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By T. C. Alex

Mechanical activation of gibbsite [?-Al(OH)3] is the theme of this paper. Industrially prepared gibbsite used in the study has a mono modal size distribution with a median size, d50=110 µm. Mechanical activation of this gibbsite has been carried out in a planetary mill at ambient conditions. Mechanical activated gibbsite samples are characterised in terms of particulate characteristics, structural characteristics and reactivity. As a result, of milling, mono modal size distribution of the unmilled gibbsite changes to a broad multimodal distribution. Size reduction has been sharp in the initial stages of milling; median size reduces to ~7 µm during 15 min of milling. Thereafter no decrease in median size is observed; rather it is found to increase gradually with further increase in milling time, indicating particle aggregation. Morphological studies of milled gibbsite have shown that the platelets forming the agglomerate are separated first; the separated platelets then undergo breakage. Aggregation of particles sets in the later stages of milling as a result of increased surface area and surface energy. X-ray diffraction (XRD) and transmission electron microscopy (TEM) studies have clearly revealed the changes in gibbsite structure during milling. Analyses of XRD data show that the crystallite size of gibbsite decreases as the milling time progresses whereas its microstrain is found to increase. Accumulation of energy in the structure is the result in both cases. TEM micrographs with signs of defects leading to disordering of gibbsite structure complement the XRD results. Reactivity of milled gibbsite, decrease in its deydroxylation temperature and increase in alkali dissolution, is found to increase with mechanical activation. Increased reactivity of milled gibbsite is found to have a strong correlation with the BET specific surface area. Keywords: mechanical activation, gibbsite, alkali dissolution, thermal dehydroxylation, reactivity

Sep 1, 2012

By R. G. Powell, R. Schuhmann, E. J. Michal

Liquidus surfaces in the ternary system FeO-Fe2O3-SiO2, were determined from 1250' to 1450°C by the procedure of equilibrating small samples in platinum crucibles, quenching, and microscopic examination. The experimental results were combined with previously published information to construct a ternary diagram for the system showing the entire temperature-composition range of stability of iron silicate slags. Metallurgical applications of the diagram, especially in copper smelting, are discussed briefly. IRON oxides are almost unique among the common oxide constituents of metallurgical slags in that the iron occurs in two different states of oxidation, ferrous and ferric. Moreover, in liquid slags the degree of oxidation of the iron is readily changed by reactions of the slags with oxidizing agents or reducing agents. This behavior of iron oxides in slags accounts, for example, for the effective transfer of large quantities of oxygen through slag layers in open hearth steelmaking. In this process, oxygen supplied by reactions at the gas-slag interface is dissolved in the slag with the oxidation of ferrous iron to ferric. Ferric oxide is transported across the slag layer by convection, and at the slag-metal interface the oxygen reacts with liquid metal while the ferric iron is reduced back to the ferrous state. Another group of processes in which variation in degree of oxidation of iron has great practical importance is in copper smelting. In matte smelting and converting, such large proportions of the iron are oxidized to the ferric state that problems are encountered in preventing or controlling the formation of solid magnetite. The ferrous-ferric relationship also affects the attack of iron oxides on high-SiO2 refractories, which appears to be most severe under reducing conditions for which ferrous iron predominates. Darken and Gurry' determined the chemical properties and phase equilibria of pure iron oxide slags. Their data show that iron oxide melts can have compositions ranging almost all the way from FeO to Fe2O3. The melts of lowest oxygen contents, which exist in equilibrium with metallic iron, approach ferrous oxide in composition but still have a small percentage of ferric oxide. The melts of highest oxygen contents, which have oxygen dissociation pressures of 1 atm, are above magnetite in oxygen content, with over two-thirds of the iron in the ferric state. The previously established phase diagrams for silicate slag systems all show FeO as the iron oxide component. However, Bowen and Schairer? who determined the FeO-SiO2 diagram and many of the other diagrams used by slag chemists, have been careful to point out that their systems always contained both ferrous and ferric iron. Thus, their data are for limiting mixtures with minimum contents of ferric iron, obtained by melting and equilibration in iron crucibles. Under these conditions, the Fe2O3 percentages found by analysis were small enough to justify simplification of the published phase diagrams by calculating the Fe2O3 to equivalent FeO and ignoring Fe2O3 as an additional component. On the basis of experimental measurements of melting points of iron oxides on silica in the presence of various gas mixtures, Darken3 worked out phase diagrams for the Fe-Si-0 system which show the important phase equilibria in terms of temperature and gas composition. This study clarified many aspects of the application of the phase rule to the FeO-Fe2Oa-SiO2 system and was an important basing

Jan 1, 1954

By F. E. Goodwin

Since the last CIM Zinc and Lead Conference ten years ago, significant technical and market forces have influenced how these metals are used, and the geographic distribution of their uses. Unprecedented price fluctuations have opened competitiveness issues, while the rapid growth of the Chinese market has created challenges both inside and outside China. Recent technical developments in battery energy storage, coatings, castings and chemical applications of lead and zinc will be reviewed together with the influence of these trends on end use markets.

Jan 1, 2008

By Jan Walaszczyk

The paper concerns the calculation of stresses and displacements in working area of room-and-pillar mining system of cooper ore mines. A three-dimensional rock mass model based on the finite element method has been developed. The complete strain-stress characteristic for pillars has been applied, but for the purpose of modeling the curve has been approximated by three segments of lines: - the first represents a behavior of pillar before a failure, -the second corresponds to a progressive pillar failure phase, - the third represents the part of the curve, where the increase of strains do not cause the stress changes, and it is called the residual strength. The criterion of model stability has been derived, which can be useful for predicting rockmass stability. The programs have been built, which allow to calculate stresses in bar elements, displacements in plate nodes, and estimate the stability of the model, which consists of plate elements and one-dimensional elements with a segment strain-stress characteristic. The programs were used to consider two different problems, which are connected with mining design and the exploitation systems.

Jan 1, 1992

By J. B. Austin

Jan 1, 1945

The treatment of the Broken Hill ores has,undergone many changes during the last ten years, and it may be of interest to some of the members to know what are the main lines on which the Proprietary Mine works at present. It must be understood that the want of absolute uniformity in the treatment amongst the various mines at the Barrier does not prove that some of the mines are working on wrong lines, for the ore is not exactly the same along the whole line of lode; this necessitates a variation in treatment, although generally only in detail.At the Proprietary Mine the ore is all mined by contract the miners are paid so much per ton for clean ore. The ore in the mine in most stopes is mixed with gangue, and the inclination of the uliners is, of course, to mix gangue with the ore, so as to be paid for as large 3 tonnage as possible. This is quite natural clean ore is easily distinguishable from clean gangue, but most lumps are a mixture of clean ore and gangue in varying proportions. The miner will naturally throw into his heap pieces which he considers still good enough, whilst the management may consider these pieces just a trifle too poor; consequently a check must be kept on this.This necessitates the first operation to which the ore is submitted. 'The trucks tare 51 cwt.; average load 21 cwt.), as they are loaded underground, have a ticket attached::showing to whiyh contract they belong on arrival at the top of the shaft they are passed over a weigh bridge...

Jan 1, 1907

By J. M. Tannenbaum

A depth-sensing micro-indentation technique is developed for evaluating mechanical properties of materials at elevated temperatures (to 1200°C). System description and design considerations of the test apparatus are described. Based on Hertzian spherical indentation approach, the micro-indentation test apparatus is capable of determining Young?s modulus and creep strength of test materials with flat, tubular, or curved architectures from room to 1200°C under either air or controlled gaseous environments. Calibration tests were conducted on a H13 Tool Steel coupon from 22°C to 500°C and single crystal Haynes 230 alloy at 1000°C with excellent agreement to the literature values. Indentation creep tests of Haynes 230 alloy were carried out at 1200°C with preliminary results showing good correlation to creep exponents. Further system refinements will be investigated, and additional testing will be conducted.

Jan 1, 2010

By A. E. Isaacson

Researchers at the Bureau of Mines, U.S. Department of the Interior, developed and tested equipment to measure corrosion rates on a commercial-scale mill. Bench-scale experiments were also designed for duplicating ore grinding conditions closely enough that realistic rate determinations can be made in laboratory tests. Rates measured in a laboratory system compared favorably with those measured in the field. Cast steel was found to have corrosion rates in a copper mill and laboratory test cell of 22 and 21 mpy, respectively. Corrosion was found to account for less than 5 pct of the total grinding media wear in the operations studied.

Jan 1, 1989

By H. Schultz

Urban refuse that was mechanically separated at the U S Bureau of Mines pilot plant in College Park, Md., was successfully evaluated for its fuel values using standard coal analysis methods. Analyses performed on refuse samples taken from five sample points included moisture, ash, sulfur, chlorine, and heating value. It was recommended that characterization of the combustible portion of urban refuse by standard coal analysis procedures should be widely adopted.

Jan 1, 1975

By L. Marais, S. Denoon-Stevens, J. Cloete

"Historically, mining companies worldwide provided housing and developed towns to accommodate their employees. At the end of the 1980s this approach became less prevalent and attempts were made to mitigate the effects of mine development and mine closure on communities living near the mines. Permanent settlement in mining towns urgently needed to be minimized. Since the advent of democracy, South African policy has moved in the opposite direction, shifting the emphasis to creating integrated communities and encouraging home ownership. Despite this policy shift, however, mines continue to influence local housing conditions. One direct outcome has been the development of informal settlements. We surveyed 260 informal settlement households in Postmasburg, a small and remotely located town in the Northern Cape Province of South Africa. We found that because they employ contract workers and thus arouse expectations of employment, the mines here contribute extensively to the development of informal settlements. But local factors also contribute, and the functional role of informal settlements as a form of housing that supports mobility should not be underestimated. We also found that both municipal and mining company policies for informal settlements were inadequate. Finally, we found that low-income informal settlers not associated with mine employment suffered the highest levels of social disruption.IntroductionA mine generates demand for labour, which in turn generates demand for housing. When settlements spring up near a mine this often means poor housing conditions. In South Africa in the 1960s and 1970s mining companies invested heavily in company towns or mining settlements, but they have become increasingly hesitant to do so, for three reasons. First, declining resource prices in the mid-1980s and the 1990s compelled them to focus on core business interests and reduce the costs of peripheral activities such as housing (Bryceson and MacKinnon, 2013); second, at the turn of the 20th century they were often accused of taking over the role of local government (IIED, 2002) and consequently became hesitant to invest in developing mining towns; and third, changing labour regimes also curbed their investment in such towns (Haslam McKenzie, 2010). Increasingly, the companies began to endorse block-roster shifts, and outsourcing also became more common in the early 1990s. Block-roster shifts in Australia (together with improved technology) have meant that miners do not need to settle near the mines but can fly in and fly out and have their urban houses as their stable homes. This has had serious negative implications for housing in remote towns in Australia, particularly worker camps, large-scale renting out of available accommodation, and ‘hot-bedding’."

Oct 1, 2018

By T. A. Toney, L. R. Fish, P. J. Bethell

With new lightweight designs, spirals have become standard equipment in coal preparation plants worldwide. To their credit, spirals typically show very low coal losses to the refuse stream under most operating conditions. However, spirals do tend to separate at cut points in excess of 1.80 S.G. Attempts to obtain lower cut points have typically resulted in coal losses to middlings. Middlings retreatment with secondary spirals is therefore becoming common place. Other forms of retreatment with water-only cyclones, hydrosizers and recirculation have been attempted with some success. This paper reports on a novel (patent applied for) approach to retreating spiral middlings in a heavymedia cyclone circuit.

Jan 1, 2000

By Carlson BL, Overton DD

This paper compares the designs of heap leach facilities for four precious metal mining projects in the southwestern United States. These four proposed projects are of small-to medium-size relative to other operating mines in the United States, and are either permitted or in the final stages of permitting. The differences and similarities in the heap leach facility designs are compared with respect to site conditions, operating conditions and regulatory requirements. This comparison provides a summary of the state-of-practice for heap leach facility design in the southwestern United States and identifies current issues in project development and process material containment.

Jan 1, 1997

By Frederick Crabtree

WHEN Professor Stock asked for a paper on the above subject, it was too late to prepare by June 1, or near that time, one that would involve any appreciable amount of experimental work or original research; but the suggestion was made that a review of the literature bearing on the subject might be submitted in good time, and that later this could be supplemented by any experimental data obtained during the summer, if experiments were carried out. In accordance with this suggestion, there are submitted the following notes on references found in the literature of recent years bearing on sulfur in gas. It is to be, understood that, ill general, these notes express the opinions of the authors whose papers are abstracted, not necessarily the opinions of the abstractors. Very little published information was found bearing directly on producer-gas sulfur, so this has been supplemented, in certain phases of the subject, by references to illuminating gas. Methods of analysis and processes for the elimination of sulfur from the gas are, without much doubt, very closely related in these two products. As in illuminating gas, sulfur is found in producer gas mainly as hydrogen sulfide, mixed with a much smaller and variable quantity of carbon bisulfide.1 The presence of minute quantities of other organic-sulfur compounds has been intimated, but no definite statement is made concerning these. The amount of sulfur present in producer gas is variable and depends on several conditions. The primary factor is the quantity of sulfur in the fuel, but the form in which the sulfur exists, the temperature of the producer, the air-steam ratio, and the efficiency of the scrubbing process are all determining factors. When the coal used contains less than 0.5 per cent. of sulfur, the sulfur in the gas will not exceed the quantity found in the average illuminating gas.2 Sulfur in producer gas may safely

Jan 9, 1919

By Timothy J. Haddon

For the mining industry in general and gold mining in particular, the past few years have been difficult. Economic conditions, coupled with growing regulatory restrictions, have led to increasingly important reasons for managing assets wisely. From a public company perspective, such asset management makes sense because it ultimately provides for an increase in shareholder wealth, and that is why we are in business. Regardless of whether a company is public or not, assets must be managed effectively to remain a player in today's competitive environment. So, as the chief executive officer of a gold mining company, how do we manage our assets to ensure that we are satisfying our obligations to our customer-the Amax Gold shareholder? The gold industry has been under siege. We have just completed the third year with average prices below $12.85/ g ($400/oz). When finding, and/or acquisition costs and development costs to operating costs are added, there isn't much of a profit margin left. What this environment provides, however, is opportunities for growth. In the gold business, you either grow or you die. Today, most North American gold producers have, at most, a 10-year mine life. We are all scrambling to add reserves so we do not become extinct. As prices remain low, opportunities abound for increasing diminishing reserves. This is the time for the opportunistic company to take advantage of market conditions and that is precisely what Amax Gold has done. There are six components to running a successful gold business: • finding reserves through exploration, acquisition or joint venture, • financing the project, • permitting and constructing the project, • operating the project, • cash management and • communication.

Jan 1, 1992

By Pritii Tam Wai Yin, Tony Leong, Neetu Bansal, James Vaughan, Amiel Boullemant

Mercury is a toxic element that is associated with many industrial activities including the Bayer process. Mercury is known to enter the Bayer process with the bauxite feed material and has the potential to accumulate as the process solution is recycled. This paper explores the speciation of mercury in Bayer process streams. The process parameters considered are the oxidising-reducing potential, basicity and temperature. The results of a refinery circuit survey are presented and compared with the thermodynamic predictions. Electrochemical measurements on relevant synthetic systems are also included.

Jan 1, 2014

By R. R. Givler

Since the 1860's the good ole days, oil has been nozzle fed to burners under pressure atomizing the oil into droplets -- 1960's has produced vaporized oil that burns oil with the flame color and consistancy of gas -- If you can tell the difference by looking at the flame, gas or oil I?ll buy the lunch. First, we must ask, "Why all the excitement about Blue Flame?" This question is best answered by you after you have studied the principle of operation and see the result. I will attempt to explain both of these so that you can draw your own conclusions.

Jan 1, 1975

By M. Abdollahy

Solvent extraction of gallium from Bayer solution of Jajarm Alumina plant was investigated us-ing Kelex100 as extractant. Taguchi experimental design method was used in order to optimize the separation factor of Ga and Al. Optimum conditions were obtained as follows: Temperatuer: 65°C, volume ratio of aqueous phase to organic phase: 3.0:1.0, process time: 60min and organic phase containing 15vol.% Kelex100, 5vol.% isodecanol in kerosene. In this conditions, 74% gallium and 0.3% aluminum was extracted and separation factor was obtained 828.63.

Jan 1, 2014

By J. A. Taylor, R. J. Fowell

Abstract: The amount of published literature pertaining to the field of rock mechanics has increased markedly in recent years. Whilst computer applications aid our understanding of the mechanisms of pillar instability, the applications do not take into account the effect of time; thus the determined pillar factor of safety has limited meaning. A more realistic approach would be to consider pillar stability in terms of time to failure. However such an approach would require a reasonable estimate of the in-situ pillar mass strength and a validated methodology linking the time to failure with in-situ pillar mass strength and the geometric layout of the working. Résumé: Le volume de bibliographie au sujet de la mécanique des roches a augmenté considérablement ces derniêres années. Alors que des modeles informatiques aident a la compréhension des mécanismes d'instabilité de pilliers, ces modèles ne prennent pas en compte les effets du temps; ainsi, la determination du coefficient de surete du pillier a un sens limité. Une approche plus réaliste devrait considérer la stabilité du pillier en fonction du temps de défaillance. Cependant une telle approche exigerait une estimation raisonnable de la resistance du massif rocheux du pillier ainsi qu'une méthodologie qui lie le temps de défaillance avec la résistance in-situ du massif rocheux du pillier et la géometrie de l'excavation souterraine. Zusammenfassung: Die Anzahl der Veröffentlichungen auf dem Gebiet der Felsmechanik ist in jüngster Zeit sehr gestiegen. Computerprogramme sind wertvoll um den Mechanismus der Pfeilerunbeständigkeit zu verstehen, aber sie vernachlässigen den Zeiteffekt. Daher haben die errechneten Sicherheitsfaktoren der Pfeiler nur begrenzte Bedeutung. Eine realistischere Bewertung wäre, die Stabilität der Pfeiler auf Grund der Zeit bis zum Verfall zu beurteilen. So ein Verfahren würde eine Schätzung der in-situ Gebirgsfestigkeit und eine validierte Methologie, die die Zeit zum Verfall in Abhängigkeit der in-situ Pfeilerfestigkeit und der geometrischen Auslage der Grube zusammenbringt, brauchen.

Jan 1, 2003

The ore is very 'refractory. It consists essentially of arsenical pyrites, iron pyrites, zinc blende, galena, antimony as sulphide and probably, in combination with galena, as Jamesonite, magnesium, and aluminium silicates with quartz. Some of the oxidized ore, of which there is very little, has a very interesting composition. A specimen shown to me by the ,general.manager, Mr. F. B. Stephens, consisted of hydrated arseniate of iron, orpiment, pyromorphite, lead oxide, with magnesium silicates and quartz. The ore found in the mine with a composition similar to this specimen was valued for gold contents at 60 oz. per ton. This ore is found as a small leader, which runs parallel to the main ore body, at intervals cutting through it.The ore is conveyed from the mine to the reduction works by means of a double road tram line. The mine is situated about rooo feet above the plant on a hill. The grade is so great (about I in 2) that the loaded trucks coming down are able to pullthe empty ones up, thus obviating the necessity of motive power for haulage. All that is necessary is two large grooved pulleys, fixed at the summit of the hilI, and provided with a rope-break for steadying the speed of the trucks down the hilI.

Jan 1, 1903

By E. R. Brownscombe, Francis Collins

A study has been made of the material balance-fluid flow method of estimating reserves and degree of water drive from pressure and production history data. By considering the effect of random pressure errors it is shown that in a particular example a standard deviation of three and one-half pounds in each of ten pressure survey? permits the determination of the reserves with a standard deviation of 8 per cent and the water drive with a standard deviation of 15 per cent, assuming that certain basic geologic data are correct. It is believed that this method of estimating reserves and water drive is useful and reliable in a number of cases. The method is particularly valuable when reservoir pressure data are accurate within a very few pounds, but may also be applied with less accurate pressure data if a relatively large reservoir pressure decline occurs early in the life of the field, as for example in an under-saturated oil field. INTRODUCTION A knowledge of the magnitude of reserves and degree of water drive present in any newly discovered petroleum reservoir is necessary to early application of proper production practices. A number of investigators have contributed to methods of relating reserves, degree of water drive, and production and pressure history. 1-8 Three types of problems of increasing complexity may be mentioned. If a reservoir is known to have no water drive. and if the ratio of the volume of the reservoir occupied by gas to the volume of the reservoir occupied by oil (which ratio permits fixing the overall compressibility of the reservoir) is known, then only one further extensive reservoir property remains to be determined, namely the magnitude of the reserves. A straightforward application of material balance considerations will permit this determination. The problem becomes very much more difficult if we wish to determine not only the magnitude of the reserves but also the magnitude of water drive, if any, which is present. In principle, a combination of material balance and fluid flow considerations will permit this evaluation. Finally, if neither the magnitude of reserves, the degree of water drive, nor the ratio of oil to gas present in the reservoir is known and it is desired to determine all three of these variables, the problem could in principle be solved by a fluid flow-material balance analysis which determines the overall compressibility of the reservoir at various points in its history. The change in compressibility with pressure would provide a means of determining the ratio of gas to liquid present, since the compressibilities of gas and liquid vary differently with pressure variation. However, in practice this problem is probably so difficult as to defy solution in terms of basic data precision apt to be available.' It is the purpose of this discussion to illustrate the second case, which involves the determination of two unknown variables, single phase reserves and degree of water drive, from pressure and production history and fluid property data, and to study the precision with which these unknowns can be determined in this manner in a particular case. Although an electric analyzer developed by Bruce as used in making the calculations to be described, numerical methods necessary in carrying out the process have been devised and have been applied for this purpose. Schilthuis,' for example, developed a comprehensive equation for the material balance in a reservoir. He combined this with a simplified water drive equation, assuming that the ratio of free gas to oil was fixed by geological data and that a period of constant pressure operation at constant rate of production was available to determine the constant for his water drive equation. On this basis he was able to compute the reserves and predict the future pressure history of the reservoir. Hurst developed a generalized equation permitting the calculation of the water drive by unsteady state expansion from a finite aquifer. He showed in a specific case how the water influx calculated by his equation, using basic geologic and reservoir data to fix the constants, matched the water influx required by material balance considerations. Old3 illustrated the simultaneous use of Schilthuis' material balance equation and Hurst's fluid flow equation for the determination of the magnitude of reserves and a water drive parameter from pressure and production history. He used this method to calculate the future pressure history of the reservoir under assumed operating conditions. As a basis for determining reserves, Old assumed a value for his water drive parameter and calculated a set of values for the reserves, using the initial reservoir pressure and each successive measured pressure. The sum of the absolute values of the deviations of the resulting reserve numbers from their mean value was taken as a criterion of the closeness of fit to the experimental data possible with the water drive parameter assumed. New values of the water drive parameter were then assumed and new sets of the reserves calculated until a set of reserves numbers having a minimum deviation from the average was established. The average value of- the re-

Jan 1, 1949