Fundamental Studies on the Role of Carbon Dioxide in a Calcite Flotation System

At low sodium-oleate concentration, calcite flotation is substantially improved by the use of CO2 instead of air. Electrophoretic mobility measurements indicate that carbonation results in the accumulation o f positive charge on the calcite particles. This heightens adsorption of oleate anion, an effect confirmed by tracer-technique measurements. Fundamental insight is obtained as to how CO2 serves better as an activator than some mineral and organic acids, how oxalic acid acts as a depressor, and why the influence of Ca++ ions, liberated during carbonation, on flotation behavior of calcite is insignificant and sometimes adverse.