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By Kuniaki Murase, Tetsuji Hirato, Yasuhiro Awakura

"Electrodeposition of CdTe was studied using aqueous ammonia-alkaline electrolytic baths in which Cd11-and Te1V-ions are dissolving as Cd11(NH3)/+ and Te1vol-ions, respectively. Ca-thodic polarization curves of the baths suggest the presence of strong interaction between the Cd11-and Te1V-ions; electrodeposition of tellurium is inhibited by the presence of Cd(NH3)/+ ions. The interaction makes it possible to electrodeposit CdTe films with stoichiometric composition. Polycrystalline CdTe thin film of about 1 µm thickness was electrodeposited at 343 K from ammonia-alkaline solutions (pH= 10.7) containing TeO32-(<20 mmol dm-3) and Cd(NH3)/+ ( < 60 mmol dm-3) ions. Increasing Cd(NH3)/42+/TeO32- mole ratio or decreasing total concentration of ammonia/ammonium-ion gave flat and smooth crystalline CdTe deposits at constant cathode potential-0.70 to -0.30 V vs SHE at 343 K.IntroductionCadmium telluride (CdTe) is well-known as a compound semiconductor whose band gap, i.e. 1.44 eV, is suitable for solar energy conversion with a photovoltaic cell. Various methods, such as CVD (chemical vapor deposition) and electrodeposition, of preparing CdTe thin films for solar cells have been investigated.Acidic sulfate solutions with a pH of 1-2 are usually employed for CdTe processing by electrodeposition.1-3) The electrodeposition of compound semiconductors is usually achieved (i) at a higher cathode potential than the redox potential of less-noble species, can in this case, and (ii) under the condition of diffusion-limiting current of a more noble species, Te1Y.4) There-fore, a suitable CdII/TeIV concentration ratio in the acidic electrolytic baths, resulting in the deposition of stoichiometric CdTe, is determined by the diffusion-limiting current density of TeIV- reduction, i.e. the concentration of HTeIVO2+ · Since the solubility ofTe1v species HTeIVO2+ in the acidic solutions is quite low, the rate at which CdTe is deposited from the acidic solutions is extremely slow."

Jan 1, 1998

By David Newman

Landslides and soil creep often occur with varying degrees of severity on steep slopes within Southern Appalachia. Ground movement may take place over years with subtle changes in topography and vegetation or it can occur rapidly in response to water inflow or disturbance at the toe of the landslide. Although the ground movement typically is restricted within the soil and colluvial layers, failure can extend into the weathered rock zone. Certain areas of Appalachia are described as "slide prone" because of historical precedent. To develop a profile of "slide prone" areas, the strength and physical properties of the soil and colluvium, topography, groundwater and surface water runoff, present and historical land use, and any surface disturbance are examined in detail. These attributes are useful in determining whether an area is potentially unstable before surface development including construction, logging, or mining. Recommendations are provided to avoid initiating ground movement concurrent with mining operations.

Jan 1, 1998

By W. M. Schafer

The risk that water quality will be degraded by mining activity can be evaluated using risk analysis techniques. Water quality impacts can occur where water-rock interactions with tailings, waste rock, or leached ore lead to increased loading of constituents into surface or groundwater. Constituent loads contributed by mining facilities are determined by the migration route and chemical evolution of mine water. Mass load contributions from mines can be determined by estimating the prototype pore water in contact with mining waste, predicting the rate and timing of flow, assessing the degree of geochemical attenuation, and modeling chemical mixing with natural surface or groundwater. Mining facility siting and design measures can alter the chemical evolution of mine water by varying the quantity or quality of flow. Stochastic risk management techniques provide a powerful tool for quantitatively identifying the environmental consequences of various siting and design alternatives.

Jan 1, 1998

By I P. Hodkinson

SMC Resources Limited is implementing a selective mining approach at the Hadleigh Castle mine, formerly operated by Aurora Gold Limited. The main ore zone has a length of 250 metres and dips at 40 - 45¦ to the south. Gold mineralisation occurs in a variety of quartz-sulphide lodes in sericitised granodiorite. Shallow dips, alteration intensity and mineralisation style combine to make mining relatively difficult. Previously unworked, high-grade, shallow dipping (30 - 45¦), narrow quartz-sulphide lodes within the hanging-wall of the deposit are also being selectively exploited. Annual production of 35 000 oz Au is forecast from 185 000 tpa ore grading 6.5 g/t Au over a currently envisaged mine life of six years. Operations completed to-date include deepening the decline and access development of the first two levels beneath the previous workings. Longhole stoping operations have commenced in the main ore zone with air leg stoping also underway in the hanging wall lodes.

Jan 1, 1998

By Xun An

Slag from an electric slag cleaning furnace was injected with methane and air mixtures to facilitate the recovery of copper and cobalt. The effects of methane-to-air ratio, gas flow rate and temperature on the reduction and metal separation were investigated. The results showed that over 90 percent copper and up to 60 percent cobalt could be recovered from the slag with a gas utilisation of around 70 percent, as calculated by thermodynamic simulation. Methane-to- air ratio was a major factor affecting the rate of reduction under the present experimental conditions. Further, injection of gaseous reductants greatly enhanced the coalescence and settling of entrained metal droplets. A reduction mechanism is proposed and the factors influencing the coalescence of copper droplets are discussed.

Jan 1, 1998

The US Geological Survey (USGS) held a one-day workshop at its Denver, CO facility to inform the public of the status of its National Mapping Program. In addition, the agency wanted to obtain information from topographic map users on what their needs are. The agency wants to know what the topographic map user wants. The USGS faces the challenge of keeping up with the changing needs of the nation. In the last few years, the agency has changed dramatically to meet these needs. For example, the "new" USGS incorporates mineral-information specialists from the former US Bureau of Mines and also uses the expertise of former National Biological Service employees. These areas complement the agency&apos;s traditional strengths in mapping, geology and water re- sources. The stated mission of the USGS&apos;s National Mapping Division is to "meet the nation&apos;s need for basic geospatial data, ensuring access to and advancing the application of these data and other related ears science information f& users worldwide." To accomplish this goal, the USGS publishes topographic maps, including shaded-relief editions of areas of special interest (state maps and national parks); photo image maps; satellite image maps; geologic maps and hydrologic maps. The geologic maps include geologic quadrangle maps, oil and gas investigation maps and charts, and coal investigations maps. The familiar 7.5-minute series topographic maps are the most widely used. The 7.5-minute- (1:24,000-scale-) format mapping was begun in 1935.

Jan 1, 1998

By Takahiro Miki

In order to use metallurgical grade silicon (MG-Si) as a starting material for solar cell, phosphorus has to be removed from silicon because phosphorus is a n-type dopant. On the other hand, silicon, ferrosilicon, and silicomanganese are widely used as deoxidizers in steel refining processes. Since most of the phosphorus introduced during the deoxidation process is brought into final products, it is important -to lower the phosphorus content of these alloys. Hence, thermodynamics of phosphorus in such metals is important for the evaluation of dephosphorization processes. In the present study, thermodynamic properties of phosphorus in molten Si-P alloys at 1723- 1848K and those of Si-Fe-P and Si-Mn-P alloys at 1723K have been determined by equilibrating respective metals in a controlled phosphorus partial pressure. The results are expressed as follows.

Jan 1, 1998

By Coskun B

The classification of selective mining units (SMU&apos;s) and the assignment of grades to those classified SMU&apos;s are very important in open pit mining, especially for precious metal mining. During ore control planning, the classification of mineral

Jan 1, 1998

By R. Q. Honaker

Recent research has shown that enhanced gravity separators provide the opportunity to effectively clean I mm x 37 micron coal. At Southern Illinois University, a detailed experimental program was performed on a continuous Falcon Concentrator, which was found to achieve separations at mass throughput capacity values in excess of 100 tonnes/hour. The apparent particle separation density for I mm x 73 micron coal was about 1.60 with relatively high efficiency (Ep = 0.12). Typical ash and sulfur rejection values of 85% and 70%, respectively, were achieved while recovering 85% of the combustible material. Metallurgical and efficiency data from the evaluation are presented in this publication.

Jan 1, 1998

Newmont Gold&apos;s methods for deposit modeling vary, depending on geology, mining and processing methods, economic feasibility and availability of historical information. It is argued that successful modeling requires understanding these factors, knowing the strengths and weaknesses of the various modeling techniques and being flexible in selecting the appropriate methods. Newmont is one of the world&apos;s largest gold mining companies, with operations in the United States, Peru, Mexico, Indonesia and Uzbekistan. And it is active in exploration worldwide. At the end of 1996, Newmont declared a total reserve of 1.15 equity kt (37.1 million equity oz) of gold and 2.17 equity Mt (2.39 million st) of copper. The gold deposits managed by Newmont totaled 752 Mt (829 million st) of ore containing 1.28 kt (41.3 million oz) of gold averaging 1.71 g/t (0.05 oz/st). In addition, Newmont is developing a porphyry copper-gold deposit that totals 9.1 Gt (1 billion st) of ore containing 380 t (12.1 million oz) of gold and 4.82 Mt (5.32 million st) of copper. (In May 1997, Newmont Gold Co. merged with Santa Fe Pacific Gold Corp., thus increasing Newmont&apos;s reserves to 1.72 kt or 55.2 million oz of gold and 2.17 Mt or 2.39 million st of copper.)

Jan 1, 1998

By M. J. Shields

There are numerous suggestions in the literature on methods of obtaining representative samples of waste rock or mill tailings. Some suggested methods would result in thousands of samples and very high costs for a large facility. There is no general rule that can (or should) be followed, such as collection of a given number of samples per mass of material, per acre of impoundment, or per foot of drillcore. Each site is different, and the adequacy of sampling must be tailored to the site. A logical approach is to let the variability at the site dictate the number of samples that should be collected and analyzed, and then to quantify and evaluate the results by means of standard statistical methods.

Jan 1, 1998

By P Geddes, K Grohs, C K. McKenzie, M Morrish

Low grade surface gold mining at the Acacia Resources, Union Reefs Gold Mine in Australia's Northern Territory, involves the excavation of benches in three slices after blasting. Blast patterns span zones of high and low grade ore, as well as zones of waste, and selective excavation is required in order to maintain economical head grades for the carbon-in-leach processing plant.

Jan 1, 1998

By J Lyall Workman

This paper examines the comparative economics of cast blasting to alternative stripping techniques. There are several scenarios where a mine may consider introducing cast blasting. However, there are other alternatives such as adding dragline capacity or introducing a prestripping operation. The question becomes which alternative will be more economical.

Jan 1, 1998

Maximising margins in today&apos;s competitive international commodity markets demands superior productivity. This requires more than selecting the best equipment. It requires continually improving the efficiency of production, commercial, marketing and administrative processes under the control of solid modern management systems.This paper introduces an integrated way of working that includes proven management systems for successfully changing work practices and attitudes, developing managers and increasing accountability. It introduces a proven methodology for systematically involving people in sustained true continuous improvement of processes for maximising productivity, safety and revenue while minimising costs.

Jan 1, 1998

By G. Tapia, R. J. Kelley

Empresa Minera de Mantos Blancos S.A. successfully commissioned two copper SX-EW plants in late 1995. The design of these solvent extraction plants is such that chloride tenors of 30-35 g/l can be tolerated in the leach solution with no contamination of the electrolyte. The design was carried out in conjunction with Bechtel-ARA engineers and was based on the successful application of the available technology in the market; this mainly focused on decreasing the aqueous entrainment in the organic phase. This entrainment can reach 20,000 ppm in conventional plants.

Jan 1, 1998

By V. N. Kolesnikov

The gold-silver deposits of the northern Primorye region are located in the eastern part of the East Sikhote-Alin volcanic belt, where the belt overlaps the Kema island-arc terrain of the Aptian-Albian age. There have been four deposits and numerous mineralization points found in the NE-trending Kema metallogenic belt that is about 1000 km long and 100 km wide. The known mineralization is of epithermal type, controlled by faults, and concentrated in quartz, quartz-fluorite-adularia, and, less commonly, sulfide-quartz vein systems hosted by the Upper Cretaceous-Lower Tertiary volcanic rocks. The vein systems extend for hundreds meters along strike, varying from tens centimeters to 50-60 meters in width. They are surrounded by wide zones of low-temperature hydrothermal alteration containing some gold-silver mineralization for which the commercial value was not studied during the early exploration. The ore bodies contain from 1 to 50-80 ppm of Au and from 1 to 1000 ppm of Ag. Gold is native, associated with quartz, and represented by particles from tens of microns to 1 mm in size. Silver occurs in native form as a constituent of argentite, pyrargyrite, stephanite, and other sulfosalts. The test work carried out for three vein systems 20 years ago showed that gold might be easily and almost completely recovered from the ore by cyanide treatment. The paper describes the geology and mineralogy of the deposits, Salut and Primorskoye, that are the most studied properties of the Kema belt. It also presents the data available on disseminated gold-silver mineralization in stockworks, altered explosive breccias, and wide zones of low-temperature hydrothermal alteration. This mineralization should be explored for possible exploitation as large open-pit, heap-leach deposits.

Jan 1, 1998

By Isrun Bohlinger

Resources recovery of brasses for semifinished products often results in the formation of hard spots impairing the quality of following abrasive and/or surface finishing processes. A short survey is given on the recycling processes, followed by the actual knowlegde of genesis, composition, and possibilities of avoidance of hard spots. Informations on genesis and composition of hard spots are completed by data from recent experiments.

Jan 1, 1998

Large variations of coal seam thickness and roof conditions are associated with the occurrence of mine floor undulation at Shoal Creek Mine, operated by Drummond Company, Inc.. Ground control problems, such as roof falls and face failures along with extremely high shield pressure and rapid face convergence, are often reported at the longwall face when these undulations exist. This greatly increases equipment downtime and causes production delays. As a result. a comprehensive study of mine geology including roof conditions and longwall performance were conducted in the mine. With the help of continuous full-face shield pressure monitoring using the Longwall Strata Control and Maintenance System (LoSCoMS), a large data base of shield pressure with various roof conditions has been established. This enables the mine operators to accurately evaluate the roof behavior and shield performance and to take the appropriate operational steps at the face to reduce the number of downtime and face failures. This paper summarizes all works and findings from the study including detailed roof geology and its effect on longwall performance.

Jan 1, 1998

By A. Anttila

The grinding mill is probably the most common unit operation used in mineral processing. There is, however, much which can still be done in the way of optimization. This paper discusses the results of a well controlled pilot scale test in which the performance of a tumbling mill with a conventional rubber lining equipped with lifter bars is compared to that with a smooth rubber lining of the magnetic type. The results indicate that the smooth lining is about 14 percent more effective with respect to energy consumption. By optimizing the size of the grinding media, the mill capacity can be increased in many grinding operations. In this specific case the -20 mm ball charge required 26 percent less grinding energy than one with a -30 mm ball charge. The energy savings can. in most cases, be converted to increased capacity. The wear of the grinding media is difficult to assess over a short period test but the results suggest it is somewhat less when a smooth lining is used. The wear of the linings has not been included in this study but it is generally accepted that the use of the magnetic lining reduces the lining costs dramatically. Computer simulation using the Millsoft code, developed by Mishra e.a. confirms and explains the increased effectiveness of comminution when smooth lining and smaller grinding balls are used.

Jan 1, 1998

In December 1997, a series of new environmental legislation was enacted including:ò Environmental Planning andAssessmentAmendmentAct 1997; ò Contaminated Land ManagementAct 1997;ò Protection of the Environment (Operations) Act 1997; ò Native Vegetation Conservation Act 1997; andò Pollution Control (Load Based Licensing) Act 1997.These new Acts will have varying degrees of impact on the coal mining industry in New South Wales when they commence later this year.

Jan 1, 1998