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Increasingly specialized blasting needs require that the explosive energy available in a borehole be reliably known for representative blasting conditions. The underwater test, when properly performed, can yield such information and thus provide a reliable rating of explosives in terms of energy release. This paper reiterates the stringent experimental conditions to be satisfied, and data analysis and interpretation techniques to be followed to achieve this. This is supported by detailed experimental studies involving select parameters in both detonator and booster sensitive explosive compositions. The paper also illustrates the inadvisability of equating blasting performance with the commonly calculated energy values.

Jan 1, 2000

By R. Hiebert, M. Canty, S. Beckman

An innovative biological process is described for the treatment of cyanide-, metals- and nitrate-contaminated mine process water. The technology was tested for its ability to detoxify cyanide and nitrate and to immobilize metals in wastewater from agitation cyanide leaching. A pilot-scale demonstration is described in which a pilot plant was constructed to demonstrate the technology on a mine process-waste stream at a mine in Nevada. The demonstration was performed jointly under the Mine Waste Technology Program (MWTP), funded by the US Environmental Protection Agency (EPA) and jointly administered by the US De¬partment of Energy's (DOE) Western Environmental Technology Office (WETO) under Interagency Agree¬ment Number DW89938513-01-0. The Superfund Innovative Technology Evaluation (SITE) demonstration program was also involved in the project. MSE Technology Applications Inc. (MSE), Butte, MT, was the contractor responsible for conducting the project, and Pintail Systems Inc., Aurora, CO, was the technology provider. The pilot-scale unit was field-tested at Echo Bay's McCoy/Cove Mine southwest of Battle Mountain, NV. The biotreatment process was considered successful in destroying cyanide in the mine process water. The process was also determined to be effective in removing metals. The pH was consistently neutralized and nitrates were successfully removed from the mine process water. From the results of these pilot-scale tests, it was concluded that the biotreatment process potentially of¬fers an innovative, cost-effective alternative for the treatment of mining wastewaters.

Jan 1, 2000

By Leo Brewer, Kazuyoshi Shimakage, Mamoru Mitomo, Toshiyuki Nishimura, Yoichiro Uemura, Shinji Hirai

"In the synthesis process of ß -La2S3 via the sulfurization of La2O3 powder using CS2 gas, La2O2S was formed. This occurred at an initial stage of the reaction for sulfurization temperatures below 973K, and ß -La2S3 was also formed at a shorter period for higher sulfurization temperatures. It was found that the oxygen content in ß -La2S3 powders decreased gradually with an increase in sulfurization temperature. On the other hand, the carbon content in these powders increased gradually with an increase in the sulfurization temperature. Though it has been reported that ß -La2S3 was transformed to Y -La2S3 at 1723K± 50K, the sintered compact of double-phase Y -La2S3 and ß. -La2S3 was formed at a rather higher temperature of 1973K when the synthetic powder of ß -La2S3 containing a high amount of oxygen was used. However, phase transformation of -La2S3 to Y -La2S3 progressed preferentially with a decrease in the oxygen content of synthetic ß -La2S3 powder. The Seebeck coefficient of the sintered double-phase Y -La2S3 and -La2S3 was higher than that of the single-phase Y -La2S3, reported previously.Introduction La2S3 exists in three polymorphic forms that are similar to a series of Ce2S3, Pr2S3 and Nd2S3: a, ß , and Y'. The a -La2S3, which is stable at low temperature, is irreversibly transformed to ß -La2S3 of various compositions in the solid-solution range between La2S3 and La3S4, at 923 ± 50K. The -La2S3 may also be an oxysulfide of La10S14O2. Moreover, the ß .-La2S3 phase is transformed to Y -La2S3 ,which has a Th3P4 structure, at 1573 ± 100K. The melting point of Y -La2S3 is 2398 ± 30K where this temperature is similar to those of common refractory materials such as silica and alumina. Therefore, it can be predicted that y -La2S3 which has a high melting point and a thermodynamic stability due to the strong affinity of La for S, would have &high refractory character and chemical inertness in many molten metals. The y -La2S3, colored vivid faint yellow is stable up to 623K in air, where oxidation starts. y -La2S3 is frequently used as pigments for plastics and paints3. Furthermore, Y -La2S3 which is a semiconductor, is considered to be useful as a thermoelectric conversion materials, because it has a high Seebeck coefficient."

Jan 1, 2000

By M Delaney

Alliancing is a contractual relationship in which organisations with an interest in a project are brought together in an atmosphere of co-operation to produce superior results to benefit all of the participants. Fundamental to the concept is the management of the risks associated with the project. The traditional risk management strategy adopted by clients has been to transfer this risk to others in the belief that this will result in the lowest overall project cost. It is assumed that competition in the market place will allow these risks to be transferred without paying a premium. However, this approach often results in the development of an adversarial climate, a high level of litigation, time and cost overruns and an overall poor project outcome. Under an alliancing arrangement the parties (client, designer and contractor) are aligned through shared interests in the projectÆs success by linking profitability to performance. Under such an arrangement, an atmosphere is created whereby the participants are motivated to focus on cost-savings, pursue best value and to innovate. Successful alliancing can result in highly motivated project teams and realisation of extraordinary productivity and cost-savings flowing from increased efficiencies. The situations in which alliancing can be successful are discussed with particular reference to the Wandoo Alliance which successfully completed the $375 million Wandoo B offshore oil platform in record time and with considerable savings to the project budget.

Jan 1, 2000

By S Jahanshahi, T Norgate

In single stage copper making appreciable amounts of copper report to the slag phase. Various strategies are available to minimise copper losses to the slag. However a slag treatment stage is likely to be required in an economically viable process. A number of slag treatment process options are available and include: flotation, leaching and thermal reduction. In the design of an industrial process some type of economic as well as technical analysis of these options will be required. In this paper an outline of the techno-economic analysis procedure used to design a single stage copper making process is presented. The calculated operating and capital costs of industrial copper making processes are compared and used to determine the optimum single stage copper making flowsheet. The most economic slag treatment options is flotation of slags containing low amounts of copper.

Jan 1, 2000

By Y. Ide, K. Kishitake

It is expected that an Al-Cr-N composite nitride film may have a higher resistance to oxidation at elevated temperatures than the well-known Ti-Al-N films. The formation conditions of Al-Cr-N films by a de reactive sputtering method and their properties were studied in this study. The films characterized with respect to their high temperature properties such as chemical composition, crystal structure, microhardness, wear and· friction. The crystal structure of the Al-Cr-N films changed from hexagonal phase to cubic phase with an increase in Cr content in the films. The resistivity to thermal oxidation of the Al-Cr-N films is superior to that of usual TI-Al-N films. A half of the friction coefficient in the Al-Cr-N film was obtained comparing with that in the ordinary TI-Al-N film at room temperature and the wear rate of Al-Cr-N film was 2 order smaller than that of TI-Al-N film. The Al-Cr-N films show a small friction coefficient at 500°C and then they are recognized to have good tribological characteristics.

Jan 1, 2000

By Hidefusa Takahara, Koichi Miyake, Dierk Raabe

"Mechanical properties of copper wires were examined. The copper wires containing 5-10 mass % chromium and 1-3 mass % silver were produced through heavily cold deformation. It was expected that the copper wire was easily fractured during cold deformation because of the existence of brittle chromium phase in the alloy. In fact, the copper wire was fractured due to large work hardening, when the true strain [n] exceeded 5. However, the copper wire annealed at 1273K for 6 ks ·in the middle of deformation process could be smoothly drawn to 11=8. After precipitation treatment for silver phase at 473k for 1.8 ks, the wire was able to further drawn to n=8.4. The final deformed wire showed tensile strength higher than 1200MPa.IntroductionDownsizing of electronic devices has led to the demand of finer and higher strength materials for cables. Conventional copper alloys have about 800MPa in ultimate tensile strength. These strength are mainly obtained by precipitation hardening. Nowadays, a process for higher strength wire has been developed, where dual phase copper alloy is used. When it is drawn heavily, the' second phase is elongated along drawing direction and the wire gets high strength due to fiber reinforcement (1). That alloy is so called in-situ formed fiber reinforced ·alloy. Cu-Ag(2), Cu-Nb(3) and Cu-Cr(4) systems are well known as such alloys. It is also well known that chromium is brittle material except single crystal and high purity of chromium. However, Mihara et al. C5l have achieved 1 GPa in ultimate tensile strength in the Cu-Cr-Zr and Cu-Cr-Ti alloys by appropriate thermo-mechanical processing.In this study, the Cu-Cr-Ag systems were investigated: The alloys contained 10 or 5% chromium and 3 or 1 % silver. It was demonstrated that silver precipitated in copper matrix contributed on further hardening."

Jan 1, 2000

By L. Ozdemir, M. Cigla

This paper presents and discusses some of the computer models developed and currently used at the Earth Mechanics Institute (EMI) of the Colorado School of Mines (CSM). These include the performance models for full and partial face machines. Examples of input and output of these models will be illustrated for typical mining operations by using machines such as Tunnel Boring Machines (TBM), Continuous Miners (CM), Marietta borer miners and longwall drum shearers. The general approach to modeling and the available models are discussed and some examples of these models are presented. The comparison between the estimated and achieved performance, as well as the degree of improvement in the performance due to balancing and modification in cutterhead design are also discussed.

Jan 1, 2000

By Robert S. Post

A highly respected coal mining company in West Virginia updated their stacker belt by switching to a new magnetic coupling. The savings they achieved are the subject of this paper. A steep incline and heavy belt loads are powered by a dual drive arrangement. The magnetic couplings were custom designed for complete fluid coupling retrofit and easy installation in the field. Maintenance personnel updated the drives in just a few hours. Over the following several weeks, adjustments were made to the couplings for optimum performance. Cost savings are found in reduced down time, no coupling maintenance, and equipment protection.

Jan 1, 2000

By H. K. Fouad, L. A. Guirguis

The starting mill strip solution· for this study· is an ammonium uranyl tricarbonate solution of pH 8.2 containing 20g uranium/liter, after a DEPA/TOPO extraction process from sulfuric acid leaching liquor. To the first portion of the concentrated acidified strip solution, hydrofuoric acid is added at 95°C in reduced condition to obtain uranium tetrafluoride. The second portion of the uranyl carbonate strip is subjected to a precipitation step by admixing 0.3 volume of non-solvent precipitating agent such as acetone per volume of uranium. ·Uranium oxide (U30 8) is obtained from this precipitate by calcination for half an hour at 800°C in air. The third portion of the strip solution is neutralized to a pH 6.5 with sulfuric acid to precipitate iron and other contaminants. The solution is further acidified to a pH 1.85 with continuous air bubbling to remove CO2, followed by H2Ch precipitation at pH 3.5 to obtain uranyl peroxide. The latter is reduced by stannous chloride to obtain uranium trioxide dihydrate UO3. 2H20. Identifications, characterization· and purity of these products are carried out by complete chemical analyses, Scanning electron microscope study, tap density determination, X-ray diffraction and infrared spectroscopic investigations. The achieved results agreed well with that of the published data for these nuclear grade purity products.

Jan 1, 2000

By Kunihiko Takeda, Kimio Imaizumi, Tsuyoshi Arai

"The study on the preparation of mono-dispersed liquid droplet was performed using ultrasonic as one of the steps of producing the perfectly mono-dispersed particle. The ultrasonic system was a 33.6kHz ultrasonic generator, an amplifier, an electric distortion element, and a bolted Langevin type horn installed in .a cell. For the first time, a liquid pillar under a nozzle of the cell ·was stably formed. Then, dense and coarse parts were alternatively constructed by oscillating the wavelength of the ultrasonic.· The diameter of those liquid droplets were found to be· perfectly uniform, therefore, it was measured by ""multiplex photography"" using a synchronized stroboscope with the ultrasonic.- From the results, more than 30,000 of perfectly uniform liquid droplets in 1 second were observed by this method.IntroductionRecently, research on the control of physical form is done in various fields of industry. Some examples are the processing technology of the minute compound material of micro-machines and integrated circuits, and the form control of molecule size like catalysts. There is a need for such material to take on various forms in correspondence to its use. ""Form control"" as used in this study will indicate ""research on physical chemistry factors which determine the size of the material"" and will refer to the contour uniformity of comparatively little particles. A well-known method of preparing particles is to spout a mist of liquid and slurry from a nozzle l) 2). Particles for metals, catalysts and food have been prepared by this method. In this case, although an approximate particle diameter can be decided by controlling the nozzle diameter and the violent outflow velocity, it is not easy to completely control ·the contour and to prepare a particle with uniform diameter. ·However, the preparation of perfectly uniform particles is necessary for solders for the adhesion of electronic wiring 3), ion exchange resins4), catalysts and so on. Large quantities of fine particles and super-fine particles are generated when manufactured in the usual way. Large quantities of these fine· particles and super-fine particles have polluted the internal and external' environments of factories. The products yield' ·decreases, also. From such a background, this study examines the preparation of perfectly uniform particles that could be· collected -100% as products. Recently, NASA has succeeded in the preparation of perfectly uniform particles in zero gravity 5). But the preparation of 'perfectly uniform particles by this method is difficult, and it can not be used in general industry"

Jan 1, 2000

By A. D. Zunkel

Increasing amounts of electric arc furnace dust (EAFD) are being generated worldwide as more steel is produced from electric furnace melting of galvanized steel scrap. In most countries, the management of this material is a costly technical, economic, and legal problem for minimill steelmakers. Many technologies and processes are being developed and implemented worldwide to manage this material to recover contained zinc, lead, and iron values and render it nonhazardous. These processes are pyrometallurgical, hydrometallurgical, or hybrid in nature. Some produce zinc oxide, some zinc metal, some lead metal, and some lead cement. Some are successful, some have failed, many are dormant. or abandoned, and others continue to be developed and emerge. This paper updates the current status of 20-30 processes in various stages of commercial application and development used worldwide to manage EAFD and recover its nonferrous, particularly zinc and lead, and ferrous values.

Jan 1, 2000

By G. Ferrara, P. Bozzato, B. Chinè

To obtain a reliable comparison between conical and cylindrical separatory vessels used in dynamic dense-medium separation systems, the following two studies were made: a study of the swirling flow in conical and cylindrical vessels using laser-Doppler velocimetry (LDV) and a study of the behavior of suspensions of magnetite and ferrosilicon in water in both separators. It was found that the tangential velocity profiles differ in conical and cylindrical vessels. In a conical cyclone, free vortex conditions affect the largest part of the vessel, while in a cylindrical vessel, the motion approaches that of a forced vortex, i.e., that of a centrifuge. It was also found that the conical vessel manifests higher centrifigal acceleration and very strong densifying (the density differential) and, hence, the density gradient inside the vessel is large. It was found that the cylindrical vessel manifests lower centrifugal acceleration and low densifying, i.e., low-density differentials, and hence, the density gradient inside the vessel is small. Also, due to greater densifying, the density cut-point in cyclones is higher than the operating medium density, while, in cylindrical vessels, the density cut- point is closer to the medium density. The results provide an interesting description of the differing behaviors of conical and cylindrical vessels, and they help explain the differences in pegormance between the two types of separators.

Jan 1, 2000

By James R. Hein

Ferromanganese oxyhydroxide crusts (Fe-Mn crusts) precipitate out of cold ambient seawater onto hard-rock surfaces at water depths of about 600-4000 m throughout the ocean basins. Fe-Mn crusts concentrate most elements in the Periodic Table above their mean concentration in the earth's crust (continental plus oceanic crust), except for the major rock-forming oxides and also notably gold and palladium. Tellurium is concentrated greater than any other element relative to its earth's crust mean (about 1 ppb). For example, mean contents of the elements heretofore known to be most enriched in crusts, Mo, Tl, Sb, Co, Mn, Bi, As, Se, and Pb are enriched 100 to 1000 times over their earth's crust mean, whereas the mean Te content in Fe-Mn crusts is enriched about 50,000 times. However, the distribution of Te in the earth is poorly known. Estimates of the mean Te content of the earth's crust range from 0.36 to 10 ppb, with 1 ppb being the most commonly cited mean content (compilations in Levinson, 1974 and Govett, 1983). If we took the highest estimate of 10 ppb, then Te would be enriched in Fe-Mn crusts five times more than the next most enriched element, or 5000 times the estimated maximum mean earth's crust.

Jan 1, 2000

By A. J. Maselli, E. C. Cemak

Hartford Steel Technologies (HST) has a pyrometallurgical and hydrometaliurgical process capable of reclaiming valuable metals from a hazardous waste· stream such as EAF Dust. The HST Process effectively addresses the growing environmental concerns surrounding the increasing production of EAF Dust without producing any hazardous waste material as byproducts. Currently EAF Dust production levels are exceeding the 1,000,000 metric tons per year mark. The HST Process is designed to separate iron, zinc, lead, cadmium, copper, and silver metals using a two-phased process. The Pyrometallurgical side of the Process utilizes a Rotary Hearth Furnace to separate the iron metal from the remaining metals. These remaining metals are further separated, using a Hydrometallurgical Process, in a series of digestion tanks. The individual metals are then collected in saleable form.

Jan 1, 2000

By Michael C. Montoya, Craig Hopper

It has been well established that the ability to soft start a conveyor will give many benefits to the conveyor user. The effects of deceleration on belt tension have not been as extensively studied. This paper presents the findings of field measurements on the belt tension of a conveyor undergoing various rates of deceleration. The control of conveyor drive motors by Variable Frequency Drives (VFDs) allows the conveyor to be controlled during both acceleration and deceleration. The conveyor is allowed to ramp to a stop without putting unnecessary stress on the belt or conveyor structure.

Jan 1, 2000

By Ian Masters, A. R. Khoei, D. T. Gethin

This paper describes an experimental investigation into the effects of process parameters on product quality during an aluminum recycling process. In order to build a model relating recovery to the process parameter variables and then use the model for prediction, process optimisation, or process control, a historical data analysis is employed by observing patterns in the datalogged information at IMCO Recycling Ltd. In previous work, we emphasised the importance of expressing the results of an experiment quantitatively, by implementation of a Taguchi approach, to facilitate understanding, interpretation and implementation. This research presents the technical tools that are needed to achieve quality improvement in recycling of aluminum. In this study we apply the use of historical data matching through a Taguchi orthogonal analysis, in order to control and improve the quality characteristic. For this purpose, a numerical model is developed to characterise the inputs and outputs of the process. A response surface methodology (RSM) is employed to find a suitable approximation for the true functional relationship between response and the process parameter variables. The method of least squares is used to estimate the approximating polynomials. Subsequently, Taguchi's method is used to determine the relative significance of each of the parameters. Finally, process management software (written in Visual Basic) is described, and its interface with the process modelling and optimisation routines is discussed.

Jan 1, 2000

By A. Arik

An accurate estimation of mining block grades continues to be a challenging task for ore reserve practitioners. Two of the factors that affect the accuracy of the estimates are the estimation method used and the variability of the mineralization in the deposit. The objectives of the study are twofold: Firstly, to see how different estimation methods perform on a given deposit. Secondly, to determine the impact of particular nature of the mineralization on the results. The comparison of several estimation methods for the prediction accuracy is performed using the conditional simulation results as the basis.

Jan 1, 2000

By Susumu Nagae, Hajime Ikeda

Recently, a number of mine development projects have been setback by social, economic and, environmental circumstances that had not been seen before. Many of these problems do not always originate from direct mine pollution. Typical examples of these are· conflicts between the exploration company and the local residents, sudden objections just before the development is to begin, and unexpected tightening of environmental regulations. The common background to these problems is expanding global environmental awareness. This includes complex factors ·such as the expansion of exploration to remote regions, the brisk activities of environmental NGOs, the increase of international environmental laws and, governmental policy changes. Today, the range of issues concerning mine development is widening significantly. The participation of local residents arid NGOs in the development planning, together with the company and government, has become essential for smoothly carrying out mine projects and making them more beneficial for stakeholders. Introduction The common image of the environmental problem with respect to mining is direct mine pollution, such as the collapse of tailings dams, pollution from refineries, and acid mine drainage. All over the world, the mining industry has made large investments in capital and technology to solve and prevent mine pollution, and these efforts have been making steady achievements. However in recent years, new cypes of environmental problems which are not originating directly from mine pollution are emerging frequently. Most of the problems are concentrated at the exploration stage to early stage of development, which have less impact on the environment. In the worst case, mining project may be forced to cancel and could cause serious damage to the industry because they could not collect their investment. I would like to take a general view of the examples of new types of trouble, their characters, background, and strategies against these problems.

Jan 1, 2000

Callide Coalfields produces a sub-bituminous, very subhydrous, low rank, steaming coal with good combustion properties, primarily for domestic power generation. Geological input into planning of coal extraction requires expedient production of detailed structural, lithological, analytical, geophysical and geotechnical data. The CSIRO-developed SIROLOG borehole logging software and hardware system allows for detailed spectrometric analysis of coal/interburden. The gamma-gamma and neutron-gamma SIROLOG techniques both provide improved prediction of ash content over other borehole techniques. The neutron-gamma technique also predicts density and some important ash constituents (especially iron, alumina and silica). The software/hardware configuration allows for quick, easy interpretation of coal seam depth and lithology, parting thickness and ash/ash constituent contents immediately after a borehole has been logged. Within certain mine areas in the Callide Basin, the iron content of mined coal is widely variable in both vertical and lateral extent within and between seams. This variability creates problems in predicting the slagging behaviour of æas-receivedÆ coal during combustion, especially where the iron content of the ash exceeds 19 per cent. Using the SIROLOG tool in co-operation with traditional borehole sample laboratory analysis results, patterns in this variability can be determined and related to geological properties and process of formation of the coal seams. Subsequently, areas of high iron can be predicted in advance of mining. Since 1992, on-going collection and interpretation of SIROLOG downhole geophysical log data has significantly contributed to a number of research projects related to gaining a preliminary understanding of the iron distribution and formation during the Coal MeasuresÆ deposition. Because the probe was able to record variations in coal mineral matter content, it was found to complement more conventional techniques such as reflected light petrography, X-Ray Diffraction and SEM techniques that examine the mineralogy of iron species. Additionally, software has been developed to allow integration of SIROLOG data into existing geology databases, enhancing coal quality modelling and daily prediction of parameters such as raw ash, silica and iron contents that are indicators of ash fusion propensity. The correlation of SIROLOG-derived iron geophysical traces between drillholes and other sample points highlighted lithological and structural controls in the iron distribution in the sequence previously not detected. This work has allowed the development of a methodology for predicting iron in advance of mining and reconciling as-sold coal quality to that predicted. Predictions are currently being assessed at the coal face as mining progresses through high-iron zones.

Jan 1, 2000