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By V. Coetzee

In 1992, a paper was compiled highlighting a common-sense approach to electric smelting at Impala Platinum. Since then, the smelter complex has undergone considerable changes. Mineral economics, UG2 exploitation, and changing environmental legislation have enforced numerous process upgrades, yet a common-sense approach has always been adopted. This document details the major changes in the smelter complex at Mineral Processes (Minpro) over the past 15 years, and provides the rationale for the changes. Keywords: Pyrometallurgy, furnace, PGM, platinum, nickel, copper, electric smelting, six-in-line, Peirce-Smith, Impala Platinum.

Jan 1, 2006

By R. D. Brown

The Federal Government's White Paper on Tax Reform received further major criticism in the reports of the Committees of the House of Commons and the Senate, which recently completed a lengthy review including public hearings of the government's proposals. These reports both criticized the emphasis placed by the White Paper on its concept of tax equity rather than on a system which would promote economic growth. However, the Finance Committee of the House of Commons was prepared to accept, with modifications, a number of the White Paper's key reform proposals. The Senate Finance Committee was more critical of the basic thrust of the tax reform program and recommended that a modification of the existing tax system would be more appropriate to Canada's needs. Both Committees re-commended a more favourable treatment of mining income than that originally proposed in the White Paper, and to some extent both Committees suggested proposals that were even more favourable to the industry than those set out in Finance Minister Benson's amended proposals made in August of this year. This article out-lines the principal recommendations and comments in the reports of both the House of Commons Committee and the Senate Finance Committee.

Jan 1, 1971

An outline of the circumstances giving rise to the current Commonwealth-States con- flict in relation to offshore mineral explor- ation and production is set out, together with an analysis of the Seas and Submerged Lands Act 1973. The bases of the claims by the Commonwealth and the States in this regard are discussed with relation to the territorial sea and the continental shelf.

Jan 1, 1974

By Al Cropp, Julie Hunt, Will Goodall, Ron Berry, Dee Bradshaw

Geometallurgy aids the understanding of ore body variability but has the most value if the data is easily available along the entire mining value chain. This requires cross-discipline communication and collaboration across traditional silos, and an organizational culture that encourages that to flourish. Data that are collected by the numerous groups (i.e. mining, geology, milling, processing, refining, smelting, marketing, environmental etc.) involved in the mining process may have relevance to other stakeholders; mineralogical and textural data for example has value to all these groups. Data required for modeling comminution or identifying acid potential from waste rock may already exist, however it needs to be made available to all the relevant stakeholders in the right format at the right time. As part of the GeM (AMIRA P843 & P843A) project the opportunity has been taken during the sponsor meetings, short courses, case studies etc. to ask the question: ‚What information do you want from further up the chain?? For example, to metallurgists ‚What information would you like from the geology group before the ore enters the mill?? The geology group may already have information important to mineral processing but not know it is of interest. This could, for example, be in the form of a geometallurgical drill core log that contains quantitative measured values. This paper focuses on the interaction between the mining, geology, mineral processing and environmental groups, using ore properties resulting from geological alteration to identify potential impacts throughout the mining process and discusses how a cross discipline approach can benefit all.

Jan 1, 2014

Mining is an inherently risky business; from the technical, environmental, social, and economic uncertainties associated with advancing an exploration prospect to a viable project to the operating, market, and safety risks and uncertainties attached to a developed mine. Since we cannot totally escape the risk and uncertainty related to resource projects, as an industry we should improve our presentation of the upside and downside risks in the context of the project?s development path and maturity. More transparent, consistent, and balanced views of technical confidence will better inform both internal and external stakeholders about the expected risk in the project. International reporting codes set out the minimum standards, recommendations, and guidelines for public reporting of Exploration Results, Mineral Resources, and Mineral Reserves. However, the reporting code principles of transparency and materiality are largely subject to the interpretation of the competent person(s), which may introduce a degree of subjectivity in reporting, particularly the level of disclosure regarding supporting information. It is fundamental that Mineral Resources, Mineral Reserves, and study outcomes are reported so as to unambiguously present the level of inherent technical uncertainty (or confidence) in a project, while conveying a balanced view of the opportunities a project presents. Reporting needs to consider various stakeholders who may rely on this information, and present the data in the context of the changing risk profile associated with project development paths and project maturity. This paper discusses the interdependence of resource-to-reserve conversion, the consideration of various technical-economic study types, and the level of confidence conveyed to stakeholders relying on these technical reports and other company public announcements.

Jan 1, 2014

By R. Yost

"This paper describes a case study that illustrates how detailed geological engineering results were communicated to address a range of stability challenges in a producing mining environment. Instead of using standard geological engineering terminology, findings and recommendations were communicated as mine design options and mining responses to accommodate possible slope instabilities and associated risk. The resulting medium- to long-range mine plan integrated the potential slope instabilities and associated mining responses to provide a higher probability of planned resource extraction. It also reduced the potential for long-lasting production and processing delays.RÉSUMÉ Cet article décrit une étude de cas illustrant l’intérêt de la communication de résultats détaillés de géologie appliquée pour résoudre un éventail de difficultés relatives à la stabilité dans un environnement minier en production. Plutôt que d’utiliser une terminologie classique de géologie appliquée, les résultats et les recommandations ont été communiqués sous forme d’options pour la conception d’une mine et de réponses dans le contexte minier permettant de surmonter les éventuelles instabilités des pentes et les risques associés. Le plan de mine sur le moyen à long terme qui a résulté intégrait les instabilités potentielles des pentes ainsi que les réponses connexes dans le contexte minier afin de renforcer la probabilité de l’extraction des ressources prévue. Il réduisait également la possibilité de retards durables dans la production et le traitement.INTRODUCTIONSlope failures in an active mining operation are unscheduled but expected events, in the sense that the geotechnical design often assumes the potential for slope failure but cannot predict exactly when a failure will occur. Unfortunately, the geotechnical engineering cycle—characterization, slope design, displacement monitoring, instability management, and failure remediation—that is necessary to manage slope-failure risk is not always well known or understood outside the geotechnical engineering profession. The first introduction many personnel have to geotechnical engineering is when a slope failure starts to develop and appears to threaten the safety and livelihood of their workplace.At that point, the task of communicating the risk management of slope failure falls to the geotechnical engineer, who must summarize analytical methodology, design concepts, monitoring trends, and analysis results, frequently to an audience with limited exposure to the geotechnical field. All too often, the response has been to present a risk-management plan in the vernacular of geological engineering— using terms such as factor of safety (FOS), pore-pressure reduction, and slope unloading—instead of expressing the problem and solution in more readily understood mine production terms."

Jan 1, 2017

By Robert F. Randolph, Jeffery L. Kohler, David C. Byrne

Multiple versions of an educational message can reach a diverse population more effectively than a single version. For instance, some workers are trained in formal classrooms while others are self-taught. The National Institute for Occupational Safety and Health has developed multiple versions of a hearing loss simulator (an interactive software package, a Web-based module, and an electronic slide show) to show how a single set of information can be readily adapted to different delivery methods. The three versions of the simulator were developed with a minimum of effort and expense compared to a single, less-flexible version. The interactive software is best for training sessions led by a hearing conservation professional, the Web pages are best suited for an individual worker, and the slide show is best for a small, more-generalized, training class. This paper will describe additional advantages and disadvantages of different delivery systems and will show what considerations are helpful in designing content that can be readily adapted to alternate presentations.

Jan 1, 2002

Misiman society is matrilineal and despite relatively long contact with Europeans and mining, it retains its traditional consensus style of decision making. Many Misimans at least understand English, and this has encouraged comfortable communication between the people and the company (Misima Mines Pty Limited). Company care in monitoring the environment (mostly using Misiman staff), its policy of maintaining a largely Misiman workforce, and its emphasis on training and safety, have all created an environment compatible with Misiman society. In addition, the company has constructed and/or upgraded community facilities such as the airstrip, roads, the health centre, police station and schools, and has actively promoted local business endeavours. All these initiatives have been accomplished by constant dialogue with the largely Misiman workforce, and with the Misiman people, both before and during implementation. Constant, careful communication, using traditional Misiman consensus methods, appears to be the key to continued community acceptance of the project.

Jan 1, 1991

By Pat C. Hautala, J. R. Hoskins

This is a new era for the minerals industry. Never before has there been more need for effective communication. So said Robert Anderson, chairman and chief executive officer of Hanna Mining Co. He was speaking to the American Mining Congress's Communication Workshop. The question is whether there is enough industry concern to meet the challenge. Anderson observed that increased workshop attendance, in continuing tough times, reflects the industry's concern for communication. But, why were students, faculty, engineers, supervisors, and managers not at the conference? Communication applies to every manager, Anderson said. But he was the only operating manager present. And only one company sent operating supervisors. The remaining conference participants were public relations personnel, generally with nonmining backgrounds. And the program dealt mostly with public relations issues. Role of Communication in the Minerals Industry. It is well known that the minerals industry faces economic, political, and social problems. Economic shifts and foreign competition have created an international minerals industry and an international marketplace. This, in turn, calls for worldwide communication. Other factors effecting communication are: • Governmental protectionism as well as regulatory reforms call for increased interaction with governing officials. • Changing social values have created environmental issues and anti-industry attitudes. This intensifies the need for improved public relations. • Traditional work values are shifting towards self-actualization and humanistic movements. The work force is better educated and more informed. Employees demand more satisfaction, equality, and job autonomy. • The mining industry's task of managing its human resources is complicated by layoffs, job uncertainties, and bleak outlooks concerning employee morale and motivation. Technology and Information for a New Era As noted, this is a new communications era, one propelled by technology and information. Technology has led to reduced demand for raw materials by developing substitutes. Copper demand, for example, will never fully recover. Copper cables are replaced by fiberoptics; copper transmission lines, with aluminum. Technology has shifted the US from traditional to high tech and service industries. The speed, frequency, and scope of information transmission have greatly increased. But the most significant characteristic of this information is not the pace of advancing technology. It is the dramatic increase in the importance and frequency of our personal transactions. Knowledge has replaced raw materials and capital as the strategic resource. Information has replaced energy as the transforming resource. And the game against nature has become an interpersonal game (D. Bell, Post-industrial society, Physics Today, '76). In Megatrends, John Naisbitt says that information will soon double every 20 months. So, professionals will become "information workers." And communication will be the life channel of the information age. Thomas Wolfe said you can't go home again. Hanna Anderson said we are, indeed, facing a new day. It will never again be "business as usual." We must move into the information age with the rest of society. We cannot trust that the world will continue to rely on our products. Nor can we place the responsibility and control for problems and solutions outside the minerals industry. Improved communication is not a panacea. But, Anderson said, it is critical to the minerals industry. What is Communication? The word communication is overused. It is applied to every aspect of our lives. Satirist Tom Lehrer got sick of hearing about the need to communicate. He said, "It seems to me that if someone is having all that trouble communicating, the very least he can do is shut up!" Obviously, we cannot follow that advice (though we might wish that some others would do so). Communication is always going on. It is inevitable. Yet we have many misconceptions about com-

Jan 1, 1985

By Alan A. Bergeron, J. L. Michels, R. L. Collins

Advanced communication and monitoring systems were developed and demonstrated in three underground mines representing different mining techniques, geographical areas, and material mined. The first mine was a large coal mine in western Pennsylvania that used room and pillar techniques and continuous mining methods. The system developed for this mine provided private telephone channels, environmental monitoring, and control of underground equipment, all on a single coaxial cable, with all system operations under the direction of a minicomputer. Many advanced features were incorporated into the system, such as paging of roving personnel, two-way section wireless, through-the-earth emergency communication, and redundant signal paths. Television was multiplexed into the system for underground equipment surveillance. A hoist radio system completed the complement of equipment at the mine. The second mine was a magnetite ore mine in eastern Pennsylvania that used block caving mining techniques. A radio system was developed that provided two-way communications between trackless vehicles and roving personnel. A unique system of uhf/vhf repeaters combined with a flleaky-feeder" transmission line offered operational and emergency features not previously found in mine communication systems. Evacuation alarming, personnel paging, fan-hole drill operator communications, and maintenance and safety vehicle dispatch were provided. The system required no dispatcher and operated during power failure. A hoist communications/shaft inspection system completed the installation. The third mine was a deep silver mine in the Cour d’Alene district of Idaho. The system developed for this mine utilizes a single wire pair to provide up to 14 voice channels. A unique combination of PBX, telephone carrier system, and intercoms offered private conversations, selective signaling, and emergency backup communications. Two hoist communication systems were installed to provide a voice link and in-cage belling signal between hoistman and cage.

Jan 11, 1981

By N. Coulson, P. F. Stewart

The Mine Health and Safety Act No. 29 of 1996, as amended, embeds an occupational health and safety management system that facilitates communication between representatives of the state, capital, and labour. In underground mines, two communication loops between these role players serve to separate the production chain of command from the political tripartite relations. Worker-elected health and safety representatives are involved in both communication loops, but are severely constrained in escalating their occupational health and safety concerns to the legalpolitical level. This has a direct bearing on the exercise of the Right to Refuse Dangerous Work (RRDW). As previously reported, health and safety representatives were found to primarily consult their production supervisors in preference to their trade-union representatives. This follow-up article presents production supervisor perspectives on the RRDW. The study demonstrates how, for mineworkers, the two distinct communication subsystems constrain, rather than facilitate, implementation of the RRDW.

Apr 14, 2024

By Robert L. Bates

The field of industrial minerals and rocks includes such a wide diversity of materials and occurrences that communication is essential to foster a sense of "belonging? among geologists and other professionals. Besides, exchange of ideas and information is essential in meeting the needs of an ever-expanding world economy. A survey of the field shows to what an extent such communication--especially in the form of conferences and their proceedings--has increased during the past 25 years.

Jan 1, 1995

By Alan J. Solomon

The function of advertising is communication. Viewing the advertisements of mineral suppliers exposes the reader to a broad spectrum of purposes: announcements of new products, availability and supply, departmental services, company image, etc. It is the advertiser's hope that the message being conveyed is the same message being perceived by the viewer. To maximize this probability, the advertiser at least must carefully construct precise copy, identify the target audience and select the appropriate advertising medium. A truly successful and efficient ad, however, also must accurately reflect a product's life cycle, i.e., the rise and fall in demand for a product. Buggy whips and radio tubes are classic examples of items formerly in high demand. Industrial minerals are similarly affected by occurrences of product life cycles.

Jan 1, 1983

This chapter analyses the parameters influencing initial design of communication systems, for new mines and upgrading existing systems. Paragraph 5.2 outlines those variables that must be taken into account during the design stages of a new wired phone system. Recommended features, general requirements, and how they can be implemented are treated in this section. Paragraph 5.3 describes ways of improving or extending the range of trolley carrier phone systems and pager phone systems already installed in the mine. 5.2 New Phone System Design The task of designing an adequate communication, control, and monitoring system for an underground mine must be addressed on a system basis. In addition to insuring that effective voice communication is established, any new system should take into account present and future requirements of remote control and monitoring functions. Chapter 4 illustrated the drastic savings in response time that can be realized when remote control and monitoring are integrated into the overall communication system. The importance of including control and monitoring in the overall design plan for any system cannot be overemphasized. Because each mine is unique, and thus usually has its own special operating characteristics and communication requirements, there is no such thing as "the one best system" to meet the requirements of all mines. The optimum communication, control, and monitoring system for a mine must be one that has been tailored to meet the special requirements of that particular mine. Factors that must be considered during system design include- a. Type of mine and mining methods (low- or high-seam coal, deep hardrock mine, stope caving, longwall, room and pillar, etc.). b. Maximum number of working sections. c. Expected mine growth rate and eventual maximum size. d. Haulage methods (tracked trolley, diesel, belt, etc.). e. Underground power distribution system (dc, ac, or both). f. Features desired (two-way radio paging, private line capability for emergency use, etc.). g. Redundant or backup systems for use during outages of the normal system. Although no two mines are alike, the following items have been established as the main characteristics desired for any underground communication system: 1. Multiple Communication Paths to Outside--the objective here is to give all telephones a second method of communicating with the surface. 2. Audible Emergency Signaling--the communication system provides the main means of alerting miners during emergencies. The system should include means to broadcast distinct audible signals for emergency signaling. Initiation of these signals should probably be controlled from. a central outside point, such as a surface control room. 3. Emergency Override--provisions should be included to permit any conversation to be overridden with emergency communication. 4. Selective Area Page--as mines grow larger it is apparent that the entire telephone system paging mode need not be activated each time a call is initiated. When the general area of a

Jan 1, 1984

Any communication system requires at least three elements in order to function: a transmitting device, a receiving device, and a transmission line or propagation medium. Even the device children use, tin cans connected with string, consists or these three elements. One speaks into one can (transmitter), which vibrates at the same frequencies as the voice. The string (transmission path) picks up the vibrations of the can and carries them along its entire length. The other can (receiver) detects the vibration and reproduces the original sounds to a lesser extent depending on distance, tightness of string, type of string, etc. All communication systems depend on these three elements: transmitter, transmission path, and receiver. Communication systems can be divided into three fundamental categories: wired phone systems, radio systems, and carrier current systems. Sections 2.2, 2.3, and 2.4, respectively, describe these systems and explain the basic principles of how each works. Hybrid systems are those systems that use various combinations of the three basic communication methods. Hybrid systems are described in section 2.5. There are some other methods of signaling (stench warning, bell signaling, etc.) that can be used in underground mines to transmit or convey information. These systems, although they cannot be considered true communication systems since they do not provide voice or even two-way communication, are briefly described in section 2.6. 2.2 Wired Phone Systems Wired phone systems are all those that depend on a wire connection between phones with the wire carrying the voice signals. Figure 2-1 is a diagram of two typical wired phone systems.The top panel shows a simple single pair party line system. In this system each phone is connected to a common pair of wires, and a person speaking into one phone will be heard at all the other phones on the line. The bottom panel shows a multipair private line phone system. In this type of system, each phone is connected by its own individual pair of wires to a central switch or telephone exchange. To establish a call between two phones in this system, the lines between the two phones must be connected (switched together) within the telephone exchange. In early exchanges, the connections were made manually by an operator. These exchanges are called Private Branch Exchanges (PBX's). Today, equipment within the exchange can automatically connect each phone to any other phone in the system. These exchanges are called Private Automatic Branch Exchanges (PABX's). There are many different types of automatic exchanges. Some utilize switches to physically make each connection according to the number dialed. Other, more advanced exchanges are completely solid state and may even be computer controlled. [ ]

Jan 1, 1984

By Howard E. Parkinson

An environment monitoring and communication system has been installed in the Bruceton Mine, and research is under way to improve mine safety. Standard day-to-day mine communications are available, along with additional systems installed to permit experimentation with wireless radio, through-the-earth phones, along-the-roof paging, and mine face machinery communications. Research is continuing and the essential concepts for a dependable whole mine communication system, providing simple environment monitoring, improved day-to-day communications and post-disaster communications, will be demonstrated in a larger mine with about 900 feet of overburden.

By V. W. Buys, R. E. Havener

11.3-1. Basic Principles. Communications systems available for application to surface mining operations can be divided into basic categories. These are: 1. Wired systems requiring some type of metallic conductor 2. Nonwired systems, or those commonly referred to as space-radio systems. Under the heading of wired systems, telephones of the ringer type utilizing magnetos were used in the early pit operations. These are still being used in underground mining operations where calling is accomplished by ringing a code made up of short and long rings. While the standard Bell Telephone Systems have not been applied extensively in underground mining, they have been used in open pit operations but have the disadvantage of using multiple pair cables which must be installed and maintained as the mining operations proceed. They have the advantage however, that when a Bell System is installed in a surface mining operation, communication is available not only within the operation but to any point in the world through the facilities of the world-wide Bell Systems. A second type of communication available is the audio system or public address system requiring the use of a special audio cable made up of shielded pairs for the loudspeaker and microphone circuits. Audio systems have one outstanding advantage over most telephone systems in that, with a high-powered amplifier, a paging call can be heard over and above the high ambient noise conditions usually found at a surface mining operation. However, they have the disadvantage of requiring special cable which must be installed and maintained. Another type of wired communication system available for surface mining is that of carrier frequency equipment similar to that used in underground mining operations. In this system, transmission is accomplished by means of a frequency modulated carrier that travels over the underground trolley wire, the rail on which locomotives travel, and adjacent telephone wires.

Jan 1, 1968

By J. R. Mackie

Reserve Mining Company, the first large-scale taconite pellet producer in the United States, mines it's crude ore at the Peter Mitchell Mire located on the eastern end of the Mesabi Iron Range near Babbitt, MN. The ore is processed at Reserve's beneficiation plant on the north shore of lake Superior at Silver Bay, M. The mine and plant are linked by a 47 mile, double track, railroad which is owned and operated by Reserve. (see Fig 1). At rated capacity, the mine can produce 33 million It/yr of crude ore, 15 million It/yr of waste rock and 1.0 - 1.4 million yd3/yr of glacial till stripping. Haulage of all mined material is accomplished using trucks. Ore is transported by tractor-trailer side dump units which have capacitys ranging from 83 to 110 long tons. Waste rock and glacial till is transported in end dump units of 50 to 120 LT capacity. Loading is accomplished by 11/13 yd3 power shovels and 7/10 yd3 front-end loaders.

Jan 1, 1985

By Arnulf Muan, Klaus Schwerdtfeger, L. S. Darken

The equilibrium ratios CO/CO, of. a gas pharse coexislitrg with selected oxide phase assemblages of the system "FeO"-MnO-SiO2 and metallic iron have been determined at 1150°C. The data obtained are combined wilh the thermodynamic data on fayalite (Fe2SiOi) and "FeO"-MnO solid solutions to derive the actiuity-coiHpQsiUon relations for the various oxide components of the olivine (Fe2SiO4-,lIn2Si04) and pyroxenoid (standard free energies of formation of ferrosilile (FeSiO,), tephroite , and rhodonite from their oxides have been evaluated. In the Appendicc~s by Darken and Schivcerdtjeger the ideal solution law for solid deri oed. THE quaternary system Fe-Mn-Si-0 is of interest in many important phases of iron- and steelmaking. For instance, reduction in the blast furnace of ores containing Fe-Mn silicates, deoxidation of liquid steel with Mn-Si alloys, formation and subsequent alterations of oxide inclusions in steels, and the oxidation of manganese- and silicon-containing steels during processing are all governed largely by the thermodynamic relations existing in the system Fe-Mn-Si-O. Although the equilibria between liquid iron and Fe-Mn silicates have been studied in detail previously,' experimental data are lacking for equilibria among the solid phases. The present paper provides such data for a selected temperature, 1150°C. I) PREVIOUS WORK The general feature of subsolidus phase relations in the system iron oxide-manganese oxide-silica under strongly reducing conditions is known.' Fig. 1 represents an isothermal section at 1150°C. The phases present, in addition to silica, are three solid-solution series, viz.. the oxide solid-solution series "Fe0"-MnO (manganowiistite), the orthosilicate solid-solution series Fe2SiO4-Mn2SiO4 (olivine), and the metasilicate solid-solution series FeSi03-MnSi03 (pyroxenoid). The "FeO"-MnO solid solution is continuous between the two end members wustite and manganositeV3 as is the orthosilicate series between the two end members Fe2SiO4 and Mn2 SiO4. 4 The metasilicate solid solution, on the other hand, extends only part way from the MnSi0.l end member toward FeSiO because the latter end member is unstable relative to the phase assemblage fayalite + silica. The letters a through m in Fig. 1 identify end members of the individual solid phases dealt with [for instance, c designates fayalite (FeZSiO4) in equilibrium with wustite, e designates fayalite in equilibrium with silica, and so forth]. In addition to the phase relations there are some thermodynamic data available for the end members of the silicate solid solutions and for the "FeO" -MnO solid solution. The free energy of formation of fayalite (Fe2Si04) from its oxide components has been studied by several investigators. Unfortunately, the data obtained show considerable discrepancies. According to recent tabulations by Kelley, the change in standard free energy Affn for the reaction

Jan 1, 1967

By Claude H. P. Lupis, John F. Elliott

QUITE generally an increase in the temperature tends to bring a system closer to ideality. It is reasonable as a first approximation to consider that the excess free energy will vary linearly with the temperature, or: where t may be defined as the "characteristic temperature" of the solution, or the temperature at which the system would become ideal if the results at T were linearly extrapolated. It must be emphasized that consideration of this hypothetical property is an appeal to intuition rather than an established physical concept. The order of magnitude of 7 for dilute solutions will depend on the nature of the solvent; a value of 3000° + 1000°K may be suggested for ordinary metallic solutions. In terms of free energy, entropy, and enthalpy first-order interaction coefficients, differentiation of the above equations with respect to composition leads to The concept of t offers a simple and plausible interpretation of Chipman and corrigan's3 recent empirical correlation between and a for a number of groups of ternary systems 1-24. The authors found that in each group the ratio was approximately constant. The corresponding calculated from their data by Eq. [4] are listed in Table I. The expected order of magnitude is obtained for 7. As noted by Darken,4 if a regular solution is not assumed, thus if utj) # 0, Chipman and Crrigan's results imply that, as T is increased, ultimately changes in sign, Fig. 1. Clearly Eq. [4] is valid only in a limited range of temperatures since at the temperature 7 at which the system becomes ideal not only should become null but also and . Thus, both and are functions of

Jan 1, 1967