Search Documents

By M. Olper

Today, copper production from direct leaching of oxidized copper ores followed by solvent extraction-electrowinning (SX-EW) accounts for about 15% of the total primary world output. SX-EW is a well-accepted process with an operating cost in the range 16-20 cents/lb. copper for small and medium size plants, depending on the plant size and local conditions. However, this technology presents some drawbacks that affect the operating cost and cause environmental concerns. ENGITEC and Paques Bio Systems have developed a new process that avoids the solvent extraction step and operates the copper electrowinning step at a lower cell voltage because of the depassivation of the anodic reaction. The consequence of this new concept is that the direct operating cost is in the range 10-12 cents/lb. copper. This new process is composed of the following steps: ? Selective precipitation of copper from leach solutions by biogenic H2S, yielding CuS and regenerating acid ? Leaching of the CuS with a ferric fluoborate solution to dissolve copper and produce elemental sulphur that is recycled back to the H2S biogeneration step ? Electrowinning of copper fluoborate solution in a diaphragm cell with the ECUPREX® Process, producing copper cathodes and regenerating the ferric fluoborate solution to be recycled back to the leaching step ? Biogeneration of H2S from the elemental: sulphur generated during the leaching step, with the nutrient source for the anaerobic bacteria selected form a wide range of organic substances and/or some industrial by-products containing carbon and hydrogen This paper describes all process steps with particular reference to the biological H2S generation technology. Also discussed' is the capability of the ECUPREX® Process to treat copper sulphide concentrates and copper matte.

Jan 1, 1999

By L. Cifuentes

Electrodialysis (ED), i.e. a technique based on the effects of electrically charged membranes on ions in solution in an electric field, has been applied to Cu-Fe-As-Sb- H2SO4 electrolytes similar to those used in copper electrorefining and electrowinning operations. The effects of current density, time and species concentration have been studied in a batch ED cell. The technique has shown to be effective in concentrating and separating a range of ions and points to possible new methods of treating copper electrometallurgy effluents.

Jan 1, 1999

By M. T. Ityokurnbul, M. P. Trubelja

Concentrate flow rates were measured for the flotation of -100-mesh Lower Kittaning coal in a computer-controlled 0.076 x 3.5-m pilot flotation column. The variables studied were recovery zone height, airflow and solid feed rates. The specific projected surface areas of the feed, concentrate and tailing streams were determined from the measured particle size distributions. The results obtained show that the concen¬trate flow rate was independent of recovery zone height but was dependent on the hydrostatic pressure setting (measure of froth depth), gas flow rate, solid loading and particle size. New correlations for column carrying capacity and yield are provided as a function of bubble surface area flux and the specific particle projected surface area.

Jan 1, 1999

By Emil B. Milosavljevic, Ljiljana Solujic

Cyanide is exceptionally reactive, and in typical gold/silver processing liquors, cyanide may be transformed into various species and forms depending on the mineralogy of the ore and chemical make-up of the process water. The exact speciation and relative concentrations depend on the Eh and pH values, as well as the free CN concentration in the system. Very good cyanide balances can be achieved by the judicious selection of the analytical techniques used. The choices an analyst has to make (which analytical methods to use and which ones to avoid) in order to gain better understanding of cyanide speciation and balances in a particular system under investigation will be discussed. Examples of cyanide balances obtained for the laboratory scale tests (agitated leach and column tests) will be presented and discussed.

Jan 1, 1999

By R. L. McNearny, K. A. Barker

A study was conducted to compare physical and numerical models of the block-caving mining method. Results from the numerical analysis closely simulated the blocky behavior of the physical model, including bridging and interlocking of the simulated orebody during draw. The draw-down patterns and the rate of draw developed during numerical modeling also closely simulated the physical models. An unexpected result from the numerical modeling was the development of a zone of downward deflection which preceded the development of the zone of material movement.

Jan 1, 1999

By Iain B. Mackenzie

In 1997, a thin layer of Microtherm Microporous Insulation was used to replace fireclay brick behind the magnesia/chrome working lining in #5 refining furnace at BHP?s San Manuel AZ smelter. A 23°C reduction in shell temperature was obtained, together with a large increase in the working capacity of the vessel. There was no sign of metal penetration as a result of the increased insulation. Following these highly favorable results, BHP have introduced this product into all of their refining furnaces.

Jan 1, 1999

By Hiroyuki. Fukuyama

The pseudo-binary phase diagram of the cuspidine (3CaO2?SiO2?CaF2) - CaF2 system has been studied by electron probe microanalysis (EPMA) and X-ray diffractometry (XRD). To prevent fluorine loss in the form of a HF gas by a reaction of CaF2 with water vapor at elevated temperatures, the equilibrium experiments were conducted with the sample hermetically sealed in a platinum tube. By employing this technique, it was successfully revealed that cuspidine exists as a stable phase and congruently melts at 1684 ± 1 K, and the cuspidine - CaF2 system presents a simple eutectic type of phase diagram, of which eutectic temperature has been estimated to be around 1540 K, corresponding to the composition of 40 mass% 3CaO?2SiO2 - 60 mass% CaF2?

Jan 1, 1999

By E E. Cloete, R I. McCrindle

Permitted explosives were previously nitroglycerine based and cap sensitive. Due to safety, health and environmental requirements, water-containing explosives, such as watergels and emulsions, were used instead. However, in order for these explosives to perform at their designed level during blasting, a more powerful stimulus than is delivered by detonators on their own is required.

Jan 1, 1999

By David G. Paton

"Electromagnetic surveys were conducted at the BXL Bulk Explosives Limited Mixing Plant andsurrounding area to characterize runoff from the site and possible impacts of salinity. The BXL Plant is located at the edge of a depressional area and any escape of soluble ions, such as nitrates, would have ended up in the slough to the west of the plant. Two electromagnetic (EM) instruments were used in the survey. A Geonics EM 3 1 was used in October 1997 and in June 1998, a new multifrequency instrument, a GSSI GEM 300 was also tested. Both instruments were individually mounted on a plastic sled with Teflon runners and towed with an ATV quad. Position was determined using a Trimble Pro XL global positioning system (GPS) with a real time correction mode Landstar receiver for an accuracy of about *l m. Both GPS and EM instruments were set to collect data at 1 second intervals. The quadrature maps for both instruments showed essentially the same information, namely of very high conductivity, appearing to emanate from the mixing plant. The levels of conductivity were highest where the saline water appeared to pool, at the southern end of the slough. Soil sampling locations were identified from the EM maps and navigated to using the real time GPS. Composite samples were collected by hand using a Dutch auger, from two locations, in increments of O-1 5, 15-30, 30-60 and 60- 90 cm. The analysis of the soil samples indicated a complete absence of nitrate or ammonium ions; the major anion was sulphate, indicating naturally saline subsoil conditions. The GEM 300 made the collection of data more efficient, as only one pass was required to collect the data from four depth intervals. The EM survey combined with the real time GPS allowed rapid characterization of the site with respect to soil salinity and proved to be cost-effective for Phase l/ Phase 2 site assessments and targeting sampling locations."

Jan 1, 1999

By R. Q. Honaker

Until recently, the application of the Jameson Cell technology in North America has been restricted to minerals processing. Recently, laboratory, pilot-plant and full-scale testing has been conducted to assess the Jameson Cell's ability to effectively treat fine coal. Based on the data, carrying-capacity relationships have been developed. In addition to its operational simplicity, the Jameson Cell has the ability to provide a separation efficiency near the theoretical separation performance on the basis of ash rejection while achieving a relatively high throughput capacity Tie results obtained from the various fine coal cleaning applications in North America is presented in this publication.

Jan 1, 1999

By M. J. Perpich

Electrochemical and chemical leaching tests were carried out on chalcocite, covellite and chalcopyrite in acidified iron sulfate solutions sparged with a mixture of O2 - SO2. The gas mixture catalyzed the ferrous to ferric oxidation reaction in situ and, therefore, increased the redox potential and oxidizing strength of the solution. Anodic polarization curves in dilute sulfuric acid on copper sulfide electrodes showed that chalcopyrite passivates and dissolves at current densities orders of magnitude less than chalcocite and covellite. The addition of a depassivating agent (Ag+) increased the passive current density of chalcopyrite and caused breakdown near 0.625 V (SCE). The depassivating effect was also observed during the leaching of chalcopyrite particulate samples as small amounts of Ag+ added to acidified iron sulfate solutions in the presence of O2 - SO2 mixtures greatly increased the leaching rate and the total amount of Cu oxidized (> 90%). Passivation was prevented in the absence of Ag+ by decreasing the initial oxidizing power of the solution and by pretreating the sample in a reductive leach. Both of these methods resulted in transformation of the chalcopyrite surface from its characteristic greenish-gold into deep black. Increased concentrations of Fe+++ due to 02 - S02 sparging were then able to oxidize the transformation product.

Jan 1, 1999

WMC was a late entrant into Indonesia in mid-1996, but had considerable experience and success in exploring in Asia, particularly the Philippines since 1988. Given the geological similarities to the Philippines and IndonesiaÆs superior æcradle to graveÆ Contract of Work (CoW) tenure system, the entry into Indonesia was a logical decision but nonetheless a result of detailed planning. At the time of WMCÆs entry, Busang in Kalimantan was still a 60 moz wonder and the euphoria of this apparent discovery had overflowed into every aspect of exploration. Many junior mining companies and tenement speculators were clamouring for properties in Kalimantan, whilst other serious and capable explorers had to compete for properties and exploration personnel in an era of high and often unrealistic expectations. The picture in late-1998 and through 1999 is dramatically different, as the worldwide downturn in the price of most metals coincides with financial and social crises throughout most Asian countries. The impact of this has been particularly severe in Indonesia and when coupled with the negative sentiment of the Busang fraud has resulted in an exodus of junior companies and also some of the majors. This is understandable given the much publicised social unrest, uncertainty of government, mooted changes to the eighth generation CoW, increasing illegal mining and heightened community expectations. The reality however is somewhat different and although clearly a crisis in many respects, it is also a time of great opportunity.

Jan 1, 1999

By P. J. Cook

Comminution is one of the fundamentals of mineral processing, requiring large expenditures to be made on capital equipment, installation, power and maintenance. The trend toward lower grades and higher operating costs, mean mining operations are becoming increasingly marginal. The challenge is to improve and more importantly, utilize crushing and milling technologies that provide for reduced capital and operating costs whilst providing increased unit efficiencies. The Svedala Barmac Autogenous Crushing Mill presents such an opportunity by providing many of the cost savings and production increases required by its ability to produce a finer mill feed size and realize reduced energy consumption. This paper briefly describes the operation of the Svedala Barmac Autogenous Crushing Mill and reviews its benefits towards improving the efficiency of crushing and milling operations.

Jan 1, 1999

By William Petruk, J. H. Gilles Laflamme, Jean Robitaille, Louis J. Cabri

"A quantitative mineralogical study using ore microscopy, electron microscopy, proton-microprobe, image analysis, and material balances was done on samples from the circuit of a concentrator in Quebec, with particular emphasis on the Cu concentrate. The ore contains many different minerals, of which the principal ones, in decreasing order of abundance, are pyrite, sphalerite, chalcopyrite, bornite, galena, tennantite, and pyrrhotite. Minor to trace amounts of covellite, chalcocite, stannoidite, mawsonite, colusite, wittichenite, miharaite, hessite, petzite, electrum, and an unidentified Cu-Pb-Bi-sulfide also occur.Liberation of pyrite is very high in all size fractions for all samples (ranging from 80-91 %). Liberation of chalcopyrite, bomite, sphalerite, and tennantite is relatively high, on average, in the head .sample and Cu concentrate (55-78% and 66-88%, respectively). Most of the chalcopyrite in the flotation tails is not liberated, whereas about one half of the tennantite and sphalerite are liberated in both the flotation and :final tails. Recoveries calculated for the Cu concentrate (on the basis of assays, mineralogy, and image analysis) are chalcopyrite 72. 5%, bornite 73. 7%, sphalerite 41.0%, tennantite 70.9 %, and galena (together with some trace minerals) 34.2%. It was also calculated that the Cu concentrate contains 10.0 % of the pyrrhotite and i.4 % of the pyrite.Materials balance calculations were done on the five major sulfide minerals to determine the mineralogical distribution of 13 major, minor, and trace elements (as determined by protonmicroprobe analyses). It was determined that tennantite is the principal carrier of Bi (67%), As (90%), and Te (86%) in the Cu concentrate. Therefore, removal oftennantite, which is mostly liberated in the Cu concentrate would significantly reduce these three contaminant elements, but at a loss of9% of the Cu, 2.0% of the Zn, and 0.7% of the Ag. The precious metals (Au, Ag) occur as discrete minerals (electrum, petzite, hessite). Some of the Ag also occurs in solid solution in bornite (23.1% of Ag in Cu concentrate), tennantite, and sphalerite. Four of the major sulfides (chalcopyrite, bomite, sphalerite, tennantite) in the ore also contain measurable concentrations of the following trace elements: Se, Cd, In, Sn, and Sb, occurring mostly as solid solutions. Some of these elements are also concentrated (up to about 18%) in minor and trace minerals such as colusite, stannoidite, and mawsonite."

Jan 1, 1999

By Fathi Habashi

"On August 3, 1888, German Patent No. 43977 entitled ""A Process for the Production of Aluminum Hydroxide"" was issued*. The discovery which led to the patent was made by the Austrian chemist Karl Josef Bayer (1847-1904) (Fig. 1) who was at that time in Russia, and the process became known as the Bayer Process in his honour(1)(2)- The process imediately achieved industrial success, displacing the pyrometallurgical process that had been used until that time to produce alumina. The Bayer Process involved the pressure leaching of bauxite with NaOH solution to obtain sodium aluminate solution from which aluminum hydroxide was precipitated by seeding. Today bauxite is not only the principal source of aluminum but also of gallium, both metals being effectively recovered by the Bayer Process. The purpose of this paper is to outline the historical background of this discovery and its importance to hydrometallurgy."

Jan 1, 1999

By Ray E. Harris

All of the major raw materials (silica, soda ash, limestone, and feldspar) needed to manufacture most grades of glass are found in Wyoming. Additional advantages for the manufacture of glass include the state's geographic location, a well-developed transportation network, a favorable tax structure (no corporate or personal-income tax), and low energy costs. Inadequate local markets and prohibitive transportation costs to other markets have been the major obstacles to developing a glass industry in Wyoming, the least- populated state in the nation. The Rocky Mountain region only recently became a major market for glass, especially for the Colorado Front Range and Utah's Wasatch Front. Currently, changing costs of the production of glass, an increased market for con- tainer glass in the Colorado Front Range, and innovative production and transportation ideas (e.g., production of selected types of glass and bulk shipments of specification-glass pellets) favor developing a glass plant in Wyoming. Thus, the Wyoming State Geological Survey (WSGS) and other state agencies have been conducting studies and contacting investors in an effort to attract a glass-manufacturing plant to the state. Between 1987 and 1993, three locations of silica-sand and -rock deposits were studied in Wyoming (Cassa, Plumbago Creek, and John Blue). Funding was provided by the WSGS operating budget and local and state Department of Commerce economic- development grants. The reports on these areas were released between 1988 and 1993. In 1988-89, a California-based company conducted additional drilling and feasibility studies and prepared to construct a glass plant in Cheyenne, using the Cassa silica source. However, due to losses incurred by some of their other investments, the company did not proceed. In 1997, the Wyoming Science, Technology, and Energy Administration (STEA) contracted a market study for glass manufactured in Wyoming, using information provided by the WSGS. The STEA contacted several major glass producers, and a major glass-producing company began feasibility studies in January 1998, for the construction of a glass plant. In June 1998, bids to supply brown beer bottles to the Budweiser brewery northeast of Fort Collins, Colorado, were submitted by at least two companies that were considering glass-plant sites in Wyoming.

Jan 1, 1999

By J. E. Friant

The Mini-DiscTM cutter drill bit is a radical design departure from the traditional tri-cone rockdrill bit. Miniature disc type cutting tools as small as 3.25 inches (82.5 mm) diameter are fitted to a bit body to cut individual concentric kerfs. The action is the same as that commonly used on large tunnel boring machines but miniaturized. The high performance rate and efficiency of a disc cutter are the result of producing a large proportion rock chips rather than sand or powder. The Mini-DiscTM drill bit, referred to as the “Disc Bit” has other unique features as well. It can be re-greased between runs. It can be rebuilt in the field in about 15 minutes, cutters can be replaced and the Disc-Bit appears to require less down hole hydraulic power than conventional bits. Thoroughly tested in the laboratory, the bit has recently been undergoing field trials in well drilling, blast hole drilling and shaft drilling. As any engineer knows, the laboratory can not shake out all the problems but it eliminates the more glaring weaknesses. Performance results have been exhilarating, and a few mechanical problems were discovered and largely overcome. This paper is a progress report.

Jan 1, 1999

By S. A. Davis

In July of 1996, the Kroll process began production again at TIMET's Henderson, NV, manufacturing facility. This, after being shut down for several years due to low market demand for titanium. Faced with limited pond capacity and increasing costs for water and wastewater disposal and storage; process changes were made to recycle water used to wash Kroll titanium sponge back into the sponge leaching process. This idea was revisited from 1992-93, when three consecutive attempts to recycle water for this application were unsuccessful due to early pump failure. Since it was uncertain why previous attempts failed, a complete understanding of the existing system was first sought. This included reviewing piping and flow diagrams; taking field measurements for all the piping, valves, and fittings; analyzing the wastewater composition; and modeling the fluid dynamics and control of the system. The fluid dynamics of the system were modeled by breaking the piping network up into nodes and applying the Bernoulli equation to each segment. The fluid flowrate control valves were modeled for this purpose also and the models were used to help specify the required processing equipment and control ranges and tolerances. Once the project was completed, an operating procedure was prepared for operation, startup, and shutdown of the washer water recycle system.

Jan 1, 1999

By Osvaldo A. Bascur, J. P. Kennedy

Companies have installed powerful desktops for their personnel and instrumentation and control systems in their plants. These desktops are, in many cases, connected to a company intranet. Still, process engineers have to obtain their data manually. Engineers use process calculations from manually calculated averages from the plant; field operators collect equipment data on log sheets; and maintenance engineers collect critical information on log sheets. All of this information resides in individual machines. What are the strategic tools that will enable collaboration between them? How can operators, engineers, and managers access plant information to proactively increase their effectiveness in process troubleshooting, plant debottleneclung, aligning with business strategic and customer demand, satisfying environmental and safety regulations, developing capital projects, and implementing control strategies? A nonintrusive environment at the desktop is required to provide the process information to these workers. How can value be added to MS Windows technologies with the legacy systems at a minimum cost? There is no straight answer; however, there is a proven framework to leverage the large investments in new technologies. Objects and components are changing the way everyone relates to their computer and networks. Three examples will be described to demonstrate paradigm change. Today, process engineers can access data at the required level of detail for analysis of critical process variables at their desk or remotely. 1. Process Troubleshooting and Analysis: The engineer can develop an inferential calculation, trigger a process advisor to deter- mine the behavior of the units for the last day, and get the population of a set of batches (heats, blocks, rolls, sheets, etc). 2. Process Control and Optimization: The engineer can connect to a process simulator at steady state or a dynamic simulator of the process to evaluate new control strategies or process unit line-ups and use the process simulator as a process observer for fault diagnosis. 3. Collaboration with Accounting and Maintenance: The engineer can review reconciled data and the process mass balances, suggest maintenance cleaning or recalibration of flowmeters, and evaluate key control performance of all advanced controls.

Jan 1, 1999

Open pit optimization and mine design depend upon a realistic estimate of the grade-tonnage dis¬tribution. The estimate should reflect what can be reasonably recovered and processed. The McCoy/Cove operation in central Nevada is a gold and silver mine. Recoverable reserve estimations of gold and silver were made using indicator kriging and the indirect log normal variance correction to construct the grade- tonnage distribution. Optimal pits were generated using this distribution, and the results were compared to the pits generated by ordinary kriging and indicator kriging block mean methods. The results indicate that the proposed method for multimetal recoverable reserve estimation shows an improvement in terms of predicting the recoverable tons and grades. The optimal pits generated from the recoverable resource model are larger than those generated by the ordinary kriging and indicator kriging block mean methods. This model maximizes the overall recovery of the mineral resource.

Jan 1, 1999