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By Gordon L. Kidd

The object of this paper is to show the relations of the East Coulee coal area to the near-by Willow Creek, Wayne, Rosedale, and Drumheller areas, all being parts of the Drumheller field. The word ?area? is here used in a more local sense than that employed by Dr. J. A. Allan, whose. 'area' is rather comparable with the 'mining division' in British Columbia. I have drawn freely from the published information, particularly from Dr. Allan's report on the "Geology of Drumheller Coat Field, Alberta", and from Dr. E. Stansfield's paper on " A Chemical Survey of Alberta Coals", to whom thanks are due. The Drumheller field is served by branch lines of the two principal Canadian railways. The C.N.R. traverses the district by its Goose Lake line from Calgary to Saskatoon; and the C.P.R. by a line from Calgary to Acme and then southeasterly to Drumheller, where it effects a junction with the C.N.R., over which the C.P.R. has running rights as far as Rosedale. From Rosedale, a joint line built during the summer of 1928 extends about forty miles down the Red Deer river to the mouth of Bull Pond creek. From that point the C.P .R. turns more southerly to connect with the Bassano-Empress line. The C.N.R., it is expected, will eventually proceed eastward to connect with a transcontinental line. The joint line from Rosedale down the Red Deer river opened up the Willow Creek and East Coulee areas.

Jan 1, 1929

By D. W. Mitchell

This Bureau of Mines report summarizes experience and past research on methods for sealing abandoned areas of a coal mine and areas from which the pillars have been wholly or partially extracted. The Federal Coal Mine Health and Safety Act of 1969 requires that such areas be ventilated or sealed with explosion-proof bulkheads, but the present study indicates that bulkheads alone cannot isolate areas in a coal mine in which methane and other dangerous gases have accumulated. Gas-air exchanges between sealed and open areas must be controlled.

Jan 1, 1971

By Y. -H. Chang, Y. -J. Jou, T. -S. Ueng, I. -H. Peng

In order to systematically study the size effect on the shear strength of rock joints, this study used the computer-aided-manufacturing system to reproduce the artificial rock joints for saw-toothed joints, Barton's standard joint profiles of JRC = 4~6 and 18~20, and natural rock joint profiles. We divided, enlarged, reduced, and assembled these joint profiles to obtain joint specimens of various sizes ranging from 75 mm to 300 mm in length. The shear strengths of these joint specimens were tested under different normal stresses using a direct shear test apparatus. The surface conditions of the joints at failure were also examined. The size and geometry effects on the shear strengths of these joints of various sizes and configurations were evaluated based on the test results. Um die künstlichen Trennflächen für reguläre dreieckige Trennflächen, Bartonsche standardmäßige Querschnitte der Trennflächen von JRC = 4~6 und 18~20 und natürliche Querschnitte von Trennflächen wiederherzustellen, benutzt diese Forschungsarbeit das Computergestützte-Erstellungssystem, damit die Maßstabswirkung auf die Scherfestigkeit von Trennflächen systematisch untersucht werden kann. Die Querschnitte werden geteilt, vergrößert, verkleinert und zusammengesetzt, um Trennflächenproben in Längen variierend von 75 mm bis 300 mm zu erhalten. Die Scherfestigkeit dieser Trennflächenproben wird unter unterschiedlichen Normalspannungen mit einem Direktscherversuchsgerät getestet. Die Querschnittszustände der Trennflächen bei Versagen werden ebenfalls untersucht. Nach den Untersuchungsergebnissen werden die Maßstabs- und Geometriewirkung auf die Scherfestigkeit dieser Trennflächen verschiedener Größen und Konfigurationen ausgewertet. Pour étudier systématiquement l’effet de la dimension des fractures des roches sur leur résistance au cisaillement un système de creation de fractures artificielles à l’ordinateur a été employé. Des fractures artificielles triangulaires, profils de fractures de Barton avec JRC = 4~6 et 18~20, et profils de fractures naturelles ont été reproduits. Les profils des fractures ont été arrangés de manière à obtenir des échantillons de longueur entre 75 et 300 mm. Une boîte de cisaillement a été utilisée pour étudier la résistance des fractures au cisaillement, sous plusieurs conditions de contraintes normales. Les conditions superficielles des fractures après rupture ont été étudiées. Les résultats de ces essais, effectués sur plusieurs échantillons de dimensions et configurations variées, ont contribué à établir l’influence des dimensions et de la géométrie des fractures sur leur résistance au cisaillement.

Jan 1, 2003

By M. C. Baumann

The Getchell Mine is located in Humboldt County, Nevada, approximately 70 km northeast of Winnemucca. Slope management has been a critical factor in the feasibility of mining operations since they began in the early 1930's. Although underground entries began in 1937, underground production was limited because hanging walls consisting of clay gouge and crushed rock tended to collapse into the workings. Controlling these collapses required extensive timbering. Due to these poor ground conditions, surface open-pit mining was the primary mode of production from 1938 to 1967 with only minor contributions from underground operations. Mining was suspended in 1967 due to economic pressures. From 1960 to 1967, the previous operator mined the property in three open pits. Initially, these pits were constructed with footwall benches, but these failed. These failures were aggravated by construction of 60° slopes in footwalls with shale partings dipping into the pit at 43° to 60°, resulting in large planar failures and wedge failures. In response, the previous operator adopted a slope parallel to the bedding planes.

Jan 1, 1993

By H. M. Park

Risk is a major factor in all mining activities, arising from many internal and external variables. The authors? research has resulted in a systematic method for the quantification of risk in mining projects (Park, 2012), and this research is being presented in a series of papers. The first paper (Park and Nelson, 2013a) identified the variables associated with risk in mining projects, and their effects and was published in the October issue of Mining Engineering magazine. The second (Park and Nelson, 2013b) discussed methods of assessing the overall risk associated with those variables (published at www.me.smenet.org), and presented a statistical model based on a survey of 31 experts. This paper will present an evaluation of the statistical model, using data from previous mining investment decisions in which the authors have been involved.

Oct 1, 2013

By D van der Spuy, T Kewe, K Keet, N Moffatt, A P. Paine

The Blue Cube Mineral Quantifier Inline (MQi) instrument uses reflective light spectroscopy and advanced chemometrics to measure mineral or elemental grade in a slurry line. The instrument takes scans continuously and sends data to the DCS or PLC control system.Controlling the concentrate grades on a flotation circuit using low-frequency measurements can be difficult or impossible, especially on a circuit that has fast process dynamics. The ability to rapidly measure changes in grade makes it possible to continuously manipulate the flotation circuit operating parameters such as level, airflow and reagent addition set points to optimise plant performance throughout changing conditions.At Barrick’s Porgera mine in Papua New Guinea the flotation circuit feeds sulfide concentrate slurry to a pressure oxidation circuit. In order to maximise gold recovery in the flotation plant and increase performance in the pressure oxidation process, there is a stringent requirement to maintain a stable and optimum sulfur grade. The gold recovery is directly affected by the sulfur grade as most of the gold at Porgera is submicroscopic and associated with the sulfides (disseminated?pyrite).Porgera considered various points in the flotation circuit for installing Blue Cube analysers. This was part of a plant upgrade to improve process control. Due to budget constraints it was decided to initially only install one Blue Cube analyser on the final concentrate stream of the flotation circuit measuring sulfur, sulfides, gold and particle size. The accuracy of the calibration results were very good for all these properties. The sulfur measurement was used in an advanced control system to optimise and stabilise the grade. The paper presents comparisons between mineral grades determined using analytical laboratory analyses and the online Blue Cube data measurements, as well as benefits achieved by measuring grade online. An analysis of the plant data before and after installation of the Blue Cube and the advanced process control upgrade indicate that the flotation recovery increased by 1.98 per cent.CITATION:Kewe, T, Moffatt, N, Strobos, P, van der Spuy, D, Paine, A P and Keet, K, 2014. Evaluation of the Blue Cube MQi slurry analyser for application in an advanced control system for the optimisation of a gold sulfide flotation circuit, in Proceedings 12th AusIMM Mill Operators’ Conference 2014 , pp 357–362 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 1, 2014

By Jr. Jacobson

Thermal reactions of l-methylpyrrole, l-butylpyrrole, and l-isopropyl-pyrrole were investigated by a flow method in the temperature range of 4500 to 5750 C. Those of I-butylpyrrole and l-isopropylpyrrole were also investigated in the 3400 to 4000 C range in a static system. The I-substituted pyrroles isomerize by an irreversible reaction to 2-substituted pyrroles. A reversible isomerization reaction shifted the alkyl group from the 2-to the 3-position on the pyrrole ring. All of the isomerization reactions are homogeneous, unimolecular, nonchain, first-order reactions having similar mechanisms and transition states. There is decomposition and cleavage of the longer alkyl side chain when it is in either the 2-or 3-position giving, as products, pyrrole, 2-and 3-methylpyrrole, 2-and 3-ethylpyrrole, pyridines, and hydrocarbons. The decomposition reactions appear to be by free-radical mechanisms. Pyridine homologs are formed by the expansion of the alkylpyrrole: butylpyrrole produces pyridine, and isopropylpyrrole produces 3-methylpyridine. Approximate Arrhenius equations are given for the formation of the decomposition products.

Jan 1, 1966

By M. W. Airth

ON THE 6TH JULY in the year 1953 an announcement was made to the public that touched off one of the greatest staking rushes in the history of mining in Canada and resulted, in tl1e space of a few short years, in the development of the greatest reserves of uranium-bearing ore in the world. It was ?On this date that the famous "Blind River back-door staking bee" was completed with the acquisition of some 2,000 claims by the Preston East Do me-Technical Mine Consultant teams under the direction of Mr. Franc Joubin and Mr. Robert C. Hart. That story has been told from coast to Coast and is too well known now to re-quire elaboration. Suffice to say that, in the short elapsed time of less tl1an five years from that momentous summer of 1953, three of the Algoma mines are in full production, three more are rapidly nearing full production, five more 1are approaching the production stage, a new hard-surfaced highway, 108, has been built to serve the area, and a brand new, completely planned city, Elliot Lake, is being built to provide the amenities of living to the 22,000 people already in the area.

Jan 1, 1958

By A. D. Davis, G. A. Zabolotney

A ground-water flow model was developed to simulate the postmining recharge rate from precipitation at the Belle Ayr surface coal mine, which is located in the Powder River Basin near Gillette, WY Wyoming state regulations require that reclaimed lands should provide a rate of recharge that approximates the premining rate. Steady-state calibration and transient simulations showed that the postmining recharge rate through spoil is at least 50 mm (2 in.) per year, exceeding the original infiltration rate of 4 mm (0.16 in.) per year to shallow overburden aquifers. Major reasons for the increase include the flat topography of the reclaimed areas and the decreased spoil density. It is expected that the backfill will disaggregate and settle over time, eventually resulting in a nearly constant recharge rate that is less than 50 mm (2 in.) per year but still somewhat greater than the premining rate.

Jan 1, 1997

By C. D. Broadbent

Open pit blasting can be a low cost routine or a high cost bottleneck depending on geology, environment and the operator's ability to master site conditions. Because blasting is a repetitive operation, there should be ample opportunity to optimize the process; but ordinarily this optimization is rarely achieved and then only if conditions remain consistent and predictable. Often, however, and particularly with porphyry coppers, hidden differences in rock characteristics nullify the operator's best efforts. At a porphyry copper deposit being mined by Kennecott Copper Corporation, all of the following rock types occur; oxidized and fresh porphyry, altered and silicified limestone, explosion breccia, rhyolite, sandstone, shale and several others. The units can cover large areas or be limited to a few tens of feet in maximum dimension. They are rarely visible on the bench surface and often do not show up in the bench slope. Even though the blastability of these rocks varies substantially, a generally-uniform blasting pattern was formerly used with disappointing results. Secondary blasting was often required and high bottoms occurred frequently, overblasting wasted drilling time, and explosives caused excessive throw.

Jan 4, 1974

By Emile Gyss

THE speed of drilling rock has become an impor-tant factor in mining operations, while the place-ment of holes, kind, and quantity of explosive used. are equally important. These are a function of the rock hardness and toughness. Both of these fac-tors must be considered in compiling a table that will enable a mine operator or engineer to estimate drilling speeds in a given rock, knowing its hardness, and from its toughness, the dynamite required. The hardness of a homogeneous rock may be defined as its resistance to a penetrating medium, such as a drill-steel bit, and toughness, its resistance to with-stand rupture by the tearing apart of its minerals or parts of the same mineral. Rock hardness, as it has here been defined, is a function of the hardness of the component grains composing it, as well as grain size, shape, arrangement, and binding minerals. Rock tough-ness depends on substantially the same factors, but is measured by a totally different method. The units in which rock hardness is usually ex-pressed are either relative values or alphabetical desig-nations which carry no definite quantitative meaning. R. M. Raymond has suggested the measurement of com-posite rock hardness, based on mineral hardness as ob-tained by the Moh scale. This is done by multiplying the percentage of each mineral in a rock by the Moh mineral hardness and dividing by 100. These values convey a clearer conception in the minds of men in-terested in rock work -and are the basis of the units used in Tables 1 and 2. The hardness of rocks as it has been variously de-fined may be determined by different methods. The first method is one in which the proportionate average of the hardness of minerals making up a rock is the basis for classification. The other factors of grain size, shape, arrangement, and binding power are not considered.

Jan 6, 1927

Utah Development Company began prospecting for coking coal in 1961 and Blackwater Mine became a reality in June 1967. Exploratory and develop- ment drilling has been a continuing effort and reserves have been assessed at several stages. Some of the history of exploration and reserves assessment is given and practices in drilling, sampling and testing are described, particularly in regard to objectives of drilling and reserves estimation. The current methods for calculation of reserves are described and some comment is made regarding use of the data in mine blending control and plant operation including correla- tion of results.

Jan 1, 1979

By M J. Schultz, R L. Rude, D M. Tomko

The US Mine Safety and Health Administration (MSHA) conducted compliance assistance diesel particulate matter (DPM) sampling throughout the underground metal and non-metal mining industry. Based on that sampling, MSHA identified mines that were having difficulty meeting the DPM limit. To provide further assistance, MSHA then visited approximately 60 of the mines that were experiencing difficulty complying with the DPM standard. As part of these visits, DPM exposures were measured and control technologies for DPM were observed and assessed. Controls consisted of ventilation, clean engines, environmental cabs, alternative fuels, diesel particulate filters (DPF) and work practices. The focus of the follow-up compliance assistance visits was to assess control effectiveness and to make recommendations to mines experiencing difficulty in meeting the DPM standard. At each mine visited, the ventilation controls were evaluated, engine emissions were determined for equipment in use, environmental cabs were examined, and operational practices were noted. Additionally, control technologies, including alternative fuels and DPF were evaluated in several mines. A comparison was made of mine and section airflow to equipment particulate indices. Based on engine emissions, horsepower and operating time, the contribution of individual engine emissions to total emissions was made. Environmental cab integrity, positive pressure and air filtration systems were checked and operational practices relating to DPM exposure were assessed. This paper summarises the preference and magnitudes of controls that were typically used or needed for successful control of DPM. Additionally, results of the assessments of alternative fuels (including bio-diesel and water emulsion fuels) and DPF are presented.

Jan 1, 2005

A number of terrane reconstructions conflict with global plate histories or with data from adjacent regional studies. Paleogeographic maps have ignored terranes thus are over-simplified. This paper represents an attempt to "marry" Mesozoic global plate reconstructions and terrane analysis to produce examples of a "third generation" of global plate tectonic maps. The best approach to global terrane analysis involves intercomparison of all regional data and the evolving global model. Data conflicts within and between terranes and regions must be resolved by a system of relative data reliability "weighting." The most reliable and useful data are those which constrain "departure" (rift) and "arrival" (collision) times. Certain ad hoc decisions aid in the analysis (e.g. only one net vector allowed per plate). The maps that follow summarize Early Mesozoic global tectonic history at three critical junctures: 240 MA (Triassic); 180 MA (Jurassic); and 120 MA (Cretaceous). Due to space limitations, maps drawn at 20 m.y. intervals appear elsewhere. A preliminary Middle Triassic reconstruction is presented in Figure 1. Major plates and continental blocks are labeled; smaller blocks are marked with abbreviations. Examination of Figure 1 indicates the necessity of modeling Triassic tectonics with at least 68 blocks. Spalling- off of microcontinental slivers from Gondwanaland is active some 70 m.y. before the actual breakup of the supercontinent. In the SW sector of the Pacific, the Australian margins were embroidered with several terranes (e.g. Sumba) which eventually rifted away and crossed Tethys. The NW sector at this time included 10 microcontinental chips forming a huge archipelago along the Asian margin. All blocks inboard of Indochina collided by latest Triassic. Terranes of the NE sector include several (e.g. Arctic Alaska) along the North American margin, and at least six large blocks (e.g. Stikinia) drifting SE with the Farallon Plate. The SE sector

Jan 1, 1987

By P. Raffinot, M. Rey, V. Formanek, G. Sitia

Six years of laboratory study, followed by three years of mill operation treating more than 10,000 tons of ore, have established the flotation of oxidized zinc ores with fatty amines as an efficient process. Recently the method has been applied with success to partially oxidized sulphide ores. In this paper the authors give an account of their research and the milling results obtained in Sardinia since 1951. CONCENTRATION of oxidized copper and lead ores by flotation has been practiced for 30 years, but flotation of oxidized zinc ores has remained unsolved until a few years ago. This problem is, however, of great importance in mining districts where large tonnages of oxidized zinc ores exist in underground mines or in dumps. Some sulphide ores also possess a degree of oxidation high enough to justify recovery of oxide zinc minerals. Various attempts have been made to float the zinc carbonate, smithsonite. It is well known' that smithsonite can be collected with fatty acids, but as the predominant gangue constituents, limestone and dolomite. are floatable with the same reagents, fatty acids are difficult to use. Gaudin has shown,' on mixture of pure minerals, that smithsonite can be floated with higher xanthates, or better, with higher mercaptans. Another procedure, briefly mentioned by Davis," consists in sulphidizing the ore, activating the zinc carbonate with copper sulphate, and floating with ordinary xanthates. This process was attempted in the writers' laboratory in 1946, but results were erratic. It has since been taken up by Italian engineers and is in operation on certain types of ores. Two other research projects should be mentioned. In 1942 Erlenmeyer and others' floated synthetic mixtures of smithsonite and gangue minerals with hydroxyquinoline, an analytical reagent for zinc. On the other hand, Bunge, Fine, and Legsdin published in 19465 Some interesting results obtained on Missouri oxidized zinc ores. With sodium oleate as a collector and a combination of sodium hydroxide, sodium silicate, and citric acid as a limestone depressor, they secured, after four cleaning operations, a good grade of concentrate. With many ores this reagent combination lacks adequate selectivity. In 1939 M. Rey initiated a program of research on this important problem. Work was pursued first at the School of Mines in Liége, Belgium"' and later in Paris in the laboratories of Société Miniére et Mbtallurgique de Penarroya and Société Minerais et Métaux. Reagents used in the beginning were higher xanthates and mercaptans, later fatty amines. Sulphidization with sodium sulphide was found necessary. These conditions make possible the flotation of zinc carbonate and zinc silicate. Two milling plants were put in operation in Sardinia in 1950 and several others are now contemplated." ' It should be mentioned that unknown to the present writers McKenna, Lessels, and Peterson were

Jan 1, 1955

By Olli Hyvärinen

The capacity of Outokumpu Pori Copper Refinery has been increased by 50 % to 70 000 t/a in the last five years by adopting periodic current reversal, reducing spacing and installing some new cells in the old tank house building. Five years operation of PCR has proved that it is possible to achieve additional capacity with PCR and yet produce high quality cathodes. The impurity level in anodes has considerably increased, and recently, arsenic, antimony and sometimes bismuth have displaced nickel as the most critical impurity.

Jan 1, 1987

By J. W. Pamplin

SOME 40 miles east of Tampa is the center of the Florida pebble phosphate deposits. These are of Pliocene age and consist of several members of the Bone Valley formation.1 Physically the phosphate-bearing formation, locally called the "matrix," varies in thickness from nothing to about 25 ft., usually averages 10 ft., and consists mainly of clay, quartz and phosphate pebble, the latter particles varying in size from colloidal to one inch diameter. The pebbles range in color from dark gray, through white, to cream, and in hardness from that which must be broken with a hammer to that which can be scratched with the fingernail. They assay from 66 to 80 per cent bone phosphate of lime (called "B.P.L." in the trade) or tricalcium phosphate (Ca3P20s) and are secondary apatites. They form from 15 to 50 per cent by weight of the matrix, Over the matrix lies a varying thickness (5 to 40 ft.) of overburden composed of quartz and clay. Briefly, mining consists of two operations2 in open pits about 200 ft. wide by ½ mile or more in length. In the first step overburden is removed by large electric draglines at the rate of about 700 cu. yd. per hour. This is followed closely by hydraulic mining of the matrix at the rate of about 300 cu. yd. per hour. This matrix yardage is moved from an improvised sump in the floor of the pit to an ore-dressing plant, some-times a mile distant, by one, two or three "pit-cars" (pumping units) working on a 12-in. pipe line called the "rock line" to distinguish it from the high-pressure water line feeding the hydraulic giants, which is known as the "hydraulic line." This 700 yd. of overburden and 300 yd. of matrix-1000 yd. in all-amounts to about 1500 tons of material moved each hour. The over-burden is dumped into the mined-out pit alongside the pit being mined. The matrix moves to the ore-dressing plant at the rate of about 7 ½ long tons in 4000 gal. of water per minute-a ratio of approximately one to two by weight, or one to six by volume. This constitutes the "mill heads," but in the pebble district it is called the "matrix."

Jan 1, 1938

PRESIDENT. CHARLES F. RAND,1 NEW YORK, N. Y. PAST PRESIDENTS. CHARLES KIRCHHOFF,1 NEW YORK, N. Y. JAMES F. KEMP,2 NEW YORK, N. Y. FIRST VICE-PRESIDENT. BENJAMIN B. THAYER,1 NEW YORK, N. Y. TREASURER. GEORGE C. STONE,1 NEW YORK, N. Y. SECRETARY EMERITUS. ROSSITER W. RAYMOND NEW YORK, N. Y.

Jan 5, 1913

By F. S. White, E. L. Kinsella

Solids fluidization utilized in two ways for the commercial production of lime is described. Crushed —6 mesh limestone is dried and dedusted in a single bed reactor, then calcined in a 5-stage reactor. Construction, operation, and results obtained with both processes are given. THE solids fluidization process brought out by the Standard Oil Development Co. in the early forties for catalytic cracking of petroleum enabled rapid transfer of large quantities of heat from gases to solids under closely controlled temperature conditions. As the technique developed, it was natural that applications for the process outside the petroleum industry would be sought. The calcination of limestone to quicklime requires the transfer of a large quantity of heat at high and closely controlled temperatures. For these reasons, this possible application was one of the first to be investigated. Laboratory work conducted by the Dorr Co. indicated that lime produced by solids fluidization would be of exceptional quality. Calculation of theoretical heat balances showed that savings in fuel could be expected. Accordingly, a pilot plant of 10 tons per day capacity was erected by the New England Lime Co. at Adams, Mass., to substantiate the process. Operation of the pilot plant, previously described,' showed that excellent lime could be produced with a saving in fuel. The work also indicated the necessity of preparing feed to remove the finer fractions if dust losses were to be held to a tolerable level. A single-stage fluidized solids drier-stripper was developed to accomplish this sizing.' Subsequently a commercial lime reactor was erected at Adams, beginning operation in June 1949, followed by air sizer facilities completed in November 1951. This paper will describe these two applications of solids fluidization. The raw material for preparation of lime by the fluidizing process is a high calcium crystalline lime- stone having the approximate chemical composition shown in Table I. The stone is first prepared by crushing and grinding in conventional equipment to pass a 6-mesh sieve. After crushing, the material is sent to the FluoDry unit for drying and dedusting. Fluidized Drying and Sizing As shown in Fig. 1, the FluoDry unit consists of a -in. cylindrical steel shell, 9-ft ID by 22-ft 6-in. overall height. Attached horizontallv at the bottom is a 6-ft diam combustion chamber, approximately 7 ft 6 in. long. A refractory constriction dome, consisting of first-quality fire brick shapes, partitions the inside into two sections. The lower section is called the windbox and the upper the bed compartment. The vertical wall of the shell is lined with 6-in. first-quality rotary kiln blocks. In the bottom of the windbox a hoppered section is formed with castable refractory to permit the windbox to be readily cleaned via a 6-in. screw conveyor. The combustion chamber is similarly lined with refractory shapes. On the 6-in. diam section, 4 in. of insulating brick, HW-26, are used. The inner combustion chamber is lined with 4-in. Korundal brick to withstand the high flame temperatures encountered. An 8-in. steel feed pipe, entering vertically through the top and fitted with an air-operated cone valve,

Jan 1, 1953

By James R. Hindman

Vermiculite is the mineralogical name generally applied to a group of hydrated, trioctahedral ferromagnesian aluminum platty or micaceous silicate minerals. In microscopic particles the mineral as mineral is differentiated from montmorillonite by a higher Si:AI ratio of approximately 3:l and a higher layer charge and higher cation exchange capacities. Commercial vermiculite, the vermiculite which is mined, beneficiated, and discussed in this chapter, is an important industrial mineral which is formed by the alteration of macroscopic particles of biotite and iron-bearing phlogopite. In natural form it has the size and shape of mica, while possessing the ion exchangeable properties of zeolites and some clays. Within the internal structure of vermiculite lie water molecules, which when rapidly heated to high temperature, transform into steam causing the vermiculite particles to increase in volume. This process of thermal exfoliation produces a lightweight product which finds use in various construction products, agriculture, horticulture, and other industrial applications. In exfoliated form it has the low density and biological inertness of expanded perlite, while maintaining a chemically active surface. Most of the uses of vermiculite are for the thermally exfoliated material. In addition, the cation exchange potential of vermiculite and its layer-silicate structure are properties which can be used as the basis for numerous products including intumescent coatings and gaskets, inorganic films, and the treatment of nuclear and other toxic waste. When chemically and physically modified, it possesses some properties common to organoclays and synthetic compounds. In high purity concentrates and manufactured products, these properties can be altered and optimized in applications to produce superior performance. GEOLOGY Mineralogy Vermiculite was first described as a mineral by Thomas H. Webb in 1824. Webb believed vermiculite to be a variety of talc and described its diagnostic property of thermal exfoliation thusly: "If subjected to the flame of a blowpipe, or that of a common lamp, it expands and shoots out into a variety of fanciful forms, resembling most generally small worms having the vermicular motion exact." Observing that with one exception, all commercial vermiculite has formed by the alteration of iron-bearing phlogopite, a simple definition of vermiculite might be the alteration product of trioctahedral micas, macroscopic particles of which display marked exfoliation when heated rapidly to temperatures above 374°C (the critical temperature of water). The first vermiculite described was found near Worcester, MA, but it was later pointed out by Brush (1866) that vermiculite had been known for some time in Japan as a children's novelty. Because the techniques for mineral analysis were somewhat primitive com- pared to those routinely available today, and because the structure and crystal chemistry of the micas and related minerals were not widely understood, the early literature generated at least 20 "new" minerals which were nothing more than variations in the color and chemistry displayed by vermiculite. Trade names such as Dugarlite, Mandolitem, Strong-LiteTM, and Zonolitem are sometimes used to denote commercial vermiculite, thermally exfoliated vermiculite and their products. Vermiculite particles resemble mica and vary in color from colorless through tan and green to black, depending on the chemical composition. Most physical and optical properties are close to those of biotite, with perfect basal cleavage, hardness between 1.5 and 2.5 Mohs, and specific gravity between 2.2 to 2.8. Fine-sized particles will feel talcose, especially when wet. However, for commercial vermiculite the diagnostic test is that of thermal exfoliation. Vermiculite can display a wide range of compositions, depending on the composition of the original mica and the change of chemistry during weathering and ion exchange. Chemical data for some commercial vermiculites are given in [Table 1]. There are numerous analyses for vermiculite given in the literature, and the analyses of vermiculites from commercial deposits will fall within the range indicated by the average analysis in the table. Many analyses separate the adsorbed water (H2OP) from crystalline water and water as hydroxyl (H20+). The basis of separation of adsorbed water is generally considered to be 100°C. However, hydrate water within the vermiculite interlayer begins to be lost at 75°C and lower. Therefore, measured water content and loss on ignition are combined in the table as H20[total].

Jan 1, 1994