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The decrepitation technique is a rapid means of measuring abundances, temperatures and to some extent the fluid compositions, of fluid inclusions in transparent and opaque minerals. The method has been used to investigate the hydrothermal fluid systems associated with gold mineralisation in the Tennant Creek, Pine Creek and Halls Creek Goldfields. At the Enterprise Mine, Pine Creek, several different stages of quartz veining are distinguished and within these, gradational changes in fluid temperatures and compositions help to define the centre and nature of the thermal system responsible for the mineralisation. In the surrounding Pine Creek region and at Tennant Creek and Halls Creek, the results were applied on a regional scale to characterize outcrops and aid in the discrimination between potentially mineral- ized and barren outcrops. The decrepitation method involves the heating of a small (lgm) sample of crushed and sized grains up to as high as 800 degrees celsius. During the heating the fluid inclu- sions within the grains develop sufficient internal pressure to physically burst, the temperature of such bursting being dependent on the type of fluid and the prevailing tem- perature at the time the inclusion was originally trapped. The resulting tabulation of the number of inclusion bursts per 10 degree temperature interval is plotted as a histogram of decrepitations versus tempera- ture and called a decrepigram. The decrepi- grams frequently show several distinct peaks at different temperatures which are caused by different populations of inclusions in the sample. The areas of the peaks indicate the abundances of inclusions in each population while the shape and mean temperature of the peak provides a guide to the type of fluids involved. Of particular importance in this study is the presence of decrepitation peaks at fairly low temperatures (around 2000 C. These are characteristic of C02 rich fluids which build up internal pressure very quickly when heated. The Enterprise Gold Mine at Pine Creek comprises a number of overlapping quartz vein systems hosted by Burrell Creek Formation sediments. The geology of this mine has been described at this conference by Dann and Delaney, who have defined several distinct stages of quartz veining based on structural, mineralogical and physical features of the veins. For this decrepitation study, 19 quartz samples from the mine and environs, including some from each stage of veining were collected. These results suggest that there are 4 major vein types, within 3 of which additional small variations can be discerned which are due to gradational changes in the temperatures and fluid compositions in the mine area.

Jan 1, 1984

By Wauchope AMH

Arsenic residues from BHAS Refinery operations are currently treated to form a calcium arsenic compound and stored in lined dams on site. Laboratory and large scale work on these residues has resulted in the development of a hydrometallurgical process for production of arsenic trioxide. The process also recovers the material from the storage dams. The residues are hot water leached to produce an alkaline arsenic liquor. This liquor is mixed with material from the storage dams and lime to form a calcium arsenic precipitate. The precipitate is then reacted with sulphuric acid to form gypsum for return to the main plant, and an acidic arsenical solution. Metallurgical gas containing 3-6% sulphur dioxide is bubbled through the solution and on cooling arsenic trioxide is precipitated. The product contains in excess of 95% arsenic trioxide. Installation of a plant at Port Pirie based on this process is being evaluated by BRAS.

Jan 1, 1984

By R. O. Burt

"Gravity Concentration, the oldest form of Mineral Processing, remains of major importance to the Industry. Current applications of Gravity Concentration are briefly examined.The Paper details one approach to the development of a Gravity Concentration Plant, from laboratory and mineralogical techniques, through Pilot Plant testing, where applicable, to the actual design of the plant.INTRODUCTIONGravity Concentration, once the major method of concentrating minerals has, for much of the twentieth century been regarded, like the dodo bird, as obsolete. However, in more recent years it is enjoying something of a renaissance, and is once again being treated as a useful, economic alternative in the Mineral Processing Engineers' arsenal.An indication of the broad application of gravity concentration is the variety of minerals presently recovered. A list is given in Table 1; this list is not exhaustive."

Jan 1, 1984

By Anthony M. Bauer

It is the nature of mining to reshape the landscape. Mining is an earth moving process with many of the same activities associated with the regrading of a site for a shopping center, drainage channel, housing project or ballfield. The difference exists only in purpose and duration of activity. The purpose of mining is to, produce a valuable product. The purpose of regrading for construction of a project is to create a predetermined landscape for a specific end use. In both situations the objective is to move earth materials as efficiently as possible. The question is then raised, if similarities exist, can mining operations be directed to shape predetermined landscapes as an integral part of its earth moving activity. This paper will explore the opportunities and issues of shaping sand, gravel and hardrock construction aggregate sites for productive end uses. It is based upon the premise that, as an earth moving operation, the process of extracting sand and gravel includes an inherent capability to shape productive lands as an integral part of the mining operation. In the course of any mining operation non-commercial materials, including overburden, fines and excess sand are handled to extract and process the commercial products. This activity exists regardless of whether or not there is a plan to reclaim the land. Moving this dirt is a basic operational cost. This cost need not be significantly increased when the material is deposited to shape land rather than be stock- piled just to clear the way for mining the deposit. Moving of dirt to create useable land can be guided by the same criteria used to remove the dirt from the deposit: for example, limiting the- hauling distance. Over a period of time earth handling costs can be reduced by minimizing the need to transport the stockpiled material a second time to the new landform location.

Jan 1, 1984

By J. N. Cox

Coal preparation is based on the properties of noncombustable materials (impurities) in coal being different from the organic constituents. The most commonly used property difference is density, via its affect on settling rates; and either gravitational or centrifugal forces can be used to remove impurities. However, examination of various particles settling rate correlations shows that at smaller sizes, particle drag becomes a very important factor. Classification, based on differential settling rates, becomes impractical and some property other than density must provide the basis for fine coal cleaning. Froth flotation and agglomeration employ differences in surface properties to clean coal. These methods are very successful except that the oxidized surface of a pyrite particle is somewhat hydrophobic and will tend to be collected with the organic portion of the coal. Surface property cleaning techniques have not been very effective in rejecting sulfur, except for two-stage flotation.

Jan 1, 1984

By J. H. Johnson, H. J. Schock

The cases of no auxiliary ventilation and ventilation with tubing were mathematically modeled, using a turbulent dispersion model. The Scooptram® used to load is modeled as a variable-speed, variable-strength source of pollutants moving in and out of the dead-ended drift. Model predictions are compared to experimental measurements. A parametric analysis was performed to determine If a relationship existed between C02 and NO levels. It was concluded from this analysis that when modeling a load-haul-dump cycle, it is necessary to use a model that can predict changes in source strength as well as source location. Carbon dioxide was used as a tracer to calibrate the model since, knowing the fuel flow rate, it is possible to calculate C02 production. The model was then verified after this calibration process using additional experimental results. With the calibrated model, it is possible to predict pollutant concentrations at any location in the heading using an engine map and the previously calculated flow field.

Jan 1, 1984

The role and policies of the Aboriginal Sacred Sites Protection Authority are described in conjunction with the provisions of the N.T Aboriginal Sacred Sites Act 1978. Comment is made on the application of the legislation and these policies to development proposals in the Northern Territory. A brief review of criticisms by both developers and Land Councils is provided together with responses to these Criticisms.

Jan 1, 1984

The Tertiary gold deposits of the Hauraki area are predominantly epithermal vein types containing mineral assemblages of quartz, calcite, pyrite, sphalerite, galena, chalcopyrite, acanthite and native gold (electrum). Sulphosalt, telluride (eg hessite), seleniferous sulphide and selenide minerals are important locally. Studies of wall rock alteration mineralogy, fluid inclusions in gangue minerals, and sulphur isotopes of sulphide minerals indicate that the ore forming fluids had the following parameters: pH, near neutral at depth but acidic near surface; temperature, predominantly 320 - 270¦C for base metal dominated assemblages, 280 - 200¦C for precious metal dominated assemblages and generally below 200¦C for late stage barite; apparent salinity, six to zero equivalent weight per cent NaCl; and CO2 concentration, generally around one mole per cent CO2. There is fluid inclusion evidence for boiling during mineralisation in some deposits. Moderate values off S2 and FO2 are indicated for base metal and mixed base metal û precious metal assemblages of most deposits by the predominance of pyrite + chalcopyrite over other iron-bearing phases; primary bornite is absent, whereas pyrrhotite, hematite and magnetite rarely occur in the veins. The largest gold û silver deposits formed from solutions in which the sulphur species in solution were predominantly reduced. Near surface environments and some deep, predominantly base metal, deposits were formed from solutions with approximately equal concentrations of oxidised and reduced sulphur species.

Jan 1, 1984

By Peter T. Chiang

A brief literature review on metal separations by ion exchange and solvent extraction of their thiocyanate complexes which are practiced in analytical chemistry as well as in industries was performed. Owing to the poor stability of free thiocyanic acid in acidic aqueous and organic media, technical and environmental problems which cause high thiocyanate consumptions often arise during the practice of the separation processes. This prompted the conducting of a second and more thorough literature review on the chemistry of thiocyanic acid. The objectives of this undertaking are to compile and interpret literature data on the physical properties and chemical reactions of thiocyanic acid, thus providing a clearer understanding of the causes of these problems and giving options as to how to minimize them. The best answer found for carrying out the separation processes is to keep the temperature, thiocyanic acid concentration and total acidity as low as practical.

Jan 1, 1984

By R. P. Killmeyer, B. S. Gottfried, J. T. Wizzard

The US Department of Energy's Coal Preparation Branch has developed a computer program to calculate the performance characteristics of coal washing devices. This program uses specific gravity analyses of the clean coal and refuse streams as input, and generates dependent and independent performance criteria for the washer. Partition curves are internally represented in a functional form by a Weibull function. Comparisons are made between performance criteria calculated by hand and the performance criteria calculated by the program for 120 different dense medium cyclone tests. Results show that the computer program gives results in close agreement with hand-calculated values while greatly reducing the amount of time involved in performing the analyses.

Jan 1, 1984

By Daniel Edelstein

Demand for arsenic trioxide dropped markedly during 1983, primarily as a result of a 27% reduction in cotton planting. As an oversupply of arsenic trioxide developed, prices declined for both domestic and imported material. Domestic Data Coverage.-Commercial-grade arsenic trioxide and arsenic metal were produced by only one U.S. company, which voluntarily reported its production to the Bureau of Mines. To prevent disclosure of proprietary data, the production data have been withheld.

Jan 1, 1984

By A Gene Riggs

The Cerrejon Coal Project in Colombia, South America is one of the largest coal mines in the world. The mine is located in northeastern Colombia on the La Guajira penninsula. The area is in a remote valley 132 miles east of the city of Barranquilla.

Jan 1, 1984

By Luis A. Fierino, M. Ashraf Mahtab

This paper reviews the background of, and solution techniques for, the major geomechanics problems affecting caving operations, including prediction of cavability, defining size distribution of or fragments, stability and support of production openings, and control of rock bursts and subsidence. Further research is also suggested in the solution of the various geomechanics problems.

Jan 1, 1984

By David C. Oyler

Methane-drainage holes must be completely filled by grout before mining to prevent the emission of large quantities of gas during mine-through, which would constitute an explosion hazard. In November 1980, seven horizontal holes at the multipurpose borehole, a small-diameter shaft drilled as a Bureau of Mines coalbed methane-drainage installation on the property of the Federal No. 2 Mine, Monongalia County, WV, were plugged using a sodium silicate gel grout. This report de- scribes the grout mix and the use of the grout at the multipurpose borehole, and discusses the results observed upon mine-through of the holes in early 1981. Cost data for the sodium silicate grout are also presented.

Jan 1, 1984

This paper is not available for inclusion in the Proceedings at the time of printing, but it will be included as an insert.

Jan 1, 1984

By G. E. Norman, R. E. Michelutti

"One of the major objectives of Falconbridge has been and continues to be, to minimize the impact of its operations on the environment around its Sudbury operations.The approach to achieving this objective and the results, are discussed under the following topics .I . Sulphur Dioxide Emission Improvements.2. Effluent Treatment Improvements .3. Effect of the Envrionmental Improvements.Sulphur Dioxide Emission ImprovementsHistoryThe rejection of pyrrhotite in the concentrators is one method of reducing the amount of sulphur to the smelter and therefore the sulphur dioxide emissions. In the 1950s and 1960s, Falconbridge developed the capability to remove 54% of this pyrrhotite. Numerous attempts were made to increase this amount by treating the pyrrhotite for recovery of nickel and in some cases elemental sulphur. Processes tested and operated were: hydrometallurgical pilot plant, roast-leach commercial operation and nickel-iron refinery. None of these processes proved to be commerically successful for both technical and economic reasons. Falconbridge therefore redirected its efforts to reducing sulphur emissions by improving its smelting process under The Smelter Environmental Improvement Project. A major component of this project was the installation of a sulphuric acid plant to recover the S02 in the roaster off-gases."

Jan 1, 1984

By Shosei Serata

Serious floor heave of up to 2.4 m in a 2.4-m high mine entry was eliminated by applying the stress control method of mining, as a last resort, at the No. 5 coal mine of Jim Walter Resources, Inc., in the Black Warrior coal basin near Birmingham. Alabama. Underground observation of the first 3-room entry created using the stress control method is discussed here. The behavior of the test entry, which eliminated the heave problem, is analyzed in relation to similar studies conducted in a salt mine under similar ground conditions by utilizing finite element analysis.

Jan 1, 1984

By Robert S. Shoemaker

At this Symposium on Gold which is sponsored by The Metallurgical Society of AIME and the International Precious Metals Institute many distinguished authors will present the latest developments in the metallurgy of gold and in operating practices at mines and in refineries. It seems appropriate then, as the introduction to this volume to recall some of the history of gold and the metallurgical developments which have been accomplished, especially during the past 100 years and some of the people who have contributed so much to the metallurgy of gold. Of all the elements gold has been the most sought after since the earliest times. Perhaps the quotation from Virgil's Aeneid best describes man's desire for gold but Pliny the Elder also put it very well when he wrote in 79 A.D. that "Gold is the first of man's follies, silver the second". This quest for gold has markedly influenced man's history and through the efforts of the early philosophers and alchemists to turn base metals into gold the foundations for modern chemistry were laid. The pages of history literally teem with references to gold. Gold is the first metal mentioned in the Bible and was the source of Croesus wealth as well as the death of King Midas whose touch turned everything into gold. And of course almost everyone has heard of Jason's Argonauts and the golden fleece. They are the subject of one of the many drawings in Agricola's De Re Metallica published in 1556. The Argonauts were probably prospectors seeking the source of the placers in the region near-the Black Sea. The time was about 1200 B.C. and the placer miners recovered gold by trapping the particles in sheep's fleeces placed in sluices. After drying, the fleeces were shaken to recover the gold. Gold is not hydrophilic, or wetted by water and thus the oils in the wool aided in collecting the particles. Here we have perhaps the earliest reference to surface chemistry and the basis for concentration of gold by flotation.

Jan 1, 1984

The reasons for and the methods of inte- gration of the gold treatment plant with the existing nickel concentrator are discussed. The integration was accomplished in three stages commencing in May 1980 and attain- ing current throughput in December 1982. The problems encountered and their solution, including the design and construction of a new tailings dam are also discussed.

Jan 1, 1984

By Charles Fairhust

Although the term 'rock mechanics' started to become popular about the time of the First U.S. Rook Mechanics Symposium in 1956, study of the mechanical behavior of rock certainly pre-dates this event. Bucky, Phillips, Von Karman, Fayol, Galileo...the list of significant contributors can be traced back over centuries, - not surprising for the oldest structural material used by man. Started with a strong mining orientation by the Colorado School of Mines, University of Minnesota, and Pennsylvania State University, joined soon after by Missouri School of Mines and the University of Texas, the Annual U.S. Symposium on Bock Mechanics has evolved into the main U.S. form for discussion of all aspects of rock mechanics, basic and applied - tectonophysics to comminution; near-surf ace foundations to deep mine support design. Although dominantly a U.S. event the annual symposium has benefitted from regular and important contributions from abroad. It would be presumptuous to attempt a comprehensive statement of significant developments over the 25-year history of the U.S. Bock Mechanics Symposium. This anniversary address will attempt instead to present a personal view of developments that appear to be of broad general significance and that may indicate directions for the future. Among the developments to be discussed in the address arc the following: - Energy Basis of Book Fracture Early rock mechanics investigators often overlooked the important distinction between a failure initiation stress and structural collapse. Although essentially synonymous in the

Jan 1, 1984