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The oxidation of zinc vapour plays a very important part in the operation of the Imperial Smelting Process. The kinetics of the reoxidation of zinc vapour by carbon dioxide and water vapour onto quartz and zinc oxide substrates is qualitatively understood and this pertains to the conditions found as the gases are being transferred from the furnace to the splash condenser. However, re-oxidation also occurs in the shaft of the furnace where the solid substrates are sinter and metallurgical coke. It was found that there was a threefold increase in the rate of oxidation on sinter, compared to quartz and a 30 to 300 increase in rate on the coke. This was attributed to the high surface area offered by these materials.

Jan 1, 2003

By T. H. Yang, K. K. Lee, Z. Z. Liang, C. A. Tang, L. C. Li, Y. Tsui, L. G. Tham

Abstract: A series of numerical tests of hydraulic fracturing in heterogeneous rocks were performed to investigate the influence of pore pressure magnitude and gradient on initiation and propagation of tensile fractures. The numerical tests were run with a Rock Failure Process Analysis code, F-RFPA2D, incorporated with a Flow-Stress-Damage coupling model (FSD). To investigate the influence of pore pressure magnitude on fracture behaviour, “pinch-off” breaking tests, originally employed by Bridgeman to investigate the effective stress law for tensile fracture in a uniform pore pressure field, were numerically modelled. In another numerical test, a double-notched sample, with fluid pressure in one notch while keeping the other one open to the atmosphere, is numerically extended to investigate how the fluid flow direction or the pore pressure gradient will influence the fracture behaviour. The simulation results show that fracture is strongly influenced by both pore pressure magnitude and pore pressure gradient. Keywords: seepage mechanics; heterogeneous; pore pressure; numerical simulation; failure process ZUSAMMENFASSUNG: Um den Einfluss der Wasserdruckgroesse der Oeffnung und der Porisitaet auf den Bruchentstanden und Verbreiten der Tension von Gebirgen zu beurteilen, wurde viele nummerische Pruefungen auf den hydraulischen Bruch in dem Gebirgen aufgenommen. Diese Pruefungen wurden mittels der Analyse- Software F-RFPA2D und Flow-stress-Damage Coupling model ( FSD) durchgefuehrt. Um den Einfluess der Wasserdruckgroesse der Oeffnung auf den Bruch zu beurteilen, wurden auch Bruchpruefung und nummerische Analogexperimenten gemacht, und dadurch wurde die ganze Phase der Bruchentstanden und Verbreiten wiedergezeigt, und die Ergebnissen ergeben sich, dass die Wasserdruckgroesse der Oeffnung und der Porisitaet sehr viel auf den Bruchentstanden und Verbreiten der Tension von Gebirgen beeinfluessen. Schluesselwoerter: Durchlaessigkeit , ungeleichmaessig, Wasserdruck der Oeffnung, nummerische Analog, Zerstoerungspahse Résumé : Une série de simulations numériques a été ménée pour analyser l’influence de la grandeur de la pression de pore et du gradient sur la naissance et la propagation des fractures de tensions par le biais de la simulation numérique des fractures hydroliques dans des rochers hétérogènes . Le logiciel F-RFPA (Rock Failure Process Analysis code ) intégrant FSD ( Flow-Stress-Damage coupling model ) y a été employé. Les résultats des simultations montrent tout le processus de la naissance et de la propagation des fractures sous la pression de pore. Ces résultats nous ont permis de constater que la grandeur de la pression de pore et le gradient exercent une influence importante sur la naissance des fractures dans les rochers et sur leur mode de propagation . Mots de clé : le mécanisme de transfusion ; l’hétéogénéité ; la pression de pore ; la simultation numérique ; le processus destructif

Jan 1, 2003

By Gülay Bulut, Mustafa Özer, Yunus Emre Benkli, Olgaç Kangal, Istanbul Technical University, Mustafa Tarkan

"Zeolites are naturally occurring as hydrated aluminosilicate minerals. They belong to the class of minerals known as “tectosilicates” and are related to the common minerals feldspar and quartz. Seven natural zeolites that occur in large, commercially exploitable deposits, are: clinoptilolite, chabazite, mordenite, phillipsite, erionite, analcite, and ferrierite. Among them, clinoptilolite is the most abundant one and is not the best known, but is one of the more useful natural zeolite. Clinoptilolite [(Na3K3) (Al6Si30O72) 24 H2O] is very closely related to heulandite and is currently being considered for disuse it self as it may just be a variety of heulandite. It differs from heulandite significantly only in its enrichment in potassium and slightly more silica and it is argued that a separate mineral is not needed.There are large zeolite deposits in western part of Turkey. The sample used in this study was taken from the Gördes region of these deposits. Screen, chemical, XRD and mineralogical analyses were used to determine properties of the natural zeolite sample used in this work.According to the size distribution of the sample, it is found that the zeolite sample used in this study is below 1 mm in size and almost 80% of it is below 0.5 mm. X-Ray Diffraction (XRD) and mineralogical analyses show that the natural zeolite is found to be in the forms of clinoptilolite and heulandite. Clinoptilolite forms as a devitrification product of volcanic glass in tuffs. Quartz, clay minerals, orthoclase, plagioclase, biotite, seruzite-muskovite and epidote were observed as impurities. XRD analysis also shows that the sample contains approximately 58-60% clinoptilolite, 5% quartz, 5% feldspar, 10% smectite, 5- 10% illite and mica and remaining volcanic tuffs. Several types of mineral processing methods were performed in order to remove impurities from the natural zeolite sample to produce high purity zeolite. Gravity separation methods such as shaking table and superpanner were carried out for separating heavy minerals, while high intensity dry magnetic separation was used for discarding magnetic minerals."

Jan 1, 2003

By Jon Kellar, William Cross, Eric Swanson, John Starkovich

Zirconium tungstate (ZrW2O8) is a unique material with a negative coefficient of thermal expansion. In order to fully utilize this material as a filler, a surface treatment needs to be developed to better improve the wetting and dispersion capabilities of the filler. This paper describes an initial study to characterize the filler as well as investigate fatty acid and silane surface treatments for eventual compounding with thermosetting matrices. It was found that ZrW20, has a point-of- zero charge between pH 2.7-3.0, and that both fatty acid and organofunctional silane treatments appear to be viable surface treatments for this unique filler.

Jan 1, 2003

By H. L. Owens, J. W. Fredland, K. K. Wu

The Mine Safety and Health Administration (MSHA) is responsible for reviewing and approving the engineering plans for impoundments, of significant size or hazard potential, that are constructed on coal-mine property. Over the years, technical review criteria have been updated as the state-of-the-practice for dam safety has evolved. The evaluation of stability under earthquake loading, for example, has gotten much more sophisticated for impoundments built using upstream construction. Recent incidents where slurry has broken into mine workings have caused MSHA, mine operators, and design engineers to re-examine this safety issue. This paper gives an overview of MSHA’s impoundment plan review process.

Jan 1, 2003

By Ali Akbar Mottahedi

Chromate conversion coating is a process for making a complex layer at the surface of zinc galvanized steel which makes the metal more resistant to corrosion, especially at marine atmosphere, and increases the adhesiveness of color. In this work the influences of various compositions on commercial zinc galvanized steel sheet to the color of chromate conversion coating has been investigated at normal temperature and the factors that affect the control and optimization of the process have been determined. A bath composition of 20 g/liter Cr203 and 10 g/liter NaOH and a dipping time of 50 seconds at room temperature (25-30°C) make a desirable color of chromate coating. A slow agitation at a constant pH of I (with additions of NaOH or H2SO4) assures a constant bath condition and develops the color. This kind of coating has more corrosion resistance and this bath condition and composition are also more economical.

Jan 1, 2003

By Ma Ying

The continuous directional solidification technique of five kinds of special ZA alloys with eutectic, peritectic and eutectoid transformation under the condition of continuous casting by heated mold was studied. The mechanism of surface defects appearing in ZA alloy line was discussed and the structure of some defects were analyzed by SEM. The results show that only when the fitting of various technique factors, pressure head, outlet temperature, pulling speed and cooling condition are reasonable under a certain range, can the ZA alloy smooth line be continuously pulled out. Unreasonable techniques will result in hot tear, rough surface, mush outlet, leaking and other defects. The shape and location of solid-liquid zone have an important influence on the formation of the above defects. When the solid-liquid zone is located in the mould outlet or inner mould, the surface of solidification will protrude into the inner mould. If the remaining liquid cannot counteract the solidification contraction, a rough surface will appear. If the solidification surface further into the mould, the ingot in the mould will have a great friction force when pulling and will form a hot tear. When the solid-liquid zone is moved out of mould, the solidification surface will turn into a plane, which easily results in leaking. A vibration or unstable operation will cause an ingot winding during pulling

Jan 1, 2003

By Michael I. Morris

The U.S. Department of Energy's (DOE's) Transuranic and Mixed Waste Focus Area (TMFA), funded from fiscal year (FY) 1996 though FY 2002, was tasked with finding solutions for the mixed waste treatment problems of the DOE complex. During TMFA's initial technical baseline development process, three of the top four technology deficiencies identified were the need for amalgamation, stabilization, and separation/removal technologies for the treatment of mercury-contaminated mixed waste. The Mercury Working Group (HgWG), a selected group of representatives from DOE sites with significant mercury waste inventories, assisted TMFA in soliciting, identifying, initiating, and managing efforts to address these areas. Solicitations and contract awards were made to the private sector to demonstrate both the amalgamation and stabilization processes using actual mixed wastes. The goal was to develop separation and removal processes that will address DOE's needs. This paper discusses the technology selection process, development activities, and the accomplishments of TMF A through these various activities.

Jan 1, 2003

By Tian Li

Simple compartmental models of a laboratory batch gibbsite precipitator were used to investigate the influence of the number of compartments, the local shear rate and solids distribution on the crystal size distribution (CSD) under the conditions where aggregation is the dominant mechanism. In the current work, a power law relationship was assumed between the local agglomeration and shear rate. The simulation results showed that both the local shear rate and solids distribution have significant effect on the CSD responses, and the interchanging flows has a lesser impact with its influence strongly depending on the former two factors. Overall, the results reveal that in an aggregation controlled precipitation system, the influence of each of the factors on the CSD depends on the local hydrodynamic conditions in the precipitator, as well as their interactions.

Jan 1, 2003

By Kurt Egger, Emily A. Baker

Rehabilitation work at the Cameron Run Tunnels entailed the restoration of seven heavily deformed, approximately 69 m long, steel liner plate supported culverts through a CSX Railroad embankment near Alexandria, Virginia. A custom fabricated expander, equipped with four 200-ton hydraulic jacks on two expansion arms was used to push back the liner plates encroaching into the proposed tunnel profile and install the steel set support. In a second phase the tunnels were then lined with 16 cm of fiber reinforced shotcrete. Geotechnical instruments both in the tunnels and on the railroad embankment were used to monitor the effects of the rehabilitation work on the two CSX Railroad tracks above the tunnels. Freight and passenger trains were required to run uninterrupted and at maximum speeds throughout construction.

Jan 1, 2003

Mining employment, gross output, local economic contributions and productivity are typical economic indicators. However, these economic indicators play a much bigger role in the overall capacity of the industry to be heard in decision-making on a national scale. Total mining employment in the USA has decreased significantly in the last 20 years. Gross output from most of the mining sectors has also declined, except in the case of construction aggregate. However, significant gains have been made in productivity. This paper explores these statistics and comments on their overall impact on academic institutions and political decision-making.

Jan 1, 2003

By W. G. Pariseau

Equivalent elastic properties of discontinuously jointed rock masses are computed using a non-representative volume element(NRVE) approach within a three dimensional finite element program. Joint persistence, defined as the percentage of a joint plane that is actually occupied by joint material, is used in the NRVE computations as a step towards greater realism in stability analysis of mine openings. Persistence p is also the probability that a segment of a joint plane is occupied by joint material. Computations reveal a threshold phenomenon in jointed rock mass moduli similar to that observed in percolation theory. A rapid decrease in moduli occurs above a critical value pc(about 0.6). A detailed analysis of the well-known solution for stress about a circular opening in isotropic, elastic ground illustrates the effects of joint set orientation, spacing and persistence. Although stable “on average”, joint segment failures reveal a threat to stability and point towards rational design of reinforcement or support of discontinuously jointed rock masses.

Jan 1, 2003

By M. Tanaka, K. Aoki, T. Mori, H. Morioka, K. Iwano, T. Kanagawa

To estimate the detailed characteristics of the rock around the cavern during excavation, new monitoring technique for dynamic properties of the rock has been applied. In this paper, micro-seismic monitoring and AE monitoring technique are applied to the excavation of large underground rock cavern and the result was discussed to clarify the acutal behavior of EDZ around the cavern. Zur Einschätzung der Gesteinseigenschaften um die Ausschachtung herum haben die Autoren eine Technik eingesetzt, mit der die physikalischen und dynamischen Änderungen im Gestein um den Schacht während der Ausschachtung beobachtet werden. In der vorliegenden Studie wurde zur mikroseismischen Überwachung ein AE Überwachungsverfahren eingesetzt und die Autoren berichten über die Veränderungen in den Gesteinseigenschaften um die Ausschachtung herum. Dans le but d'évaluer en détail les propriétés des roches qui forment les parois des cavernes creusées, les auteurs ont utilisé une technique de mesure permettant d’observer les modifications physico-dynamiques des roches aux alentours de la caverne pendant son excavation. Dans le cadre de cet article, une technique de surveillance de l’agitation et du bruit microséismiques a été mise en œuvre et les auteurs font état de la modification des propriétés de la roche environnante.

Jan 1, 2003

By F. Kongoli

Viscosity is an important parameter of copper smelting and converting processes. It affects the settling of matte or metal droplets in the slag, distribution of elements etc, Despite this importance, confusion exists on the viscosity of copper smelting slags as a result of disagreements found among the measured viscosity data of several authors especially in the slags of high ferric iron content and close to magnetite precipitation. In this work a critical review of the existing data on the viscosity of copper smelting slags has been first carried out and the effect of oxygen potential on the viscosity of copper smelting slags has been clarified through a coupled quantification of viscosity and liquidus temperature. The confusion in the literature has been clarified and the importance of the relation between the viscosity and the liquidus temperature is discussed,

Jan 1, 2003

By E J. Gardiner, C M. Hogan

Acidic drainage has long been recognised as the largest environmental liability facing the mining industry, and to a lesser extent, the public, through abandoned mines. The Canadian Mine Environment Neutral Drainage (MEND) initiative was the first international multi-stakeholder program to develop scientifically based technologies to reduce the effect of acidic drainage. The original MEND Program extended over a nine-year time frame ending in 1997, with technology transfer activities continuing to the end of year 2000 under the MEND 2000 program. Both programs have contributed enormously to the understanding of acidic drainage and how to prevent it. MEND3, launched in 2001, intends to further this effort with a strong, research-driven program. The successes of the MEND initiative have come through the collaborative efforts of the partners, the sharing of experiences, the thorough evaluation of technologies and their incremental improvements. As a result, the knowledge base on acidic drainage has grown considerably. An international model of alliance between the various worldwide initiative involved in acidic drainage is being formalised at this conference. This global alliance will enhance technology transfer capabilities and will lead to improved environmental performance for the industry. It is through collaboration that we have achieved the most progress in environmental performance, and this formal relationship will further expand these benefits.

Jan 1, 2003

By Chris Adams

The application of pre-tensioned tendon roof support assisted Harworth Colliery in their revival, from impending closure to lowest cost deep-mined producer in the UK, over just six months last year. The paper describes this success story, how it came about, the reasons "why", and the method "how"

Jan 1, 2003

By Jury P. Nazarov

"At present the traditional study of crystal lattices of nmerials in a topic “flota tion mineralogy ” is used up. The present investigation is development of the a sclsical approaches to t he analy sis of ideal crystal lattices and f ormation on the basic obtained results of consultation, having practical chara cter.The strategy of develop ment floatation reagents i s offered, which basic pr inciple – complementary assembling m olecules forming surface co mpounds so thatth e steric charact eristic of the “visitor "" (of a polar gro up of molecule SAS) corresponded to the st er ic requirements of the ""o wner"" (elementary cell of a mineral), or coincided inter molecular cavities). In itsh case process of for mation of surface com pounds ca n be considered(a first approximation) as a realization of a principle of the design er "" LEGO "".The approach, which basic idea consi deration actioonf reactant ions and ions of ele mentary cell as three-di mensional objects is developed. And at suchp paroach the laws of a ster eometry - laws describin g spatial effect s are applicable. Thus it is possible toconsider a miner al surface as a mat r ix - basis for formation of the requirem ents to polar group of a molleec cuollector, and or (it is possible) depressant. As a whole approach represents a generalized principle double com plementation, enveloping both power, and geometric asp ects (concept ""lock "" and “key "" - spatial conform ity. Figure 7 (left). Fragment of a crystal lat tice of ap atite. Oleic acid ions interact on ly with th e calcium cations locate d on a long axi s of an elementary c ell. Magenta colour represe nts the calciu m cations, which are n ot particip atin g in interactio n, as th e degree of screening by ions neighbours exceeds 1.Figure 2. (right)The illustration of space complementary. “Afterbuilding” an elementary cell of apatite (radical PO4) related molecules of the visitor – alkyl phosphate (polar group PO4). Cations of calcium are not shown."

Jan 1, 2003

By J. R. Frederick

Introduction In response to industry needs and requests, Joy Mining Machinery is aggressively evolving a "game changing" system of underground development mining machinery. This entry-development system (EDS) project is concentrated on providing clean, protected and ergonomic operator areas and a quantum leap in productivity. To meet these goals, a virtually continuous and automated mining system is needed. Operators must be able to efficiently and ergonomically perform required functions from a protected environment. Health-related issues, such as respirable dust and noise, must also be addressed. A new concept system of integrated face equipment, from the continuous miner to and including advancing the section belt and services, is needed. Phase I of the project was aimed at developing the bolting technology required. Through acquisition of Cram Australia and joint development efforts with Canyon Fuel Co., Joy now has this capability. The test platform, known as the Joy Multibolter, has successfully completed its trials at Canyon Fuel's SUFCo Mine (Fig. 1). These tests validated the bolting technology and operator protection and ergonomic issues. Phase II includes the development and testing of an integrated mining machine (IMM) capable of advancing a heading 1.5 m (5 ft) while simultaneously cutting a fullface width (single pass) and installing a complete bolt pattern. The IMM, unveiled at MINExpo 2000, incorporates the bolting technology of the Multibolter with automated full-face cutting. This machine was designed to meet Joy's stringent health, operator protection and 300m/d (1,000-ft/d) productivity goals. Phases III through V will include development of processes and integrated haulage, ventilation, power, material handling and section services advancing equipment. Processes and equipment developed will be designed for seamless integration into a complete entry development system. The focus of this paper is the new continuous miner (IMM) development, proposed testing and expectations for the EDS. The IMM is scheduled for commissioning and trials beginning in April 2001 at the SUFCo Mine. SUFCo Mine Canyon Fuel Co. is jointly owned by Arch Western Resources and the Itochu Corp. of Japan. It owns and operates three coal mines in Utah: the SUFCo Mine in Sevier County, the Skyline Mine in Carbon and Emery Counties and the Dougout Canyon Mine in Carbon County. Incorporating state-of-the-art-mining technology and advanced mine management practices, the SUFCo Mine is one of the most efficient underground coal mines in the world. The SUFCo Mine is located approximately 50-km (30 miles) northeast of Salina, UT, in the Wasatch Plateau portion of the Uinta coal basin. The mine property consists of 9,900 hm2 (24,470 acres) with approximately 118 Mt (130 million st) of recoverable reserves. Public utilities and industrial concerns purchase approximately 95% of the coal mined at SUFCo through short- or long-term contracts. Coal reserves are extracted by longwall mining, and the panels are developed using continuous miners. The longwall face at SUFCo Mine is 283-m (930-ft) wide, and the seam height ranges from 2.4 to 4 m (8 to 13 ft). The two development sections are in full operation using Joy 12CM12 continuous miners. Two super longwall panels, under development in the northeast portion of the lease block, are 4,270-m (14,000-ft) long with a 283-m (930-ft) wide longwall face. Each panel contains approximately 5.4 Mt (6 million st) of recoverable coal. SUFCo has been a world leader in productivity for a

Jan 1, 2003

A variety of rockbolt designs and resin anchors are currently in use in underground mines. This paper identifies possible risk factors that may affect the intended performance of rockbolts. The paper also presents the outcome of a study on the variability of some aspects of fully encapsulated rockbolts undertaken across seven coal mines within the context of previous research findings on rockbolt anchorage performance.

Jan 1, 2003

By Helmut Antrekowitsch

Nowadays nearly the half of the world zinc production is used for galvanizing. After their life span most of the galvanized products return as scrap to the steel mill. During the steel process the zinc is collected in the flue dust It is astonishing to notice that between 40 and 50 % of the zinc produced is brought into the steel processing cycle by the coated scrap while only 3 to 5 % of the zinc production can be covered by the recycling of the zinc-bearing steel mill dusts. Responsible for this worse ratio is the fact that the established recycling technologies suffer from high energy consumption, low zinc yields, halogen problems and hardly any iron recovery. A development of new or an optimization of current recycling procedures for the dusts is unalterable because of increasing zinc amounts in these residues and the rising costs for the disposal. Different pyrometallurgical recycling technologies are tested in rotary kilns and vertical retorts at the Department of Nonferrous Metallurgy, University of Leoben, Austria. Various reducing agents from carbon monoxide to hydrogen and combinations are used. The results should make it possible to draw conclusions that allow an economical and ecological judgement of the different varieties. The goal is to support the affected industry to increase the low recycling rate and prevent a loss of high zinc values in the steel industry filter dusts.

Jan 1, 2003