The petrology and mineralogy of porphyry copper deposits are thoroughly described in recent literature and cited as the definitive characteristics for this type of deposit. The magmatic-hydrothermal aspect of genesis is also dealt with in detail. However, descriptions of their internal structure and regional setting are not as rigorous, and the genesis of this structure is simply stated as the release of high fluid pressures in a cooling magma emplaced along large fault zones. Genetic relationships between internal structure, regional setting and the tectonic evolution of continents has been alluded to infrequently in the past, but can now be considered together within the developing concept of orogeny at the margins of drifting crustal plates.Tensional structures, on both local and regional scale, and a Triassic to Tertiary age are described for porphyry copper deposits. We contend that such structure and age are distinct and unifying characteristics for this type of deposit and are genetically related to major crustal movements. British Columbia has porphyry copper deposits contemporaneous with plutons 180 to 200 million years old and 40 to 60 million years old. The former age group correlates with early stages of the continent's westward drift, and the latter group with a change in tectonic style during late development of the Canadian Cordillera. Hence, one can in British Columbia reflect on the genesis of a deposit's structure in the broader context of tectonic evolution. Such consideration should lead to more definitive criteria for area selection in exploration."

Jan 1, 1972

By V. F. Swanson

A petrographic study was made of the type and sources of mineral contamination occurring in Florida phosphate rock products. Emphasis was placed on contaminants in the screened rock (+1 mm), since this portion of the product undergoes no physical beneficiation except for scrubbing to remove slimes. Since iron and aluminum contents of the finished product affect the salability, special emphasis was placed on identifying types and sources of these contaminants and relating chemical composition to visual characteristics. Wavellite derived from the overburden was the major aluminum contaminant with some aluminum being included as secondary clay balls. Iron occurred as phosphates in the overburden and as colloidal oxides included in the phosphate pebbles. Chert and limestone contamination derived from the Hawthorne formation underlying the phosphate matrix.

Jan 1, 1972

By José Arce

El presente texto señala la importancia de los métodos geofísicos en la exploración de yacimientos minerales del Perú. De acuerdo a las diferentes situaciones geológicas se elige el método más adecuado. Para el caso de vetas de gran buzamiento con sulfuros metálicos se utiliza el método electromagnético autopotencial, cuyo accesorio es la resistividad; para el caso de Mantos de bajo ángulo o bolsonadas con sulfuros metálicos, se cuenta con el método electromagnético y para la estructura de sulfuros diseminados Placeres Hierro, pirrotita, cobalto, níquel, se emplea la polarización inducida y el electromagnético, cuyo accesorio es la resistividad y gravimétrica.

Jan 1, 1972

By D. B. Eccleston

Natural gas and mixtures of natural gas and hydrogen were used as fuels in a laboratory engine to determine the relationship of emissions to air-fuel ratio and to establish practical lean limits for air-fuel ratio. Synthetic gas manufactured from coal (Synthane) and natural gas were used as fuels in a vehicle to obtain comparative data on emissions and performance. Results showed that lean limits for air-fuel ratio when using hydrogen-enriched natural gas were extended significantly beyond Chat of natural gas. Synthane pro¬duced exhaust that was significantly less reactive than exhaust from natural gas. With lean air-fuel ratios, the acceleration performance of a vehicle fueled with Synthane was improved over its performance when fueled with natural gas.

Jan 1, 1972

By Robert M. Lewis

Can wet-ground mica be produced from mica schist ores, and if so, would its properties be comparable with products now on the market? This was the problem which prompted the development of a flowsheet for the beneficiation of mica schist. The fine-ground mica industry relies on weathered pegmatites and alaskite ores as sources of raw material. The mica concentrates obtained from these ores are relatively clean and require moderate beneficiation to meet color and bulk-density specifications. Mica obtained from mica schist is iron-stained and decrepitated and requires additional beneficiation to produce a wet-ground mica product. Despite these adversities, there are several advantages to be gained by mining and processing mica schist ores. The mica content of these ores is considerably higher than that of the pegmatites and alaskite ores now being mined, often containing in excess of 40% mica. This higher-grade mica feed should promote a lower mining and milling cost. The mica schist ores with their higher mica content would mean less tailings to handle; however, there would have to be a means for disposing of acid and sulfate wastes. A flowsheet was developed whereby mica could be recovered from mica schist ores and beneficiated in a way that would result in a high-quality end product.' The essential phase of the process involves using reducing reagents to increase the magnetic susceptibility of iron contaminants which then can be removed with a magnetic separator. General Treatment Procedure The mica is floated by either of two methods, an amine float in an acid circuit' or the U.S. Bureau of Mines (USBM) amine-fatty acid float in an alkaline circuit' The flotation mica is ground in a pebble mill to liberate contaminated particles and expose iron-stained surfaces. The concentrate is then conditioned with a reducing reagent and passed through a Frantz Ferrofilter for the removal of magnetic material. The nonmagnetic product is acid-leached to further reduce the iron contamination. The leached material is then ground to product size and checked for specifications. Discussion of Flowsheet and Its Development Flotation: The mica is concentrated by flotation using either of two methods: an amine float in an acid circuit, or the USBM amine-fatty acid float in an alkaline circuit.' The writer does not wish to elaborate on the relative merits of the two flotation procedures; however, after investigating ores from various localities, it was felt that the amine float in an acid circuit was more consistent when using a standard procedure. Iron Reduction and Magnetic Separation: This phase of the flowsheet may be considered the key to the process. It was developed when it became apparent that hot acid leaching had just about reached its maximum effective¬ness for color improvement. S. C. Sun and William Hirsh in "Hydrochloric Acid Leaching of Iron From Pennsylvania Aluminous Clays,"` reported iron extraction for -20-mesh minerals of 82.20% for hematite and only 33.46% for magnetite. The test procedure employs a 19% hydrochloric acid solution, 104°C temperature, and 10% solids. It was felt that magnetic removal of some of the iron contaminants before leaching therefore would be advantageous. Since the iron minerals present as contaminants vary in magnetic susceptibility, it was decided to experiment with reducing reagents as a means of influencing their magnetic properties. Zinc hydrosulfite or sodium hydrosulfite were the reagents used throughout the tests. The procedure developed consists of conditioning the mica concentrate in a closed container at approximately 5% solids with a reducing reagent. Approximately 10.0 lb of zinc hydrosulfite per ton of mica concentrate is used. The ferric iron is reduced to the ferrous state (magnetic) and oxidation is retarded by isolation from the atmosphere in a closed container. After the desired conditioning time has elapsed, the material is passed through a Frantz Ferrofilter where the magnetic particles are retained and discarded as

Jan 1, 1972

By D. E. Seizinger

The Bureau of Mines has developed analytical methods, primarily gas chromatographic, for measurement of exhaust oxygenates produced from selected simple fuels. The resulting data were used to estimate levels of carbonyls and noncarbonyl oxygenates in exhaust from gasoline fuels. Estimated noncarbonyl oxygenates in gasoline exhaust may comprise as much as 30 pct of total oxygenates which include unsaturated carbonyls and noncarbonyls believed to be significant potential pollutants.

Jan 1, 1972

By Duncan B

Shortwall continuous mining as first introduced at Burwood colliery, and currently being used at John Darling, Lambton, and Corrimal collieries, is a method of coal winning which was pioneered in the Newcastle district. The system uses individual hydraulic self-advancing chocks for roof support and the coal winning operation is by continuous miners and shuttle cars. Where physical conditions are suitable the system provides a safe, efficient and economically viable basis for pillar extraction. Shortwall operations have been conducted successfully in the Victoria and Dudley seam, near the coastal fringe of the Newcastle district and are now being tried out in the more difficult conditions of the Bulli seam in the Illawarra district.

Jan 1, 1972

By Fred N. Kissell

In this report the importance of diffusion in controlling the emission of methane in mines is examined. An in-situ diffusion parameter is defined and calculated for a hypothetical unfractured lump of coal in the Pittsburgh and Pocahontas No. 3 coalbeds. The values obtained are similar to those obtained with lump coal in laboratory experiments.

Jan 1, 1972

By R. A. Mosser

Production control of aluminum content of low carbon aluminum killed open hearth steels is being achieved by using an oxygen probe unit. Based on the free oxygen content of the bath after block, a preliminary chart for aluminum additions has been established. The aluminum aim is .040%. Controlled aluminum contents will result in eliminating coarse grain heats, high aluminum contents, and a reduction in aluminum costs. By reducing the frequency of high aluminum contents both cleaner and better rolling heats will be obtained. The savings in aluminum costs is an added benefit of lesser importance in comparison to the quality improvements gained by controlled aluminum contents. Although the main goal for the oxygen probe at Republic Steel has been to adapt it for production control of aluminum contents, future usage could be extensive. Immediate plans for using the probe are on degassed material, on fully blocked open hearth heats to improve manganese recoveries and ranges, and on machining grades to control oxygen content. Also by controlling the oxygen content of the steel to as close to equilibrium conditions as possible, cleaner steel will result.

Jan 1, 1972

By N. Mohan, A. K. Biswas, V. Y. Sampat Kumar

At low sodium-oleate concentration, calcite flotation is substantially improved by the use of CO2 instead of air. Electrophoretic mobility measurements indicate that carbonation results in the accumulation o f positive charge on the calcite particles. This heightens adsorption of oleate anion, an effect confirmed by tracer-technique measurements. Fundamental insight is obtained as to how CO2 serves better as an activator than some mineral and organic acids, how oxalic acid acts as a depressor, and why the influence of Ca++ ions, liberated during carbonation, on flotation behavior of calcite is insignificant and sometimes adverse.

Jan 1, 1972

By C. Melvin Lepper

A solid-state amplifier for the bridge circuit of an atomic-absorption mercury detector is presented and described. Operational advantages over previously used circuitry include improved time and temperature stability, increased measurement accuracy, and simplified setup, calibration, and operation.

Jan 1, 1972

By B. A. McKee, T. Adamcewicz

For a capital expenditure of only $46,000, Caland Ore Company has successfully converted its three dry grinding center peripheral discharge rod mills to dry grinding ball mills. The conversion has resulted in a significant capacity increase, operating cost reductions and in-plant environmental improvements. This paper describes why and how• the conversion was made.

Jan 1, 1972

By T. Cameron Kenney

INTRODUCTION Whereas the design of rock slopes in open-pit mines is done largely by mining engineers and geologists, the design of slopes in overburden at this point in time is a problem for which civil engineers or geotechnical engineers are best prepared to deal. The reasons for this situation are to be found in the educational curricula and the technical journals of the two groups, where soil mechanics has received little attention by mining engineers and geologists, and rock mechanics has similarly received little attention by civil engineers. In ten years' time this paper will hopefully be considered by young mining engineers to be a repeat of the material that they studied at university. However, even in ten years time I believe that the civil (or geotechnical) engineers will be extensively used as consultants on overburden- slope problems of open pit mines because mining companies will find this more expedient than maintaining their own geotechnical staff, special field equipment and special testing laboratories. For this reason, the purpose of this paper is not to condense several university soil mechanics courses into a twenty-page text for mining engineers and geologists. Rather, the purpose of the paper is to offer a general explanation of various factors affecting slope stability so that mining engineers and geologists will have a better understanding of the behaviour of overburden soils in slopes. A great deal has been written in soil mechanics literature on the subject of slope stability. No attempt will be made to reference all this material but rather only a selected number of references will be cited. Excellent general treatments of the subject of stability of overburden slopes are available (1,2,3,4). Further information of a more specialized nature is to be found in such publications as the Journal of the Soil Mechanics and Foundation Division of the American Society of Civil Engineers, Geotechnique (printed by the Institution of Civil Engineers, England), Canadian Geotechnical Journal, and the proceedings of the conferences of the International Society for Soil Mechanics and Foundation Engineering. FACTORS INFLUENCING SLOPE STABILITY There are two general scales of slope-stability problems, gross stability and local stability. Gross stability refers to large volumes of soil, and gross instability would involve large rotational-type shear failures. Local stability refers to something much smaller and examples

Jan 1, 1972

By Michael Zurowski

This paper traces the history of International Mogul's assessment program on the Lake Ainslie barite-fluorite deposits of Cape Breton Island. The geology of the area is outlined, and the main vein systems described. The geophysical and geochemical exploration techniques employed are explained, the metallurgy of the ore is covered, and the market prices and economics of operation are described.

Jan 1, 1972

Only limited work has been reported in the literature about the use of latex in soil. Unisol 91 2,3 (a 9:l oil-latex emulsion made b International Synthetic Rubber Company) and Phil1ips Petroset4 geotechnic emulsions are surface soil stabilizers which penetrate a maximum of two inches, but do not reduce permeability. Diamond Alkali 5 found that styrene-butadiene rubber latex as a one percent latex-soil mixture reduced permeability to 0.7 from 21 feet per year under a head of twenty feet of brine. We have found no literature reference for use of latex as sealant at depth in the soil, although asphalt has been applied at depth using civil engineering methods6,7. Most of the materials investigated as soil sealants in the present work were latexes, although some studies were also conducted with a variety of inorganic and organic chemicals. Of the latexes tested, most were rubber but a few were plastic, e.g. polyvinyl chloride. Sealants examined in this investigation are listed individually in Table I with supplier, code number, and other pertinent information. The materials consisted of the following general classes with additional details as indicated: 1.Anionic latexes: a. styrene-butadiene copolymers and terpolymers (SBR) b. butadiene-acrylonitrile copolymer (Paracrils®) c. polyvinyl chloride homopolymers and copolymers (WC) d. ethylene-propylene terpolymer e. vinyl acetate homopolymers and copolymers (VA) f. acrylics (acrylate copolymers) g. 2-chlorobutadiene homopolymer (chloroprene) (prepared specially as cationic material coagulated by soil). 2. Water Soluble polymers: a. polyvinyl ether b. methylcellulose c. polyethyleneimines d. polyacrylic acid homopolymer e. copolymers and terpolymers with acrylic acid types (water soluble as sodium or ammonium salts) f. alginates g. monomers (for polymerization in soil, e.g. acrylamide)

Jan 1, 1972