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By Horst H. Gielen

Bong Mining Company/Liberia provides the rare opportunity to compare two generations of grate kiln pelletizing plants operating on the same magnetite/hematite ore basis. In this paper advantages and drawbacks are compared: mechanical aspects, energy-savings, pellet quality. Plant I with up- and down-draft drying gas flow. Plant II runs only on down draft drying and incorporates a heat-recoup system. Ferteco Mineracao/Brazil operates a Lurgi straight grate plant since 1977 on hematitic pelletfeed. Energy-political situation and char- coal as energy source in Brazil are reflected also in the search for alternative fuels for pelletizing. First measures and results are reported as well as intended further steps towards a 100 % oil replacement.

Jan 1, 1983

A simple method of designing effective fill drainage systems for slurry backfill is presented. By using the proposed method, it is easy to calculate and predict the expected fill drainage rates or to provide additional drainage systems to accelerate the fill drainage. The fundamentals of hydraulic fill and an efficient method to determine its permeability is also explained. The safety in hydraulic filling and bulkhead stability depends totally on achieving effective drainage regime for the fill. This paper provides the basis for creating such efficient drainage regimes. The recent fatal fill bulkhead failures in Australia were the result of poor drainage from the respective fill masses, and therefore it is more important to provide suitable drainage arrangements to continue using hydraulic fill to the benefit of the mining industry. At present there is no procedure available to mine operators to estimate the expected bulkhead pressures to design a satisfactory bulkhead. Some mines are constructing bulkheads after their initial investigations carried out years ago. Other mines have simply borrowed the ideas from the pioneer mines and using in their areas. It is high time that we develop a rational approach to estimate the expected bulkhead pressures for the design of bulkheads. We need a simple model that could be understood and used by the mine operators on a day-to-day basis. This paper also presents a model to predict the bulkhead pressures for designing safe bulkheads.

Jan 1, 2002

By P. Bevilacqua, G. Ferrara, M. C. Williams, T. P. Meloy

Tabling is an old environmentally friendly separation unit operation. This paper models shaking tables and explores the action and design of riffles on shaking tables. By reassessing riffle shape and riffle patterns, significant improvements in tabling performance appear feasible. While table sales appear at their nadir, a high-tech environmentally friendly table may have a significant market in the coming decade. Riffles on a shaking table impact particle separation. Particles are affected by riffles and their exit position on the table is dramatically changed, Riffle shape determines how much the riffle will influence a given material. Moreover, riffle patterns influence the concentration of a given material and its exit points on a table. This effect of riffle placement and design is modeled in a spreadsheet. Major performance and separation improvements may he expected by improved table design. Two physical laws of tabling have been derived. These laws aid in the design of sophisticated high-tech tables.

Jan 1, 1995

By A Gerdes, H BrStz, E GSbler, D Davis, F Henjes-Kunst, S Dewaele, T Graupner, T Oberthnr, M Sitnikova

Following the United Nations initiative to fingerprint the origin of conflict materials, the German Federal Ministry for Economic Cooperation and Development has decided to fund a pilot study on coltan ores. Since 2006, our working group has been investigating columbite- tantalite (coltan) mineralisation, especially in Africa, also within the wider framework of establishing certified trade chains. More than 300 samples were obtained from the worldÆs major coltan producing areas. Special attention is, however, directed to samples and concentrates from Ta-Nb-Sn provinces in Africa: Democratic Republic of the Congo, Rwanda, Mozambique, Ethiopia and Namibia. Using state of the art analytical tools, we investigate mineralogical and chemical parameters obtained from columbite-tantalite ores and concentrates in order to distinguish between ore provinces, likely even down to the deposit scale. Methods employed include fully automated electron microscopy (mineral liberation analysis), electron microprobe analysis (major and minor elements), laser ablation plasma-source mass spectrometry (trace elements and U-Pb dating), X-ray fluorescence spectroscopy (bulk major and trace elements), X-ray diffraction analysis (mineralogy and structure) and thermal-ionisation mass-spectrometry (U-Pb dating). Major and trace element concentration patterns, mineral assemblages in the ore concentrates, and zoning characteristics in the different pegmatites from Africa distinctly differ from each other. Furthermore, the following age populations are evident:Archaean (>2.6 Ga);Palaeoproterozoic (1.9 - 2.1 Ga);early Neoproterozoic (æKibaranÆ; 0.98 - 0.93 Ga); andlate Neoproterozoic to early Palaeozoic (ca 0.5 Ga). Currently, we focus on the resolution of the fingerprinting system from region via ore province down to deposit scale. Our preliminary analytical results indicate that a certification scheme including fingerprinting of sources of coltan ores is feasible.

Jan 1, 2008

By E. Pourjenaei, P. Ghobadi

High Pressure Grinding Roll (HPGR) is efficient equipment in comminution process. HPGR could be a good option for preparing ball mill feed at the first stage of grinding due to its high efficiency and low energy consumption. Closing with a screen, these mills are utilizing as one of the principle parts in mineral processing industries, especially for iron ores. Recently, HPGRs are working as primary mills at 4 developing lines in Gol-e-Gohar Iron Ore Processing Complex, Iran. Different mechanism of particle crushing in compare to the other tumbling mills makes the HPGR as certain equipment with its own particular controlling parameters. Hydraulic pressure, roller speed and level of material inside feeding hopper are the most important variables influencing grinding efficiency of the HPGR. To figure out how they impress the process and operation situation, different industrial tests were carried out and the best result (d80 about 8 mm for HPGR discharge) was achieved at 180-190 bar pressure (P), 300 rpm speed (S) and 50% of hopper level (L). It is worth noting that this finding has been observed through past pilot test too. We also used design expert method (DX7 software) to develop the best design and analysis the test results, as well. According to the mechanical restriction of HPGR and process limitation in the plant (based on the industrial results), we adjusted value of each parameter in a logical range. Therefore, 20 industrial tests were conducted, as DX7 recommended, and the various impacts of the parameters and their interaction were identified based on statistical analysis. As the authors expected, it was revealed that after presser, roller speed is a critical variable because of its significant role in residence time of the particles between the rollers. The function below has been determined to explain the relation between different parameters and the response.

Jan 1, 2018

Jan 1, 1970

By H Dehghan Jan Abadi, K Shahriar

The iron ore district of Gol-e-Gohar (GEG) is located 60 km south-west of the city of Sirjan, in the Kerman Province of the Islamic Republic of Iran. Six exploration targets have been identified and iron ore has been mined from one area with dry and wet concentrate products sold. Prior to mining commencing in 1999, the proven reserves were estimated at 265 million tonnes (Mt) in 2004 and 40 Mt of 100 Mt overburden has since been mined. Of the six exploration targets, the largest anomaly in the GEG district is Deposit No 3. This paper discusses economic considerations focusing on mine extraction and construction of a concentration and pelletising plant to process ore from Deposit No 3 of GEG. Planned capacity of 10 Mt product (concentrate and pellet) per year is targeted to commence in 2011, and nominal capacity by 2014. The economical evaluation and analysis is one of the most important stages in the feasibility study of mine development. Financial calculations including the provision of financial resources, operation period revenue, loss and profit statement, cash flow, net cash flow, internal rate of return and net present value have been undertaken as part of the feasibility study. The feasibility study operating plan assumes a large open pit mine containing proven reserves of approximately 250 Mt. The feasibility study assumed an economic return of $80 per tonne iron pellet. The economic study determined that Deposit No 3 of GEG can be economically developed by open pit mining followed by magnetite separation and flotation to generate iron concentrate and pellets.

Jan 1, 2007

"The global demand for the copper metal is continuously increasing however, the high-grade copper ore deposits are constantly depleting. As a result, ore bodies with complex mineralogy characteristics and rich in arsenic-copper bearing minerals are increasingly processed. Arsenic-copper sulphides such as enargite can represent a significant amount of arsenic in concentrate, which causes high financial penalties by smelters. On the other hand, arsenic (As) is a highly toxic inorganic pollutant, which causes human health and environmental problems. Recent research studies have demonstrated promising results showing the possibility of separating arsenic-copper sulphides from copper sulphides using controlled pulp potential (Eh) flotation at laboratory scale. However, the selective removal of arsenic-copper minerals in real ore systems is not well understood. Two ore samples were selected from the Tampakan copper-gold deposit located in the Philippines named the HAS (high arsenic sample) and the LAS (low arsenic sample) samples and the mineralogical analyses were performed on both samples. The floatability of enargite in a batch flotation system under controlled pulp potential conditions was investigated for the HAS and the LAS samples. It was observed that it is possible to selectively separate enargite from other copper minerals after reducing the pulp potential to about -200 mV SHE at pH 11 in the LAS sample. However, no separation between enargite and other copper minerals was observed at a reducing potential for the HAS sample. Mineralogical analyses and surface chemistry studies were undertaken for both samples to find out the reasons for different observations. This study has an important implication in sulphide flotation to achieve sustainable development in the utilisation of arsenic-copper mineral resources. INTRODUCTIONAs the demand for copper is increasing, the extraction and development of resources including complex deposits is becoming necessary. These complex deposits often have issues such as: lower grade ores, floatable non-sulphide gangue, very fine-grained ore and therefore poor liberation and significant regrinding, mixed copper mineralogy, complicated galvanic interactions, economic levels of gold and silver, and high levels of impurities such as arsenic. There is currently no established methodology for separating arsenic-bearing copper minerals from other copper sulphide minerals by flotation. The possibility of separating arsenic-copper sulphides from other copper minerals by controlling the potential of the flotation pulp has been shown in previous studies. However most of these studies were conducted on single mineral systems and the selective removal of arsenic-copper minerals in complex ore systems is not well understood. The flotation behaviour of arsenic-bearing minerals within complex ores differs significantly from that of pure mineral systems due to the effects of mineralogical composition, the degree of liberation, and the surface oxidation. The understanding and manipulation of these effects can lead to improvements in the selective flotation recovery of arsenic-bearing species from complex ore systems."

Jan 1, 2018

By Norman A. M Macleod

FOR the past seven years, all flotation at the Britannia mill has been done in Forrester Air-Lift cells. Prior to 1931, the roughing and part of the cleaning operation had been performed in four 21-cell and two 14-cell M.S. machines. The resulting economies in reagent, power, maintenance, and general operating costs, and the increased recovery, more than justified the exclusive use of the Forrester machine. About three years ago, the possibility of still further improving the efficiency of the flotation section was the subject of considerable discussion and experiment. Arising from these experiments, tests were made of the practicability of using a cell of greater depth than that of any pneumatic or mechanically-agitated machine in common use. Cells were constructed with depths of 7 .5 feet, 10 feet, and 15 feet, and, in all cases, a very definite improvement in operation was indicated. The cell now being used in the mill treats from 5,500 to 6,200 tons of dry feed per day. It is 100 ft. long by 5 ft. wide by 8 ft. deep, and has replaced a total length of over 500 feet of standard Forrester machine. The choice of a depth of 8 feet was governed by the type of blower which was available-in this case, a Roots-Connersville blower, driven by a synchronous motor and delivering 6,000 c.f.m. of free air at 4.0 pounds per square inch. At the Chelan Division of the Howe Sound Company, where a new mill was recently built, all flotation is carried on in cells 10 feet deep, with good results.

Jan 1, 1938

An investigation was made into the mineralogical characteristics of the upper portions of the 650 and 750 copper lodes. The investigation was based on a comprehensive suite of geological specimens representing all types of mineralization encountered during mining until the end of 1954 and the chief aims of the investigation were to determine (a) the minerals present and their textures and associations, (b) the paragenetic sequence of deposition of minerals in the orebodies, (c) significant changes, if any, which could be found in the orebodies with depth, and (d) the nature and mode of occurrence of nickel in the ore. The general structure of the orebodies is outlined and their mineral composition given. 10 textures exhibited by the ore minerals are described and a paragenetic sequence of events in the formation of the copper orebodies is outlined. No decrease in the complexity of the sulphide mineral textures with depth could be seen and no evidence was found to suggest that the tenor of the ore would decrease with depth although some factors which may eventually limit the extent of the orebodies are noted. The mode of occurrence of minor elements in the orebodies is described. Notes on the occurrence of pyrite, aikinite and berthierite in the orebodies is given and the orebodies are considered to be identified with LiIidgren's mesothermal type of sulphide ore deposit in which considerable replacement of older by younger generations of sulphide minerals occurred.INTRODUCTIONA mineragraphic study was made by Stillwell and Edwards (1945) of a suite of specimens submitted by Mount Isa Mines Limited from the Mount Isa Black Star copper orebodies with a view to determining 1. the nature, extent and association of arsenic, antimonyand bismuth minerals, 2. the mode of occurrence of silver and 3. whether galena and sphalerite occurred in minute forms and below the sizes readily observed in hand specimens.

Jan 1, 1961

By W. N. Lacey, R. H. Olds, B. H. Sage

The volumetric behavior of five mixtures of black oil and natural gas and of two mixtures of condensate and natural gas from a field in the San Joaquin Valley was experimentally established. This work was carried out at roo°, I9o° and 250°F in the pressure interval between 400 and 5000 psi. The viscosity of the liquid phase of four mixtures of black oil and natural gas was experimentally measured in the above-indicated temperature and pressure intervals. The effect of methane upon the precipitation of bitumen from the black oil was studied at 230°F. Introduction The solution of a number of the economical and technological problems which arise in connection with petroleum production is dependent upon the availability of the necessary quantitative information covering the materials involved. This requires data concerning physical properties of naturally occurring hydrocarbon mixtures at the pressures and temperatures characteristic of underground petroleum reservoirs. The experimental determination of the desired data for each situation encountered is relatively time-consuming. However, it is considered to yield results sufficiently more reliable than those obtained from correlations to justify the effort. For these reasons there was undertaken a laboratory investigation of the viscosity of the liquid phase and the volu- metric and phase behavior of mixtures of oil and gas samples obtained from wells in a field located in the San Joaquin Valley. Terminology The nomenclature of petroleum engineering is not at present entirely standardized. Many commonly used technical terms are not everywhere given the same meanings. For the purposes of this paper the following definitions will be adopted: Black oil refers to the dark-colored, hydrocarbon liquid obtained when the producing horizon of the well lies partly in the condensed hydrocarbon phase of the reservoir. Condensate is the term applied to the relatively volatile, pale yellow or amber-colored hydrocarbon liquid that is often obtained from the surface separator system when the producing horizon of the well lies in the gas cap of the reservoir. The gas obtained from the surface separator system is called natural gas regardless of whether the well is producing black oil or condensate. As might be expected from the multi-component character of naturally occurring hydrocarbon materials, the compositions of black oil, condensate and natural gas are subject to considerable variation depending upon the temperatures and pressures prevailing in the surface separator system as well as upon the overall composition of the material produced from the reservoir. In order to obtain samples capable of reproducing the total hydrocarbon material produced by the well, all oil and gas mixtures used in this investigation were com-

Jan 1, 1949

By F. Rosenblum, P. Spira

"Self-heating of broken sulphide ore or waste rock underground can lead to ignition and cause serious problems in a mine operation. An extensive study has demonstrated that it is caused by oxidation of certain species of pyrrhotite. Self-heating was found to take place in two stages, first progressing from ambient temperature to 1000C with exothermic formation of elemental sulphur in the presence of moisture and oxygen, and proceeding to a second stage in which the sulphur oxidizes to SO2. Ignition may eventually follow. An apparatus was developed to assess the propensity of sulphide rock to self-heating and the potential for hazardous behaviour. The effect of temperature, time, rock size, and surface treatment with chemicals is presented. On the basis of these results, possible approaches for preventing a runaway reaction are suggested for further investigation.IntroductionThe oxidation of sulphide ore, waste rock or tailings backfill, which may cause hazardous conditions underground through heating, oxygen depletion and, in some cases, fire, is well documented (Farnsworth, 1977; Ninteman, 1978; Rosenblum et al., 1982; Reimers, 1987). The self-heating mechanism, nevertheless, has not been satisfactorily explained. The onset of heating from ambient temperature, in particular, has not drawn the attention of researchers. In the course of a previous study (Rosenblum et al., 1982) aimed at finding a method to assess the hazard from using sulphide tailings as backfill, the authors developed an apparatus to measure self-heating rate under controlled, near ambient conditions. This has since provided decisive information in backfill investigations in the Noranda Group.The test methodology devised for tailings failed to predict self-heating in a broken waste rock known to be active. Upon repeated testing, however, a freshly crushed sample began to exhibit appreciable heating and oxygen uptake (Fig. I). After 14 tests, the self-heating rate reached a plateau of about 4O°C/h and then fell progressively to < 5°C/h after 30 tests. It was hypothesized that weathering in the presence of moisture and oxygen during testing had caused the onset of self-heating. Active tailings, on the other hand, are exposed to natural surface oxidation and need not be weathered to show heating. Based on this finding, a new apparatus was developed capable of simultaneously weathering a sample of rock and monitoring its self-heating behaviour."

Jan 1, 1995

By F. W. Jessen, John C. Miller

In many areas where carbonate rocks form important parts of the stratigraphic sequence, stratigraphers have experienced varying degrees of difficulty in differentiating and correlating limestone and dolomite units in both surface and subsurface work. With early Paleozoic rocks of the Mid-Continent, insoluble residues yield a remarkable amount of strati-graphic data and relatively good correlations may be carried over broad distances.&apos; Unfortunately, neither such information nor electric logs and radioactive logs have been particularly helpful in interpreting the limestone sections of the Permian Basin of West Texas. This is because: (1) the variations in the sections may be very slight; (2) no completely satisfactory method of interpretation has been developed; and (3) the measurements themselves are not sensitive enough for small variations. Also, such logs are influenced by the fluid content. Paleontology and micro-paleontology remain the ultimate arbiters. As a routine tool, however, paleontol-ogical examination is slow and tedious. Chemical analysis may be used, but this, too, is extremely slow. Although rocks are not classified according to chemical composition, there is considerable variation with rock types. Correlation by chemical composition has two advantages, first, the characteristics determined are subject to minimum human error and interpretation, and secondly, the lithologic changes are not masked by fluid content as in the case of electric and radioactive logs. Some fossils concentrate certain elements which tentatively might be used to date rock units.&apos; Rapid chemical analysis by spec-trographic means could be used as an adjunct to other means employed in correlation work, or might, in itself, present a suitable method. PURPOSE OF THIS INVESTIGATION Sloss and Cooke&apos; have published data concerning spectrographic analysis of limestone rocks specifically for purposes of direct correlation of a single formation. These authors found satisfactory evidence that differences in percentage of four elements (Mg, Fe, Al, and Sr) in the Mississippian limestones of northern Montana were useful in carrying out correlation of this formation over a distance of approximately 50 miles. It was concluded from the preliminary work that the spectrochemical method offered possibilities of solution of some problems of correlation heretofore not possible. Since the work of Sloss and Cooke&apos; was confined to one particular limestone zone, extension of the use of the method to examine two or more geologic formations would aid materially in the over-all problem of correlation of such rocks. Equipment is now available commercially with which very rapid spectrographic analyses may be made, and hence the problem was to determine whether the variations existing in the minor constituents of limestones were sufficient for use in possible correlation. Qualitative and semi-quantitative investigations were made to determine whether significant changes in the chemical condition occurred. It was a further purpose to investigate the geologic time-boundaries to see whether significant chemical variation could be found corresponding to the paleontological breaks. It was desirable to attempt correlation of a thick section of limestone or dolomite rock and to have as much information as possible on the section. Furthermore, it was felt that examination of formations more difficult to correlate by other means would enhance the value of the method should definite points of correlation be found. Samples were chosen from the Chapman-McFarlin Cogdell No. 25 well in the Cogdell field, Kent County, Tex., and from the General Crude Oil Co., Coleman No. 193-2 well in the Salt Creek field, Kent County, Tex. These fields belong to the famous series of "Canyon" reef fields of West Texas. Cores from the above wells were available from the United States Geological Survey, Austin, Tex. THE SPECTROGRAPHIC METHOD The choice of procedure to be followed in this investigation was based on the anticipated requirements peculiar to the problem. Since the problem was primarily to investigate the possibilities of applying the spec-trograph to problems of correlation in thick carbonate sections, a precise quantitative analysis did not appear necessary. A qualitative analysis to show the possible absence of presence of any element, or a semi-quantitative analysis of the elements present to show the relative changes in magnitude of selected elements was required. Both types of analysis were employed. The two most widely applied methods of semi-quantitative estimates are those of Harvey and of Slavin4,5 though various other procedures have been described.6 while the Harvey method has been modified by Addink,7 this refinement did not seem necessary to the present problem. Essentially, the procedure employed is a variation of the total energy method of Slavin with two exceptions: (1) stressing matrix effect, and (2) using densitometer measurements. As measured by a densito-

Jan 1, 1956

By J. R. Addison

Commissioned in September 1987, the Phelps Dodge Morenci, Inc. (PDMI) Central Electrowinning (EW) Tankhouse bas undergone two major expansions in its eleven-year history. A third tankhouse renovation, which began in November 1998, entails complete conversion of the 548-cell facility from a copper starter sheet based operation to Mt. Isa Process stainless steel mother blank technology. This paper outlines the operating history of the Central EW Tankhouse and reviews the conversion process, the rationale that led PDMI to undertake this project, and describes various design optimizations which have been implemented during the conversion.

Jan 1, 1999

By B. Geelhoed

A generalization of Gy?s 1979 model for the variance of the fundamental sampling error has been proposed at WCSB2?2005 by Geelhoed. This generalized model can potentially lead to a better correspondence with actual sampling processes. However, a new parameter is required by the new model: ?the parameter for the dependent selection of particles?(Cij). It is important that this new parameter, which is at the basis of the new theory, is well understood in the sampling and blending community. In order to clarify the meaning of Cijand to prevent potential misinterpretation of Cij, we discuss the difference between Cij and an intuitively associated, but different, parameter: ?the parameter for the dependent selection of particle types?(Mij). In this contribution, the theoretical difference between both parameters is clarified. Simulations demonstrate that, numerically, the difference between Cij and Mij can be large. Some additional advantages of the approach which uses Cij are discussed: (i) the approach based on Cijis more general; (ii) in all cases where Mij is known, Cij can be determined as well, while the reverse is not true; (iii) an equation already exists that relates the sample variance to the value of Cij.

Jan 1, 2009

By C. W. Owings, F. E. Cash

"Transportation of explosives in mines is extremely hazardous, and where electric haulage is employed the danger is intensified. Insulated mine-car couplings have been adopted by at least five companies in Alabama and Pennsylvania - and undoubtedly in other States - to prevent an electric current passing from a mine locomotive to a car or between care joined by this coupling. The need for such protection is recognized in the report of an explosion.""Four hundred kegs of black blasting powder had been loaded into four mine cars at the railroad, to be hauled to the magazine, upgrade, by a trolley locomotive. On starting, the motorman put sand on the rail and a grounded circuit passed through the hitchings and so exploded the powder. No insulation was used between the locomotive and cars."" When used on man trips the insulated coupling further serves the purpose of guarding the men against shock. Four couplings are described so that a clearer understanding may be obtained of the details of construction.ConstructionThe general principles of construction are similar in all insulated couplings. The piece containing the hole for the coupling pin is made of steel and the steel parts are separated by an insulating material, such as fiber or wood. The coupling is either rigid or semirigid to prevent the bumpers of the mine cars from coming in contact and to keep the cars insulated from one another at all times."

Apr 1, 1928

By George F. Klernrnick

The Pokorny sulfur deposit is located in the northwest comer of the Delaware basin in the Rustler Springs sulfur district of west Texas. To date, 57 sulfur test wells have been drilled by Addwest Minerals delineating a resource of greater than one million long tons (It) of native sulfur. The deposit, hosted by the Permian Ochoan Castile Formation evaporite sequence, is a sulfur-bearing bioepigenetic limestone replacement of banded bituminous anhydrite. Three distinct mineralized horizons are present that correlate with zones of halite dissolution in the Castile. Sulfur mineralization occurs as hydrocarbon-poor disseminated grains, and as crystalline linings of discontinuous planar voids and large vugs.

Jan 1, 1992

By Igor Gonzales G.

The Southern Peru Copper Corp. (SPCC) recently built an integrated copper project consisting of dump- and heap-leaching operations at its mine complex in Peru. The pregnant leach solution (PLS) containing the solubilized copper from the leaching operations is processed in a new solvent extraction/electrowinning (SX/EW) facility to produce high-purity cathode copper. The dump leaching and SX/EW facilities are located near the Toquepala mine site. The crushing and heap-leaching operation is located at the Cuajone Mine. The pregnant leach solution from Toquepala and Cuajone is pumped 35 km (22 miles) to the SX/EW plant at Toquepala. The SX/EW plant consists of three trains of solvent extraction (SX), a tank farm area and an electrowinning (EW) facility. The solvent extraction plant has a total PLS flow capacity of 3,210 m3/hr (113,360 cu ft/hr). The electrowinning facility has an expected long-term production capacity of 97 t/d(107 stpd) or about 35 kt/a (38,500 stpy) of cathode copper. However, present production exceeds the expected long-term by about 20%.

Jan 1, 1996

By Trois P

A fully instrumented and bench-mounted diamond drilling machine, purpose designed and built, has been used for investigating the effect of aqueous solutions of various chemical compounds when used as drilling fluids. The rocks investigated were andesite, basalt and granite, the chemical compounds were alkylamines, with various hydrocarbon chain lengths, aluminium chloride and dioxane. Rotation speed seems to be one of the major factors affecting the emergence of mechanochemical effects as the results obtained with aluminium chloride clearly indicate. Penetration rate is either unaf- fected or enhanced by the presence of certain compounds, such as aluminium chloride. On the other hand, penetration rate diminishes when the drilling fluid contains dioxane and exhibits an apparently unpredictable behaviour with alkylamine solutions, although it appears that an increase in hydrocarbon chain length usually equates to an increase in penetration 1. Full Professor, Mining and Mineral Dressing Department University of Cagliari - Italy 2. Associate Professor, Mining and Mineral Ikea- sing Department University of Cagliari û Italy rate. Rock texture seems to have a pronounced effect on test repeatability. With hexadecy- lamine acetate solutions in concentrations ranging from 10-5 to 5 .10-4 molò dm 3 and 41.88 radòs-1 rotation speed, 46 % increments in penetration rate of andesite were observed, with respect to water, whereas penetration rate decreased in basalt by as much as 60¦%o when a dioxane solution was used as drilling fluid. An interpretation of the observed effects is proposed in the light of current knowledge of solid state physics and physical Chemistry.

Jan 1, 1992

By J. R. Morison, M. P. O’Brein, J. W. Johnson, S. A. Schaaf

The force exerted by unbroken surface waves on a cylindrical object, such as a pile, which extends from the bottom upward above the wave crest, is made up of two components, namely: 1. A drag force proportional to the square of the velocity which may be represented by a drag coefficient having substantially the same value as for steady flow, and 2. A virtual mass force proportional to the horizontal component of the accelerative force exerted on the mass of water displaced by the pile. These relationships follow directly from wave theory and have been confirmed by measurements in the Fluid Mechanics Laboratory of the University of California, Berkeley. The maximum force exerted by breakers or incipient breakers is impulsive in nature, reaching a value much greater than that produced by unbroken waves but enduring for only a short time interval. This impulsive force represents the ultimate development of the accelerative force and is produced by the steep wave front and large horizontal acceleration at the front of a breaker. This impulsive force greatly exceed. the drag force computed from the particle velocities of the breaker. The reader is cautioned that these preliminary results are applicable only to single piles without bracing and are likely to be modified somewhat where multiple piles are driven, one within the influence of the other or where multiple piles are connected by submerged bracing. This paper is essentially a preliminary report submitted at this time because of the current importance of wave forces in the design of offshore structures. An extended series of additional experiments is planned for the near future. Theoretical Relationships For the sake of simplicity of treatment, the theory will be developed from the equations for waves of small amplitude. The horizontal displacement of a water particle is described by the equation 2p cosh — (d + z) H L 2pt X =----------------------sin ----- . , (1) 2 2pD T sinh------ L The horizontal component of the orbital velocity is obtained by differentiation with respect to time as 2p cosh — (d + z) pH L 2pt u = ------------------- cos— .... (2) sinh- L The acceleration of the water particles at any position is obtained by again differentiating with respect to time as 2p cosh — (d + z) 9 u -2vH L 2pt -----=----------------------------sin ----- . . (3) 3 t T2 2pd T sinh------ L where H = wave height — ft L = wave length — ft d = still water depth — ft z = depth below the still water measured negatively downward — ft. T = wave period — sec t = time — sec The force exerted on a differential section, dz, in length is pD2 s u pD 1 dF= [CM (p/4) st + Cn/2 u2] dz • • (4) where D = pile diameter — ft p = water mass density — slugs/ft3 C, = coefficient of mass C,, = coefficient of drag Substituting for a s u/s t arid u2 from Eqs. (3) and (2), the force per unit length at any position z is dF p2 pD H2 &apos; / = — [- fM sin ? ± fD cos2 ? ] . . . (5) dz 2T2 fM D fD 2pt Cm = pA/H:CD = A2;? = T [+ cos2 ? for 0 < ? < p/2 cosh— (d+z) 3p L — < o < 2p Sin L -cos2 ? for p/2 <? <3p/2 The sin 9 term (inertia) i- negative for 0 < 0 < p and positive for p < ? < 2p. Values of A and A&apos; appear in Fig. 1

Jan 1, 1950