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By W. W. Albrecht

I. Introduction Refractory metals like tungsten, molybdenum, rhenium, tantalum and niobium and their compounds are essential ingredients of our modern technology. Especially in purified form, they are used in special alloys, electronics, optics and ceramics. The processing route from raw material to high purity refractory metals and their compounds includes, as a prime option, the following steps: - dissolution of raw materials. - liquid liquid extraction. - precipitation of high purity intermediate compounds. - calcination/reduction to high purity oxides/metals. Especially in the first three steps, major amounts of chemicals like acids or sodium hydroxide are used and, as by-products, substantial quantities of residues and effluents are generated. The impact of environmental regulations on these by-products and the attempt to reduce or minimize the amount of residues and effluents produced will be discussed in this presentation using Ta/Nb chemistry as the example. The basis of our considerations will be the way these by-products are handled at HCST, a major, and in some cases, the biggest producer of refractory metals (tungsten, molybdenum, rhenium, tantalum, and niobium).

Jan 1, 1992

By Poul Hansen

"In mid-1986, a world-class mining enterprise was created in Highland Valley, British Columbia, bringing together the copper mining operations of Lomex and Cominco . In 1988, Highmont joined the new partnership.Highland Valley Copper is the largest copper mine in North America in terms of both tonnage mined and tonnage milled, and it is one of the largest in the world. Due to its relatively low ore grade its production of copper in concentrate ranks about ninth in the Western World.The current eighteen year mine plan is based on ore reserves of 761 million tonnes. The daily milling rate is 133 000 tonnes. At the end of mine life, a total area of approximately 6500 hectares will have been disturbed. At this time, vegetation has been established on about 600 hectares and while work will be done during the operating years, it will not be until the end of mine life, about 2008, that the last half of the land can be reclaimed and revegetated.Once final reclamation has been accomplished, Highland Valley Copper will have completed its "" temporary use of the land"". In the meantime, about 1250people have had employment for about 50 000 man years, at wages ranking among the best in Canada.IntroductionTo provide and sustain our way of life, we need steel, copper, aluminum, zinc and many other minerals.To sustain mining, we must have adequate ore reserves and replacement of reserves as they are mined. Each year the search becomes more difficult as more of the Earth's surface is investigated and depo sits are mined. This calls for aggressive and sustained efforts.In British Columbia, past and present mining activities have disturbed less than one-tenth of one per cent of the land.With today’s technology, mining operations can be substantially reclaimed and thus complete the cycle of ""A Temporary Use of the Land""."

Jan 1, 1992

By Fletcher G

This paper will outline the design process, and the constmction and rehabilitation techniques proposed for the external waste dumps associated with the mining of the Wolfang Basin coal measures.The basin is located to the north of Clermont and immediately west of the Bowen Basin in Central Queensland, Australia. Development of the Clermont Coal Mine is planned for the mid-1990s after adequate sales commitments are obtained to allow the project to proceed.

Jan 1, 1992

By Robert W. Bartlett

Chalcopyrite in copper flotation concentrates can be hydrothermally converted to digenite with oxygen in a continuous process, with rapid kinetics when operated above 200°C. This eliminates large amounts of sulfur and iron. These "super-concentrates" have potential for debottlenecking smelters and avoiding capital intensive future smelter expansions, otherwise required in the late 1990s. The technology of producing super- concentrates is described, with cost estimates, and the use of super-concentrates as smelter feed is discussed, with examples.

Jan 1, 1992

By Renato G. Bautista

The prospect for recovery of rare earths from red mud, the bauxite tailings from the production of alumina is examined. The Jamaican red mud by far has the higher trace concentrations of lanthanum, cerium, neodymium, and yttrium. Scandium is also present. The dissolution of the rare earths is a major extraction problem because of the large volume of other materials present. The recovery processes that have been proposed include the production of co-products such as iron, alumina, and titania concentrates, with the rare earths going with the titania A critical examination of the possible chemical processes for the complete utilization of the red mud are presented Recommendations for research projects considered to be important in the development of a chemical separation process where no pig iron product is contemplated are also discussed.

Jan 1, 1992

By Y. Shu, A. R. Laplante

"A laboratory Knelson Concentrator (LKC), 7.5 cm in diameter, was used to study the performance of a similar unit at plant scale, 76 cm in diameter, This paper reports on sampling and assaying procedures and problems, and discusses the performance of the plant unit.The sampling procedure was based on the extraction of large samples, 5-15 kg, and their complete processing with a LKC, to characterize size-by-size performance. The procedure yielded reliable estimates of overall gold assays, after blatant assaying errors were corrected. The plant centrifugal unit concentrate was sampled in situ, which yielded very erratic grades, with a large overall negative bias. Due to the very heterogeneous nature of the concentrate, which can be linked to flow patterns in the riffles of the unit, it is recommended that for future testwork, the concentrate be recovered separately, blended and then sampled.The plant centrifugal separator, when operated at a feed rate of 25 t/h, yielded total and free gold recoveries of 41 % and 62%, respectively. This is much lower than previously reported data, and suggest that at 25 t/h, the unit is overloaded. However, recovery did not decrease with time over a loading cycle of 2 hours, which suggests that present loading cycles, generally 1 hour, can be significantly increased. INTRODUCTIONThe study of gold gravity circuits is plagued with the statistical problem of determining the behaviour of particles occurring with a very low frequency. This problem becomes particularly acute with increasing particle size. For example, considering the average weight of a gold flake in the 840-1200 µm (20/28 mesh) to be about 5 mg (Banisi et al, 1991), a reasonably high grade feed of 10 git would require, for a relative error (standard deviation) of 10% on grade, 100 particles, that is 0.5 g of gold, or 50 kg of 840-1200 µm material (a Poisson distribution is assumed). Gy's formula, for the same data, yields a weight of 33 kg, with a shape factor of 0.1 and a size distribution factor of 0.5. Both results are comparable; to obtain the suggested weight of material, a stream containing 5% weight in the 840-1200 µm would require 1 tonne samples (of unsized material). The problem rapidly disappears with decreasing particle size. Still with Banisi et al's data, a gold flake in the 300-420 µm range averages 0.5 mg in weight; the same 10% error on grade corresponds to a weight of 5 kg. Gy's formula for the same size distribution and particle shape factors as above predicts a required mass of 1.4 kg. This would correspond to an unsized sample weight of 10 kg with 14% weight in the 300-420 µm, for example."

Jan 1, 1992

By J. Weinstein

New erosion, corrosion resistant metal, ceramic, and polymer composite technologies are being developed and marketed by Alanx Products L.P. for use in hydrocyclones, pumps, valves, and other applications in mining and minerals processing. This paper will present an overview of the ceramic/metal composite material system and properties developed, which include excellent erosion/ corrosion resistance. Wear data will be shown from a variety of laboratory tests in dry and wet conditions, in aqueous neutral and corrosive environments. Comparisons will be made with a variety of competitive materials currently used in the industries sited. Data will also be presented on field tests with pumps and hydrocyclones in hard rock mining and other abrasive/corrosive environments. Field data from North and South America, as well as Australian mining applications will be highlighted.

Jan 1, 1992

By Donald R. Sadoway

The viability of treating certain forms of hazardous waste by direct electrolysis in molten oxides is under investigation. Secondary residue or waste mud produced in the course of chromate chemical production is the focus of attention in this study. The goal is to reduce the water soluble hexavalent chromium either to insoluble trivalent chromium or to chromium metal. Electrolysis tests have been conducted in a high temperature cell containing chromate sludge dissolved in an electrolyte composed of Al2O3, SiO2, CaO, and MgO. Oxygen production on a carbon-free anode has been confirmed.

Jan 1, 1992

By David C. Scott

Between 1990 and 1991, the Bureau of Mines studied the mineral resources of the Kaibab National Forest to appraise the resources present and to determine the types of deposits, and their location. The study included a comprehensive literature search and a limited amount of field investigation of minerals and mining activity in and near the Forest. Small amounts of copper with lesser amounts of gold and silver have been produced from limestone-hosted, strata-bound deposits in the North Kaibab and Tusayan Ranger Districts. In addition to these small metallic deposits, volcanic cinders, pumice, flagstone, and sand and gravel have been quarried in the Chalendar and Williams Ranger Districts. At least ten uranium-mineralized breccia pipes have been identified in the Tusayan Ranger District, One of these, the Canyon pipe, contains a high-grade uranium ore body with associated silver, copper, lead, vanadium, and zinc. The mine permit for the Canyon pipe has been approved and the mine shaft head frame erected.

Jan 1, 1992

By G. W. Luxbacher

With the advent of acid rain legislation included within the Clean Air Act Amendments of 1990, a great deal of uncertainty with regard to price, source and production quantities has been cast into the coal market. Powder River Basin and other western coals continue a rapidly accelerating migration eastward, South American coals move into the northern markets, states propose legislation to assist utilities in complying with the new regulations in hopes of maintaining their own coal industries, while some utilities question the long term availability of eastern compliance coal. Any major coal producer must make decisions now to assure their continuing presence in the market place; several companies have adopted a strategy to acquire eastern compliance reserves while others have invested in technology to compete as a low cost producer. This paper discusses some of these options in light of the uncertainties of the market place, from an eastern coal producer?s viewpoint.

Jan 1, 1992

By Hunter M. M

The present value of the future profits of a mining operation, using a discount factor which represents the effective cost of venture capital, provides a measure of the projected success of the operation. The present value can be maximised by appropriate selection of cut-off grades successively through the life of the operation. A case study is presented in which detailed optimisation of cut-off grade results in a worthwhile increase in profitability compared with the use of a constant, break even, cut-off grade.Some implications of this approach to profit optimisation are discussed.

Jan 1, 1992

By E. J. Fuller, J. C. Monette

"Gold and silver cyanide complexes are presently desorbed from activated carbon by means of hot caustic elutions. These solutions may or may not contain additional sodium cyanide. There are several parameters which affect the rate of stripping. Some of these include pH, ionic strength, and temperature. (1) Stripping is conducted in recirculating (ZADRA) or once through (AARL) circuits.This paper describes the development of a new chemical eluant which significantly increases the rate of stripping of both gold and silver cyanide complexes from activated carbon. Two case history applications are also described.INTRODUCTIONAdditional cyanide is used in strip circuits in order to prevent its depletion which could lead to precipitation of base metals or lead to a change in the nature of the gold cyanide complex to one which does not strip as easily. (2)The strip circuits that are able to function efficiently without the use of cyanide are mostly those where the carbon is acid-cleaned after stripping.Once the minimum cyanide requirement to maintain the complexes in their proper state are fullfilled, any futher incremental increase in the level of cyanide will have no bearing on the rate of stripping. (3)DEVELOPMENT OF THE NEW ELUANTGeneral DiscussionVarious carboxylated materials were investigated including octanoic acid, polycarboxylic acid (various molecular weights), salicylic acid, polymaleic acid, acetic acid. benzoic acid, terephthalic acid, 4, bi-phenyl carboxylic acid, phosphoric acid and stearic acid.The initial work was done on medium activiiy, non acid-cleaned carbon. The silver to gold ratio on the carbon varied greatly.Two different blanks were used. The first was an elution using a 2% caustic and 0.4% cyanide solution while the second was a 2% caustic elution."

Jan 1, 1992

By Zhou Y, Karmis M, Haycocks C

Hazard analysis utilizes interaction mecha- nisms in combination with geologic, structural and mining conditions to delineate areas of potential damage in seams subject to interaction. Using characterizations of conditions peculiar to multi- seam mining, such as innerburden thickness, geol- ogy and structures, initial interaction contour maps can be constructed. Geologic hazard analysis is then carried out on roof, pillar and floor condi- tions in the affected seam using lower seam rock properties and layout geometries in the overlying seam. Either safety factors or damage ratings can then be developed representing degree of hazard in the lower seam. The final hazard map shows both the aerial extent and magnitude of potential dam- age from interaction.

Jan 1, 1992

Structural assemblages of veins, shear zones, and wallrock alteration zones arising from fault-valve action on steep reverse fault systems are reviewed using observations from mesothermal gold-quartz lodes in the Archean Yellowknife, Abitibi, and Yilgarn greenstone belts of Canada and Western Australia, the Cretaceous Mother Lode system in the Foothills Metamorphic Belt of the western Sierra Nevada, California and the Victorian goldfield hosted in a folded quartz-turbidite succession of Paleozoic age in Australia. Despite differences in the host rock assemblages, the deposits have many structural characteristics in common. These form a useful exploration guide when re-evaluating comparable, but poorly described gold-quartz vein systems such as those in the Reefton area of New Zealand.

Jan 1, 1992

By Batterham R. J

Some developments in copper, lead and zinc extractive metallurgy which have gone in to production or seem to be close to production scale are described with emphasis on why these innovations have been adopted.Mineral processing operations are now using: automated quantitative mineralogy,high capacity fine crushing equipment, ò fine grinding equipment, andcolumn cell flotation.Extractive metallurgy plants are using:ò bath smelting of concentrate at various scales, and ò flash converting of copper.Hydrometallurgical process developments are slower to make a commercial impact. Concerns about ability to handle impurities in the feed and production of saleable by-products are often major hurdles.An expression for the probability of implementing the first example of a new development is presented.

Jan 1, 1992

By Bounsombath P

Underground mine development remains as one of the most important factors in cost effective mining. Various forms of continuous development have been proposed with some of the earliest conceived centuries ago.The bore, fire and muck approach remains, in the late 20th century, as the predominant method of underground development, despite intense efforts over the past decade or so to develop other systems.Following a comprehensive analysis of development in the Australian mining industry, the reasons why the traditional development cycle has remained unchanged are identified and potential directions for the future are suggested.

Jan 1, 1992

The Western Cape Branch of the SAIMM recently held a one-day colloquium on the use of artificial intelligence (AI) in process engineering in the I.S. Gericke conference room at the University of Stellenbosch

Jan 1, 1992

By D. E. Ranta, George F. Weaton

Estimating the Iron Ore reserves of Minnesota are directly related to both the geology of the deposit and the Scandinavian heritage of its people. The flat lying deposits, when properly prospected, make estimating easy and accurate across wide areas of the Mesabi Range. It also makes taxation simple on the unmined reserves. The reserves are their heritage and all the people should benefit, not just the owners. Heritage also dictates that newly discovered ores were there before discovery, hence, subject to the omitted property tax and liable for six years back taxes.

Jan 1, 1992

By Pharis E. Williams

The ability of voids, microballoons, and even solids to sensitize explosives has been known and used for many years. This phenomenon has generally been studied and reported under the terminology of "hot spots" because of the increase in local pressure and temperature when a shock wave encounters such sensitizers. A method for treating this phenomenon in detonation theory or in a detonation model has been studied for almost the same length of time. Perhaps because of the complexity and non-linearity of the void, or microballoon collapse, several of these studies have used the expediency of including additional terms in the burn rate law to account for the influence of hot spots. The detonation model proposed here considers the sensitization due to discontinuities in the shock impedance to be a mechanical phenomenon to be accounted for in the mechanical equations governing the detonation and not in the burn rate law. While this is not a new contention, the method for handling this non-linear phenomenon within the proposed model is new. The model also includes a method which accounts for the manufacturing variables of emulsion matrix cell size, microballoon size and type, as well as energetic additives.

Jan 1, 1992

By A. David MacPhail

"Highland Valley Copper is a large volume producer of copper and molybdenum concentrates. Production is by conventional truck and shovel operation combined with an extensive ore handling in-pit crushing and conveying system.Grade of the two orebodies is low at 0.4% copper and 0.007% molybdenum and this demands a production rate in excess of 260 000 tpd at a stripping ratio of 1: 1. Mining cost has to be kept at minimum levels to keep the mine profitable and thus, it is necessary to keep in the forefront: of technology. As well as the in-pit crushing system, the mine has pioneered the use of shovel weighing coupled with a state-of-the-art dispatch system.Maintenance of the equipment is carried out at the on-site mine maintenance shop with assistance from local shops for engine and wheel motor rebuilds and other large jobs such as those requiring stress relieving. Shovel and truck rebuilds are undertaken by mine crews. Both long- and short-term planning is designed and scheduled in the mine engineering section. Outside consultants are used to assist in slope design, reclamation and blasting technology."

Jan 1, 1992