A Novel Solvent Extraction Process with Bottom Gas Injection in a Horizontal Contactor

A novel solvent extraction process, called the SOHNEX process, has been developed at the University of Utah. In this process, the organic and the aqueous phases flow countercurrently in a horizontal vessel, and the emulsion between the two liquid phases is generated by high-velocity gas jets injected at the bottom. The gas jets are located at certain intervals along the bottom of the vessel with phase disengagement zones on either side of the plume zone created by the gas jet. The system is simple, having no mechanical moving parts or complex internal structures, and yet provides good contact between the phases with minimal backmixing. Tests have shown that emulsions with a wide range of specific interfacial area, including that typically encountered in mixer-settlers, can be generated in this process. It has significant built-in flexibility of operation including the control of the flowrate and hold-up of each liquid phase. The SOHNEX process overcomes the difficulties in the operation of conventional solvent extraction equipment such as mixer-settlers and column extractors. A major advantage of the SOHNEX process is that the energy of mixing can be closely controlled by adjusting the strength of the gas jet. This allows an optimal control of the drop-size distribution of the dispersed phase and thus the specific interfacial area. The process is continuous, and any number of extraction and separation stages may be built into a single vessel. The gas can be recirculated in a closed loop, thus eliminating solvent loss and mist problems, especially for high-temperature operations. The SOHNEX problem can handle solutions that contain suspended solids and that form third phases. The simplicity of the equipment and operation with low maintenance will mean much reduced capital and operating costs as well as low environmental risks and improved safety. The SOHNEX process has been tested for continuous copper extraction from a dilute solution. Calculations also showed that uranium and other radioactive elements can readily be extracted in a small unit of the SOHNEX extractor while satisfying the nuclear criticality condition.