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By Chr. Kersch

This project further develops supercritlcal fluid extraction as an industrial soil remediation process. Heavy metals are removed from sand using CO2, The effect of the type of complexing ligands, pressure and water content on the extraction efficiency is investigated.

Jan 1, 1999

By Harry C. Oussoren, James C. Miles

A new seven kilometer long subway line is being constructed through dense glacial soils under a major thoroughfare in Toronto. Eductor, deep well and vacuum wellpoint systems are being used to lower the water levels by as much as 16 metres for the construction of the twin tunnels and associated structures. The design and performance of the dewatering systems will be described. Unanticipated difficulties and their solution will be presented.

Jan 1, 1999

By H. Simonsen

Risk assessment consists of a search for the answers to: ?What can happen? ?How likely it is that it can happen? ?What are the consequences if it does happen? Perhaps the most important aim of risk analysis is to predict the likelihood that a planned profit will be achieved over a given period of time. A typical risk model employed for this purpose includes a stochastic connection between the dependent variable of an expression that describes a process and independent variables represented as random quantities. The output will be a probabilistic distribution. The uncertainties in a planned mining operation include: ?Commodity market characteristics, particularly price ?Ore reserves and mineralogical composition ?Mining method ?Process performance ?Capital and operating costs ?Schedule duration ?Economic environment effects. The processes employed in the probabilistic estimation of a project?s outcome include both Monte Carlo simulations and simulations where variable correlation is considered important. The risk model, once developed and tested, provides a framework for a rational approach to risk analysis and the testing of alternatives.

Jan 1, 1999

By David R. Klug, Chris Gause, Troy L. Page

The Inter-Island Tunnel is one of two undersea tunnels which are part of the Boston Harbor Clean-Up Program. The tunnel is 7.7 km (25,160 ft) long, bored to a 4.3 m (14 ft) diameter in the Cambridge Argillite Formation and was finished to a 3.5 m (11.5 ft) diameter final concrete lining. The owner is the Massachusetts Water Resources Authority (MWRA) who is a regional authority responsible for overall design and construction. The tunnel's primary purpose is the transport of untreated effluent from Nut Island facility in Quincy, MA to the new treatment plant at Deer Island. Two sludge lines are installed for the transport of sludge from Deer Island to Nut Island. During construction the contractor encountered fault zones, fractured strata, and soft ground tunnel sections which liberated more ground water than was originally anticipated by the project designer. Ground water was controlled during mining and the placing of the final lining. The final lining of cast-in-place concrete had to be backfill grouted to cut off water inflows and provide contact for equal tunnel loading which is critical in long-term design. This paper deals with an engineered backfill grouting system which was the first of its type to be used in North America. It discusses the geological conditions encountered, the design criteria used in the evaluation process, and an indepth review of the various system components. It demonstrates how contractors can use knowledgeable and professional industry suppliers to solve difficult construction problems.

Jan 1, 1999

By M. Hancer

The sign of the surface charge of selected potassium soluble salt minerals namely KClO4 , K2SO4 , KNO3, and KCl was determined from nonequilibrium electrophoresis measurements and found to be negative for each of the salt. Dodecylamine flotation of these salts revealed that the concentration of amine required for flotation increases in the order KClO4< K2SO4< KNO3<KCI. Precipitation of the amine collector colloid was not required for flotation of the oxyanion salts and in this case it appears that adsorption of the dodecylamine cation is sufficient to create the hydrophobic surface state. The order for flotation is explained in terms of surface hydration of these respective potassium salts based on contact angle measurements and FT Raman spectroscopic characterization of water structure.

Jan 1, 1999

By J. E. Lees

Advanced remote sensing can be a powerful new information tool to help private and public entities make better environmental and resource management decisions. However, some regulated entities are reluctant to develop or use this tool because of their concerns that it will lead to increased risks and costs of environmental legal liability. They fear that new ways of monitoring the environment will increase liability, undermine existing enforcement agreements, reopen compliance agreements, and generally provide a competitive disadvantage to early adopters by accelerating environmental cleanup costs. Others counter that the increased risks are marginal, and that several advantages outweigh these risks, including the opportunity to more effectively manage environmental operations, target and set priorities, measure and track management and compliance effectiveness, provide more defensible environmental assessments and baseline conditions, make and defend optimal siting decisions, and avoid or resolve environmental disputes. This paper offers strategic advice on ways regulated entities can enjoy the benefits of these powerful new information tools while mitigating down-side legal and compliance risks as much as possible.

Jan 1, 1999

By J. E. Lees

Advanced remote sensing can be a powerful new information tool to help private and public entities make better environmental and resource management decisions. However, some regulated entities are reluctant to develop or use this tool because of their concerns that it will lead to increased risks and costs of environmental legal liability. They fear that new ways of monitoring the environment will increase liability, undermine existing enforcement agreements, reopen compliance agreements, and generally provide a competitive disadvantage to early adopters by accelerating environmental cleanup costs. Others counter that the increased risks are marginal, and that several advantages outweigh these risks, including the opportunity to more effectively manage environmental operations, target and set priorities, measure and track management and compliance effectiveness, provide more defensible environmental assessments and baseline conditions, make and defend optimal siting decisions, and avoid or resolve environmental disputes. This paper offers strategic advice on ways regulated entities can enjoy the benefits of these powerful new information tools while mitigating down-side legal and compliance risks as much as possible.

Jan 1, 1999

By J. L. Jambor, H. W. Nesbitt

Oxidative dissolution of pyrrhotite and pyrite is largely responsible for the sulfate-rich waters of the vadose zone in the Waite Amulet tailings. Although the shallowest of the sulfate-rich waters are of the Fe-SO4 type, they change to Mg-SO4-type, near-neutral waters within 1-2 m of the tailings surface. Phyllosilicates and amphiboles are the only minerals present in sufficient quantity to ameliorate the amount of acidity produced. X-ray diffraction and microscopic studies of bulk sample indicate that quartz, chlorite, talc, amphiboles, magnetite, albite, and micas are the major and minor non-sulfide minerals, but their variations with depth do not give clear indications of depletion in the vadose zone. Mineralogical and bulk chemical compositions of the tailings confirm that Fe2O 3 has accumulated in large quantity in the vadose zone, with the Fe having been derived from Fe sulfides. When the effect of Fe2O3 is accounted for, the bulk compositions suggest that SiO2 is slightly more abundant in the vadose zone than in the saturated zone. This may be the result of residual enrichment of siliceous minerals such as quartz and albite in the vadose zone. Weathering of the tailings since the cessation of deposition in 1962 has resulted in a well-defined zone of sulfide depletion and secondary sulfate-mineral development. Although some silicate dissolution is indicated by pore-water compositions, the role of silicates in providing neutralization seems to have been minimal. The contribution by silicate minerals in laboratory tests of neutralization potential may be excessive relative to that in natural settings.

Jan 1, 1999

By Hu Long

Pyrite, as the host mineral in refractory gold ores and concentrates, has been treated by pressure oxidation in sulfuric acid solutions at temperatures above 180°C to liberate gold prior to cyanidation since the 1980&apos;s. However, no data is available on the kinetics of pyrite during acid pressure oxidation over the temperature range of 180 to 230°C which is the range employed by most commercial plants. The dissolution of pyrite (FeS,) in sulfuric acid solution under oxygen pressure was investigated at temperatures ranging from 170 to 230°C. The effects of temperature, particle size, agitation speed, oxygen partial pressure, and pulp density were evaluated. The effects of foreign ion addition and the concentration of sulfuric acid were also examined. The apparent activation energy was estimated to be 42.6 kJ/mol in the temperature range 170 to 230°C. The reaction orders with respect to particle size and oxygen partial pressure were found to be -1.5 and 0.5 at 210°C, respectively. Experimental evidence suggests that the kinetics are limited by the surface chemical reaction initially, and then also to some extent by the diffusion of ferrous ions away from the particle surface.

Jan 1, 1999

By N. Choi, W. D. Cho

Distribution coefficients of gold and silver between matte and slag during the pyrometallurgical treatment of nickel-copper sulfide concentrates were evaluated as a function of matte and slag compositions in the temperature range of 1,250oC to 1,300oC. It was observed that the composition of the matte phase, including matte grade and copper content in the matte, significantly affected the distribution behavior of gold and silver in the matte-slag system. Both gold and silver preferentially concentrated in the matte phase as the matte grade increased With increasing temperature and copper content in the matte, the distribution coefficients of silver increased, while the gold distribution coefficients decreased. It was also, found that slag additives such as CaO, MgO, and A12O3 caused a significant decrease in the solubility of both gold and silver in silica-saturated iron silicate slag. An activity coefficient of gold in matte was derived from the experimenta1 results.

Jan 1, 1999

By A. W. Laughlin

Laser-Induced Breakdown Spectroscopy or LIBS can be used to provide exploration companies with precise and accurate chemical analyses in the field, in real-time, resulting in major time and cost savings. Using a Field-Portable Analyzer (FPA), anomalies can be followed up immediately while crews are still in the field. Lower limits of detection (LLDs) are element dependent, but many are sufficiently low to be useful in exploration. LLDs in ppm for selected elements of interest are: Be-2, Cu-3, Zn-20, As-200, Sb-500, Pb-30, Ag4, Mo-100, B-33, Ti-500, V-350, and Cr-1. LIBS analyses require little or no sample preparation.

Jan 1, 1999

By Tsuneyoshi Funazaki, Takayoshi Nakamura, Keizo Miki, Takashi Imaishi

The underground portion (about 10 km) of Tokyo Wan Aqua-Line consists of eight shield tunnels connected with Kawasaki Man-Made Island in between, at four underground locations. The connection work had to fulfill strict precision and safety requirements in the ground about 60 m below soft seabed, but was completed successfully in May 1997. This report describes the connection work in detail, featuring the method of investigating shield machines’ relative positions, ground freezing method and connection mechanism and procedures. It also mentions the present state of Tokyo Wan Aqua-Line that was put in service on December 18, 1997.

Jan 1, 1999

By O. C. Rojas

Improvements and modifications on lay out and process, from 1997 till 1998, are presented. Based on a Teniente Converter, started up 1993, a Strategic Development Plan was structured to increase the production efficiency and comply with the enviromental regulations, too. It considered the oxygen supplies to the Teniente Converter and Peirce Smith converters; reverberatory furnace shut down as a smelting unit; and the Teniente converter slag treatment through a combined process between a Slag Settler furnace and flotation. Also it included the off-gas handling and treatment.

Jan 1, 1999

By R. K. Hill

The Hidalgo Smelter successfully reduced operating costs by 25% compared to the previous two years through a focused holistic approach to development of its entire workforce. The first phase involved basic team training skills for natural work teams. The second phase provided leadership training via breakthrough education to 40 of the smelter leader-both hourly and salaried. The third phase stretched out the teams training to include rewards for performance that resulted in hourly teams converting to salaried status-part of a company wide initiative. The fourth phase saw 1998 become the "Year of Safe Cost Reduction" where 7 breakthrough projects focused on different areas of expenditure. Implementation of lean manufacturing as a tool for teams to truly get their arms around what they controlled, introduced accountability and responsibility for operating results at the team level. This will allow the release of experienced supervisors from this role, to a pool of technical expertise, where our future breakthroughs will be designed and implemented.

Jan 1, 1999

By D. Royston, D. Denlay

Pulp lifters are used to discharge ground pulp from non-overflow grinding mills. In straight-radial channel pulp lifters, discharge is often incomplete and back-flow down the pulp lifter can occur. Leading-curve channel pulp lifters can be used to ensure complete discharge, especially at high mill rotational speeds. The complex motion of solid materials in pulp lifters has been modelled mathematically for both straight-radial and curved pulp lifters in order to make comparisons between the two types. The model is supported by practical observations of the performance of curved pulp-lifters in a commercial 24ftSAG Mill as well as observations of the discharge from several commercial straight-radial pulp-lifter AG/SAG Mills.

Jan 1, 1999

By Garland Likins

Where soil conditions are favorable, augercast piles have significant economic advantages, but they also have some uncertainty due to the in construction methods. To confirm structural integrity, static testing can be performed on a small sample of piles. Other Non-Destructive Evaluation methods like Pulse Echo are frequently specified for a large percentage of the remaining production piles. However, such NDE methods require testing the pile after the grout/concrete has hardened. If problems are found, then the repair or replacement can be relatively expensive. The confidence in the quality of these piles can be improved by automatically monitoring the grout pumped as a function of depth during the grouting phase of installation. If a low grout volume is detected, the pile can be redrilled and regrouted immediately while the piling rig is still in place and the grout still fluid. This considerably reduces remedial costs. To be effective, such installation monitors must accurately determine both grout volume and depth during installation and be rugged simple to operate. Such an equipment can be of great help to the installation crews. The assurance gained may reduce the need for subsequent NDE tests. The quality of inspection of driven piles depends heavily on the inspection personnel. While inspection is critical in a good installation, it is sometimes assigned a low priority. Inspection personnel in many cases are technicians with little pile experience. They may not understand the project needs or even how the pile driving equipment works. The task is often monotonous and any distraction makes accurate record keeping difficult. In some cases inspection is totally ignored for lack of qualified personnel. Electronic systems can automatically and accurately monitor driven pile installations and include documentation of certain hammer performance parameters. This paper describes equipment available and routinely in use for automated monitoring of both augercast and driven piles and demonstrates applications on typical construction sites. The paper also discusses benefits and limitations of the alternative NDE tests. KEYWORDS: Augercast Piles, Piles, Installation Monitoring, Pulse Echo Method, Integrity Testing

Jan 1, 1999

By Leslie Burnside

Homestake Mining Co. set out to complete final reclamation at a former open-pit gold mine in west central Nevada. The goal was to exceed regulatory standards by satisfying the company&apos;s own high corporate standards for successful reclamation. Homestake&apos;s completion requirements challenged available technology due to the unsuitability of heap material as a growth medium, the harsh environmental conditions of the site and the region&apos;s lack of native growth medium. Accomplishing these goals required enlisting a multidisciplinary project team to develop, test and implement appropriate and cost-effective revegetation alternatives.

Jan 1, 1999

By Theodore C. Hile, Floyd P. Henry, Ken Gragg

"Conventional explosive-storage methods usually rely on combinations of earth and concrete barriers, along with sufficient distance between limited explosive loads, to avoid accidental conflagration. However, under many circumstances, Air National Guard (ANG) facilities co-located with civilian airfields have trouble meeting necessary Quantity-Distance (Q-D) requirements for Explosive Hazard Class/Division 1.1 and 1.4 materials. Because of the danger posed by explosives stored in earthcovered magazines (ECMs) too close to civilian activities, ANG units often find itdifftcult to maintain adequate stores of ordnance needed to meet unit mission goals."

Jan 1, 1999

By E. M. R. Santos

Acid mine drainage (AMD) is a serious environmental problem in mining activities. Prediction is the first step for evaluate the potential of acid generation and there are some possible methods to estimate it. They are described as static tests, which examine the balance between acid producing and acid consuming materials, and kinetic tests, which attempt to predict drainage quality over time. Static methods are very simple and give a qualitative classification of the ores based on their potential to generate acid drainage. The characterization of ores to determine their acid producing potential is vital for the prevention of long term environmental liabilities. Laboratory tests were conducted under different methodologies to predict the acid producing potential of sulphide overburden, ore materials and tailings from a deposit of copper ore.

Jan 1, 1999

By D. A. Robbins

The application of remote sensing for environmental measurements is already being utilized. Aircraft mounted imaging spectroscopy has been utilized to evaluate areas of historical mining operations as well as active mine sites. To the extent that remote sensing can provide more sensitive, cost effective, and timely monitoring potential, the technology is of interest to the industry. Questions remain about the application and validation of the data and the availability of the technology in the private sector. This presentation will discuss some of the potential uses, benefits, and concerns related to remote sensing and efforts to monitor the technology&apos;s development.

Jan 1, 1999