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By Daniel S. Witkowsky

The Pollution Prevention Act of 1990 provides few specifics to assist the non-fuel mining and mineral processing industries of the United States in achieving pollution prevention (P2) compliance. The U.S. Bureau of Mines (USBM) recognizes the absence of specific information to reduce pollution impacts from mining and mineral processing of hardrock and industrial minerals. Therefore, the USBM has prepared this publication to help reduce or eliminate environmental pollution and to assure the viability of these segments of the domestic mining industry. This report includes worksheets designed to help operators of mining and milling facilities to establish a P2 program. The report can also be used by citizen and environmental groups, State and local governments, and academia to gain an understanding of P2 as it relates to mining and mineral processing.

Jan 1, 1995

By M.E. Crump

Gallium occurs at above background levels in most samples collected from 11 of the major geothermal areas in the Taupo Volcanic Zone. Concentrations of Ga in the 48 samples ranged from 8 to 144 mg kg-' and varies widely from place to place within each geothermal area. Gallium is contained within the alumino-silicate structure of clay in the mud, having substituted mainly for Al. Suggested deposition mechanisms for Ga also involve co-precipitation with Sb, As, and SiO. colloids. Digestion trials, carried out to determine extraction conditions for possible commercial exploitation, showed that heating the mud to 500 -600¦C for 1 hour followed by acid/alkali treatment gave complete recoveries.

Jan 1, 1995

By Thomas M. Keevin, Gregory L. Hempen

"Natural resource agencies, under various regulatory authorities, are challenged with permitting underwater explosive use while at the same time protecting aquatic resources. Deciding on whether or not to allow use of explosives requires striking a balance between development and aquatic resource protection. A company’s goal in underwater explosive use is to select methods that are both expedient and cost effective. The use of explosives is often the best alternative for engineering reasons or economic considerations. Over and above legal requirements, indiscriminate destructionof fish and other aquatic resources is not in a company’s best interests because of concerns relatingto public image, as well as the need to secure future contracts."

Jan 1, 1995

By W.J. Atkinson

The first recorded discovery of diamonds in Australia was in 1851 from New South Wales. Subsequent prospecting has shown alluvial occurrences of diamond to be relatively widespread through much of the Tasman Fold Belts of Eastern Australia and production to date is estimated to be some 500 000 carats from a number of 'small alluvial fields. Despite extensive exploration though, no primary rock source carrying significant diamond contents has ever been confirmed in Eastern Australia. Conversely, diamond exploration of the older Western and Central Cratons of Australia over the past 30 years has discovered 12 fields containing 360 kimberlites, lamproites and lamprophyric volcanic pipes, dykes and other intrusives, of which 180 have been confirmed to be diamondiferous. Only one pipe however, the 1200 Ma high grade Argyle lamproite and associated near-by alluvials, has proved to be economically exploitable with current annual production of 40 million carats valued at approximately US$400 million. Production from the open-pit will be sustainable until at least 2003. This paper briefly summarizes the history of diamond discovery in Australia, principal diamondiferous provinces and deposits, current exploration activities and the potential for future discoveries.

Jan 1, 1995

By MacDonald B. Johnson, Douglass P. Bacon

"W ith the advance of science, rise of public interest in environmental matters, and continuing erosion of air quality, federal and state regulators are demanding an increasing complex array of data concerning emissions produced by burning and detonating energetic materials. The U.S. Department of Defense, one of the world’s largest consumers of energetic materials, now must characterize combustion products resulting from open burning/open detonation disposal operations. The catch-all phrase “below detection limits” no longer satisfies the regulators who nowwant testing to delve into the ppt level for volatile organic compounds and ppt level for semivolatile organic compounds."

Jan 1, 1995

Controlled blasting experiments in small development drifts were conducted at CANMET's Experimental Mine, from August 1992 to November 1993. The objective of these experiments was to develop suitable controlled blasting techniques for small development headings drilled by jackleg with 32 mm diameter holes. The experimentation also aimed to provide insight into blast damage mechanisms. Particular attention was given to the physical-mechanical properties of the rock and the rockmass structural data in order to make the results applicable to other geological environments. The drift faces were approximately 2.4 m by 2.4 m with 36 to 43 holes drilled to a depth of 2.4 m. Cartridged water gels, emulsions and semigelatin dynamite were used in the cuts and as primers, ANFO as the main explosive and decoupled 19 mm diameter semigelatin dynamite charges were used in the perimeter holes. Smooth blasting techniques and pre-splitting were tested in the underground mine. All the blasts were monitored with a multi-channel blast vibration monitor to which was attached sets of high frequency geophones and accelerometers. This first set of experiments has illustrated the efficiency of con-trolled blasting techniques to reduce blast damage and demonstrated the need for further research to improve the safe and efficient use of explosives.

Jan 1, 1995

By G. L. Mowrey

In addition to developing various types of coal interface detection systems, the U.S. Bureau of Mines is actively involved in developing a coal rib thickness monitoring system for high wall mining applications. One particular system that appears to show promise uses a ground-penetrating radar system to detect the coal-air boundaries of coal ribs. Based on preliminary laboratory and field tests, results indicate that this method can be applied successfully in highwall mines to maintain a constant rib thickness. The coal seam should be relatively clean in the vicinity of the antenna (e.g., have minimal partings or dirt bands) for best results.

Jan 1, 1995

By C. J. Bise

Safety training requirements differ from mine to mine due to changes in the demographic characteristics of the workers or changes in job and organizational characteristics. Accordingly, a microcomputer-based procedure has been developed to assist mine trainers is determining if undesired worksite performances result from lack of knowledge or skill, which are trainable categories, or from categories that are considered to be non-trainable (such as equipment limitations or management procedures). A special effort was made to understand the psychology of worker behavior by analyzing worker reactions to various organizational and job characteristics.

Jan 1, 1995

By Dale S. Preece

A Discrete element computer program named DMC (Distinct Motion Code) has been developed for modeling rock blasting. This program employs explicit time integration and uses spherical or cylindrical elements which are represented as circles in 2-D. DMC calculations have been compared with measurements on bench blasts in the field with relatively good comparison. Structural geology and joint sets have a significant impact on any blast and DMC has not, until now, included these effects. This paper discusses a recently added DMC capability for treating joints and bedding planes in bench blast simulations.

Jan 1, 1995

By K. J. Shoop

An analysis of an iron ore processing plant showed that its performance was affected by seasonal temperature variations, resulting in reduced grinding efficiency in the winter months. Laboratory and pilot plant studies were conducted to determine the cause of the observed loss of efficiency at lower temperatures. Experiments were divided into two groups: 1) Drop testing, which was performed to determine the effect of brittleness and frozen pore water on the breakage characteristics of the ore. 2) Wet grinding, which was further divided into laboratory tumble tests and pilot plant scale tests. Laboratory tumble tests were performed to determine the effect of temperature on the grinding of iron ore. This was done by varying the percentage of fines and percentage of metamorphic clay material added to the iron ore grinding charge. The pilot plant scale tests were conducted as a scale-up of the laboratory tumble tests and to determine the effect of temperature on slurry rheology, and how this changing rheology affected the grinding of iron ore. The combined results of drop testing and wet grinding were used to make some predictions of the performance of plant scale autogenous grinding. In drop tests the breakage characteristics of the iron ore had no noticeable change in size stabilities for dry and water saturated samples over the temperature range studied (-25°C to 25°C). The effect of frozen pore water was not observed due to the low apparent porosity of the iron ore. The addition of fines to the test charge caused a decrease in the amount of new fines produced for both the laboratory tumble tests and pilot plant scale tests. The production of fines further decreased when tests were performed at the colder temperature. The increased energy consumption at lower temperatures was dominated by rheology phenomena. The addition of metamorphic clay material to the iron ore test charge resulted in more fines being produced in the laboratory tumble tests. This was due to the metamorphic clay material grinding easier than the iron ore. This caused an increase in the amount of fines in the mill, which in turn, would prematurely slow down the grinding of iron ore because of an increase in the viscosity of the slurry.

Jan 1, 1995

By Keith S. Liddell

he selection of mill design parameters to suit the applica­tion requirements can result in quite different operating parame­ters for each generic type of application, even though the basic mechanical layout of the mills may remain similar. The selection of the type and size of grinding media is very important to efficient and cost-effective operation, and to ensuring that the milled product achieves the required properties. Accordingly, the grinding media selection is seen as an integral part of the mill design. Consideration of the requirement for classification is important in order to achieve the optimum mill and circuit performance. This can lead to the circuit feed not being classified for a steady feed with minimal slimes and a low size reduction ratio. Feed containing on-size particles would be deslimed by open circuit classification. Closed circuit classification is performed where the feed fluctuates. The rheological characteris­tics of the circuit feed slurry can have an influence on mill performance, and needs to be allowed for. A common misconception frequently encountered is the belief that "a mill is just a mill". This is not the case with stirred types of mills, since the operating parameters selected for the mill can have a large effect on the product characteristics. For example, horizontal shaft high speed stirred mills have a com­pletely different grinding action to vertical shaft low to medium speed stirred mills, which results in large differences between the surface area produced at a given product size (Liddell, 1986). Hence, it can be misleading to apply test results or design procedures obtained from one type of mill to other types for scale-up. The Metprotech stirred mill, as applied in the mining and minerals industries, is a low to medium speed vertical shaft mill. The basic design has been discussed previously (Liddell, 1989). Currently, the largest mills that have been manufactured have an installed power of 400 kW. The largest chamber volume at this power is 6000 litres, containing IO t of grinding media. It is intended that the installed power will increase up to lMW as applications requiring larger sizes arise.

Jan 1, 1995

By F. Lincoln & B. Rodier, G. Poniatowski, N. Kawashima, T. J. White, J. H. Kyle, G. F. Eaton

The history of Australia is a narrative of the discovery and development of its mineral wealth. The gold strike at Ballarat, Victoria, in 1851 transformed the colony by triggering the first great influx of migrants to Australia, and the development of subsequent mineral discoveries lead to a vast resource industry. However, beneficiation of base and precious metal ores carried with it an environmental penalty, not addressed until the last quarter of this century. In particular, the extensive deposits of gold, silver, lead, copper and zinc reside in sulphurous ores which often contain arsenic, antimony and mercury as significant contaminants that are released as unwanted by-products during smelting and refining. Until recently, these toxic concentrates were discharged to the atmosphere or receiving waters, collected in tailings ponds close to the smelters, or dumped at sea. Although such procedures . were acceptable in the past, more stringent environmental controls have required a re-examination of these practices and encouraged intensive efforts to develop enduring solutions to the disposal of these wastes. From this research has emerged a promising new generic technology called Xtaltite (pronounced crystal-tight). In this approach, geochemical principles are employed, first, to reduce the toxicity of heavy metals to low levels, and second, to identify and engineer suitable repositories for the permanent disposal of the consolidated waste form. In this paper, we emphasise the application of Xtaltite to the disposal of arsenious smelter fumes derived from gold winning. The principles ofXtaltite will be described and its technical and economic performance compared with conventional technolo­gies.

Jan 1, 1995

By H. H. Hughes, J. G. Dunn, P. G. Fernandez, H. G. Linge

Dissolved Arsenic (As) is stabilised primarily as As(III) and As(V) and enters ground water streams from sources such as the increasing metallurgical processing of As - containing ores [1]. As(III) is more toxic than As(V) and is less effectively removed from solution by oxide precipitation. Even for dilute As(III) solutions, skin contact or ingestion can cause dermatitis or cancer and there are stringent effluent control standards in place for As containing effluent from mining operations [2]. Chemtronics (Perth, Australia) has manufactured a compact digital voltamme­ter, based on anodic stripping voltammetry (ASV) and suitable for use in the laboratory or field. In this paper we demonstrate the utility of this equipment for measuring As(III) concentration with a detection limit of ca. 10 ppb.

Jan 1, 1995

By H. G. Linge

Pyrrhotite (FeS1+x ,0<x<0.15) is an iron sulfide which is considered to be a pest in carbon-in-pulp/ leach (CIP/L) gold processing [l].The perceived influence of pyrrhotite on gold processing by CIP/L is a competing consumption of 02 and CN­as the pyrrhotite dissolves by oxidation [1,2]. The few studies of the oxidation chemistry, kinetics and mechanism of the oxidation ofpyrrhotite are reviewed in detail elsewhere [3].There is broad agreement that the surface of pyrrhotite is very rapidly oxidized to form a thin (e.g. 10 nm) ferric hydroxy-oxide layer which overlays an iron-deficient sulfide lattice covering the original pyrrhotite. The reaction can be summarized thus:

Jan 1, 1995

Roof bolting has been widely used in hard rock underground mines for its many advantages. In this paper, the applicability of roof bolts to mine openings in frozen ground and effects of bolts on the stability of the openings are presented. A comprehensive finite element program ABAQUS, was used to analyze the temperature distribution, the stress field, and the displacement field around a mine opening. Openings supported by roof bolts and unsupported were analyzed. The thermal and mechanical processes were treated as a quasi-coupled problem, with the thermal analyses being conducted first, followed by the mechanical analyses in each case. For the opening under consideration with a roof area of 15 m2, five to seven roof bolts are appropriate. When the number of bolts are less than five, the displacement within the ground can be improved only locally.

Jan 1, 1995

By M. L. Leming

The mechanisms of Alkali-Silica Reactivity (ASR) are briefly reviewed, test methods are examined, and typical specifications are discussed. In addition, views on responsibility of the aggregate supplier regarding specifications are presented.

Jan 1, 1995

By R Kerrich

Early-Archaean (3.26 Ga) volcanogenic massive sulphide (VMS) deposits located within the low strain and sub-prehnite-pumpellyite metamorphic-grade Strelley greenstone belt, East Pilbara, Western Australia, contain exceptionally well preserved sulphide textures which are directly analogous to those of sulphide chimneys formed by black smokers at present day submarine hydrothermal vents. The VMS deposits are associated with seafloor alteration zones in and below silica-carbonate laminites, at the top of tholeiitic to calc-alkaline intermediate and felsic rocks. VMS mineralisation comprises stratabound Zn-rich sulphide lenses with significant Cu and barite, and variable Pb and Ag, above Cu-rich stringer zones, all of which are similar to Phanerozoic polymetallic or Kuroko VMS deposits. Sulphide-sulphate mineralisation implicates hydrothermal discharge into sulphate-bearing ocean waters, ruling out a globally anoxic Archaean hydrosphere. The volcanic rocks and co-magmatic sub-volcanic intrusion hosting the VMS deposits are characterised by the conjunction of LILE&gt;LREE&gt;HREE, and Phanerozoic La/Yb with negative normalised anomalies of Nb, P and Ti, consistent with derivation via subduction zone hydrous metasomatism fusing the mantle lithosphere.

Jan 1, 1995

By W. Dan Hausel

"Hundreds of diamonds have been found in the United States. The majority of the discoveries occurred during the 19th century as a by-product of placer gold mining. Most of these early diamond finds have no known source, and in many cases are situated in areas unfavorable for diamond exploration based on current models that require kimberlite or lamproite to be emplaced in a stable Archean craton or Proterozoic craton margin.Diamonds have also been recovered in situ from lamproite at Murfreesburo, Arkansas, from kimberlite in the Lake Ellen region of Michigan, and in several kimberlites in the Colorado–Wyoming State Line district. Unverifed reports also suggest that diamonds may have been recovered from other related intrusions at a number of localities in the United States.IntroductionTo date, diamonds have been recovered in situ from kimberlite in the Colorado–Wyoming State Line district and from a kimberlite in Michigan. Additionally, diamonds have been recovered from lamproites in Arkansas. Diamonds have also been reported from kimberlite in Kansas, and from peridotite in New York and Maryland. However, these latter reports have not been verified."

Jan 1, 1995

Gallium occurs at above background levels in most samples collected from 11 of the major geothermal areas in the Taupo Volcanic Zone. Concentrations of Ga in the 48 samples ranged from 8 to 144 mg kg-1 and varies widely from place to place within each geothermal area. Gallium is contained within the alumino-silicate structure of clay in the mud, having substituted mainly for Al. Suggested deposition mechanisms for Ga also involve co-precipitation with Sb, As, and SiO2 colloids. Digestion trials, carried out to determine extraction conditions for possible commercial exploitation, showed that heating the mud to 500 - 600¦C for 1 hour followed by acid/alkali treatment gave complete recoveries.

Jan 1, 1995

By Stuart Brashear, Robert Brush, Ben Cook

In early 1993, the Piney River quarry owned and operated by the Blue Ridge Stone Corporation of W.W. Boxley, received a series of complaints from the owners of a 130 year-old historic farmhouse that had been converted into a bed and breakfast establishment. Since the distance from the quarry to the farmhouse was substantial, a unique method of seismic data acquisition was utilized to determine if perceived blast effects were caused by air blast or low amplitude, low frequency ground vibration.

Jan 1, 1995