Search Documents

By Anna Sukhanova, Svetlana Babaeva, Sergey Andreev, Victor Beltenev

"The Zenith-Victoria /1/ and Jubileynoye /2/ hydrothermal fields have symmetrical structural position on the Mid Atlantic Ridge (Fig. 1). In order to compare the evolution of hydrothermal systems, we conducted mineralogical and geochemical studies of SMS from both sites.Radiochemical and geochemical investigations of massive sulfides of the Zenith-Victoria field distinguishes three major stages of evolution: initial, interim and final represented by Fe-S, Cu-Fe and Zn-Fe types of SMS respectively /3/. In this talk, we describe the results of geochemical analysis of massive sulfides from the Zenith-Victoria field. Geochemical varieties of SMS are considered to be indicators of the evolutionary stages of the hydrothermal system."

Sep 1, 2014

By Nicholas Dyriw, Georgy Cherkashov, Tamara Stepanova, John Parianos, Anna Firstova

"Seafloor massive sulfide (SMS) deposits are a new frontier in global metal resources. Hydrothermal chimney’s (black smokers) precipitate Cu, Zn, Ag and Au rich from hot fluids (>250°C) during interaction with cold seawater ~2-4°C. Here we compare the sulfide mineralogy and geochemistry of Cu-sulfide chimney samples from two different tectonic locations: Solwara 1, a Cu-rich, transitional arc-back arc (Arc-BA) type SMS ore deposit and; Ashadze-1, a Cu-rich, ocean ridge type SMS deposit (Hannington et al., 2011).This work represents the first stage of a project aimed at investigating and understanding the significance of high Cu concentrations in SMS systems. Comparing these particular systems is significant because they share critical similarities despite being located at different seafloor depths, hosted in different rocks and are located in two different endmember tectonic environments. Critical similarities include: 1) age of mineralization, ~6000 years to current (Firstova et al., 2016; Johns et al., 2014); and 2) high copper contents, with chalcopyrite dominating sulfide mineralization (Firstova et al., 2016; Lipton, 2012). The reason for high Cu concentrations in both of these locations is still not entirely understood. The youthfulness (<6000y to current) of both locations is important because it reduces the possibility of increased zone refining, allowing us to understand the source characteristics better. This research will advance our understanding of the copper systematics of SMS systems by investigating and comparing the mineralogical and geochemical signatures from two, Cu-rich, end-member type SMS sites."

Jan 1, 2017

The term geochemistry - chcmbtry&apos; of the earth - is almost limitless in its implied subject, but of recent years a major trend of research in this field has been towards economic application in the search for mineral deposits, and in particular for those of some ofthe less common elements for which a demand now exists.Geochemistry is in a state of slow transition from a purely descriptive subject to a fundamental science concerned with the relationships that exist between the distribution of the elements in the earth&apos;s crust and the physical characteristics of the atoms of those elements. The progress achieved promises a set of basic principles which will relate the atomic characteristics of an element to the physico-chemical conditions that make for its dispersion or concentration. This means that, given a geological map of an areasufficiently detailed for the physico-chemical conditions existing in past geological eras to be deduced, there is the possibility that the relative distribution throughout that area of any element present, and its likely mode of occurrence, could be predicted from a consideration of its atomic characteristics.Since the atomic characteristics of the elements are becoming increasingly well defined by physical research, the attainment of this ideal of prediction depends upon:(a) the strengthening of geochemical theory; and(b) the development of petrological and mineralogical methods of assessing the conditions of temperature and pressure prevailing in geological formations at various stages in their history.The other prime requirement is a d.etailed geological map - a requirement that is all too often lacking.The fact that there has been very little &quot;geochemical approach&quot; to problems of economic geology in Australia should not be taken to mean that there is little point in trying to develop such an approach here in as active and as rigidly scientific a manner as possible. The degree of success that has attended the attempts so far made, to which reference is made below, suggests the reverse, particularly in view of the relatively slight cost involved if the investigations were properly organised on a centralised basis. There are three aspects of geochemistry that are directly applicable to the search for economic minerals.(a) The classic technique of the prospector can be made more sensitive and reliable by the use of modern equipment coupled with the application of geochemical theory to geological and structural data. The case of the rare alkali elements (see below) is givenhere as an illustration of the way in which the distribution of elements can be predicted from the first principles of geochemistry, thereby replacing the prospector&apos;s dependence on his &quot;sixth sense&quot; that enabled him to suggest that a certain area of formation was&quot;favourable&quot; for the occurrence of a certain type of mineral deposit.At its best, this sixth sense amounted to an almost subconscious correlation of all relevant associations and typical occurrences of the particular mineral experienced by the prospector during his...

Jan 1, 1950

By W. E. Hale, G. J. S. Govett

An orientation survey was conducted over a known disseminated copper deposit and a Au-Cu vein deposit and employed geological, geophysical, and geochemical methods. Geochemical techniques proved the most effective and economical means of locating and defining areas underlain by these types of mineralization. Six additional, widely separated occurrences were also investigated and mineralization was confirmed by determination of cold-extractable copper in stream sediments. The length of anomalous drainage varies from several to 16 km and depends on the type and tenor of mineralization. Despite generally marked relief and extreme physical and chemical weathering, cold-extractable copper anomalies in soils appear to reflect closely variations in the ore mineral content of immediately underlying rocks. Threshold values vary with local geological conditions and type and grade of mineralization. Significant thresholds in stream sediments are about 65 ppm and 10 ppm for cold-extractable copper in disseminated and vein copper occurrences respectively. Similar differences are encountered in soils. This necessitates the use of a scale of threshold values at progressive stages in each exploration program. Dis-seminated copper occurrences are presently the major source of mineral production m the Philippines. Much potentially productive ground remains to be investigated and applied geochemistry appears to offer the best available approach. The Institute of Applied Geology (I.A.G.), a joint project sponsored by the University of the Philippines, the Philippine Bureau of Mines and the United Nations Development Program (Special Fund) undertook during 1965-66 a number of field projects in Northern Luzon Island (Fig. 1). These field operations were of a two-fold nature and involved both orientation and exploration. During approximately six weeks, an orientation survey, involving geological mapping, geophysical surveying and geochemical prospecting, was conducted over a partly developed, disseminated copper deposit at Santo Nino (Fig. 1). This study demonstrated the economic and technical feasibility of geochemical ptospecting, relative to the other methods tested, for the location and delineation of a typical disseminated copper occurrence characteristic of those that represent the major source of metal in the Philippines.&apos; Geochemical techniques, similar to those tested at Santo Nino, were then applied in a second orientation study of a vein occurrence at Suyoc (Fig. 1). The results of these two orientation studies suggest that, in reconnaissance work in this region, stream sediment analyses, combined with the determination of pH in the same streams, can be used to indicate areas underlain by rock containing anomalous concentrations of copper, whether it occurs in the large tonnage, low grade, disseminated deposits or in the comparatively small tonnage, higher grade, gold vein occurrences. Furthermore, the orientation surveys demonstrate that soil sampling and analysis serve effectively to outline more closely the mineralized zones within the generally anomalous areas identified from the stream reconnaissance. To further test the methods selected from the two earlier trials, six additional, widely separated prospects were investigated. The geological and geochem-

Jan 1, 1970

By John R. Keith

Lead and zinc contents of elm, maple, and oak trees and of soils in which the trees grew were determined in samples from the Upper Mississippi Valley mining district, and from an area outside but contiguous to the district. The lead and zinc analyses of plant materials served to differentiate the mineralized and nonminer-alized areas. Stems contained about two times as much lead and about two to five times as much zinc as did leaves taken from the same stems. Lead and zinc analyses of all soil horizons could be used to differentiate between the two areas. Soils at most sample sites in the mineralized district seemed to be more reliable than plants for geochemical prospecting and are a more practical sampling medium. Soil samples from areas with thick loess cover, however, failed to indicate the presence of mineralized bodies whereas tree samples from the same sites contained anomalous amounts of lead and zinc. It is suggested that in areas of thick loess cover, plant samples could be used in prospecting for lead and zinc. The important part that plants play in the cycling of elements through the soil horizons is well-known. The concentration of elements in the upper soil horizons by the action of plants has been called the Goldschmidt enrichment principle.&apos; The fact that plant species vary greatly in their ability to concentrate particular elements in their tissues is also well-known.&apos; Agricultural literature has dealt extensively with relationships of the major nutritive elements in soils and plants3 The extent, however, to which plant actions cycle the minor nutritive and the nonmetabolic elements in the soil has not been adequately investigated. Lead is non-nutritive and toxic to plants, whereas zinc is a micronutrient in low, but toxic in high, concentrations.4 This report presents the results of a biogeochemical study concerned with the amounts of lead and zinc in some plants and soils that occurred both within and adjacent to the Upper Mississippi Valley lead-zinc district. Field work for this study was done in the summers of 1961 and 1962. SAMPLE TARGETS AND CHEMICAL ANALYSES Geologic and physiographic descriptions of&apos; the district have been made by Heyl 5 and several other authors in a series of U.S. Geological Survey (USGS) reports and quadrangle maps.6-I Sedimentary rocks, mostly dolomite, limestone, shale, and sandstone, of Cambrian, Ordovician, and Silurian age predominate in the area. Mineral deposits are of the vein and cavity-fill type; the principal ore minerals are galena and sphalerite. Vegetation of the area was characterized by Curtis1 6 as southern hardwood forest interspersed with patches of oak savanna and prairie. Plant genera typical of the eastern United States Temperate Zone, including ash, cherry, dogwood, elm, hackberry, hickory, maple, oak, and other woody and herbaceous genera, are present. The natural vegetation has been greatly modified by agricultural, logging, and mining operations. The species of the original flora are present, but not in their former relative abundance. Soils of this district belong, for the most part, to the Brunizem and Gray-Brown Podzolic great soil groups. The Brunizems are the soils developed under prairie vegetation.&apos;&apos; The Gray-Brown Podzolics are the soils developed under deciduous forests,18 They are derived from both bedrock and from loess parent materials, and

Jan 1, 1970

By R. E. Whippo, B. L. Murowchick

The commercially exploited sedimentary apatites exhibit a number of variable lattice substitutions which affect their chemical composition. Carbonate is a major diluent of phosphorus values in sedimentary apatites. Substantial amounts of water as hydroxyl, hydronium, and tetrahedral hydroxyl ions substitute for fluorine and oxygen, calcium, and phosphate, respectively. Calcium is also replaced by several other divalent and monovalent cations. The structural formula demonstrates the substitutions in the lattice of the sedimentary apatites studied in view of the crystal-chemical relationships which have been postulated for the isomorphous apatite series. The lattice constant a. varies from 9.29 to 9.40 A for the apatites studied. Quantitative relationships between this constant and lattice substitution are complicated by the interaction of multiple substitutions whose influence is non-additive. The mineral apatite, the principal raw material source of phosphorus for agricultural and industrial applications, offers a wide area for investigation. Considerable research effort has been expended in the study of apatite crystal-chemistry by medical, biological, and earth scientists. Few of these studies deal directly with the sedimentary apatites from the major occurrences which are widely exploited for commercial uses. It is the purpose here to present chemical analyses of several sedimentary apatites and discuss their chemical composition in relation to the structural and crystalchemical principles which have been postulated for the apatite isomorphous series. THE STRUCTURE OF FLUORAPATITE The atomic structure of fluorapatite was described, independently, by Ngray-Szabd and Mehmel in 1930 and has been accepted as presented, with only minor changes,4 since that time. The hexaogonal unit cell with dimensions of a = 9.37 0.01 A and c = 6.88 0.01 A contains two molecules of the composition "There are six (PO4) groups in the cell, four calcium ions on the trigonal axes, surrounded prismati-cally by six oxygen ions and six calcium ions surrounded by an irregular polyhedron of a fluorine and five oxygens. Fluorines are at the comers of the reflexion planes, touching three calcium ions each".l7

Jan 1, 1968

By Evan J. Owen, Virginia T. McLemore

The Zuni Mountains, located in Cibola County, New Mexico is an uplifted area that exposes Proterozoic igneous and metamorphic rocks overlain by Permian and younger sediments. Sedimentary-hosted Cu deposits and fluorite veins in the district have recorded production, but other deposits exist. Proterozoic ultramafic rocks may host Ni and PGE. A recent regional stream sediment survey collected 76 samples as part of an exploration geochemistry course at New Mexico Tech with the goal of assessing the critical minerals potential of the district. Whole rock and trace element chemistry of the sediment samples (<2 mm) show a variety of critical minerals possibly worthy of future targeted exploration including up to 700 ppm As, 2100 ppm Ba, 26 ppm Bi, 25 ppm Co, 640 ppm Cu, 145 ppm Ni, 110 ppm Sb, 170 ppm V, and 500 ppm Zr. Positive correlation between Bi, As, Cu, and Sb suggest that these critical minerals are found together within copper veins related to shear zones in the district. Samples collected from streams that drained outcrop of mafic and ultramafic rocks were found to generally contain more Ni, Co, and V. Samples elevated in Ni will be reanalyzed for PGE.

Feb 1, 2025

By Dennis Hoffmann

"Abstract - Banded iron formation rocks associated with massive sulfide lenses in the Broken Hill Pb-Zn-Cu-Ag deposit in the Namaqualand Metamorphic Complex, South Africa , were investigated with respect to the geochemistry of manganiferous silicate-rich bands. Two common varieties of these are: amphibole- and garnet-rich iron formation bands. The results reveal that the former are enriched in Fe, Mg, Cu, Co and S. The garnet-rich bands are enriched in Mn, Ca, P, Pb and Ba with significant detrital contamination of Ti, Al, Zr, Cr, Y, V, Ni and Nd.The silicate-rich bands have compositions, in terms of, Si/Al, Si/Fe, Fe/Mn, La/Ce and Co/Zn, comparable to submarine chemical sediments which precipitated from hydrothermal fluids. The garnet­ and amphibole-rich bands are interpreted as ""evolved"" and ""immature"" hydrothermal sediments, respectively. The latter resulted from rapid precipitation after exhalation, whereas the former had a longer residence within sea water. The silicate-rich bands both exhibit increasing Mn/(Mn+ Fe) fractions, which are consistent with a variation expected from proximal to distal depositional settings. The prevalence of garnet-rich bands over amphibole-rich bands is interpreted as the result of injection of hydrothermal fluids from a single vent situated along the northwest margin of the Broken Hill deposit."

Jan 1, 1994

By Denni Hoffmann

"Banded iron formation rocks associated with massive sulfide lenses in the Broken Hill Pb-Zn-Cu-Ag deposit in the Namaqualand Metamorphic Complex, South Africa, were investigated with respect to the geochemistry of manganiferous silicate-rich bands. Two common varieties of these are: amphibole- and garnet-rich iron formation bands. The results reveal that the former are enriched in Fe, Mg, Cu, Co and S. The garnet-rich bands are enriched in Mn, Ca, P, Pb and Ba with significant detrital contamination of Ti, AI, Zr, Cr, Y, V, Ni and Nd.The silicate-rich bands have compositions, in terms of, Si/AI, SilFe, FelMn, LalCe and Co/Zn, comparable to submarine chemical sediments which precipitated from hydrothermal fluids. The garnetand amphibole-rich bands are interpreted as ""evolved"" and ""immature"" hydrothermal sediments, respectively. The latter resulted from rapid precipitation after exhalation, whereas the former had a longer residence within sea water. The silicate-rich bands both exhibit increasing Mn/(Mn+Fe) fractions, which are consistent with a variation expected from proximal to distal depositional settings. The prevalence of garnet-rich bands over amphibole-rich bands is interpreted as the result of injection of hydrothermal fluids from a single vent situated along the northwest margin of the Broken Hill deposit."

Jan 1, 1994

By D. R. Boyle

"Abstract - The Murray Brook precious metal (Au, Ag) gossan deposit is one of nine supergene mineral deposits that have developed over polymetallic massive sulfide deposits in the Bathurst Camp of New Brunswick. Reserves consist of 1.9 Mt of gossan containing 1.53 g/t Au and 65.9 g/t Ag. The supergene zone at Murray Brook consists of six distinct units: a) altered massive sulfide, b) pyrite-quartz sand, c) massive sulfide gossan, d) disseminated sulfide gossan, e) ferruginized wallrock, and f) leached bedrock. The massive sulfide gossan constitutes the main body of economic mineralization and consists of goethite, primary quartz, secondary amorphous silica, K-Fe-Pb-As- Sb-Ag hydrated sulfate and oxide minerals (beudantite, plumbojarosite, jarosite, bindheimite, scorodite), trace cinnabar, and cassiterite of primary origin. The order of stability of sulfide minerals during oxidation was pyrite > arsenopyrite > galena > Bi-Sb sulfosalts > chalcopyrite > tetrahedrite group > sphalerite.Two mass balance techniques (isovolumetric and conservative element) indicate elemental depletion in gossan relative to primary ore in the order: S>Cd=Zn>Cu=Mn>Na=Ca>Fe=Al=V> Mg= K=Se=Hg>Pb>Ti>Ag>Mo=P>Ba; and enrichment in the order Au>As>Sb>Si>Bi. Tin, as cassiterite, is conservative.Mineralogic and paleomagnetic data suggest that the gossan deposit formed under a warm temperate climate throughout the Pliocene. The rate of oxidation and the compositional nature of the ore was significantly influenced by: a) the position of the primary sulfide zone in a downward moving hydrological system, b) primary sulfide composition and zonation that promoted the development of a strong electrochemical oxidation system, and c) pronounced intercalation of carbonate and sphalerite mineralization in sulfide zones, which promoted rapid development of secondary porosity, permeability and downward flow of oxygenated groundwater.During progressive oxidation and physico-chemical erosion of the gossan zone, Au was trans- ported downward in groundwaters, probably as a Auo colloid complex, to be concentrated in the lower horizons of the gossan profile. The precipitation of Au was greatly increased in the pyrite/arsenopyrite zones. Gold concentration was multi-cyclic with continual dissolution and nucleation of the metal until final concentration in the void structures of the gossan. Leaching experiments and microprobe analyses indicate that Au is present in the gossan as submicron composite sols of Au-Ag-silica."

Jan 1, 1995

By D. R. Boyle

"The Murray Brook precious metal (Au, Ag) gossan deposit is one of nine supergene mineral deposits that have developed over polymetallic massive sulfide deposits in the Bathurst Camp of New Brunswick. Reserves consist of 1.9 Mt of gossan containing 1.53 g/t Au and 65.9 g/t Ag. The supergene zone at Murray Brook consists of six distinct units: a) altered massive sulfide, b) pyrite-quartz sand, c) massive sulfide gossan, d) disseminated sulfide gossan, e) ferruginized wallrock, and f) leached bedrock. The massive sulfide gossan constitutes the main body of economic mineralization and consists of goethite, primary quartz, secondary amorphous silica, K-Fe-Pb-As- Sb-Ag hydrated sulfate and oxide minerals (beudantite, plumbojarosite, jarosite, bindheimite, scorodite), trace cinnabar, and cassiterite of primary origin. The order of stability of sulfide minerals during oxidation was pyrite _ arsenopyrite _ galena _ Bi-Sb sulfosalts _ chalcopyrite _ tetrahedrite group _ sphalerite.Two mass balance techniques (isovolumetric and conservative element) indicate elemental depletion in gossan relative to primary ore in the order: S>Cd=Zn>Cu=Mn>Na=Ca>Fe=Al=V> Mg= K=Se=Hg>Pb>Ti>Ag>Mo=P>Ba; and enrichment in the order Au>As>Sb>Si>Bi. Tin, as cassiterite, is conservative.Mineralogic and paleomagnetic data suggest that the gossan deposit formed under a warm temperate climate throughout the Pliocene. The rate of oxidation and the compositional nature of the ore was significantly influenced by: a) the position of the primary sulfide zone in a downward moving hydrological system, b) primary sulfide composition and zonation that promoted the development of a strong electrochemical oxidation system, and c) pronounced intercalation of carbonate and sphalerite mineralization in sulfide zones, which promoted rapid development of secondary porosity, permeability and downward flow of oxygenated groundwater.During progressive oxidation and physico-chemical erosion of the gossan zone, Au was transported downward in groundwaters, probably as a Auo colloid complex, to be concentrated in the lower horizons of the gossan profile. The precipitation of Au was greatly increased in the pyrite/arsenopyrite zones. Gold concentration was multi-cyclic with continual dissolution and nucleation of the metal until final concentration in the void structures of the gossan. Leaching experiments and microprobe analyses indicate that Au is present in the gossan as submicron composite sols of Au-Ag-silica."

Jan 1, 1995

By Ralph C. Holmer

IN the field of mineral exploration, 1956 can be looked upon as the International Geochemical Year. This is not because of unusual developments in geochemical prospecting but rather because of the world-wide effort in geochemistry and the realization that geochemistry is now an established exploration method. Use of mining geophysics has continued to increase. Those extensively employing exploration techniques indicate that developments of the past few years have permitted better programming of methods, from reconnaissance to location of drill- holes. There is greater diversification of methods- reliance is not placed on results of one. However, it is realized that often it is more economical to drill an anomaly than to conduct additional expensive geophysical surveys

Jan 2, 1957

By Brown P. L

A study has been made of the geochemistry of the Ronneburg mine district as input to the overall management strategy for the rehabilitation of the mine site. The study drew on the geological data and information store developed over the 40 years of mineral exploration and mining at Ronneburg, and on chemical data from the literature which described the chemical processes of weathering, oxidation, dissolution and precipitation of minerals. The geochemical processes were divided into three groups based on their rate of reaction. Fast processes were assumed to proceed to equilibrium and were modelled using equilibrium chemistry equations; slow processes were assumed to be proceeding at a quasi-steady state rate and were modelled using chemical rate equations; very slow processes were assumed to have no role in describing the geochemistry for rehabilitation purposes.

Jan 1, 1995

Orebodies are defined in economic terms in that they must satisfy conditions determined by costs of mining, extraction and marketing before being so described. Despite this they have an essential chemical character as specialized products resulting from geochemical differentiation, and it is surprising that so little basic geochemical research has been carried out with respect to ore occurrence and that prospecting methods based on geochemical principles are not more widely applied.Many exploration geologists associate geochemistry with analytical techniques applied to the detection of dispersed traces of metals from actual orebodies. Geochemical research, applied to economic geology, goes far beyond this limited field and the purpose of this paper is to discuss aspects of such research and its use in formulating exploration principles.THE GEOCHEMICAL BACKGROUND TO MINERAL OCCURRENCE AND EXPLORATIONThe three aspects of economic mineral deposits to which geochemical research can be of use in determining ore guides are genesis, control of deposition and mode of dispersion from orebodies after emplacement. Prospecting for mineral deposits is primarily based on theories of ore occurrence which deal with the genetic and depositional influences controlling localization of ore. There are many such theories and they will not be discussed here as they have been adequately reviewed in geological publications. Some are based on differing argument concerning the same empirically observed associations of ore. In this respect it is perhaps fortunate that they are not always mutually exclusive as regards the...

Jan 1, 1960

By D. D. Runnells, D. C. Keith, G. A. Doyle, J. Tilk

Until the suspension of conventional operations in 1996, the White Pine Mine was the second-largest active underground copper mine in the United States, underlying an area of approximately 30 km2 (13 sq. miles) in the Upper Peninsula of Michigan. The mine operator intends to initiate in-stope solution copper mining by circulating a solution (lixiviant) of mine water, sulfuric acid and ferric iron through rubblized ore. As planned, the solution would be retired in the mined-out stopes following completion of the solution-mining activities. Investigations into the fate of the retired solution indicated that the solution, through time, would change from an acidic, metal-rich solution to a near-neutral, reducing solution containing much lower concentrations of metals. Investigations included reaction-path modeling (EQ3/6) and laboratory and in-mine tests. The combination of neutralization and reduction will result in precipitation of most metals, primarily as metallic sulfates, chlorides and sulfides.

Jan 1, 1998

By G. A. Doyle

Until the suspension of conventional operations in 1996, the White Pine Mine was the second-largest active underground copper mine in the United States, underlying an area of approximately 30 km2 (13 sq. miles) in the Upper Peninsula of Michigan. The mine operator intends to initiate in-stope solution copper mining by circulating a solution (lixiviant) of mine water, sulfuric acid and ferric iron through rubblized ore. As planned, the solution would be retired in the mined-out stopes following completion of the solution-mining activities. Investigations into the fate of the retired solution indicated that the solution, through time, would change from an acidic, metal-rich solution to a near-neutral, reducing solution containing much lower concentrations of metals. Investigations included reaction-path modeling (EQ3/6) and laboratory and in-mine tests. The combination of neutralization and reduction will result in precipitation of most metals, primarily as metallic sulfates, chlorides and sulfides.

Jan 1, 1997

By S F. Simmons

The Ohaaki Rhyolite and the Rautiwiri Breccia are two volcanic units occurring in the shallow and deep parts of the Broadlands-Ohaaki geothermal system. Alteration of these units by chloride waters results in distinct mineral assemblages that also have distinct whole rock compositions. The Ohaaki rhyolite is altered to an assemblage dominated by quartz, adularia, illite and pyrite as a consequence of silica, potassium and sulfur metasomatism. Locally, these rocks contain up to 0.5 ppm Au. The Rautiwiri Breccia by contrast is altered to an assemblage dominated by albite, adularia, quartz, illite, chlorite and pyrite in association with modest sodium metasomatism. Whole rock oxygen isotope compositions of altered rocks range between 3.3 and 7.5 ë, and are generally lower compared to their fresh rock equivalents having values of 9.5 to 10.6 ë; the result is broad pattern of lower values with increasing alteration intensity.

Jan 1, 2002

By A. Gene Collins

The demand for lithium may increase because of its potential use id lithium batteries and in the generation of electrical power by fusion. Therefore, lithium abundance in some United States oil-field brines was surveyed. Oil-field brines from numerous locations were found to contain more than 100 mg/l lithium and several exceeded 500 mg/l. An area of 25,000 km2, with a reservoir thickness of 60 m, an effective porosity of 5 percent, and a brine with a specific gravity of 1.2 containing 100 mg/l of lithium, contains about 0.75 x 106 tonnes (1 tonne = 1 metric ton = 1,000 kg) of lithium in 7.5 km3 of brine. It is postulated that the brines were enriched in lithium by lithium-rich spring water or lithium leached from volcanic rocks followed by evaporation sequences.

Jan 1, 1978

By Alden B. Carpenter

The Dead Sea is the only relatively large body of surface water having bromide concentrations comparable to those in the brines of the Smackover Formation in Arkansas. The Dead Sea, like the Smackover brines, contains a great deal of calcium and is very low in sulfate and iodide. The relationships between potassium, divalent cations, and chloride indicate that over 20 percent of the bromide in the Dead Sea is derived from some source other than by the evaporation of sea water. A similar type of study of the Smackover brines in Arkansas indicates that approximately 60 percent of the bromide has been derived from some source other than sea water. Both the Dead Sea and Smackover brines are very low in iodide suggesting that the excess bromide has not been derived from organic matter. The origin of the excess bromide is probably the same for both of these brines, but the source of this bromide remains unknown.

Jan 1, 1978

By Zohreh Kazemi Motlagh, Virginia T. McLemore

Critical minerals are nonfuel minerals, essential to the U.S. economy and national security, whose supply chain may be disrupted. Mine wastes are potential sources of critical minerals. The goal of this project is to estimate and characterize critical minerals endowment in three mining districts in New Mexico: Black Hawk (Grant County), Hillsboro (Sierra County), and Magdalena (Socorro County), and assess their acid-generating potential. The Black Hawk district is an arsenide five-element vein deposit (Ag, Ni, Co, As, U, Bi, and local minerals like Pb, Cu, Zn, W, and Sn). The Copper Flat mine in Hillsboro district is a copper porphyry deposit. The Kelly mine in Magdalena was first mined at 1878 and are carbonate-hosted Pb-Zn deposits. Mine waste rock piles and tailings are sampled using USGS Beta sampling procedure. Geochemistry results show that Black Hawk district mine wastes samples are elevated in Ag (>200 ppm), Co (290 ppm), Ni (2,130 ppm), and Zn (8,463 ppm). Copper Flat mine tailing is elevated in Bi (111 ppm), Cu (7,453 ppm), and Zn (2,360 ppm). Downhole profile plots in Copper Flat show the positive correlation between Cu, S and Te values. Magdalena samples are elevated in Cu (5,700 ppm), Zn (129,500 ppm), and Pb (58,100 ppm). Determination of acid-generating potential in these areas suggests that Black Hawk district mine wastes are non-acid-forming while high S present in some Copper Flat and Magdalena samples can potentially cause acid mine drainage.

Feb 1, 2025