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By H. H. Hughes, J. G. Dunn, P. G. Fernandez, H. G. Linge

Dissolved Arsenic (As) is stabilised primarily as As(III) and As(V) and enters ground water streams from sources such as the increasing metallurgical processing of As - containing ores [1]. As(III) is more toxic than As(V) and is less effectively removed from solution by oxide precipitation. Even for dilute As(III) solutions, skin contact or ingestion can cause dermatitis or cancer and there are stringent effluent control standards in place for As containing effluent from mining operations [2]. Chemtronics (Perth, Australia) has manufactured a compact digital voltamme­ter, based on anodic stripping voltammetry (ASV) and suitable for use in the laboratory or field. In this paper we demonstrate the utility of this equipment for measuring As(III) concentration with a detection limit of ca. 10 ppb.

Jan 1, 1995

By H. G. Linge

Pyrrhotite (FeS1+x ,0<x<0.15) is an iron sulfide which is considered to be a pest in carbon-in-pulp/ leach (CIP/L) gold processing [l].The perceived influence of pyrrhotite on gold processing by CIP/L is a competing consumption of 02 and CN­as the pyrrhotite dissolves by oxidation [1,2]. The few studies of the oxidation chemistry, kinetics and mechanism of the oxidation ofpyrrhotite are reviewed in detail elsewhere [3].There is broad agreement that the surface of pyrrhotite is very rapidly oxidized to form a thin (e.g. 10 nm) ferric hydroxy-oxide layer which overlays an iron-deficient sulfide lattice covering the original pyrrhotite. The reaction can be summarized thus:

Jan 1, 1995

Roof bolting has been widely used in hard rock underground mines for its many advantages. In this paper, the applicability of roof bolts to mine openings in frozen ground and effects of bolts on the stability of the openings are presented. A comprehensive finite element program ABAQUS, was used to analyze the temperature distribution, the stress field, and the displacement field around a mine opening. Openings supported by roof bolts and unsupported were analyzed. The thermal and mechanical processes were treated as a quasi-coupled problem, with the thermal analyses being conducted first, followed by the mechanical analyses in each case. For the opening under consideration with a roof area of 15 m2, five to seven roof bolts are appropriate. When the number of bolts are less than five, the displacement within the ground can be improved only locally.

Jan 1, 1995

By M. L. Leming

The mechanisms of Alkali-Silica Reactivity (ASR) are briefly reviewed, test methods are examined, and typical specifications are discussed. In addition, views on responsibility of the aggregate supplier regarding specifications are presented.

Jan 1, 1995

By R. Buchan

A number of mineral processing techniques have been adopted for the separation of the plastics making up a typical beverage bottle, and a complete flowsheet developed. Thus, size reduction, heavy media separation and flotation were used to separate PE, PVC and PET from their mixtures with cellulose fibers and aluminum, which makes up the cap of such bottles. It is shown that while heavy media separation allows the separation of a PVC/PET mixture from the solid waste, froth flotation can be readily used to separate PVC and PET from a mixture of the two. For this purpose, the differential action of an alkaline aqueous solution (PH=II) which contains methanol and MIBC as surface tension control agents has been found to be a suitable flotation medium. This paper reports some aspects of the flotation flowsheet developed for the separation of plastics from municipal solid waste mixtures and PVC from PET.

Jan 1, 1995

By S. A. Diatchkov

There is a misconception that mineral-project economic evaluations in the former Soviet Union are either nonexistent or very limited. This is not the case. In fact, there are at least two basic methods that can be utilized to evaluate the vast mineral resources of the Commonwealth of Independent States (CIS). Evaluation procedures are based either on a comparison to known projects, which may rely on limited available data, or on potential-profit calculations, which generally uses more extensive databases. Significant philosophical differences between these systems and those utilized in the Western world include the following: •Under the centralized-government system, the economic evaluation of a mineral project was based on artificially determined mineral prices and costs. Every ten to 12 years, prices for concentrates and metals were established by the Council of Ministers and remained unchanged until the next reconsideration of prices .

Jan 1, 1995

By W. J. Dolinar

The U.S. Bureau of Mines implemented the Fe2+ /Fe3+-SO2 anode reaction in a Cu electrowinning cell with full-size electrodes. Electrowinning was conducted using industrial electrolyte at 258 A/m2 (24 A/ft2) and 40 &apos;C. Manifold injection of electrolyte provided circulation between the electrodes. Five-day operation using an optimized manifold gave an average cell voltage of 0.94 V at 89% current efficiency, which amounted to an energy savings of 2.82 MJ/kg (0.355 kW-hr/lb) compared to conventional electrowinning. Acid misting was completely eliminated, and SO2 concentration 23 cm (9 in.) above the cell averaged 0.06 ppm.

Jan 1, 1995

By David A. Collins

Red Dome Gold Mine classifies ore types within the pit by gold and copper grades. Copper grades are further distinguished by total copper and cyanide soluble copper levels. At present, Cyanide Soluble Copper samples take six hours of agitating before they can be assayed. This agitation time produces results which are a proportion of the total cyanide amenable copper. This relates to our plant's performance. Frequently the total copper result is needed before we can begin the cyanide soluble copper analysis. This caused a protracted tum around time. Mennetech Pty. Ltd has produced a catalyst proven by David Martin Menne to accelerate the cyanidation of gold. David said that the information at hand indicated that Leach WELL TM also accelerates the leaching of cyanidable copper substantially. Test work was undertaken on-site at Red Dome Gold Mine to investigate the potential of Leach WELL TM to reduce the leaching period and therefore, the overall tum around time required for cyanide soluble copper determinations.

Jan 1, 1995

By Darryl J. Butcher

The Akjoujt Project is operated by MORAK SA, a company incorporated in the Islamic Republic of Mauritania. MORAK is jointly owned by General Gold International SA (A wholly owned subsidiary of General Gold Resources NL.), SAMIN, and the International Finance Corporation. The project was devel­oped to treat approximately 2.1 million tonnes of TORCO (Treatment of Refractory Copper Ores) tailings containing an average 3.2gAu/t, and 0.75%Cu/t. The process involves the use of ammoniacal cyanidation for gold extraction, and conventional carbon adsorption, and eventual desorption, of gold values. This is believed to be only the second commercial application of this leach chemistry in the world. The other being a small vat leach operation on the Paris Mine Dumps. (This operation was described by Mr M Ruane in a paper to a previous Randol Forum.) Initial work on the process, and the Akjoujt process design assumed that the reaction involved was anaerobic. This paper describes the operating experience, plant trial, and eventual installation which has lead MORAK to the conclusion that the process is not anaerobic, but requires oxygen, or an oxidant to proceed.

Jan 1, 1995

By Robert S. MacPhail, Bret G. Cousins

Many copper-bearing ores with associated gold use Sodium Isopropyl Xanthate (SIPX) as a flotation agent. In general, SIPX will float to some extent other minerals that may not be desirable, such as pyrite. FLEX 31 is a chemically enhanced SIPX product with many of the same properties as SIPX. But FLEX 31 has the ability to reject more pyrite from concentrates and improves copper recovery when using up to 50% less FLEX 31 than is required if using SIPX. Copper activated minerals such as sphalerite and arsenopyrite show increased recoveries as well using FLEX 31. Tests have been performed on copper/zinc ores and an arsenopyrite/pyrite ore.

Jan 1, 1995

By Gary Jobson

The Mt Todd Gold Mine is owned and operated by Zapopan NL, and is located 300km south of Darwin near the town of Katherine. The crushing plant and heap leach facility, which has operated since November 1993, has recently been expanded to treat 6 Mtpa with 1995 budget gold production reaching 120,000 oz from a head grade of 1.12 git. The process flowsheet and equipment are described, with innovative key features including:

Jan 1, 1995

By Mike D. Adams

Testwork was conducted on loaded carbon samples from a small gold mine in South Africa. It was shown that a 75% saving in reagent consumption in the Zadra elution circuit could be achieved by adopting a cyanide-free elution approach, i.e. by cutting back the NaCN level from 1 % to nil, and the NaOH level from 3% to 1 %. This process change was also shown to result in a 20% improvement in the elution kinetics. Furthermore, it was also shown that a 50% enhancement in elution rate over the current situation could be achieved by use of an eluant containing 0.5% NaOH and 0.15% NaCN, corresponding to an 84% saving in reagent consumption. A further improvement in elution kinetics was found to occur by increasing the NaCN level to 3%, but this would lead to a concomitant increase in reagent consumption, due to the decomposition of cyanide at high temperatures. The presence of base metals loaded onto the carbon was also found to have a significant effect on the elution. Copper tends to adsorb as Cu(CN)2- during the adsorption stage, and acid washing converts this species to CuCN. Copper in this form is not eluted during cyanide-free elution, whereas it is eluted during a conventional cyanide elution, consuming the initial cyanide in the process. The elution data was analysed and the fit to a simple model was verified.

Jan 1, 1995

By P. M. May, J. S. Solis, G. T. Hefter

Chemical speciation plays a critical role in many areas of gold processing. These include the formation of HCN in plant liquors, interference by copper in the extraction efficiency of gold, the recovery of adsorbed gold, and the behaviour of plant effluents in the environment. Thermodynamic modelling provides a cost-efficient method of rationalizing and even predicting of chemical behaviour. Unfortunately, because thermodynamic data for cyanide complexes are of poor quality and few are known under hydrometallurgical conditions. Such models are currently of limited use. This paper describes recent work on the thermodynamics of cyanide complexes of a range of metal ions. Data will be presented on the stabilities and enthal­pies (heats) and entropies of formation of a variety of metal ion species determined by potentiometry and calorimetry. Particular emphasis will be placed on the Cu(I)/CN- system.

Jan 1, 1995

By Mark W. Johns

The design or optimization of a carbon-in-pulp (CIP) plant requires the determination and setting of a number of parameters to ensure optimum economic performance. A number of these parameters are either fixed, a function of the pulp, interdepen­dent, affect other parameters or outputs, so only a limited number of degrees of freedom exist from a metallurgical point of view. The traditional CIP contactor employs a low carbon concen­tration, a low agitation intensity and a reasonably long pulp residence time. The pump cell contactor employs a high carbon concentration, a high agitation intensity and a reasonably short pulp residence time. The two philosophies are dipolar in nature and the question arises as to which configuration is the optimum configuration for a CIP plant. The carbon particle size is shown to have a small effect on the capital cost of a CIP plant. A decrease in the pulp residence time, an increase in the pulp density, an increase in the carbon residence time, an increase in the agitation intensity and an increase in the number of stages are shown to have a positive effect on the capital cost of a CIP plant. The pulp residence time, the pulp density and carbon particle size are shown to have a small effect on the operating cost of a CIP plant. An increase in the carbon residence time, a decrease in the agitation intensity and an increase in the number of stages are shown to have a positive effect on the operating cost of a CIP plant. The optimum CIP plant, therefore, employs a short pulp residence time, the traditional pulp density, a long carbon residence time, the traditional carbon particle size, the traditional agitation intensity, and the traditional number of stages. Neither the pump cell configuration nor the traditional CIP configurations match the optimum configuration.

Jan 1, 1995

By G. S. Walker, W. van Bronswijk

The accurate determination of free cyanide and metal cyanide complexes is of increasing interest to Carbon-in-Pulp (CIP) gold extraction operations as cyanide consumption is an important economic factor in the processing of complex ores. Characteristically complex ores are high cyanide consumers and these ores usually contain a range of sulfide minerals e.g. covellite (CuS), digenite (Cu1,S), chalcocite (Cu, S), Pyrrhotite (Feci-x)S), marcasite (FeS2), arsenic and antimony sulfides and zinc sulfide. These minerals can consume significant quantities of cyanide, e.g. various copper(!) cyanide complexes such as CuCN, Cu(CN)2·, Cu(CN)/ and Cu(CN)/ can form, depending on the cyanide to copper ratio in solution. Measurement of free and complexed cyanide is thus a prerequisite for efficient cyanide dosage control. Free cyanide can be determined potentiometrically or amperometrically but the methods are prone to error and are laborious [1]. Metal cyanide complexes can be determined by reverse phase HPLC, however, the species ofa single cation (e.g. Cu(CN)i-, Cu(CN);2 and Cu(CN)/) elute as one species [2]. Additionally the high amount of suspended matter in CIP leach solutions tends to introduce errors. Raman spectroscopy has the potential to be used as an in­line or on-line method of analysis. Free cyanide and the cyanides of gold, silver, copper and iron have been studied in aqueous alkaline solutions with a view to developing such a method. Spectra were obtained with a Bruker RFSl00 FT-Raman spectrometer using a 1064 nm laser delivering 800 mW of power at the sample. Depending on the solution, 250, 1000 or 4000 scans at 4 cm-1 resolution were accumulated. The cyanide stretches observed were relatively narrow (10 15 cm-1 full width at half height) and well resolved (Figure 1 ).

Jan 1, 1995

By Peter J. Stewart

My first experience with carbon reactivation in the gold industry was at Whim Creek, Meekatharra some 15 years ago. Very little was known, in fact, carbon reactivation kilns in the gold room were a complete mystery. Ten years ago at conferences such as this the mystery was more as to why field kilns would not reproduce activities achieved in the laboratory. A carbon reactivation kiln manufac­turer was thought to be brave or stupid to speak at a venue such as this. Reactivation kiln design has improved dramatically in the past 10 years and with a few exceptions, most kilns operate well. May I suggest that now, the focus is on plant practice rather than kiln design, and that the basics of plant practice as it relates to carbon activity needs revisiting. As metallurgists like to talk on engineering, accountants on the Economy and vice versa, my presentation on Carbon Reactivation will focus on plant design and operation as it effects carbon reactivation. There have been some excellent papers published over the past 15 years on the basics of carbon reactivation in relation to gold processingl,2,}. Taken that kilns operate and are effective to a greater or lesser degree, plant design and operating practise have an enormous bearing on carbon activity, solution tail, carbon loss and other cost items. This presentation will not argue the merits of equipment used for the thermal reactivation of organically fouled carbon, questions on this subject are welcome over a drink after this session.

Jan 1, 1995

By Kimberlie Staheli

A new sanitary sewer was installed in Pleasant Hill, California using microtunnelling methods. The project consisted of 693 meters of 1372 mm and 1981 mm concrete pipe. A Herrenknecht AVN 1200 was used to install the nominal 1372 mm pipe in three drives. The machine was then fitted with an oversized shield used to install the large diameter pipeline. This articulated shield allowed the excavation of a 2362 mm diameter hole with a 1524 mm machine-- a technique new to North America. This paper reviews the design considerations for the articulated shield and reports on the project challenges and solutions to overcome these challenges.

Jan 1, 1995

By D. Lelinski

Air-sparged hydrocyclone (ASH) flotation is one of the new promising technologies. Numerous applications have been successfully tested since its conception; nevertheless, research and development efforts have continued to provide for further improvements with respect to operating conditions and design considerations. Results from experimental studies on bubbles generation in the ASH system are presented in this paper. Bubble size distributions generated during ASH operation have been determined using a high-speed photographic technique. The influence of many factors including surfactant concentration, water flowrate, and porous tube pore size has been studied. Test results indicate that these process variables have a profound effect on the bubble size distribution. With an increase in surfactant concentration or water flowrate (shear field) the bubble size distributions become narrower and shift toward smaller average bubble diameters. However, the influence of pore size is more complicated. Depending on the experimental conditions the average bubble size was found to range from about 100 to 300 microns in diameter.

Jan 1, 1995

By V. C. Lo

The major cost in comminution is energy consumption, which can be as high as 50 percent of the operating cost. Improvements in plant operations have resulted in up to a 15-percent reduction in energy usage (kwh/t). These improvements have been made through optimization of grinding efficiency and use of expert model-based control systems. Optimization involves the determination of the levels of the critical operating conditions that result in the most efficient breakage of ore in the mill. These optimal levels are identified through plant/laboratory testwork and computer simulation using advanced process models. Model-based expert control achieves the maximum performance from the grinding circuit by identifying the characteristics of the ore in the mill with an optimal on-line estimator. Using this information, the control system dynamically determines the operating point that will yield the optimal performance. Two industrial applications of grinding circuit optimization and model-based control are presented to demonstrate the power of this new technology.

Jan 1, 1995

By Barry Cloutt

Western Mining Corporation Limited owns and operates the St Ives Gold Plant located near Kambalda, approximately 90 kilometres south of Kalgoorlie in Western Australia. Production commenced in March 1988 at a design capacity of approxi­mately two million tonnes per year. The plant was quickly expanded as a result of new ore discoveries in the district and has been processing ore since 1993 at the rate of three million tonnes per year. The plant has recovered over 50 tonnes of gold since the operation began, The plant was able to maintain acceptable recoveries throughout the plant expansion phases. Further gains in recovery were possible since there was still free gold in the tailings after approximately 24 hours of leaching. Testwork carried out on prospective orebodies showed that some contained considerable quantities of free visible gold, while others were seen to be semi­refractory using a conventional grind - leach circuit. Alternative treatment techniques were considered because a substantial amount of revenue was lost with the treatment of these ore bodies using conventional milling techniquies. The basis for all the investigations was to maximise the gold recovery from each orebody while minimising the effective cost per ounce of gold produced,

Jan 1, 1995