Search Documents

By J Webb

Anoxic limestone drains (ALDs) have been widely used in the passive treatment of acid mine drainage (AMD), but their effectiveness has often been less than anticipated. Iron hydroxide often precipitates around limestone particles and inhibits neutralisation. To determine the conditions under which iron hydroxide precipitates, a small-scale laboratory ALD system was built to enable a detailed examination of the chemistry of iron within the drain. For one experiment, a mixture of limestone and quartz was introduced to the drain to assist in the determination of the key mechanism governing iron precipitation. Synthetic anaerobic acid mine drainage containing Fe2+ (~130 ppm), SO4 2- and H+ was pumped at a rate of 30 mL/min up a 90 cm tall, 15 cm diameter vertical column filled with limestone gravel of 98 per cent purity. Three sampling ports were fitted at equal intervals along the column; water was periodically extracted for analysis at the sampling ports over an 11-hour period. Experiments were run at influent pH levels of 2 and 4. Results show that acid neutralisation to pH greater than 6 occurred at the inflow end of the drain. The greatest amount of iron precipitation (19.5 per cent) also occurred in this area. The lack of iron precipitation on the quartz surfaces in the quartz/limestone mixture indicates that neutralisation is the key mechanism for the precipitation of iron hydroxide on limestone particles. A pe-pH stability diagram derived for the laboratory ALD system indicates that ALDs will not be effective for AMD with pH 2. Influent waters with pH 2 require a pe of -2 (Eh: -118.4 mV) to avoid Fe precipitation upon neutralisation. Influent waters of pH 4 require a pe between -2 and -4.

Jan 1, 2003

By Markus A. Reuter, Jacques J. Eksteen

The modelling of bath type furnaces tends to be either fundamental in nature or total empirical "black box models". While models of the first kind are robust, they tend to lack accuracy, in cases where they are to be used for process control, and may take an overly long in development time. On the other hand, black box models tend to lack robustness of prediction for all circumstances and tend to be limited to interpolate based on historical data. While this may very often provide short-term accuracy, the models may have problems with stability in the long term. Moreover, the model structure may not reflect any of the fundamental properties of the system and remains opaque to fundamental analysis. The aim of the model development is in obtaining a model that have robustness, high accuracy, a short development time and which is adaptive to a changing environment. The models are specifically developed for on-line decision support or control of furnaces. The modelling approach is evaluated for a chromite bath smelting furnace. The role of systems analysis, mass balance smoothing, thermodynamic analysis are integrated into one generic algorithm for bath type furnaces. Therefore, this paper argues that to understand complex metallurgical furnaces a hybrid approach is the only method to fully grasp the intricacies of metallurgy, to improve operations, economics as well as environmental performance.

Jan 1, 2003

A review of the most widely used global extraction sequences in sublevel is undertaken. The review includes techniques used to extract massive as well as single or multiple steeply dipping tabular orebodies. The paper also deals with thick flat lying orebodies suitable for open stoping. Techniques used to minimise the effect of stress redistributions on a global scale are discussed for all the extraction sequences analysed.

Jan 1, 2003

By A. E. M. Warner

Inco Limited has long and extensive experience in converting nickel-copper primary smelting mattes over a broad range of nickel/copper weight ratios and combined nickel-copper-cobalt contents. At the Copper Cliff Smelter, the composition of the converter product matte has to meet the requirements of the matte separation process; at the Thompson Smelter, converter matte of a different composition is cast into anodes for nickel electrorefining; and in Soroako, Indonesia, a very low copper product matte is granulated for the Japanese market. Recently, Inco has conducted pilot plant testing of three possible nickel-copper matte continuous converting routes, namely flash converting, oxygen top blowing-nitrogen bottom stirring, and tuyere blowing. This test work has generated substantial new information on nickel-copper matte converting chemistry. This overview paper reviews the metallurgy of nickel-copper matte converting, in particular the behaviour of cobalt and the operating conditions required to meet the iron and sulfur specifications of the product matte. The relevant thermodynamic information is used to discuss the industrial data.

Jan 1, 2003

During the period May to July 2003, East Mine overcored and recovered from goaf edges a total of 55 1.8 metre CVX grade bolts to analyse installation quality. Some 95 per cent of the pneumatically (hand-held Gophers) installed bolts show gloving, with 75 per cent showing gloving of at least one-third of the effective bolt length. Hydraulically installed (continuous miner-mounted bolting rigs) bolts show in some areas less gloving but do have significant unencapsulation lengths. Trials of newly developed bolt end profiles show considerable improvements in eliminating gloving but do show variable and unacceptable variations of unencapsulation.

Jan 1, 2003

By Mikiya Tanaka

This paper outlines our attempt to establish a recycle process of nickel in the spent baths and waste rinse water of electroless nickel plating plants using solvent extraction and solvent-impregnated support, Solvent extraction studies of nickel from actual spent baths revealed that (i) nickel is efficiently extracted by a hydroxyoxime extractant such as LIX84I at a pH greater than 6 and is readily stripped with sulfuric acid, and (ii) the mixtures of LIX63 and acidic organophosphorus extractants (D2ERP A, PC88A, and Cyanex 272) enhanee the nickel extraction efficiency to a sufficient degree without pH adjustment, but at the same time, reduce the stripping efficiency. The application of acidic organophosphorus extractants to selectively remove impurity metal ions (iron and zinc) from a real spent bath before extracting nickel lead to the finding that PC88A and Cyanex 272 effectively remove iron and zinc without pH adjustment leaving nickel in the raffinate. The removal of nickel from the waste rinse water was also studied. Solvent-impregnated supports with a macroporous resin and oil sorbents made of natural kapok fiber and synthetic fiber as supports were applied using D2EHPA and LIX860 as the extractants. During the batch operation, nickel is removed with a high efficiency without pH adjustment. During the column operation, however, the effective removal is hindered by (i) the dissolution of the nickel-D2EHPA complex into the aqueous phase in the high loading region, and (ii) the slow removal rate of the LIX860-impregnated support.

Jan 1, 2003

By Guo Xueyi

The reaction mechanism for the manganese dioxide reductive dissolution in acidic chloride media in the presence of ferrous/ferric ions are based on theoretical delineation and dual cell experiments. In terms of the Buttler-Volmer equation and chemical kinetic principles, a electrochemical kinetic equation was deduced, which successfully provided a theoretical basis for describing the role of Cl-, Fe2+, Fe3+ and H+ in solution, as well as their interrelationship in manganese dioxide reductive dissolution. Dual cell experimental studies indicate that the increases of Cl- and Fe2 in solution are helpful to accelerate the couple process; while, Fe3and Mn2+ hinder the coupled reaction to some degree. Higher acidity in solution is beneficial to the dissolution of MnO2. All the dual cell experimental results are consistent with the theoretical deduction. This study will be useful to understand the mechanism for the leaching of manganese nodules from the deep ocean, as well as the leaching of manganese dioxide ore from land.

Jan 1, 2003

By Pierre Pelletier, Julie Fournier, Gianni Bartolacci, Yves Breau, Dominique Girard, Ahmed Bouajila, Carl Duchesne

"The development of on-stream analyzers (OSA), such as those based on X-ray fluorescence (XRF), has been key to improve metallurgical performance of flotation processes. However, since these analyzers are shared between several streams, they typically provide grade measurements every about 10-15 minutes. In general, this frequency is too long compared to process dynamics and so, implementing an efficient feedback control strategy based on OSA can be difficult. In addition, due to the limited capacity of OSA systems, several important intermediate streams are not analysed, but could provide relevant information about the state of a flotation circuit.To overcome this problem, vision systems have been developed in the past to predict concentrate grade based on froth color – this could be very useful to control flotation performance between OSA measurements. However, applications reported in the literature typically use univariate summary statistics of the full red, blue, and green color distribution of froth images, while RGB images are truly multivariate. Although, in some cases, grade prediction was achieved with reasonable accuracy, one may, by using only summary statistics, miss important information about the state of the flotation process.This paper investigates the application of Multivariate Image Analysis (MIA) concepts to flotation froth images. These techniques are based on multivariate statistical methods such as PCA and PLS, which have the ability to analyze large databases (such as digital images) and summarize the relevant information content of the data into a small number of latent variables, capturing the most important features of the images for concentrate grade prediction. The potential of application of these methods in the mineral processing industry is illustrated using a few industrial case studies."

Jan 1, 2003

By Stephen L. Chryssoulis, Daniela Venter, Stamen Dimov

"Comparative surface analysis of floated and rejected free gold grains from a number of full scale benefication plants and from pilot plant testwork, has shown silver (the most common impurity in gold) and sulphur invariably in greater concentration on floated gold grains, implying that they assisted gold flotation (gold activators). Collector loading measurements on individual gold grains from concentrates of staged rougher flotation tests on a cyclone U/F product of a pyritic gold ore, revealed first progressively lower concentrations of the collector monomer on gold from each follow-up concentrate and secondly a direct proportionality between the surface concentration of silver and the collector monomer. These two observations leave no doubt that silver activates gold and that collector monomers play a significant, previously not fully recognized role in gold flotation.INTRODUCTIONGold to some degree is naturally floatable in industrial systems, which means that it can be recovered without collector addition (Marsden and House, 1992). This is due to the adsorption of hydrocarbons and deposition of sulphur, which are dependent on the metallic properties of gold, particularly its high electrical conductivity, which allows surface electrochemical reactions to occur catalytically and selectively. Cyclic voltammetry has shown that gold can be rendered hydrophobic by deposition of a surface layer of sulphur (Sº) from S2- and HS- solutions (Walker et al., 1984). Twenty monolayers of sulphur were required to produce a hydrophobic gold surface.However, no sulphide flotation plant relies solely on the natural floatability of gold for its recovery. Gold hydrophobicity is enhanced by the addition of flotation collectors such as xanthates (X), dithiophosphates (DTP), dithiophosphinates (DTPI), mercaptobenzothiolates (MBC) etc., as used in sulphide mineral flotation (Dekok, 1973: Adams et al., 1986). The mechanism invoked in enhancing the hydrophobicity of pure gold with the aforementioned four groups of collectors is similar to that of pyrite, whereby collector anions are oxidized at the gold surface to form dimers (Groot, 1987; Marsden and House, 1992; Basilio et al., 1992) As an example, xanthate ions are oxidized at the gold surface to form the neutral dimer dixanthogen (X2):"

Jan 1, 2003

By P Commander

Western Australia is a major exporter of minerals, which places significant economic and environmental responsibility on Government and the stateÆs mining industry. Moving into the 21st century, mineral production in Western Australia is $14 billion accounting for 50 per cent of the stateÆs export income. There are over 60 large-scale mining operations distributed throughout the arid regions of the state (less than 300 mm/year rainfall). There are four key mineral provinces in arid Western Australia including the Pilbara (iron ore), Murchison (gold), Northern and Southern Goldfields (gold and nickel). These provinces have significant differences, particularly in respect to groundwater demand from mining and mineral processing, aquifer systems that are utilised, and approaches to groundwater management. The arid nature of the stateÆs interior and subsequent lack of surface water resources has required substantial groundwater resource development by the mining industry. A variety of aquifers have been explored and utilised ranging from shallow alluvium and calcrete, discrete fractured zones in bedrock, concealed palaeochannels and inland sedimentary basins. Groundwater usage by the mining industry is about 150 GL/year with most abstraction related to mine dewatering, mineral processing and dust suppression. Groundwater abstraction in Western Australia is regulated by the Water and Rivers Commission. In the Goldfields, the depletion of brackish (>2000 mg/L) and saline groundwater from storage is permissible, as mining is considered the beneficial use for groundwater which may be as much as 200 000 mg/L. In contrast, the low salinity groundwater of the Murchison and Pilbara is allocated on a sustainable basis. The role of monitoring and ongoing aquifer reassessment is crucial in water management, in evaluating the condition and performance of stressed aquifer systems. Mining operations face a variety of water resource issues ranging from insufficient availability for processing to excessive mine dewatering. These issues also change as a mine operation proceeds through its development, commonly starting with a deficiency and moving into surplus as deeper pits require more dewatering. Operating mines have to contend with three main issues: water supply, wastewater disposal and contamination of local water resources. In contrast, post closure issues are related to aquifer recovery or re-establishment of groundwater equilibrium, development of pit lakes in mine voids and isolation of waste products and associated seepage or run-off.

Jan 1, 2003

By Josef Arnold, Norbert Fuegenschuh

The “Eggequerung” is an important part of the German Railway’s (Deutsche BahnAG) modernized Dortmund—Kassel line. The heart of this 13-km-long (8 miles)construction lot is the double-track Egge Tunnel with a total length of 2,880 m(9,450 ft.). The tunnel was driven using the New Austrian Tunnelling Method (NATM).The construction contract also called for a reinforced concrete secondary lining, guaranteed for a full water pressure of 30 m (100 ft.) water column. Preliminary geological study already showed that very problematic geological-hydrological conditions would have to be expected. This talk describes the chosen NATM driving concept that was adapted to the prevailing geological and hydrological conditions, the special driving method applied in geologically difficult zones as well as the water control concept used during driving. The flexibility and the limits of the NATM under exceptional hydrological conditions are illustrated. Also described are reinforced concrete lining works for the watertight secondary vault (reinforced concrete secondary lining without water-proofing membrane).

Jan 1, 2003

By Bruno Mattle, Max John

For tunnels with low overburden, the shotcrete lining is the main element of ground support, which is why shotcrete behavior is of prime importance. Following its application, shotcrete not only gains strength and stiffness with time but—if loaded at an early stage—it is also subject to creep which in turn leads to stress relaxation. For two-dimensional FE calculations, a computational modulus of elasticity of shotcrete is to be used. Based on parameter studies it was found that the modulus of elasticity of shotcrete depends on both shotcrete mix and ground behavior. While the Young’s Modulus used for young shotcrete may range from 1,000 to 7,000 MPa, the Young’s Modulus used for hardened shotcrete is best represented by a value of 15,000 MPa.

Jan 1, 2003

By Joe Milbourne

The potential for treating copper-nickel-cobalt-platinum group metal concentrates by a fully hydrometallurgical route is discussed. Processes specifically developed for treating these feeds and the potential application of the processes developed for the treatment of chalcopyrite copper concentrates are included in the evaluation. Block flowsheets are provided and the technical characteristics of various processes are compared. The current state of development for each process is summarized and probable economic impacts of the technical features are qualitatively assessed. Perceived risks and rewards associated with each technical concept are provided in the conclusions.

Jan 1, 2003

By T. R. Ellis

Considerable movement is afoot internationally to rationalize standards and regulations relating to valuations and the qualifications for valuation professionals. In July 2000 the International Valuation Standards Committee released expanded standards, and additional important improvements are planned by 2003. Possible updates to the International Accounting Standards (IAS) and potential adoption of IAS by the United States could significantly impact minerals appraisers. Standards designed specifically for mineral asset valuation are under development in Canada and the United States, with Australia's internationally respected VALMIN Code providing the benchmark. In the United States, the all-encompassing Uniform Standards of Professional Appraisal Practice (USPAP) is annually modified and continues to gain deeper acceptance, while the SEC holds fast to its 1981 rule prohibiting reporting of a quantitative estimate and value for non-reserve mineralization. Some important international trade agreements are driving actions to free the trade in professional services. In July 2000, an international workshop was held to initiate discussion on minimum qualifications for appraisers to work internationally. Pressure for uniform minimum qualifications and rules for professionals internationally will continue to build. The United States is historically among the slowest countries to implement such initiatives, with its state level licensure barriers having the potential to cause some of its professionals to be stranded in an international backwater. Structural change is needed in Australia's VALMIN Code to remove conflict with the latest International Valuation Standards. The mineral valuation standards developers of Australia, Canada and the United States should work jointly on updating VALMIN for global use.

Jan 1, 2003

By Faruk Oksuz, Clay Haynes, David Egger

The United States Army Corps of Engineers (USACE) has committed to solve a major drainage problem in the suburban Chicago community of Griffith, Indiana. The Cady Marsh Ditch is currently undersized and on occasion spills its banks causing flooding and economic setbacks to the community. Preliminary studies have identified both tunnel and surface solutions as being attractive and viable. The USACE has decided that this project is an opportunity to use the design-build contracting approach to maximize ingenuity in project approach and to allow the market to dictate whether a surface or subsurface solution is most attractive. The tunnel would be over one-mile in length through sands, gravels and clay. Water control will be an issue during tunneling. The paper will explore the contracting approach to the project and the adaptation of Underground Technology Research Council (UTRC) guidelines for underground contracting to a design build project. The roles of Owner, Owner’s consultant, and design-build contractor will be defined as interpreted by the USACE and key contract provisions will be described and contrasted with a traditional design-bid-build approach to tunnel construction.

Jan 1, 2003

"At the May 15, 2006 and the May 1, 2007 Canadian Securities Administrators (CSA) Canadian Institute of Mining, Metallurgy and Petroleum (CIM) meetings in Vancouver and Montreal, CSA requested CIM consider certain issues arising out of the CSA review of Technical Reports and public disclosure, in general, regarding the practice of estimation and reporting of Mineral Resources and Mineral Reserves. The following is a summary of the issues raised by the CSA and the responses of the CIM.Preamble: At the May 15, 2006 and the May 1, 2007 Canadian Securities Administrators (CSA)-Canadian Institute of Mining, Metallurgy and Petroleum (CIM) meetings in Vancouver and Montreal, CSA requested CIM consider certain issues arising out of the CSA review of Technical Reports and public disclosure, in general, regarding the practice of estimation and reporting of Mineral Resources and Mineral Reserves. The following is a summary of the issues raised by the CSA and the responses of the CIM Reserve Definition and the CIM Estimation Best Practices Committees (the Committees). This information is intended to provide the Qualified Person (QP) with further guidance when estimating Mineral Resources and Mineral Reserves and in preparing a technical report written under National Instrument 43-101 (NI 43-101). Several members of the CIM Reserve Definition Committee, the CIM Estimation Best Practices Committee and some members of the Committee for Mineral Resources International Reporting Standards have reviewed these issues and provide the following commentary.Issue 1. - CSA requested CIM review and comment on the selection of an appropriate commodity price to be used in Mineral Resources and Mineral Reserves estimates.Commodity prices are used in the estimation of Mineral Resources and Mineral Reserves and in the economic analysis of a property. In times of rapidly changing commodity prices, or when prices are at the extreme ends of a commodity price cycle, the QP has a difficult job in selecting an appropriate commodity price.• The selection of appropriate technical variables, including commodity price, is clearly the responsibility of the Qualified Person (QP). The QP must describe the reasons for selecting these variables, including price, in the technical report.• The definition of a ""Mineral Resource"" contains the wording ""reasonable prospects for economic extraction,"" therefore, a QP must select economic parameters, including commodity price, that will result in an estimate of Mineral Resources and Mineral Reserves that have ""reasonable prospects for economic extraction""."

Jan 1, 2003

Iron ore in the Pilbara Region of Western Australia varies in composition giving iron ore a range of densities. An accurate density figure of the material leads to accurate calculations of production throughput. Density studies of two separate iron ore mines were conducted in the Pilbara. Procedures and results are reported here.The Pilbara Region of Western Australia has a number of iron ore operations. Two mines have conducted density studies of their materials. The purpose for the studies was to determine an accurate in situ bulk density that could be applied to volume and tonnage calculations of the operation. It was identified that density was one culprit causing calculation variations. Density is an important figure used to estimate ore reserves, equipment requirements, production rates and indirectly costs and sales revenue. One study was conducted at Rio TintoÆs Robe River Mine based near the town of Pannawonica. Its Mesa J orebody is currently being mined and is a low-grade deposit of goethite and hematite (Burnham, 2003). A separate study was conducted at BHP BillitonÆs Yarrie Mine situated north of Newman and east of Pardoo. Its orebody consists of high grade formed by a supergene enrichment of cherty material and a burial metamorphism to produce hematite (Richardson, 2002). The method used to determine density was by large-scale samples using the pre-mining in situ volume of the material and the weight in tonnes after mining.

Jan 1, 2003

By Alain Langlais, Caroline Boudrias Chapleau, Claude Bazin, Ahmed Bouajila

"Slurry «viscosity» has been recognised for several decades as a variable that significantly influences the operation of grinding mills. This paper describes an instrument that can be used in a laboratory or a plant to measure and monitor the flow properties of mineral slurries. Laboratory results obtained for two different ore samples are consistent with results obtained during a full scale trial. The results provide a basis for analysing the effect of the solids concentration and particle size distribution on the slurry flow properties. Grinding tests were also conducted in an attempt to link the grinding efficiency to the rheological properties of mineral slurries.INTRODUCTIONThe flow properties, or incorrectly called «viscosity», of a slurry influence the operation of mineral processing devices. Work has been conducted for instance to assess the effect of this variable on the operation of hydrocyclones (Kawatra et al. 1996; Klimpel, 1982a) and dense media separators for coal (Napier-Munn, 1996). However, most of the research effort has been oriented toward the grinding processes which is still the most energy demanding operation for ore dressing (Fuerstenau et al., 1995).Results of investigations of the influence of slurry flow properties upon grinding performances are presented regularly in the literature since 1950. In the 70's, most of the research work was conducted with the aim of using slurry flow properties for the control of grinding mill and to analyze the effect of that variable upon the population balance model breakage and rate functions (Austin et al., 1984; Hemmings et Boyes, 1977). In the 80's, most of the litterature dealing with slurry rheology was devoted to the use of viscosity modifiers to adjust the slurry flow properties, allowing an increase of grinding mill throughputs (Klimpel, 1982b; Fuerstenau et al., 1985). Although laboratory and pilot plant results show the benefits of adding these modifiers to the slurry, few plants have published results concerning the advantages of such addition (Fuerstenau et al., 1985). It is felt that the use of these modifiers introduce operating difficulties with the concentration circuits, especially flotation (Kawatra et Eisele, 1988)."

Jan 1, 2003

By D Ray, D Brett

A clay-capping trial was established in 1996 on Magazine Dump at the Mt Lyell Copper Mine. The trial was initially constructed under the Mount Lyell Remediation Research and Demonstration Program, a co-operative venture between the State and Federal governments. The detailed engineering design for the clay cover included the following features; reshaping and compaction of dump batters, 5 m vertical bench interval, overall side-slopes of 2.5:1, emplacement of clay in four 150 mm lifts, compaction by a 10 t vibrating roller or ætrack rollingÆ on batters with density testing for quality control. A small section at the base of the dump ( The trial also generated certain unexpected findings. Field permeability tests on the cover yielded uncertain results and oxygen remains available throughout the dump. The flow data indicate that, while total outflow has decreased as a result of storm shedding, inputs from groundwater and batter infiltration are still significant. Outflow during the driest weeks of the year may have risen following capping. Detailed assessment of the data is hampered by insufficient pre-capping information; however, there is a possibility that conductivity flux emitted when flows in the receiving environment are at their annual minimum is unchanged or worse post-capping.

Jan 1, 2003

By P Hawkes

Within the mining industry computers have made their most significant impact with 3D design, visualisation and resource modelling/ optimisation. Recently, the application of computers to data gathering and accounting functions has also started to reap benefits. These two areas of application cover the beginning and end of the mining process. There has been limited use of computers on the middle section, the actual mining process. This is interesting when considering the relative proportion of overall mining costs that this section produces. There is a certain amount of irony in the lack of mining application software for developing accurate budgets compared to the systems/software then used to review performance against budget. Computers have been used extensively in the manufacturing industry to design, model and simulate the manufacturing process. This has not been extended to the mining process. But, we all strive to have an open pit that replicates a manufacturing plant û smooth, efficient, optimal production. If we could model mining operations with the confidence of plastic box makers we would reduce risk by an order of magnitude, improve planning and focus on value drivers. Cost û benefit analysis would be easy. The extrapolation of manufacturing to mining process models is difficult. The variables in the manufacturing process are fewer in number, have low volatility and are highly predictable. The time between a box falling on a conveyor belt and falling off is very consistent. Mining is quite the opposite. It has large numbers of variables, some of which are unpredictable and volatile. The time to fill an excavator bucket could vary by 30 per cent and the frequency distribution is unlikely to be a mathematically simple normal distribution. Further, each of these variables can be distorted by one-another û they are interrelated. The mining process is a disjointed flow of parcels whereas manufacturing is a controlled continuous feed. A loaded truck might join a ramp and follow a slow water cart up. This is the equivalent of a localised voltage drop on equipment in a manufacturing plant. The manufacturing plant is quite likely to rapidly recover to full capacity. Whereas the slow truck might throw the mining fleet cycle out of balance for hours û trucks queuing at the ROM bin and so on. A mining process simulation has been created that addresses these mining variable issues to produce a highly accurate model of the open pit mining process. The number of uses for such a model is growing rapidly as it is being utilised for a variety of projects within the industry. This paper discusses the need for and application of mining process models.

Jan 1, 2003