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By Hassan El-Shall, Abbas A. Zaman, Brij M. Moudgil

The addition of organic and inorganic dispersants to aqueous suspensions of heterogeneous particles (kaolin) was found to significantly affect the solubility of metal ions from kaolin particles and stability of the dispersion. In most of the industrial applications of kaolin, highly concentrated slurries of controlled stability and fluidity are required. The solubility of kaolin particles in terms of aluminum and silicon ions and its effect on the stability of the slurry was investigated. The main objectives of this study were (1) to study the effect of the extracted metals on the properties and performance of the slurry, (2) to understand the reaction mechanism of dissolution of metals from kaolin, and (3) to understand the interaction mechanism of dispersants with kaolin particles. The controlling variables were dispersant dosage, slurry pH, solids loading, and aging.

Jan 1, 2003

By A. N. Zagorodnyaya, T. N. Bukurov, Z. S. Abisheva, A. S. Sharipova

"This work presents the results of the development of a flowchart for the processing of copper production dusts resulting in the production of of lead sulphate, tribasic lead sulfate (TBLS), ammonium perrhenate, zinc, copper-cadmium cake.Dust having the following composition (wt. %): Pb 39.3, Zn 6.5, Cu 5.5, Stotal 10.8, As 1.05, SiO2 0.6, Cd 0.8, Bi 0.04, Ag 0.02, Re 0.03 was used in the work. Chemical and X-ray analyses indicated that lead, zinc and copper are generally present in dusts in the form of sulfates, various amounts of oxides, sulfides, silicates; sulfur (according to chemical analysis data) is present in the form of sulfates (~ 90%) and in the form of sulfides (~ 10%).Studies have been made on two-stage stripping of copper production dusts containing lead, zinc, copper, cadmium, rhenium in the form of various compounds, at first with soda solution, then with nitric acid solution. It has been indicated that the combination of the operations allows the recovery of 98% rhenium, 82% lead, 92% copper, and 96% zinc and cadmium each in the solution. Furthermore, at the stage of dust leaching with soda, 80% of rhenium and 0.01% of nonferrous metals each are recovered in the solution. Remaining quantities of all metals are recovered in nitric acid solution up to maximum values. Such behaviour of metals is caused by metal phase content in dusts and properties being formed during leaching of compounds. At the stage of dust leaching with soda solutions, carbonates with various compositions are formed due to the exchange reaction between nonferrous metal sulfates and sodium carbonate. The conversion of PbSO4 into PbCO3 is apparently occurs in the solid phase and the conversion of readily watersoluble zinc, copper, and cadmium sulfates into that of carbonate salts occurs in the liquid phase. Rhenium passes into solution due to the presence of rhenium greater quantity in dust in the form of readily soluble perrhenate. Some portion of the perrhenate is, probable, blocked by lead sulfate and liberated in the conversion of PbSO4 into PbCO3."

Jan 1, 2003

By R Farana

The future challenges in mining instrumentation, mainly on future intelligent mines, are to continue providing instruments with the highest level of reliability at the lowest possible cost, and also to take advantage of technology existing in other industries and to adapt it to the mining context. New wireless instruments (smart sensors, smart actuators, smart controllers) would also be very useful, as well as instruments fully adapted to the monitoring of large movements that are observed, in both underground and open pit mines. Mining instrumentation is found to various degrees in most mines, both open pit and underground. Smart mining instruments present a certain number of aspects specific to the environment in which the instruments are installed. Namely, the instruments can be installed either for short-term or long-term purposes. The mining industry is always looking for useful instruments that can provide relevant information on ground behaviour adjacent to mining stopes or permanent infrastructure. The instruments must meet the various criteria, and must also evolve with the new mining technologies that are continuously being implemented. A strong collaboration between the mining industry, research organisations, and instrument manufacturers is the key to meeting these objectives. This contribution describes the current trends on smart sensors and smart instrumentation with Wireless LAN support.

Jan 1, 2003

By Sunil Jayasekera

This paper describes the results of a study carried out to examine the feasibility of electrolytic recovery of silver from cyanide leach liquor generated from a Western Australian silver mine tailings using a novel high mass transfer electrowinning cell. The proposed circuit involves heap leaching and electrowinning in a closed loop. The filter-press-like closed electrode arrangement of the cell allowed much improved mass transfer of metal ions to the cathode surface, making direct electrowinning of metals from dilute solutions feasible. The tests were conducted both in the laboratory and at large scale using a prototype with ~1.0 m2 cathode area. The results showed that the recovery of silver from as low as 250 mg L-1tenor was feasible. The silver deposit produced with the prototype cell was non-adherent and powdery and could be readily removed from the closed cell. A system was developed so that silver powder was discharged continuously during the run.

Jan 1, 2003

By Takaaki Ishikawa

The distribution equilibria of lead, zinc and copper between CaO-Si02-Ah03 melts and liquid copper were measured at 1623K under a controlled H2-C02 atmosphere. The distribution ratios were plotted against the oxygen partial pressure, and reasonable oxide forms dissolved in the melts were estimated from the slopes of the plots. The activity coefficients of zinc oxide (ZnO), lead oxide (PbO) and cuprous oxide (CuO0.5) increased with increasing slag basicity, defined by XCao/Xsio2 The temperature dependence of the activity coefficients was also measured.

Jan 1, 2003

By K. Sørli, H. Elstad, I. M. Skaar, A. Hildal

Generally, monitoring of refractory furnace linings is of interest to the metallurgical industry. The main issues are to control wear of the furnace lining and break out of molten metal. Penetration of molten metal through the lining can cause considerable damage to equipment in the vicinity of the furnace and endanger operators. Rebuilding of a furnace lining is expensive, mainly because it stops production, but also because the lining materials are expensive. Here, two methods for monitoring the lining of a smelting furnace are presented. The methods are based on monitoring of the temperature distribution in the lining, more specific monitoring an isotherm in the lining. One method is based on the assumption of unidirectional heat flow locally, reducing the problem to a set of one-dimensional heat conduction problems. The other method is based on inverse heat conduction. In this context inverse heat conduction means estimating the wear from temperature measurements using mathematical optimization techniques. The study is based on the ilmenite smelting furnace at Tinfos Titan & Iron KS. Some results from real temperature measurements and real observations from the ilmenite smelting furnaces is presented.

Jan 1, 2003

By P. S. Pashkovsky, S. N. Smolanov

The essence of the method consists in creation of drop of opposite sign at the isolating stoppings, by which air losses through the accident district change direction of their motion. The period of reversal is selected in that way so that air may not find itself in the zone of burning. The method of fighting the fire considered was repeatedly used in the coal mines of the Ukraine. The theoretical basis of efficiency and two examples of use of this method by fighting the underground fires are adduced in the paper.

Jan 1, 2003

By Sharad Mathur

The purpose of this paper is to present the benefits of high reactivity meta kaolin (HRM) in high performance cement-based systems. HRM, unlike other pozzolans, is manufactured from selected naturally occurring kaolin ore and carefully processed under stringent conditions to result in a consistent product with highly pozzolanic properties. HRM is an ultrafine pozzolan that enhances the mechanical properties (workability and strength) and chemical stability (durability) of Portland cement concrete and cement-based products. HRM is unique with respect to its white color which makes it an ideal choice for architectural applications where visual and aesthetic concerns are critical.

Jan 1, 2003

By J Vann, S Dunham, M Job

Two-dimensional (2D) estimation approaches have significant advantages over three-dimensional (3D) approaches when dealing with a narrow vein- or layer-like geometry. The main motivation for 2D estimation is that bias due to non-additivity of grade is avoided. The various aspects of 2D estimation are illustrated by use of a case study from the 1A Shoot Nickel deposit at Leinster, Western Australia. The width of the 1A mineralisation is variable, and so are the angles of drilling intersection. Consequently, the variable of interest (in this case nickel grade) is not suitable for direct kriging because it is defined on non-uniform support. However, grade can also be defined as the ratio of two variables that are suitable for direct kriging: thickness and accumulation. In the 2D approach, tonnage equates to thickness and metal equates to the product of grade and thickness, also called æaccumulationÆ. In the simplest approach we can independently krige accumulation and thickness and derive the grade by the ratio of the two resultant estimates. The thickness and accumulation variables must be in a consistent projection orientation, for example a horizontal projection in the case of steeply inclined mineralisation like 1A. Because the density is not constant across the 1A (and most other) deposits, the issue of density weighting is also discussed. The impact of the correlation between grade and length, or grade and density are important issues in implementation of 2D estimation. The circumstances under which these correlations need to be taken into account (by co-kriging) are reviewed. Finally some comments are made on the final use of the resultant 2D estimate for mine planning purposes.

Jan 1, 2003

By Florian Kongoli

Slags and fluxes are important interchangeable dimensions of pyrometallurgical processes. They can increase the efficiency of the smelting, converting and refining processes and improve the quality of the final products. A good slag should have appropriate physicochemical properties such as low liquidus temperature, optimal viscosity, maximum ability to attract undesirable elements, minimum potential of attracting valuable elements, etc .. A good flux, on the other hand, when properly used, can considerably improve the physicochemical properties of the slag since by modifYing its chemical composition it could decrease the liquidus temperature, improve viscosity etc.. Consequently, the choice of a good slag and the corresponding fluxing strategies has become indispensable in most of industrial processes. However, the properties of multi component slags as well as the effect of several fluxes are known only empirically and confusion exists in the literature and in the industrial practice. In today's reality of frequent changes in the composition of raw materials and that of the fluxes themselves, in the existing or new developing technologies, the quantification of the thermophysicochemical properties of multicomponent slags and the effect of fluxes becomes indispensable. This paper reviews some of the work carried out by the author's group during the last ten years on the quantification of the thermophysicochemical properties of multicomponent slags and on the effect of fluxes in several smelting and converting processes in close relation to their individual characteristics. Several examples have been given in order to demonstrate the fact that when taken outside the context some fluxes can become in fact anti-fluxes.

Jan 1, 2003

By P. N. Erasmus, M. Heyns, M. J. Pretorius

The characteristic of stope supports plays a vital role in the design of the supports. This paper deals with the characterisation of both cellular lightweight concrete and timber supports since both supports absorb and dissipate the energy in different ways. The behaviour of the support and hence its performance is simulated for different loading conditions by constructing a model consisting of various mechanical components like springs, dampers and blow-off valves. When the force exerted by the stope support increases significantly during deformation of the support, the stresses in the hangingwall could exceed values where failure of the hangingwall may occur. There is a need to understand this phenomena and the work presented in this paper is a first attempt to start with the characterisation of the stope support. Les caractéristiques des supports de taille jouent un rôle vital dans la conception des supports. L’étude présente traite de la caractérisation des supports cellulaires en béton léger et en bois, puisque ces deux types absorbent et dissipent l’énergie de façons différentes. Le comportement du support et par conséquent sa performance est simulée pour des conditions différentes de chargement en construisant un modèle qui consiste en des organes mécaniques variés tels que ressorts, registres et valves d’échappement. Quand la force exercée par le support de taille augmente considérablement pendant la déformation du support, les contraintes dans le toit peuvent dépasser des valeurs qui pourraient entraîner la défaillance du toit. Il est nécessaire de comprendre ce phénomène et l’étude ici présentée constitue un premier essai dans la caractérisation du support de taille. Die Charakteristika der Strossenunterstützung spielt im Design von Unterstützungen eine vitale Rolle. Diese Arbeit befaßt sich mit der Charaketerisierung sowohl der porösen Leichtgewichtbeton- als auch mit der Holzunterstützung, da beide Unterstützungen Energien auf verschiedene Art und Weise absorbieren und auflösen. Das Verhalten der Unterstützung und folglich seine Leistung wird für unterschiedliche Ladezustände simuliert, indem ein Model konstruiert wird, welches verschiedene mechanische Komponenten wie Federn, Dämpfer und Ausblaseventile enthält. Wenn die von Strossenunterstützung während einer Unterstützungsdeformation aufgebotene Kraft signifikant ansteigt, könnten die Spannungen im Bereiche des Stollenfirstes Werte überschreiten wo ein Versagen des Stollenfirstes eintreten kann. Es besteht die Notwendigkeit dieses Phänomen zu verstehen, und die Arbeit, die in diesem Elaborat dargestellt wird, ist ein erster Versuch, mit der Charaketerisierung der Strossenunterstützung zu beginnen.

Jan 1, 2003

By Kelly A. Cosgrove

Jan 1, 2003

By William R. Yernberg

The 2003 Rapid Excavation and Tunneling Conference (RETC) was held at the New Orleans Marriott, New Orleans, LA, June 15-18. The New Orleans conference was the 16th since the RETC was formed in 1971. This year’s conference was sponsored by the Society for Mining, Metallurgy, and Exploration, Inc.(SME), with co-sponsorship of the Construction Institute of ASCE. Attendance at the meeting was 1,178, a conference record. This was up significantly from the771 attendees at the 2001 meeting in San Diego, CA. The RETC was formed to “advance the engineering and scientific knowledge of rapid underground excavation and tunneling through interdisciplinary meetings, publications, technical-educational exhibitions and encouragement of research.” The RETC conferences are now held every other year. They provide an opportunity for individuals to meet with designers, contractors and manufacturers associated with the tunneling industry to share experiences in all phases of tunnel design and construction.

Jan 1, 2003

By J. T. Jordaan

Paper written on project work carried out in partial fulfilment of B. Eng (Mining Engineering) degree This paper addresses the critical parameters that need to be considered when designing a mechanized bord-and-pillar mining layout for a narrow tabular steep dipping orebody. These parameters are : ?Reef dip ?Reef width ?Geological structures within the orebody ?Physical dimensions of the selection of machines ?Gradeability of the selection of machines. The main objective in designing such a layout is to maximize machine efficiencies whilst minimizing dilution. This methodology was then applied in the design of a mechanized bord-and-pillar mining layout for a given piece of ground (Vlakpoort and Moddergat) using a given selection of machines. This piece of ground contains the PGM bearing UG2 Reef with an average thickness of 124 cm and dipping at 18°withadverse strike and dip changes. Two bord-and-pillar layouts were designed for this area. Layout 1 is characterized by the use of strike conveyors to convey ore on strike with an average LHD hauling distance of 35 m. Layout2 uses LHDs for all on strike conveyance of ore with an average hauling distance of 75 m. These two layouts were then technically and financially compared. It was concluded that layout 1 is theoretically superior but layout 2 was chosen due to its greater flexibility and probability of operational success. Layout 2 was also compared to conventional mining and it was concluded to be more economically feasible. However the latter is a proven mining method in these conditions and has a lower risk operational failure. Bord-and-pillar mining has some favourable promises such as improving labour difficulties, lowering operating costs and providing safer working conditions. The success of mechanized bord-and-pillar mining in narrow tabular steep dipping orebodies will depend on the extent of the research and development efforts which need to create and innovate technologies to overcome some of the current limitations stated in the above-mentioned parameters.

Jan 1, 2003

By A. V. Peake

Continuous Mining presents an opportunity to extract reef in the stope ?continuously? by integrating the drill and blast activity using propellants or low energy charges. To date, the majority of effort spent on Continuous Mining systems has focused on developing an effective rock breaking process (micro breaking process), and to some extent, eliminating fumes and dust. The perceived benefits of applying low energy charges have been identified as: ?Concentrated mining yielding face advances of 40 to 60 m per month ?Lower stoping widths through better-controlled breaking ?Increase in the advance per blast ?Increase in labour productivity ?The potential to mine reefs where specific conditions make conventional mining uneconomic e.g. reefs with shales in the immediate hangingwall. However, the ability to successfully use low energy charges to create a ?Continuous or Semi-Continuous? mining method is dependent on overcoming the following challenges. ?Improving reliability of rock breaking. This is dependent upon achieving:? Improved drilling accuracy, and? Successful stemming or gas confinement, particularly in fractured rock ?Reducing gas and dust levels ?Reducing high costs. Through the research carried out in Future Mine, many different low energy rock breaking methods and systems were investigated. Whilst detailed results cannot be published here, the guidelines for overcoming low energy rock breaking challenges are discussed.

Jan 1, 2003

By K Hskansson

In earlier studies along a mining region recipient (the river VormbScken, northern Sweden), the fraction of certain trace metals recovered in the particulate phase has been found to increase with increasing concentrations of particulate iron. This study was conducted to see if the pattern could be reproduced by adding minor amounts of ferrous iron, simulating groundwater inputs. When the iron is oxidised in the near neutral river water, it will form iron oxyhydroxides and precipitate. Trace metals may be either co-precipitated along with the iron, or adsorbed onto the freshly formed precipitates. If this is the case, such a mechanism may be incorporated as a part of a final polishing step in a mine drainage treatment system based on natural attenuation processes. The experiments were performed at 0¦C and 22¦C, on authentic river waters collected during the winter and summer of 2002, respectively. In order to investigate the influence of particles and bacteria initially present, filtered river waters (4 solution were added to the experimental beakers, increasing the iron content of the waters by 0 - 1.5 mg/L. The oxidation and precipitation processes were followed by means of filtration (0.2 ¦m) for up to seven days. In order to be able to compare the experimental results with the actual field situation, on both experimental occasions, surface water samples were collected also from three stations situated along the river. The samples collected were analysed for iron, calcium, and trace metals by AAS and ICP-MS. The iron oxyhydroxides formed in the experiment did not influence the partitioning of As, Cu, and Pb to the same extent as the particulate iron encountered along the river appeared to do. Cd and Zn were recovered mainly in the dissolved (

Jan 1, 2003

By Larry Stolarczyk

A clear vision of the future coal mining industry was developed into a hierarchy of technology needs by the National Mining Association (NMA) and the Chief Executive Officers of the mining industry. Although improvements in safety and environmental factors were the main drivers in the technology roadmapping workshop sponsored by the Department of Energy, the agile mining machine of the future must efficiently extract coal from deeper, thinner, and more geologically complex coal beds. One of the challenges will be to develop sensors and software that enable clean coal cutting in a changing geologic environment. The roadmap identifies imaging ahead of raining and horizon control within the top ten needed technologies. For these technologies to be adopted by the mining industry, they must be proven to be effective while driving down mining cost and risk. This paper describes how three-dimensional imaging ahead of mining and horizon sensors enable improved ground control and safety in the mining of underground coal.

Jan 1, 2003

By Mark L. Dietz

The unique physicochemical properties of room-temperature ionic liquids (RTILs) have led to intense interest in these materials as alternatives to conventional organic solvents in a range of synthetic, catalytic, and electrochemical applications. Recently, there has been growing interest in their potential use in various separation processes, among them the liquid-liquid extraction of metal ions. Although certain RTIL-extractant combinations (e.g., crown ethers in 1-alkyl-3-methylimidazolium bis[(trifluoromethylsulfonyl] imides) have been shown to provide extraction efficiencies far exceeding those observed with conventional solvents, recent work suggests that the utility of RTILs may be limited by solubilization losses and difficulties in recovering extracted metal ions. In this work, we demonstrate that these limitations arise, in part, from differences in the mechanism of metal ion partitioning in RTIL systems versus conventional organic diluents and consider approaches by which they might be overcome.

Jan 1, 2003

At its Copper Cliff Smelter, Inco Limited processes a bulk copper-nickel concentrate in two Inco oxygen flash furnaces. The furnace matte is converted to low iron matte for further processing, and the molten converter slag is recycled to the flash furnaces. The flash furnace slag is discarded. Natural gas or coke supplies a minor proportion of the process heat requirements, thus limiting the flash furnace matte grade to the target 45% CuNiCo. Coke addition to the furnace offers a potential means of establishing a reducing barrier on the surface of the molten bath. Such a practice would be conducive to producing sulfur deficient (partially metallized) matte. At the same iron content, the iron activity of sulfur deficient matte is higher than that of regular matte. A supernatant coke barrier could, therefore, be expected to lead to higher nickel and cobalt recoveries, reduction or even elimination of magnetite furnace bottom build-up and increased sulfur elimination as SO2 in the flash furnace. Preliminary experiments were conducted in a mini plant flash furnace to investigate the effect on process metallurgy of the suggested modified scheme. This paper presents the experimental results and discusses key aspects of the possible operation of the Inco flash furnace with a coke barrier separating the freeboard from the molten bath.

Jan 1, 2003

By Aziza A. Yousef, Suzan S. Ibrahim, Mahmoud A. Arafa, Mohamed A. Abdel Khalek

Due to the shortage of fresh water in the Middle East, seawater has been used as an alternative in flotation beneficiation. The flotation process requires about 7 m3 of water/mt ore. This article aims to study the effect of seawater cations and anions on the flotation. Natural pure francolite, calcite, dolomite and quartz were characterized by chemical, thermal and x-ray diffraction analyses, surface area, solubility and zeta potential. Synthetic seawater was prepared with the major chemical composition similar to natural seawater as follow; 2.45% NaCl, 0.52% MgCl2, 0.41% Na2SO4, 0.116% CaCl2 and 0.07% KCl. Also, natural seawater was used in application. The point zero of charge was estimated at pH 6.5, 7.8, 9.2 and 2.2 for francolite, calcite, dolomite and quartz, respectively. Calcium ions were released from the three minerals with Mg2+ and P2O5 3– released from dolomite and phosphate, respectively. The adsorption of collector, zeta-potential and floatability of pure minerals were studied. The effect of individual cations and anions predominant in seawater are studied on individual mineral or group. The troublesome Ca2+ and Mg2+ ions should be controlled by soda ash addition. Sodium silicate improved the selectivity of mineral mixtures and natural ore. At optimum conditions the calcareous phosphate ore yielded a concentrate of 34% P2O5, at 83% recovery with 0.61% MgO, from an ore assaying 25.3% P2O5 and 9.4% MgO. To minimize the Clcontent, fresh water of about 0.5 m3 /t was used and the Cl- decreased to about 0.09 %

Jan 1, 2003