The Use of a Novel Chemistry Significantly Enhances the Strip Rate of both Gold and Silver from Carbon in Strip Circuits

"Gold and silver cyanide complexes are presently desorbed from activated carbon by means of hot caustic elutions. These solutions may or may not contain additional sodium cyanide. There are several parameters which affect the rate of stripping. Some of these include pH, ionic strength, and temperature. (1) Stripping is conducted in recirculating (ZADRA) or once through (AARL) circuits.This paper describes the development of a new chemical eluant which significantly increases the rate of stripping of both gold and silver cyanide complexes from activated carbon. Two case history applications are also described.INTRODUCTIONAdditional cyanide is used in strip circuits in order to prevent its depletion which could lead to precipitation of base metals or lead to a change in the nature of the gold cyanide complex to one which does not strip as easily. (2)The strip circuits that are able to function efficiently without the use of cyanide are mostly those where the carbon is acid-cleaned after stripping.Once the minimum cyanide requirement to maintain the complexes in their proper state are fullfilled, any futher incremental increase in the level of cyanide will have no bearing on the rate of stripping. (3)DEVELOPMENT OF THE NEW ELUANTGeneral DiscussionVarious carboxylated materials were investigated including octanoic acid, polycarboxylic acid (various molecular weights), salicylic acid, polymaleic acid, acetic acid. benzoic acid, terephthalic acid, 4, bi-phenyl carboxylic acid, phosphoric acid and stearic acid.The initial work was done on medium activiiy, non acid-cleaned carbon. The silver to gold ratio on the carbon varied greatly.Two different blanks were used. The first was an elution using a 2% caustic and 0.4% cyanide solution while the second was a 2% caustic elution."