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By R Herbert, M E. Malmstr÷, S U. Salmon

The study focuses on sulfide oxidation processes in unweathered pyrite-rich mine tailings from a soil-covered impoundment in northern Sweden. To simulate the oxygen-limited conditions in water saturated tailings two long-term column experiments were performed. Results are presented for the first 11 months of the experiments at room temperature. The tailings used in the experiments were of two different grain sizes (one coarse grained, in the range 0.02 - 0.6 mm with a grain surface area of 1.86 m2 g-1, and one fine-grained, in the range 0.0015 - 0.06 mm with a grain surface area of 10.00 m2 g-1) and with slightly different mineralogical composition. The S:Fe molar ratio in the leachates (1.0 - 1.5) indicates either that pyrrhotite is the main iron sulfide undergoing oxidation in our experiments, or, alternatively that the S:Fe molar ratio in the leachate is determined by pyrite weathering in conjunction with other processes releasing iron or immobilising sulfate. However, speciation modelling of the leachates indicates that ferrihydrite was close to saturation, suggesting that a ferric oxyhydroxide may have dissolved/ precipitated during the experimental period, thereby affecting the S:Fe molar ratio. Pyrite oxidation rates obtained from the two column experiments during æsteady-stateÆ were 2.25 + 10-13 and 8.45 + 10-14 mol m-2 s-1 in the coarse and fine tailings, respectively. Pyrrhotite oxidation rates, as an alternative, were 2.31 + 10-12 and 1.24 + 10-11 mol m-2 s-1 in the coarse and fine tailings, respectively. Natural microbial activity was confirmed in both the tailings and the leachates; therefore, the obtained oxidation rates are not strictly abiotic. It is thus concluded, based on the experimental results, that tailing heterogeneity will result in zones with different oxidation rates, related to their physical and chemical properties.

Jan 1, 2003

By Ch. Schroeder, F. Collin, R. Charlier, Y. J. Cui

The paper proposes two numerical models ot the mechanical behaviour of chalk. First, an elasto-plastic constitutive law reproduces the different plastic mechanisms of the chalk and the influence of pore fluids by introducing the concept of suction. Secondly, a model able to reproduce time dependence behaviour. Eventually, the paper gives a simulation of an academic reservoir during depletion and waterflooding phase. Der Artikel stellt zwei numerische Modelle des mechanischen Verhaltens der Kreide vor. Das erste ist ein elasto-plastisches Modell, das verschiedene plastische Mechanismen der Kreide und den Einfluss von Porenflüssigkeit, unter dem Begriff der Suktion, reproduziert. Das zweite Modell berücksichtigt darüberhinaus das zeitabhängige Verhalten. Schliesslich zeigt die Veröffentlichung eine Simulation einer theoretischen Lagerstätte während der Entleerung und der Wasserinjektion. L'article propose deux modèles numériques du comportement mécanique de la craie. Le premier est une loi élasto-plastique qui reproduit les différents mécanismes plastiques de la craie et l'influence du fluide interstitiel par l'introduction de la notion de succion. Le second est un modèle prenant en compte les effets différés. Enfin, l'article présente une simulation d'un réservoir académique durant les phases de déplétion et d'injection d'eau.

Jan 1, 2003

By Bora Derin

The partial pressure ratios of sulfur and oxygen for several copper flash smelting plants were derived using the Reddy-Blander (RB) model and predicted dissolved sulfur contents available in the literature. The sulfide capacities (Cs) of six different flash smelting plants (FeO-CuOo.5- CaO-MgO-FeOu-AlO15-SiO2) slags were calculated. The log (PO2/PS2) versus matte grades of various industrial processes was determined. The PO2/PS2 ratio increased with an increase of copper grade. The calculated partial pressure ratios for the copper flash smelting are in good agreement with those of the experimental data.

Jan 1, 2003

Published by ?MILOS CONFERENCE CENTER ? GEORGE ELIOPOULOS? Editor Professor Z. AGIOUTANTIS Editorial Coordinator HELIOTOPOS ? PROFESSIONAL CONGRESS ORGANIZERS Layout IRINI KALOGIRU Production HELIOTOPOS ? PROFESSIONAL CONGRESS ORGANIZERS Cover PANAYOTIS PAPASTAMATIS HELIOTOPOS - PROFESSIONAL CONGRESS ORGANIZERS

Jan 1, 2003

Mining is an intensive resource development industry, where operations are often of relatively short duration and can result in dramatic impacts on the natural environment during the operational period and for many years post mining. An integral component of all mining operations is water û through exploration, resource definition, mine development and operation, rehabilitation and the long-term post-mining land use. Water is a basic requirement in the provision of worker amenities, in drilling, as a means of dust suppression, as a medium for washing or processing the mine product, and as an aid in establishing vegetation on post-mining landforms. Water also plays an important role in mobilising environmental contaminants and is the primary medium for the transport of contaminants off the mine or processing site into the wider environment. It is for this second reason that the mining industry considers water management as a key component of mine management. Cost-effective water management relies on planning that incorporates a total mine system approach commencing prior to exploration and continuing through to rehabilitation and decommissioning. One of the primary considerations that will provide confidence to both government and community at the time of mine closure and lease relinquishment, will be the evidence that any water originating from, or passing through, the mine site is of a quality that will not have any negative impact on the surrounding environs into the future. The role of vegetation in stabilising disturbances to a landscape is well known, as is the recognition of vegetation being a fundamental component of the water cycle through the physiological processes resulting in the transfer of water back to the atmosphere through transpiration. In terms of water management at a mine site, the two crucial issues are the æquantityÆ and æqualityÆ of water that enters a receiving æoff-leaseÆ catchment. In terms of tolerances of the receiving environment, the total load of potential contaminants becomes critical, a reduction in which can be achieved through reduced volumes of water discharged, reduced chemical and physical concentrations of contaminants in that water, and ideally, both. This paper examines the potential role of vegetation in reducing the quantity of water released from a site, and secondly considers vegetation in the role of influencing the quality of that water.

Jan 1, 2003

By Jhon Cuya

Titanium dioxide is the well-known catalyst for the photodecomposition of water in UV region and its nanoparticles show better performance than its bulk materials. Furthermore, partially sulfurized TiO2 is expected to be chemically stable and have an enhanced photocatalytic activity compared with TiO2. For this purpose, the sulfurization behavior of TiO2 nanoparticles was thermogravimetically (TG) studied by a thermo-balance with a quartz spring using CS2. From the TG curve of TiO2 nanoparticles, first, the weight decrease appeared down to around 8 wt% and then sulfurization reaction started at around 500 °C at heating rate of 1O 'Cumin. The weight increase curve showed a maximum of ca 30 wt% at around 750 T and then gradually decreased to ca 12w% at 1000OC. This would be caused by the formation of TiS2 followed by the decomposition of TiS2 to lower sulfides, such as Til.08S2 and Ti3S4. From the comparison of the sulfurization of TiO2 nanpparticles with that of anatase, rutile and Ti(OH)4, it was found that TiO2 nanoparticles showed a similar behavior to that of Ti(OH)4.

Jan 1, 2003

By R Carreau

The results of a detailed acid rock drainage (ARD) prediction program were used to revise the waste rock segregation criteria at the Restigouche open pit mine. Waste rock at the site was predominately derived from altered volcanic rocks that hosted a massive sulfide lead/zinc orebody. The program assessed the five years of drainage chemistry from both the potentially acid generating and the non-acid generating waste rock storage facilities in addition to laboratory-based kinetic test results. Material-specific leaching characteristics including relative metal-release rates and neutralisation potential depletion rates were determined from 12 laboratory-based kinetic tests. Solid-phase analyses indicated that, although pyrite was typically the most abundant sulfide mineral in the waste rock, its abundance varied significantly as documented by total sulfur contents ranging from 4.0 per cent. Kinetic test results were used to establish revised waste rock segregation criteria based on total sulfur content and neutralisation potential. The revised criteria maintain that waste material with a total sulfur content 4.0 per cent as potentially acid generating. When present in sufficient quantities, ankerite provided an effective source of neutralisation potential for the range of observed sulfide oxidation rates. Kinetic testing documented that up to 6 kg CaCO3/t was ineffective at neutralising acidity in samples that contained >4 per cent S. The carbonate molar ratio measured from the humidity cells was adjusted to reflect the stoichiometry of the ankerite and applied as an NP/AP criteria for waste rock containing 0.1 <S per cent <4.0.

Jan 1, 2003

By J. H. Huang

In this investigation, the selective precipitation of cobalt and molybdenum from Co-Mo aqueous solutions was studied in order to recover efficiently valuable elements from industrial effluents generated from a novel electrodeposition of nanocrystalline Co-based alloys process and reduce the effluent impact on environment. It was found that the behavior of cobalt in aqueous solutions was substantially affected by the presence of molybdenum. When adding 11.6 to 46.6g/L molybdenum to a 50g/L cobalt solution, the co-precipitation of molybdenum and cobalt started to occur at pH value of 3-4. However, without the presence of molybdenum, cobalt could only be precipitated out of the solution at about pH 6. Most of the molybdenum was found in the solid phase when the solution pH reached 5. After further increasing pH to greater than 7, the molybdenum dissolved back into the solution. Cobalt kept precipitating as the pH increased. When the pH was greater than 7, most of the cobalt was present in the solid phase. The chemical and physical characteristics of the precipitated materials were investigated by SEM, XRD, AAS and EDX. It was revealed that the precipitate was initially present as cobalt molybdate oxide hydrate and subsequently transformed as sodium cobalt molybdenum oxide. With further increasing the solution pH, the precipitate was transformed into cobalt hydroxide. Further investigation implied that most of molybdenum was chemically tied to the precipitate produced at the low pH, yet at the same time, physically entrapped at the high pH. The paper also presents the influence of reaction temperature and time on the precipitation process and kinetics.

Jan 1, 2003

By G. C. Yao

Iron and silicon impurities can form needle and branch shape intermetallie compounds in molten aluminum when there is no manganese. It is difficult to separate them from molten aluminum by electromagnetic separation. The Fe-Si-AI and Fe-AI intcrmetallic compounds were transformed into Mn-Fe-Si-AI and Mn-Fe-AI compounds by the addition of manganesc into molten aluminum, In molten aluminum the morphology of these intermetallic compound particles is lumpish and spherical. Migration resistance of these impurity particles is small, which is beneficial to separation. FeSiMnAl4 and FeMnAl6 arc paramagnetic. These impurity particles can be moved by magnetic force and can be separated from the molten aluminum.

Jan 1, 2003

By R C. Cox

The Brukunga pyrite mine was operated from 1955 to 1972 to supply feedstock for sulfuric acid production in the South Australian fertilizer industry. Iron sulfide ore, mined by Nairne Pyrite Ltd, was finely crushed and concentrated onsite with the concentrates being sent by road and rail to Port Adelaide for roasting. Waste rock was dumped at two locations on the western side of Dawesley Creek and the tailings pumped to a valley-fill storage facility on the eastern side. Production of 1.5 Mt concentrate resulted in 3.5 Mt tailings and 8 Mt waste rock. The site has been administered by the South Australian Government since August 1977 and a lime treatment plant has been operated on the site since September 1980. Environmental issues arising from these operations included: diversion of Dawesley Creek to accommodate the waste rock dumps; dumping of low-grade sulfidic ore in waste rock dumps at the angle of repose immediately adjacent to Dawesley Creek; exposed fresh sulfide mineralisation in the quarry floor; tailings storage facility dam wall constructed by upstream up-lift using tailings and waste rock; an acid water pond sited on the tailings; and pollution of natural drainage. As a result, the minesite rapidly became a source of acid drainage and potential contaminants (sulfate, Al, Fe, Mn, Cd, Zn, and Ni). Various Government bodies have been responsible for considerable effort and expenditure in reducing the flow of acid seepage and contaminants into Dawesley Creek. Presently an estimated 60 per cent of seepage from the waste rock dumps, tailings storage facility and quarry is collected and neutralised prior to discharge into the creek. Tailings have been covered with waste rock, biosolids, neutralisation sludge and soil and planted with grasses, shrubs and trees to reduce rainfall infiltration. Monitoring of water flows, water quality and riparian ecosystems is on-going. Consultants have been engaged to develop cost-effective remediation techniques and a five-member Brukunga Mine Site Remediation Board was appointed to oversee remediation of the site and liaise with the community. Construction has commenced on the diversion of Dawesley Creek, and plans are being developed for the relocation of waste rock back to the quarry benches and upgrading of the neutralisation plant. The paper examines operations, environmental monitoring, remediation, research and community involvement with respect to current best practice.

Jan 1, 2003

By John Frostiak

"Kahama Mining Corporation Limited, a wholly owned subsidiary of Barrick Gold Corporation, poured the first dore bar and filtered the first concentrate produced at the Bulyanhulu mine on February 28, 2001. This event marked the completion of the initial development of the Bulyanhulu Mine – Barrick’s first mine located outside of the Americas.Bulyanhulu is a 2,500 tpd underground mine located in the Lake Victoria gold belt of northern Tanzania. Gold is recovered as a gravity concentrate and smelted on site to produce dore bars or collected in copper concentrate that is shipped to offshore smelters. The facilities were constructed to meet Canadian standards. Unit operations include single stage crushing, SAG milling, gravity recovery, flotation, thickening and dewatering. Tailings are converted to paste and returned underground as paste backfill or pumped to the surface tailing site. The surface paste tailing disposal system is believed to be first of its kind in the gold industry. Paste disposal has several advantages over slurry, including lower dam construction costs, reduced water losses, and lower reclamation costs. This paper describes the facilities and discusses the challenges faced during development and construction including logistics, lack of infrastructure, recruiting and training, security, and social issues as well as initial operating results.INTRODUCTIONBarrick Gold Corporation completed the Bulyanhulu mine development in 2001. Capital cost of the project was US$280 million. The mine produced 241,575 ounces from start of milling to year end at a total cash cost of $197 per ounce. Numerous challenges were overcome in the mine’s development due to the general lack of infrastructure in Tanzania and the mine’s location some 1200 km inland by road from the port of Dar es Salaam."

Jan 1, 2003

By J. I. Adetunji

Mining activities usually affect the soil, subsurface layers, water resources, the atmosphere and in general the lives of the people. The effects can be mechanical, biological, ecological and economical in nature and these effects can be characterized by their intensity, frequency, duration and scale. In Oyo State, Southwestern Nigeria efforts are being made to employ a sustainable method in the exploration and exploitation of abundant industrial minerals present in the state. The minerals exploited include talc, clay, marble, sillimanite, tantalite, niobium, beryl, tourmaline aquamarine, rock aggregates, etc. Results of this sustainable approach show that the environmental impacts of surface and underground mining of industrial minerals are not spread far beyond the mines site acreage. More lands are being reclaimed, the amount of dust released into the air has been minimized, the quality of sewage waters produced during operations are minimized, top soils removed during subsurface mining are preserved, the tonnages of minerals exploited are being monitored and controlled. All these point to a positive development in practicing sustainable methods in mineral exploitation to meet the developmental needs of the Oyo State at present and to conserve for the future.

Jan 1, 2003

By D. P. Hatfield, G. de Jager

"Recent developments in image analysis techniques and the power of computer hardware have spurred international interest in the potential uses of image analysis techniques in a range of industrial applications. One of these applications is the control of the complex flotation process. Despite years of work, the flotation process is still poorly understood. Current attempts to control flotation cells focus on consistently duplicating the control achieved by human operators.In human control of flotation two of the dominant visual cues are the froth flow speed and the froth stability. These two factors can be measured and inferred respectively from image analysis of video of the froth surface. Two important hydrodynamic variables for control of the flotation process are the air addition rate and the level of the froth pulp interface.The current work focuses on the relationship between froth flow speed and the rate of recovery of concentrate from a flotation cell. Results are presented that show a strong relationship between flow speed and concentrate yield. These results include tests where the conditions in the cell were not changed, as well as tests involving changes to the cell level and air addition rate. Preliminary results are presented which show a correlation between froth stability and froth percent solids.Future developments of the system will include comprehensive froth texture typing, colour space and stability analyses."

Jan 1, 2003

By Heinrich Hutchison, Thomas von Moltke, Roelof F. Sandenbergh, Katarina P. Cerovic

In the leaching of gold in aqueous cyanide solutions the rate of gold leaching may be decreased by the passivation of the gold, that may however be prevented or reversed in the presence of lead species in solution. In the present study potentiostatic, potentiodyanamic and XPS (X-ray photoelectron spectroscopy) analysis were used to further clarify the action of lead ions on the anodic activity of gold in alkaline cyanide solutions. It was found that lead increased the gold dissolution rate as it deposited on the gold surface at potentials more positive than its reversible Nernst potential for bulk metal deposition, i.e. by underpotential deposition mechanism, but that it decreased gold activity if present as bulk plated lead on the gold.

Jan 1, 2003

By B. Solar Menéndez, M. B. Díaz Aguado, I. Á. Fernández, C. González Nicieza

The analysis of subsidence due to the opening of an underground void (mining, water exploitation or civil works hole) is a problem usually hard to solve. First of all, it requires a predictive model, in order to define both the displacement magnitude and area affected by subsidence. Such model should be validated with measurements of the actual movements sustained on the surface, in order to adjust it properly and enable influence of future behaviour in a reliable way. Two different kinds of problems might arise. On one side, it is necessary to control and measure surface movements in a very exhaustive way during a long period of time, beginning before underground works take place and finishing years after they are over. Furthermore, three factors bring in errors, some times of magnitudes higher than the displacement magnitudes measured. These include: the fact that reliable and long-term information cannot always be achieved; the precision of measuring devices; and the design of the topographical network itself. In addition, the predictive models more widely used only apply to certain excavation geometries, mainly to horizontal holes. In light of this background, the Group of Rock Engineering, of the University of Oviedo Mining Department, has developed a working methodology and a specific software tool, Subsidence 3D, to estimate ground displacements and strains. The program will allow for predictive models to be defined and also allows the treatment of data related with topographical marks and its comparative analysis with calculated results. The software has been programmed using Visual C++. Graphical outputs however are generated using AutoCAD 2000. This paper mainly refers to a practical situation, an underground coalmine, remarking the main difficulties arisen during the study of the available information and proposing how to solve them. A predictive model in subsidence 3D was established and validated. The actual behaviour of the ground was that in the model.

Jan 1, 2003

By Markus A. Reuter, Yongxiang Yang, James R. Post

The packed coke bed in the lower part of an iron making blast furnace, the dead man, dissolves slowly in a pool of hot metal, which is tapped regularly. The coke particles of the dead man not only exhibit a size distribution, but also their size distribution is non-uniform throughout the dead man and as a result, the porosity of the dead man is non-uniform. This causes the flow of hot metal through the dead man to be irregular and non-uniform, bringing about channelling in the coke bed. Channelling is detrimental to the refractory lining life of the hearth of a blast furnace. Using population balance modelling and a porosity model it is possible to keep track of the local changes in size distribution and bed porosity during dissolution of coke particles. Numerical simulations show that carbon dissolution from a packed coke bed (with particles which exhibit a size distribution) increases the average porosity, decreases the mean particle size and changes the size distribution to a distribution with a smaller size range. Influence of the type of initial size distribution (mean, variance) is investigated. The calculated changes in porosity are used to dynamically adapt the flow and the mass transfer (kinetics) during calculations. This approach provides the possibility to implement dynamic porosity calculations for CFD applications, and thus simulate the results of various coke types and particle size distributions on dissolution and flow behaviour.

Jan 1, 2003

By Yi Luo

The severity of disturbances caused by longwall mining subsidence to various residential structures can be re¬duced. The success of such mitigation efforts depends on accurate subsidence prediction, correct assessments of the subsidence influences, and careful design and implementa¬tion of the proper mitigation measures. This paper presents the systematic approach involved in the subsidence mitiga¬tion efforts with a case demonstration.

Jan 1, 2003

By J J. McNee and, J Crusius, T F. Pedersen

The use of water covers is a globally-applied method for minimising acid rock drainage (ARD) and metal leaching. Although the subaqueous disposal of potentially acid-generating materials has been shown to effectively limit ARD, under certain scenarios, metal remobilisation can occur at circum-neutral pH. The following paper presents data from four case studies in which metal mobility from submerged mine waste resulted in degradation to water quality in the overlying water cover. Subcentimetre resolution profiling of dissolved constituents across the tailings-water interface (dialysis arrays), in conjunction with mineralogical information, were used to elucidate the controls governing metal mobility. The data illustrate four pathways of metal remobilisation, including: the release of zinc via the oxidative remineralisation of metal-rich organics at the tailings-water interface; enhanced remobilisation of arsenic as a result of anthropogenic eutrophication; the release of copper resulting from the pH-driven dissolution of treatment sludges; and the release of radium from uranium mill tailings due to the dissolution of radiobarite [(Ra,Ba)SO4] by sulfate-reducing bacteria. The results highlight the conclusion that the chemical stability of submerged tailings reflects both: the solid-phase characteristics of the tailings material; and the physical, chemical and biological characteristics of the depositional environment. In particular, the data illustrate that rigorous characterisation of both the waste solids and receiving environment must be performed in order to assess their compatibility. The results have relevance to the management of tailings repositories including constructed impoundments, pit lakes and natural lakes.

Jan 1, 2003

By C. G. Anderson

Over the past 15 years numerous pressure oxidation plants for pretreatment of gold ores and concentrates have been installed throughout the world. While, this technology is now established, it suffers in term of the complex engineering and operational characteristics inherent in utilization of high temperatures (i.e. up to225°C) and high pressures (i.e. > 400 PSIG). This paper outlines the application of an industrially proven pressure leaching methodology utilizing nitrogen species catalyzed pressure leaching and alkaline sulfide gold leaching. As such, it stands as an economic and engineering advancement in pressure leach treatment of gold ores and concentrates.

Jan 1, 2003

By John Hollow

The Fort Knox Mine is an open-pit operation, located in Alaska, which started commercial production in March 1997. A conventional Mill processes 38,000 tpd of a low grade (1.0 g/t Au) free milling gold ore with a low sulphide component (below 1%). Gold production (11% from gravity and 89% from cyanidation) exceeds 400,000 ounces per year. Short retention time (20h), low temperature (7oC) and low grade make high leaching kinetics critical for the performance of the process. In April 2001, the treatment of True North ore, which represented 14.4% of the mill throughput and contained more sulphide in the form of pyrite, arsenopyrite and stibnite, resulted in a substantial drop in the average gold extraction from 87% to 72.6%. Laboratory investigations indicated that the addition of lead nitrate increased gold extraction to 91.7%. Further investigations were initiated to determine the leaching parameters and the nature of the problem. Subsequently, a lead nitrate addition scheme was implemented at the Fort Knox Mill that resulted in 2002 gold production being in excess of 31,000 ounces higher than that estimated for the non-lead nitrate reagent scheme. This paper presents the results of laboratory investigations and modifications in plant operating practices.

Jan 1, 2003