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By G. V. Cullen, N. G. Siviour

It has previously been reported that metal loadings of up to 6.8 m. eq/g. of dry coal can be obtained by contacting brown coal or lignite with ammoniacal solutions of ammine forming metals. Application of equilibrium expressions to further experimental results indicates that the extraction is by ion exchange, that the exchange is divalent-univalent for Zn, Cd and Ni, but is mainly univalent-univalent for Cu, and that to obtain reasonably uniform values for the equilibrium constants correction formulae must be applied to compensate for multiple functionality of the coal and its pH dependence in ion exchange. The results are shown to be consistent with the hypothesis that metal ammine complex cations are exchanged for protons derived from carboxyl and/or phenolic hydroxyl groups in the coal.

Jan 1, 1981

By Robert W. Buechley, Charles R. Key, Jonathan M. Samet, Marion V. Morgan, Arnolfo A. Valdivia

INTRODUCTION The Uranium Epidemiology Study at the University of New Mexico was initiated in 1977 with the objective of assessing health effects of uranium mining in the Grants, New Mexico, area. The planned approach was a cohort study of mortality that would capitalize on the availability of health records at the Grants Clinic. During the first year, emphasis was placed on determining the feasibility of the proposed study: Were adequate records available? What was the quality of available information? Could a cohort be established? The first year's work confirmed the study's feasibility (Buechley, 1979). Subsequent efforts have focused on the health and exposure data base and comprehensive follow-up. A retrospective cohort study of early miners is in progress; a prospective cohort study of miners who began working under the current Federal standard is planned. This report will summarize the current status of the Uranium Epidemiology Study. A chronology of the study's activities follows (Table 1). TABLE 1. Uranium Epidemiology Study Timetable 12/77 Official start of study. 12/77-8/78 Abstracted Grants Clinic records of 21,780 persons examined for mining companies from 7/57 through 12/76. Checked company personnel records to establish who had worked underground 1 year or more through 12/76. 7/78- Obtained physical exam and mining history information on qualified miners from Grants Clinic and companies. 9/78- Obtained working level month information from companies and other sources. 12/78- Checked qualified miners list with New Mexico death tapes and New Mexico Tumor Registry files. 9/80- Submitted qualified miners list to Social Security Administration for search of its records. 12/80- Obtained copies or abstracts of early State Health Department and Mine Inspector's reports. 3/81-4/81 Conducted Pilot Respiratory Disease Survey. 3/81- Verified underground status of qualified miners via company personnel records. 3/81- Verified smoking and mining histories of qualified miners via Grants Clinic records. 3/81- Began establishing cohort with first underground experience after 1970. 4/81- Checked qualified miners list with Post Office, Voter Registration Office, Motor Vehicle Division, telephone directories, city directories, and other sources. BACKGROUND Uranium Mining in New Mexico The Grants, New Mexico, uranium belt measures some 110 by 25 miles in Cibola, McKinley, and Sandoval counties (Kelley, 1963). The three chief mining districts are, from east to west, Laguna, Grants, and Gallup. Average annual production was about 5,500 tons, or 45% of United States uranium, from 1966 through 1978. Despite a drop in this figure in 1979, to 40%, New Mexico still leads the nation in uranium reserves and production (Hatchell, 1981). In 1918 carnotite, a yellow uranium vanadate, was identified in the Shiprock area (Chenoweth and Learned, 1980; N.M. Energy and Minerals Department, 1981). It received little attention at the time because of its apparently limited volume. In 1950 an important uranium outcropping was discovered by chance in limestone at Haystack Butte, northwest of Grants. In 1951 deposits were discovered in sandstone at Poison Canyon, north of Grants, and at Jackpile, northeast of Laguna. In 1955 finding of radioactive cuttings at an abandoned oil test site near Ambrosia Lake led to drilling and discovery of the first underground deposits (Melancon, 1963). Ore bodies were also found near Church Rock in the 1950's (Rautman, 1977). A uranium rush followed. At various times during 1952-1962, 60 mines and 5 mills were in operation (Gay, 1963). In the early 1960's the price of uranium fell, and many miners left the area. Subsequent market fluctuations have produced shutdowns and consolidations, development and expansion. Many early uranium miners came to New Mexico with

Jan 1, 1981

By Irvin Pritts

This report describes the design, fabrication, and testing of a prototype instrument which demonstrates the feasibility of determining respirable coal dust concentrations by light reflectance photometry. Coal dust is collected on a filter and the quantity collected is continuously monitored by reflectance-photometry. Light emission and detection is accomplished by reflective object sensors, which have both light source and detector in one chip. The use of a pulsed light source insures low drift characteristics of the measuring circuitry. The collection of the respirable coal dust on filters facilitates accurate calibration and also allows measurement verification, if desired, by well-accepted, gravimetric methods.

Jan 1, 1981

By J. D. Scott

This paper consists of a review of the development and application of spherical charge blasting at Inco Metals Company. Topics will include the Livingston Strain Equation, the field data required for its use in full scale operation, the type of ground in which mining has been carried out, explosives in use and their characteristics and finally, an overview of actual production applications. These applications include Primary Stope Mining, Secondary Mining Against Fill, Mining a Faulted Ore Zone and Drop Raise Blasting. INTRODUCTION Crater blasting in itself has been in use for over twenty years, but only recently has the technique been combined with a spherical size charge to form the Vertical Retreat Mining Method. This article endeavours to put the Livingston Strain Equation in a practical light, to describe several actual hard rock applications, and the results achieved in each case. THE LIVINGSTON STRAIN ENERGY EQUATION C.W. Livingston put forward the following equation as a standard means of determining the optimum burden required for full crater production blasting. The constant "E" is included in an attempt to recognize secondary breakage caused by strain waves.

Jan 1, 1981

By Z. Zitron

In 1978 the South African Coal Processing Society (SACPS), together with the Institute for Energy Studies of the Rand Afrikaans University, ran a school on coal processing. This was judged by both the organizers and the participants to have been extremely successful. As a result, it was decided to hold a second coal school in 1980. NIM reports Report no. 1958 A mineralogical investigation of sulphide-bearing chromitite from the Loskop Dam ar..a.(10th Feb., 1978; reissued 1st De!)., 1980). Report no. 2067 List of unrestricted NI M publications issued from 1966 to 1980. Report no. 2076 Wet high-intensity magnetic separation. Laboratory tests conducted in 1978 and 1979. Report no. 2083 The determination, by anodic-stripping voltammetry, of zinc and lead in six NIMROC reference samples. Report no. 2086 An automatic sampling probe for use in the carbon-I npulp process.

Jan 1, 1981

By Samuel M. Cassidy

The exact date of man's first use of coal is lost in antiquity. The discovery that certain black rock would burn was undoubtedly accidental and probably occurred independently and many times in the world over thousands of years. It is quite likely that these independent discoveries were made when primitive man chanced to build camp fires on exposed ledges of a black rock, then was amazed when it caught fire. The Chinese recorded the use of coal 1100 years before the Christian Era and from the Bible we learn that King Solomon was familiar with coal in what is now Syria. In Wales, there is evidence that the Bronze Age people used coal for funeral pyres, and it is known that the Romans used this fuel. There are other ancient references. So the knowledge that coal would burn, and even some uses of that knowledge, go back thousands of years. However, practical and consistent use of coal seems to date to England in the Middle Ages. COAL IN AMERICA In the Americas, there is evidence here and there of occasional use by the Indians. However, the first recorded discovery of coal, in what is now the US, was by French explorers, who reported an outcrop exposure on the Illinois River in 1679. Following this, other discoveries were made by French and British explorers, but the first recorded actual usage was in Virginia in 1702, where a French settler was granted permission to use coal for his forge. Earliest recorded commercial mining was in 1750, from the James River coalfield near Richmond, VA, a deposit now abandoned. Besides local consumption from this field, shipments were made to Philadelphia, New York, and Boston. During the Revolution this coal was of importance in the manufacture of shot and shell; so important, in fact, that the British sent an expedition in 1781 to destroy the iron works and

Jan 1, 1981

By Wm. J. McCracken

HISTORICAL REVIEW OF BOARD OPERATIONS The Ontario Worker's Compensation Board was established in law enacted by the legislature of the Province of Ontario in 1915. It was designed to pay insurance benefits to injured workers, and at the same time to protect employers from legal suit. It was based upon an enquiry system rather than an adversary system such as that used in the courts process. Initially, the system was designed to pay compensation benefits and subsequently, to pay for the cost of medical treatment and pensions for disability and disease resultant from the effects of traumatic injury. In 1947, the Act was changed to include industrial or occupational generated diseases, not specifically related to traumatology. Such occupational diseases were therefore accepted and benefits paid subsequent to that date. As will be discussed in several minutes, even today the vast preponderance of compensation claims with the Ontario Board continues to be related to the effects of trauma. HISTORICAL REVIEW OF EXPOSURE TO RADON GAS DECAY PRODUCTS In some areas of Ontario, especially in Northern Ontario, there is a natural leaching of radon gas from the underlying rock formation. This constitutes very low levels of radon gas decay product radiation exposure to those persons coming in contact and inhaling these substances. This paper however is designed to discuss the occupational generated types of radon gas exposures. For many years dating back to the 1930's, partially refined ores were being shipped from Northern Canada to a refinery located at Port Hope, Ontario, still in operation and currently operated by Eldorado Nuclear Limited of Canada. Initially, the purpose for the operation was extraction of radium to be sold on world markets for medical treatment purposes. With the advent of World War II, this market collapsed. Subsequent to World War II, the availability of other sources of radiation for medical radio-therapy generally replaced the requirements for radium. During World War II, a new market opened up for the Port Hope refinery however as work into nuclear chain reactions and the development of the atomic bomb identified the need for uranium and enriched uranium. During the period of operations where radium was being extracted at the Port Hope refinery, it is now known that an identifiable radon gas hazard did exist. This hazard disappeared when the production line for extraction of radium ceased operations. In 1954, uranium mining operations opened up in Ontario at two locations, Bancroft and Elliot Lake. At the peak of operations, 16 mines were operational and 11,000 workers were employed in these mining operations. A high level of mining activity continued over a 10 year interval with the Bancroft Mines closing permanently in 1964 following a 10 year life of operation. The other mines in Elliot Lake closed about the same time with the exception of two uranium mine operations which have continued to be operational up to the present time. By 1965, due to a dramatic drop in world demand for uranium, the total work force had fallen to 1/10 of the peak work force, and approximately 1,300 workers remained in employment. It is of interest to note that one significant difference in the work environment between Elliot Lake and Bancroft was the high silica content of the Elliot Lake ore. This gave rise to a number of cases of silicosis developing in relatively short intervals of time in the Elliot Lake miner population. No cases of silicosis were identified from the Bancroft operations. Based upon the experience in investigating and evaluating actual cases of lung cancer in the uranium miners over the years, the medical staff at the Ontario Board also developed the impression that radiation levels were much higher in the Bancroft operations, especially in the earlier years of operation, than at Elliot Lake. This resulted in accumulation of higher levels of Working Level Months (WLM), usually over a shorter exposure interval in many of the cases. This aspect will be further evaluated in this presentation. Subsequent to 1965, the work force remained quite static in numbers until 1975. At that time, there began to develop an increase in the work force, and this increase is continuing at a moderate rate up to the present. INITIAL METHOD OF HANDLING LUNG CANCER CLAIMS The first lung cancer claims in Ontario from uranium mining operations were accepted on the perceived cause-effect relationship. This relationship was based upon the data from the Colorado observations and the Czechoslovakia data. Initially, a series of regression equations on mortality were developed and used to estimate the effect of exposure to low cumulative doses of radon daughters as it might relate to the frequency of occurrence of lung cancer at any particular cumulative exposure level. A probability of cancer being radiation induced as against it being caused from other factors was calculated. This method was discontinued subsequent to 1972 due to problems encountered in carrying out this complex evaluation. Thereafter, each case was dealt with on an individual basis, being based upon whether or not the tumour was of the oat cell type, a cumulative exposure in excess of 120 WLM; latency periods in excess of 10 years, commencement of mining prior to

Jan 1, 1981

By William L. Young

I think I should let you in on one of Canada's best-kept secrets, if you will promise not to tell it all over the place. Believe it or not, good, honest, enterprising capitalism is still alive and flourishing north of our common border, and I am living proof that capitalism is still working for the little guy. My personal story of mining development in Canada isn't all that rare -- you've probably heard something like it from other areas and other days several times -- but my case brings it up-to-date. I would like to Tell you briefly the history of Northumberland Mines Limited, a contemporary case of individual enterprise getting a mining operation underway. And if I can do it you probably can too.

Jan 1, 1981

By Robert A. Westin

Polychlorinated biphenyls (PCBs) are a group of chlorinated chemicals that were used in many different fire resistant hydraulic fluids, heat transfer fluids, and in electrical equipment as dielectric liquids. PCBs were manufactured primarily by Monsanto Chemical Company under the tradename Aroclor, and were used by many different electrical equipment manufacturers. PCBs are noted chiefly for their extreme chemical inertness. This resulted in exceptional fire resistance and long life in applications involving exposure to high temperatures and intense electrical fields. This combination of properties resulted in PCBs being widely used in electrical equipment used in mines, including transformers, capacitors, and some electric motors. PCBs were also used as working fluids in some heat transfer and hydraulic sys terns. The same chemical resistance that gave PCBs long life in industrial applications give PCBs essantially eternal life when they are released into the environment. PCBs are not highly toxic in the sense that exposure does not cause immediate health problems. However, PCBs accumulate in the human body and neither degrade nor are eliminated from the body, and long-term exposure to PCBs can result in changes in liver function which may increase susceptibility to the carcinogenic effects of other chemicals. PCBs also accumulate in the food chain; the concentration of PCBs in fresh water fish may be several hundred thousand times as high as in the water the fish are taken from.

Jan 1, 1981

By Victor E. Archer

INTRODUCTION Man is exposed to many agents which induce mutations in germ cells and/or cancer at work, at play, and at home. In this total mix of mutagenic and carcinogenic agents, how important are radon and its daughters? Before man moved into caves and other permanent dwellings, the principal mutagenic and carcinogenic agent to which he was exposed was natural background radiation--cosmic rays, radium and potassium-40 in his food, plus gamma rays and radon from the soil and rocks. When man moved into caves, captured fire, and began to preserve and store foods, his exposure to carcinogens and mutagens took a quantum leap. Carcinogens and mutagens appear to act in the same way, that is, by altering the DNA or nuclear proteins of cells. Most mutagens are carcinogens, and vice versa, so when I say mutagens from here on, I will be referring to both. The relationship of the two is emphasized by the fact that administration of a carcinogen to a group of animals not only increases cancer rates among the exposed animals, but also among their progeny (Tomatis 1979). Environmental Mutagens Smoke from man's fires, overheated foods, and foods preserved by smoking, resulted in ingestion and inhalation of many polycyclic aromatic hydrocarbons--many of which are mutagens. Caves and houses with tight windows and doors tend to collect the radon which is constantly emanating out of soil, rocks and concrete, so man's exposure to the radon daughter component of background radiation increased several fold. Preserving food by salting or pickling with material that contained nitrites and nitrates led to increased ingestion of nitrosamines, which are potent mutagens. When his grains and other foods were stored in slightly damp rooms, fungi or mold would grow on them. Several of these fungi are now known to produce very potent mutagens. The best known of these is aflatoxin B (Ramachandra 1979). It may seem strange that a living organism would produce a mutagen. One might think that it would scramble its own genetic heritage. The reason it does not is that it produces the mutagen in an inactive form. It can be activated only by an animal's enzyme systems after being eaten. When man moved into cities, the collective smoke from wood and coal fires further increased his exposure. That particular smoke has now mostly disappeared, but has been replaced by smoke from automobiles and industry. When man moved into the age of technology, his exposure to mutagens again increased dramatically. Many mutagenic chemicals, from benzene and beta naphthylamine to a long array of pesticides and tobacco products have been added to our environment. Excess deaths from cancer are now being observed among chemists in most industrialized nations. Mutagens are even found in much of our wine, beer, and whiskey (Keller 1980). Some of the chemical mutagens were widely used in food or in other commercial products before their potential was discovered. Striking examples of this is the original butter coloring agent and the polychlorinated biphenyls that have been widely used in brake fluids and electrical transformers. Large quantities of them have been discarded or disposed of in a careless manner--in such a way that many of them have contaminated our food, our ground water and air (Landrigan 1981). In this nation, with the help of several recent laws, we were just beginning to get control of the industrial chemical mutagens. With the relaxing of these laws that is currently going on, it appears that it will be many more years before we really bring chemical mutagens under control. Many nations have yet to come to grips with this problem. On top of this massive array of chemical mutagens we have now added radiation from many artificial sources. For most of us this means medical X-ray and fallout from nuclear weapons testing. Ionizing radiation is one of the most potent mutagens, so it has caught the public eye, and its contribution cannot be ignored. Fortunately, by the time we started using radioactive materials in quantity with the Manhattan Project, we had experience with radium and X-ray (some of it bad); we knew enough radiobiology and enough about methods of radiation protection so that most nuclear laboratories have had a phenomenal record of radiation safety. Radiation is one new technology with great potential for harm that has not exhibited that potential except for a few isolated situations like that of radium dial painters, uranium miners and atomic bomb victims. Uranium miners slipped into this list almost by accident. We could have protected our uranium miners just as well as we did the workers in nuclear laboratories; but we failed to do so. Why didn't we? The reason is simple. The Atomic Energy Commission was charged with protecting the health of their workers. They did not wait for a pile of bodies before they introduced controls. Congress appropriated the money, and taxpayers were willing to pay for the protection against radiation. Miners unfortunately did not work for the Atomic Energy Commission. Although mine operators were ignorant about radiation, the key item was that in the 1950s nobody was willing to pay the extra costs of adequate ventilation to control the high levels of radon and radon daughters in uranium mines. Control was not achieved until new laws and regulations were passed which made it compulsory. BIRTH DEFECTS AND CANCER

Jan 1, 1981

By Carl (Original by) Hrovatic

Land is a precious resource and should be treated as such by all members of our society. The soil covering this earth is only a very thin outer layer, varying in thickness from a few inches to a few feet and covering the rocks and minerals lying beneath the surface. The wise use of this valuable commodity is the responsibility of everyone. Many everyday activities disturb e earth's surface. Examples are highway construction, housing and commercial developments, agriculture, and various types of mining. This chapter discusses the relationships of the environment to land as it applies to surface operations in the coal industry. Mining by surface methods disturbs, for a brief period of time, thousands of acres of land annually. In addition, refuse piles, slurry ponds, abandoned mine structures, unprotected mine openings, and unsightly cleaning plants can also adversely affect land unless properly handled.

Jan 1, 1981

By T J. Wilton, K A. Broadhurst

The United Kingdom, although a relatively small island, has a wealth of mineral deposits, coal, granite, limestone, gypsum, lead, florspar, etc. Coal is a major source of energy with 71 opencast coal sites, 52 using explosives. Many of these sites are in rural areas, the average area worked being 250 acres. The smallest is 35 acres, the largest 2,000 acres, but only 600 acres can be operated at any one time.

Jan 1, 1981

By Tor L. Brekke, Alberto Marulanda P.

The paper describes hazardous water inflows during construction that have taken place over the last three years in tunnels in Colombia. The projects involved are the Chivor II Hydroelectric Power Project (penstock tunnel), and the Chingaza Water Project (two tunnels). In all cases, loss of face control led to significant loss of ground; in one case some 70,000 m3 of slide material was involved, much of which came out through the portal situated 1.6 km from the face. Emphasis is given to: (a) the geologic setting, (b) the remedial measures taken, and (c) the main efforts that can be made to prevent hazardous conditions from developing.

Jan 1, 1981

By A B. Andrews

The use of sequential blasting techniques that combine surface and in-thehole delays has provided blasters with increased flexibility in blast design to promote good rock fragmentation and displacement while minimizing offsite blast effects such as air blast, flyrock, and ground vibration.

Jan 1, 1981

The direction taken by mineral processing in the next 20 years will be determined by sharing of Australia's resources to fill world needs; by the low energy costs in Australia; by environmental considerations; and by Re- search and Development contributions. Examples of the interplay of these factors are given by consideration of eight minerals.

Jan 1, 1981

By J. A. L. Napier

An essential requirement for the planning of the global capacity of a mine is a knowledge of the functional relationship between the production level and the capital expenditure necessary to establish that level. An underlying mechanism connecting capital expenditure and mine production capacity is proposed in terms of a characteristic profile of the expenditure that both precedes and succeeds production expansion. By the assignment of a representative shape to this profile, the capital expenditure of individual mines can be modelled. The empirical values describing the characteristic profile are computed for a number of gold mines, and an attempt is made to explain variations in the model coefficients from mine to mine in terms of physical parameters such as shaft depth, shaft concentration, and average rate of depth increase during the life of the mine.

Jan 1, 1981

By D. C. Dahlin

The Bureau of Mines conducted laboratory batch beneficiation tests on samples from four potential platinum resources in southeastern Alaska to concentrate platinum and other precious metals. Thin Investigation was done as part of the mission of the Bureau to insure an adequate supply of minerals to meet the Nation's needs. Petrographic studies and beneficiation methods including gravity concentration, froth flotation, and magnetic separation were used to determine mineral association and to attempt to concentrate the platinum values with a primary mineral value such as chromite, copper sulfide, or magnetite. A high-graded sample from the Salt Chuck copper sulfide deposit yielded the platinum-group metal concentrate; the maximum grade attained was 0.04 oz Pt and 1.5 oz Pd per ton of high-grade copper sulfide concentrate. The other samples yielded low-grade primary mineral concentrates with low platinum-group values, and/or the platinum-group metals did not concentrate with the primary mineral value.

Jan 1, 1981

By Olav Klomstadlien

The lean, but extensive iron ore deposits of the Dunderland Valley north of Mo i Rana, Norway, are the raw material base for Rana Mines, a division of the state-owned A/S Norsk Jernverk steel mill. The iron bearing minerals are magnetite and specular hematite. The magnetite/hematite ratio varies considerably both within each deposit and from one deposit to another. The ore bodies that lend themselves to mining have generally a thickness of 30-60 m grading 30-35% Fe and 0.15-0.25% P. The grain size varies from 0.05 to 2.5 mm. The fine grained ores are hard while the coarse grained ores are soft and easy to grind. The A/S Norsk Jernverk steel mill operates both a sinter and a pellet plant, and this necessitates production of two types of concentrates. The present flowsheet is shown in [Fig. 1]. The crude ore from the pits is crushed in a 1.07-m gyratory crusher with an open side setting of 12.7 cm. The crusher product is transported by rail to the concentrator located 25 km from the mines. The ore is fed by twelve 1.22 X 1.83 m vibratory feeders onto conveyor belts which carry the ore to a surge bin ahead of the autogenous mills. The feed rate is automatically adjusted to maintain a set power load at a level suitable for the ore type being processed. The mills operate in closed circuit with twelve dual-drum screens equipped with a 0.8-mm screen cloth. Oversize is returned by gravity to the mill feed while undersize flows to the gravity separation section which consists of Humphrey spirals in three stages. The ores are very heterogenous and analysis may vary quite considerably. The quantitative need for concentrate in the steel mill may also change rapidly. The process in the concentrator must therefore be easily changed, and consequently alternative process lines have been established. This is indicated with the dotted lines in the flowsheet. Apatite is removed by flotation by fatty acids to give a final sinter concentrate of 63% Fe and 0.020% P or less. Pellet concentrate contains about 65% Fe and less than 0.020% P. The fineness is about 1500 Blain.

Jan 1, 1981

By Jon C. Volkwein

The canopy-air curtain was originally developed by the Bureau of Mines to surround the operator of a continuous mining machine with a zone of clean air. This report describes the application and testing of a canopy-air curtain on a gathering-arm loader, as well as some of the problems associated with providing a zone of clean air to a standing, semimobile operator. The area of air-curtain coverage and effects of air velocity are discussed. In its present form, the canopy-air curtain provides a 50 percent reduction in respirable dust to the operator.

Jan 1, 1981

By J. E. Robinson, W. Pilkington, J. L. Taylor, B. J. Bluhm, E. B. Viljoen, P. Le Grange

The Chemwes uranium plant was designed and constructed within fifteen months; commissioning started during. June 1979, and the plant was producing at design capacity four months later. This account highlights the procedures and methods adopted to bring the plant Into production. The description of the various phases includes some details of the early evaluation, and the feasibility and optimization studies; of the financing, project management, design, construction, and commissioning of the plant; and of the training of personnel. Some of the mistakes made and the factors that contributed to the success are also listed.

Jan 1, 1981