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By Edouard Asselin, Guikuan Yue

"In the present study, electrochemical measurements, especially cathodic potentiodynamic polarization (CPC) and cyclic potentiodynamic polarization (CPP), have been employed to study the kinetics of ferric reduction on chalcopyrite in aqueous Fe( II )-Fe(III)-H2S04 solution at 25°C and 70 °C. Results from the calculation ofspeciation in the above solution reveal that, at both 25 °C and 70 °C, the real Fe3+/Fe2+ ratio is much lower than the nominal ratio, which leads to smaller values for the reversible potential of the ferric/ferrous couple based on the Nemst equation. Exchange current densities of the ferric/ferrous couple were obtained by extrapolating the cathodic linear Tafel line to the reversible potential and are on the order of 10-7·10-6 A/cm2 at 25°C and 10·6-10-5 A/cm2 at 70 °C, respectively. The transfer coefficients were about 0.35-0.38 at 25°C and 0.35-0.45 at 70 °C. Polarization plots of CPC and CPP under different nominal Fe3+/Fe2+ ratios are in good agreement at 25 ·c and at 70 °C. Based on the obtained exchange current densities, the rate constant k, was calculated and is on the order of 10-1 cm/s at 25 °C and 10 1 cm/s at 70 °C.IntroductionChalcopyrite is the most abundant copper mineral in nature, accounting for about 70% of copper reserves in the world [I]. In recent years, the metallurgical industry has been searching for a hydrometallurgical process as an alternative to pyrometallurgical treatment due to high emissions of S02 and capital costs associated with smelting. Activity in this area has increased recently due to some inherent advantages associated with hydrometallurgical processing, such as the possibility of treating low-grade ores (increasingly more abundant in the case of copper) and easier control of waste, with the attendant benefits to the environment [I]. Chalcopyrite is highly refractory under most hydrometallurgical conditions, owing to the formation of an anodic passivation layer on the chalcopyrite surface which renders the process kinetics very slow. Most of the currently proposed processes are based on sulfuric acid with ferric ions and/or dissolved oxygen as oxidants. Sulfuric acid is preferred over all other leaching reagents in terms of cost, environmental friendliness, and ease of its regeneration during electro-winning. Some of these processes have been piloted in attempts to implement these technologies on an industrial scale,"

Jan 1, 2012

By N Schofield

For the sampling of particulate materials in mineral exploration and mining, the fundamental sampling error (FSE) introduced by Gy is a measure of the constitutional heterogeneity of the sample lot and is expressed as the relative standard deviation of subsample grades of a particular mass. The FSE is presently regarded as an important indicator of quality for samples used in resource estimation. Constitutional heterogeneity describes an ideal state of heterogeneity with respect to all constituents of the lot such that the fundamental error among subsamples of a particular mass is minimised.In this paper, the term ‘sampling precision’ used in relation to mineral resource sampling usually refers to a statistic based on the assay results drawn from pairs of separate subsample splits of multiple sample lots. The pairs of splits are extracted after the lots have been prepared by crushing and pulverising to meet specified criteria of grain size and subsample mass. There is presently no generally accepted method of calculating the ‘sampling precision’ from such paired data but some form of the relative standard deviation that is consistent with definition of the FSE is preferred here. The work of Thompson and Howarth in the 1970s on geochemical analytical precision, which has been subjected to extensive examination and criticism by Stanley and Lawie (2007), and that of Francois-Bongarçon since the 1990s forms the background to the discussion in the paper.A significant aspect of the application of Gy’s sampling theory to sampling in gold deposits is the requirement that the fundamental error be maintained at less than ±20 per cent. The most important reason for this is to ensure that the effects of other sampling errors such as the grouping and segregation, and increment delimitation which can cause local and global biases in sampling are kept as small as possible. This paper is focused mainly on the quality of sampling in gold deposits and looks at an alternative to the use of a constant sampling precision applied to a collection of lots with varying average grade. A theoretical model for the FSE based on duplicate sampling is presented and the simulated results of the model are compared to practical outcomes of real duplicate pairs drawn from multiple sample lots. The goal of the work is to present a more informative analysis of duplicate sample data from multiple lots which may allow a more informed view of the potential for bias generating errors during sample preparation and processing.

Aug 22, 2011

By G Reynolds, N A. Ware, L Lu

Queensland Pacific Metals (QPM) is progressing its Townsville Energy Chemicals Hub (TECH) project to produce nickel and cobalt sulfates for advanced battery materials. Apart from the nickel and cobalt sulfates, the process also generates a hematite by-product (~640 ktpa). The hematite byproduct precipitated from the process, hereafter ‘hematite precipitate’, is high in Fe and particularly low in impurities. However, it is a fine <20 μm crystalline, hydrometallurgical precipitate and is produced as a filter cake containing a high moisture content of about 15 per cent. This is considerably different from natural hematite ore and is expected to change its performance during sintering. In the present study, laboratory scale sintering tests were undertaken to evaluate the potential impacts of substitution of the hematite precipitate for traditional magnetite concentrates and further for Australian hematite-goethite ores in a simulated industry base blend. Substitution of hematite precipitate for magnetite concentrates was found to slightly increase the sintering temperature required to achieve the strength of laboratory sinters. However, further substitution of hematite precipitate for Australian hematite-goethite ores slightly reduced the sintering temperature required to achieve the laboratory sinter strength. These results reflect the reduction in Al2O3 contents of the blends and are consistent with the trend observed in industry and pilot scale facilities. The reduction in sintering temperature generally correlates to a reduction in fuel rate in the larger scale sintering process. The pore structure of selected laboratory sinters was further examined and discussed in conjunction with sinter strength. The pore structure images highlighted the relative difference between the blends with the most obvious difference being seen at 1290°C which correlates well with the laboratory tumble index (TI). The laboratory sinter samples showed an increase in porosity and irregularity of pore shape, as hematite substitution increased demonstrating the correlation between a more porous structure and a lower TI.

Sep 18, 2023

By K Uchino, M Inoue

Self-potential anomalies are generated by fluid pressure gradient, by temperature gradient or by chemical gradient. On the basis of this principle, a new technique is proposed to locate the fire source of spontaneous combustion of coal by the self-potential method. In order to investigate whether this method can be applied to locate the spontaneous combustion of coal in practice, surveys of self-potential distributions were undertaken in a coal waste pile undergoing spontaneous combustion. The results showed that there is a negative centre of the electrical potential distribution in the measurement area. The potential in this centre is about 140 mV lower than that in the surrounding area. Moreover, the negative centre of electrical potential distribution almost overlaps with the high temperature zone. Therefore, it is concluded that it is possible to locate the heat source by the measurement of self-potential distribution.

Jan 1, 2005

By D. B. Dreisinger, M. Mokmeli, B. Wassink

Dissemination of selenium and tellurium in sulphide minerals results in the contamination of pregnant leach solutions and electrolytes in the hydrometallurgical treatment of sulphide ores and residues. The selenium and tellurium content of the copper sulphate-sulfuric acid solution may be reduced into insoluble precipitates of copper selenides and tellurides using cuprous ion. This study presents the use of the thermodynamics and kinetics for the removal process of selenium and tellurium in real life application. Dominant species of selenium and tellurium in acidic copper sulfate solutions were identified and the reduction rates of species were compared. The findings were applied to industrial conditions by modeling the Vale’s CRED (Sudbury, Canada) plant’s selenium and tellurium purification circuit. Rate reducing factors on selenium and tellurium removal were identified and discussed.

Jan 1, 2014

By G. P. Wong

"In the Inco matte separation process, a slow-cooled converter matte is separated into three main discrete mineral phases: chalcocite (Cc), heazlewoodite (Hz) and a Cu-Ni-Fe alloy. After magnetic removal of the alloy, Cc and Hz are separated by flotation at pH>12 with diphenyl guanidine (DPG) as both collector and frother. High selectivity is achieved in rougher flotation. However, in later flotation stages such as in the middlings circuit, as oxidation takes place, Hz becomes highly floatable, resulting in a very poor separation between Cc and Hz.Starch and dextrin as Hz depressants were evaluated on the middlings circuit feed and showed no positive impact on Cc/Hz separation selectivity. Ethylene diamine tetra-acetic acid (EDTA) extraction showed the existence of abundant surface Cu and Ni ions. The use of triethylene triamine (TETA) or EDTA in flotation did not improve Cc/Hz separation selectivity. Microflotation tests were carried out on pure synthetic Cc and Hz minerals. It was found that Hz did not float in the presence of DPG. However, Hz conditioned with either copper sulfate solution or in contact with Cc floated readily in the presence of DPG. It is concluded that the major reason for Hz flotation in the middlings circuit is due to Cc oxidation releasing Cu ions that adsorb on the Hz surface making it reactive with DPG thus rendering the Hz floatable."

Jan 1, 2003

By G. P. Wong

"The Inco Matte Separation process was the first commercial application using mineral processing techniques to separate nickel from copper from a slow-cooled matte in Sudbury since 1945. In Inco Sudbury operations, bulk sulphide concentrate containing chalcopyrite, pentlandite, pyrrhotite and some gangue minerals is flash smelted and converted to Bessemer matte. During the controlled slow-cooling of the Bessemer matte, discrete mineral grains of new mineral phases are formed: copper sulfide precipitates as chalcocite (Cu2S), nickel sulfide as heazlewoodite (Ni3S2) and a Cu-Ni-Fe alloy is also formed. Flotation is employed to separate Cc from Hz under high lime conditions (pH>12) with diphenyl guanidine (DPG) as both collector and frother.A simplified matte separation flowsheet is as follows. After grinding, the Cu-Ni-Fe alloy is removed by magnetic separation. All precious metals are recovered in the metallic alloy. Following the rougher flotation, a Cu concentrate is produced after cleaner and re-cleaner flotation in mechanical and column cells. Two Ni concentrates are produced: a high-grade Ni product containing less than 0.8% Cu from the scavenger column tails and a low-grade Ni product containing 5% Cu from the middlings circuit tails. A stream containing the inseparable Cc and Hz from the middlings circuit is generated and recycled back to the smelter. The quantity of this stream is typically about 3% of total feed and can be as high as 5%, greatly decreasing the overall matte separation efficiency. The large mass of the recycle stream is a direct result of poor Cc/Hz separation selectivity in the middlings circuit. The middlings circuit, consisting of a thickener, a regrind mill and two columns, processes two streams: cleaner tailings and scavenger concentrates. The thickener contributes significantly to oxidation due to the long residence time of the pulp in this unit."

Jan 1, 2003

By Jian Li, Robbie McDonald, David Robinson

"The pressure oxidation of sulfide minerals at temperatures above 200°C enables the extraction of base metals, improves the extractability of gold from refractory ores, enables solubilisation of PGEs and can be used to hydrothermally upgrade base metal-containing feeds. Fundamental studies reveal that the solution chemistry (and mineralogy of the solids) during pressure oxidation can be manipulated with outcomes that include (1) increased leaching rates, (2) lower oxygen requirements and (3) the formation of chemically more stable residues. This paper presents examples describing how these outcomes might be achieved based upon fundamental investigations.INTRODUCTION The application of pressure oxidation to the processing of gold ores and concentrates dates back several decades and continues to be the process of choice at operations such as Pueblo Viejo (pyritic gold) which host the largest autoclave of its kind in the world (Barrick Gold Corporation, 2016). Commercial application to the processing of base metals and PGMs resides with long established processes such as the Sherritt process, ore specific applications such as by Noril’sk, at Sepon etc. or has not proceeded to date beyond pilot scale testing (e.g. Phelps Dodge, CESL, Activox, Platsol). Recently there has been significant interest in hydrothermal upgrading options for concentrates including the NONOX and Toowong processes (Rohner et al., 2016; Weidenbach et al., 2016). The latter options suggest directions where sound knowledge of the underlying fundamentals enables novel outcomes and efficiencies to be obtained. It comes as no surprise that investigations similar to those underpinning these developing processes can be traced back several decades. It is not the subject of this paper to provide a historical perspective of the relevant autoclave chemistries but rather, to present some potential opportunities suggested by studies in our laboratories. Topics to be discussed in this paper include (1) control of metal extraction rates, (2) control of iron-residue composition and (3) control of sulfur oxidation and hence acid generation and oxygen requirements. The work described will focus upon the pressure oxidation of a nickel concentrate."

Jan 1, 2017

By Yoshiaki Numata

It is a matter of importance to use the lower alkyl monoethers of propylene glycol (polyPGME) as a frother in sulfide mineral flotation, for their compounds are highly soluble in water and are surface active frothers to some extent. The purpose of this study is to clarify fundamental roles of frothers in sulfide mineral flotation by investigating the effects of polyPGME on the floatability of galena with xanthate and adsorption property those ethers at the liquid/air interface. Fundamental investigation on the flotation of sulfide minerals using o,o-dialkyl dithiophosphates has been carried out through galena floatability tests in the following two cases:(l)single use of dithiophosphate for sulfide mineral collection and (2) joint use of dithiophosphates for its collection.

Jan 1, 1991

By V. M. Lovell, N. P. Finkelstein

The concepts involved in flotation research are discussed and aims are presented. Three different methods of investigation can be used, all of which are applied at the National Institute for Metallurgy (N.I.M.), and these are the empirical, trial and error method, the chemical engineering method, and the physicochemical approaches. This paper is devoted to the last of these. Because of the complexity of the physicochemical interactions involved, the work has, to a large extent, been concentrated on only one aspect, viz. the interaction between the mineral surface and reagents in solution, which was considered of major importance in the understanding of the process. The aspects on which work has been done are the concentration of uranium, the reaction between salt minerals and fatty acids, mixed xanthate-cationic collector systems, and the reaction between sulphide minerals and thiol reagents. Selected problems from the first two of these are discussed in some detail and deal with the agglomeration flotation of uranium and the chemical control of the flotation process for phoscorite. A detailed discussion is also presented of the progress made in the understanding of the interaction between sulphide minerals and thiol reagents, which is of more general application. Finally, an indication is given of the future direction of physicochemical research at the N.I.M.

By V. M. Lovell, N. P. Finkelstein

The concepts involved in flotation research are discussed and aims are presented. Three different method. of investigation can be used, all of which are applied at the National Institute for Metallurgy (N.I.M.), and these are the empirical, trial and error method, the chemical engineering method, and the physicochemical approachs This paper is devoted to the last of these. Because of the complexity of the physicochemical interactions involved, the work has, to a large extent, been concentrated on only one aspect, viz. the interaction between the mineral surface and reagents in solution, which was considered of major importance in the understanding of the process. The aspects on which work has been done are the concentration of uranium, the reaction between salt minerals and fatty acids, mixed xanthate-cationic collector systems, and the reaction between sulphide minerals and thiol reagents. Selected problems from the first two of these are discussed in some detail and deal with the agglomeration flotation of uranium and the chemical control of the flotation process for phoscorite. A detailed discussion is also presented of the progress made in the understanding of the interaction between sulphide minerals and thiol reagents, which is of more general application. Finally, an indication is given of the future direction of physicochemical research at the N.I.M.

By V. M. Lovell, N. P. Finkelstein

Fundamental studies of the flotation process: The work of the National I nstitute of Metallurgy N. P. Flnkelsteln and V. M. Love Presented at the Colloquim on Flotation, March 1972, and published in the Journal, July, 1972. AUTHORS&apos; REPLY TO DISCUSSION In his contribution to our paper Dr Lloyd makes two criticisms: The first criticism, as we interpret it, is that the agglomerate flotation process that we described is not really necessary because previously described processes effect almost the same results or could be made to give the same results by including sufficient paraffin in the reagent combination.

By Luben Savov

This paper presents recent research works on the removal of the tramp elements Cu, Sn, Zn and Pb from steel. The evaporation of Cu and Sn in iron-based melts treated at reduced pressure of the gas phase was studied in a vacuum induction melting furnace. The effect of chamber pressure, temperature and melt composition was investigated. Since the main source of contamination of steel with Sn and Zn is the recycling of tinplate and zinc coated steel, respectively, possibilities for the removal of meta1ic coatings in a scrap pre-treatment stage were studied, too. Tin was removed in the temperature range 400-5S0°C by treatment with reactive gases featuring high sulphur potential. Zinc can be removed by evaporation or by a combination of thermal and mechanical treatment. The paper discusses the thermodynamics of Pb in carbon-saturated iron melts, too.

Jan 1, 2001

By H. Jiang, S. Yang

"The main processes for nickel metallurgy in China consist of electric arc furnace smelting to produce low grade nickel matte and converter to high grade nickel matte, grinding and flotation to separate nickel sulfide from copper sulfide and direct electrolysis of nickel matte. Systematic studies on the properties of electric furnace slag, smelting process for nickel matte, anodic process of nickel matte, cathodic process of nickel electrolysis have been done in our labs. In addition, an approach to a new hydrometallurgy process for nickel matte has been done. The feature of the new process is one stage acidic leaching of high grade nickel matte. The leaching solution could be purified by deposition way or by solvent extraction way. There are two leaching rate-determing steps, chemistry reaction-determing one at temperatures below 600C and diffusion-determing one at temperatures higher than 600 c. The acidic leaching fraction reacted dvaties with leaching time t according to the equation 1-(1- a ) 1/3=kt. The experimental data also show that the leaching reaction rate varies with concentrations of H+, Cl-, and it is also effected by copper sulfide and Cu++. The Cu++ ion can retard the leaching reaction due to forming a copper sulfide layer on the matte surface and the equation 1- 2/3 a. - (1- a: ) 2/3 akt can be used for the case. However the copper sulfide added into nickel matte can facilitate the leaching process. The research work for nickel metallurgy done by others in China has also been mentioned in this paper.Large scale production of nickel in China started in 1960s.The main processes consist of electric arc furnace smelting to produce low grade nickel matte and converter to high grade nickel matte grinding and floatation to separate copper sulfide from nickel sulfide and direct electrolysis of nickel matte.To reduce nickel loss in slag a reseaech group organized by Jinchuan Company and Central South Institute of Mining and Metallurgy (now the Central South University of Technology) measured the viscosity surface tention density conductance melting point and structure of the slag(I).lt has been found that the physico-chemical properties of the slag depend on the components SiO2 ,MgO and FeO but FeO in the slag is too high and the statistic analysis of data from industry gave an equation to correlate the content of Ni in slag with the content of Ni in matte and the composition of slag again it was pointed out that the content of FeO in slag effected the loss of Ni in slag very much (2). The ratio (FeO+MgO) to SiO2shouid be less than 1.13 and the content of Fe3O4should be as low as possible but the reaction"

Jan 1, 1988

By Erich U. Petersen, J. B. Hiskey, William J. Tafuri, Donald M. Hausen, X. H. Jiang, Douglas N. Halbe, G. Ramadorai

The extraction of gold from chloride solutions with activated carbon is examined. It is shown that the uptake of gold by activated carbon from chloride solution follows a mechanism whereby gold is reduced to the metallic state. Metallic gold appears as deposits both on the carbon surface and in pore space within the carbon particle. The deposition rate is dependant on the carbon particle size and pH. At low initial gold concentrations, the initial rate is insensitive to gold concentration. Sodium hypochlorite exhibits an adverse effect on the reduction reaction. The overall loading and initial rate of reduction are both decreased in the presence of NaC10. The effect of iodide on the loading of gold was also examined in an attempt to overcome the superficial deposition of gold on carbon.

Jan 1, 1990

A rotating-discelectrode system was used to evaluate the electrochemical behaviour of Eu(III) during its reduction in NaCl solutions. The solution pH and NaCl concentration have a great effect on the reduction kinetics. The thermodynamic modelling study also revealed that Eu(III) exists in various forms in NaCl solutions. At a low concentration of NaCl, the predominant species is the free Eu3+. Other Eu-chloro complexes become more predominant when the NaCl concentration increases.

Jan 1, 1992

By N. Mohan, A. K. Biswas, V. Y. Sampat Kumar

At low sodium-oleate concentration, calcite flotation is substantially improved by the use of CO2 instead of air. Electrophoretic mobility measurements indicate that carbonation results in the accumulation o f positive charge on the calcite particles. This heightens adsorption of oleate anion, an effect confirmed by tracer-technique measurements. Fundamental insight is obtained as to how CO2 serves better as an activator than some mineral and organic acids, how oxalic acid acts as a depressor, and why the influence of Ca++ ions, liberated during carbonation, on flotation behavior of calcite is insignificant and sometimes adverse.

Jan 1, 1972

By T Takayama, R Muroi, M Matsumura

The steel industry occupies 14 per cent of CO2 emissions in Japan, and the sintering process is one of the major emitters. Since most of CO2 released from the sintering process comes from coke fine combustion, replacement of coke fines with biomass char as bonding agent is a potential countermeasure. In order to explore the effective use of biomass char, we chose char made from Palm Kernel Shell (PKS) as a sample. First, the char’s combustion behaviour was examined with varying the char’s particle size by means of admixing the char in alumina ball packed bed placed in an electric furnace. As a result, the finer the PKS char the faster the burning rate and reaching a higher temperature compared to coke fine. In addition, it is also concluded that the optimum size of PKS char was larger than coke fines. Next, the effect of different heat profiles on sinter structure was examined by sintering tablet made of chemical reagents. In this experiment, the chemical composition is designed based on sinter composition. By this sintering test, even at high temperature, rapid cooling is effective to make fine sinter matrix and fine pores, which has possibility for high sinter reducibility. Based on these two experiments, using PKS char as a sinter fine source has the possibility to improve sinter reducibility.

Nov 8, 2021

By Junji Shibata

Waste solution from the Ni non-electric plating process contains 4.0 kg/m3 Ni, 0.1 kglm3 Fe, 0.0 I kg/m3 Zn, 48 kg/m3 S042-, 98 kg/m3 HP032-and 31 kg/m3 laetic acid as a typical composition. Solvent extraction, cementation, ion exchange resin and precipitation methods are possible to use for the treatment of this kind of solution. In this study, solvent extraction of Ni was investigated using two kinds of extractants to clarify the relation between extraction percent and pH for various extractant mixtures. As Ni ion has an octahedral structure with ligands, the synergistic effect for Ni extraction is considered to take place in solvent extraction using two types of extractants. The investigation of the synergistic effect for Ni extraction was carried out in case of various extractant systems.

Jan 1, 2003

Japan is the largest coal importer in the world, importing from Australia, China, Indonesia, Canada, Vietnam, etc. In Indonesia, most of the produced coal is extracted from open cut mines. More open cut coal mines will be developed to fill the demand for coal in Indonesia and the world. Many surveys and projects for developing new coal mines and transferring mining technology are being conducted in tropical counties such as Indonesia and Vietnam with the aid of the Japanese Government. It has, however, been pointed out that excessive and precarious development of mines in tropical areas will damage the environments around the mines including cultivated lands, and reduce the precious rainforest. This would undoubtedly exacerbate the instability of the global climate and the food crisis in the world. This paper describes the effects of flyash on the control of acid mine drainage in order to avoid potential negative impacts on the environment caused from open cut coal mines.

Dec 6, 2010