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By P. J. Hyde

Cyanide is a significant contributor to the cost of producing gold. Any reduction in consumption that can be achieved through more reliable measurement and/or more efficient management of dosing rates can have a significant financial impact. An automated analyser, by its mechanical nature, is not prone to the variations of human operators, particularly notice­able from shift to shift. Reducing the standard deviation of the measurement (ie, reducing noise ), the automated measurement will give the metallurgist a truer picture of the underlying patterns of usage. The combination of automated analysis with on-line operation and a control loop provides timely information that is efficiently utilised in the management of the plant. Until the release of the Chemtronics On-Line Cyanide Analyser (OTA3000) about 12 months ago, the Australian experience with automated analysers (especially on-line) had been substantially negative. Since its release, the Chemtronics instrument has outperformed both manual titrations and other automated instruments, gaining an enviable reputation for accuracy and reliability in the process. The instrument is built around the technique ofpotentiomet­ric titrations, in which the potential of an indicator electrode is measured as a function of the volume oftitrant that is added to the sample. As the cyanide in the sample is depleted, the potential on the indicator electrode changes rapidly, producing a typical sigmoidal curve. The OTA3000 takes the first differ­ential of the curve, identifies the apex of the peak as the endpoint and reports the result in parts per million of sodium cyanide. The OTA3000 accepts the peak as valid only if it exceeds a certain minimum height. That minimum height is a programma­ble parameter and is used to optimise the relationship between sensitivity and the rejection of spurious peaks. The instrument will track cyanide trends through both positive and negative slopes of any magnitude, but it will provide a warning if it the slope becomes excessive, not because it affects the instrument but because it means that something unusual is occurring in the tanks. There are a limited number of conditions under which the instrument will produce a result of zero. In these cases the OTA3000 holds any output lines at the last valid result while it repeats the titration. This feature was incorporated for reasons of stability in a feedback loop.

Jan 1, 1995

By Matthew Horsnell

Greenbank Terotech is a member of the Halley & Mellowes Group of Companies and is accredited t AS3902. Greenbank has been involved within the wear resistant lining industry for over 20 years. Initially supplying cast Basalt piping systems through to the present day breakthroughs with SiTech cyclone linings. The challenge of finding the most cost effective cyclone lining has been a difficult process. Over the years many varieties of ceramics have come and gone. In particular within cyclone applications, many people have become disillusioned with the term "Ceramic." In practice, it was discovered that if a ceramic worked in one part of the plant, it did not necessarily work in the cyclone area. A good example of this is Alumina chute and pipe linings. An Alumina lined cyclone underflow bend would provide exceptional wear resistance, whereas an Alumina Spigot would have failed miserably. After Alumina's were tried, Silicon Carbides were experi­mented with. The results in many trials were mixed. What worked at one mine did not work at another. The results did not conclude decisively that ceramics were here to stay within the hard rock cyclone area. It was then that Greenbank Terotech started to look at the reason "Why do some linings work and others don't." We came to the conclusion that the matrix holding the particles together had to be the key to a successful cyclone material. At the time we looked at materials such as Alumina Bonded Silicon Carbides, Metallic (Aluminium) Bonded Silicon Carbide, 99% Alumina Ceramics and Nitride Bonded Silicon Carbides, but all these materials either suffered from chemical attack on the Aluminium matrix (via cyanide) or the matrix simply was not hard enough causing wear rates to be excessive. It was then we looked at SiTech. SiTech is a unique material in that the primary particles are Silicon Carbide, but the matrix is made up of a Secondary Silicon Carbide formed within the reaction bonding process.

Jan 1, 1995

By P. B. Hearse, R. L. Flood

TQM is a term of which most metallurgists have heard and a system of which some have had first hand experience. This paper is designed to encourage further thinking on TQM and how it can effect your organisation. Consideration of organisational culture and objectives are a prime pre-requisite when planning for the implementation of TQM. It is argued that there is no "brand" of quality culture of TQM which can be applied en masse to the mining industry. Definitions ofTQM are proposed, and the essence ofTQM as being about increasing customer service, improving the quality of goods and services, and involving people in their work is discussed, in conjunction with the concept of Customer as applied to the metallurgical industry and TQM. The integration of TQM into Quality Accreditation Stan­dards is then discussed. Finally, examples of the benefits that may be achieved with Implementation ofTQM into metallurgical and operations groups is presented, along with an analysis of the difficulties of implementation into our businesses and operations.

Jan 1, 1995

By Brian Burdett, Terry I. Mudder, Robert T. Richins, James A. Stevenson, Michael M. Botz, Alan L. Wilder

The first Cyanisorb process was constructed in 1991 at the Golden Cross Mine in Waihi, New Zealand to recover cyanide from CIL tailings. The Golden Cross operation consists of an open-pit and underground gold mine with a conventional crushing, grinding and CIL circuit with Merrill Crowe zinc precipitation for gold recovery. Prior to disposal in the tailings pond, slurry tailings are stripped of cyanide at a pH of approxi­mately 7.5 using the Cyanisorb process. Mill throughput is approximately 2,500 tons per day (TPD), and CIL slurry tailings average 37% solids with a specific gravity of 1.27. CIL tailings WAD cyanide average 150 mg/L. The Cyanisorb process recovers approximately 85% of tailings WAD cyanide, produc­ing a slurry effluent with approximately 20 mg/L WAD cyanide. A second Cyanisorb process was commissioned at the NERCO DeLamar silver mine in southwest Idaho in May, 1992. The ore milling and silver recovery operation consists of crushing, grinding, a CIP circuit and Merrill Crowe zinc precipi­tation for silver recovery. Cyanide recovery is from clarified tailings with WAD cyanide ranging from 3 50 mg/L to 600 mg/L, producing an effluent with less than 30 mg/L to 60 mg/L WAD cyanide. Due to the presence of zinc-cyanide complexes in mill tailings resulting from the Merrill Crowe process, cyanide is stripped at a pH of approximately 5.5.

Jan 1, 1995

By Dr. H. Askew

The input needs of the steady state modelling process are outlined and a methodology for designing a plant survey to meet those needs described.

Jan 1, 1995

By Steven Hart, Graeme Hill

Boddington Gold Mine is situated 130km South-east of Perth, WA. The operation is managed by Worsley Alumina Pty Ltd. The Direct Leach plant was commissioned in mid 1986 at a rate of 3 million tonnes per annum. The plant was upgraded to 4.5 mtpa in 1988 and almost immediately to 6mtpa in 1989. Subsequent debottlenecking resulted in further increases in throughput up to 7mtpa by 1991. The SupergenelBasement Plant was constructed in 1990 and commissioned in early 1991. It was designed to process both copper-gold-silver anomalies within the laterite gold orebody and future hard rock ores. The Supergene plant incorporated control potential s­ulphidisation (CPS) and flotation ahead of CIL to remove a host of copper minerals. It operated in that configuration for 2 years at rates up to 350,000 tpa and average grades of 6.0 git gold and 1.2% copper. Gold recovery averaged 90.7% and copper recovery averaged 80.0% before the flotation circuit was decommissioned in March 1993. Quartz hosted high grade, free milling oxide and basement ores were discovered at the northern end of the orebody in 1990 and now comprise the major feed source to the basement plant. Oxide ores are currently milled at a rate of 550,000 tpa, while basement ores are milled at a 420,000 tpa rate. Metallurgical testwork during the feasibility stages indicated that up to 30% of gold in plant feed could be recovered by gravity separation methods. It was also highlighted that signifi­cant improvements in overall plant recovery and reduced operating costs would be achieved by maximising gravity gold recovery ahead of cyanidation. To achieve this, rec;iesign and upgrade of the gravity circuit was necessary.

Jan 1, 1995

By Jean Rainville

Gold was first discovered in the central region of French Guiana in the mid 1860's. Production was based strictly from placer mining of the various rivers in the region. At the moment, a number of companies are actively engaged in hard rock gold exploration, concentrated in the northern and central regions of the country. The Franc-Or/BRGM joint venture in the Sophie-Repentir region of Central French Guiana offers an exceptional opportu­nity for the discovery of one or more million-plus ounce deposits of gold owing to a highly favorable structural setting in Precam­brian greenstones that host several known vein gold occurrences, some of which appear to occur near the border of a potassic granitoid intrusion. At this point in time, based mostly on predecessors' work, mineable reserves could be estimated to be in the 500,000 ounces range over the length of the property. The exploration campaign under way has the objective to delineate probable reserves of at least 2 million ounces that could be mined by open pit mining methods in the area. The program should be completed in the next 18-24 months. In order to efficiently and effectively evaluate this very large property area, all of the necessary camp, mechanical and drilling equipment has been purchased and is being transported to the property. Most of that equipment was purchased in Canada. The first drill target is the Repentir sector because of its access and the amount of detailed work that has been done by BRGM on that concession, but geological evidence suggests that many areas on the property could offer even more potential.

Jan 1, 1995

By Pierre Louis, Jacques Duparque

ACTIRED is a new process for gold and silver elution from activated carbon based on the addition of hydrazine, needing no extra investment and which generates a systematic increase in elutions kinetics. This process either operates at a lower temperature and maximizes financial gain or reduces elution time or operates at a compromise between these two options taking into account the needs of each plant. Industrial use of the process at SNC Lastours, France (Zadra elution column 3,5 bars -125°C) has proved at 95 ° C the following points:

Jan 1, 1995

By W. H. Jay, F. Lawson, D. F. A. Koch

Ion exchange resins may in the future displace activated carbon in gold plants where cyanidation is practiced. Recently patented technology based on interpenetrated polyurethane polymers shows that these new materials offer significantly improved loading kinetics over both activated carbon and commercially available ion exchange resins. These polymers are not restricted either in particle size or in density and therefore offer the gold industry the potential for a further technological advancement.

Jan 1, 1995

By Keith J. Henley, Nicholas C. Clarke, Paul Sauter

A detailed investigation of the stability in cyanide solutions of native gold and gold-silver tellurides in a flotation concentrate from the Golden Mile, Kalgoorlie, has been undertaken to assess whether leaching under different conditions can be used to quantify the distribution of Au between native gold and gold-silver tellurides, as suggested by, for example, Chryssoulis and Cabri (1990). The leaching was carried out on +20 µm native gold and gold-silver tellurides separated from a high-grade flotation concentrate and then diluted with barren quartz. The material leached assayed 270 ppm Au and 118 ppm Te and the leach conditions used were:- Stage 1: Leaching in dilute cyanide (0 .1 % ) at pH 9 .5 for 24 hours to dissolve native gold but not gold-silver tel­lurides. Stage 2: Leaching the residue from Stage 1 in strong cyanide (2%) and pH 12.5 for 96 hours to dissolve gold-silver tellurides.

Jan 1, 1995

By Neil Jagger, Ian Arbuthnot, Mitchell Gordon

Ultra high density underflow is required in many thickener applications and in mineral processing is typically required for tailings to improve the thickened slurry rheology for either tailings dam development or for paste backfill applications. The improved liquid-solid separation resulting from the production ofultra high density underflow has both environmental and process benefits in the gold industry. Additional cyanide is recovered in the thickener overflow thus reducing plant cyanide costs and perhaps more significantly, a reduced quantity of cyanide is discharged to the tailings thus reducing either the toxic effect on the environment or the costs of cyanide destruction. Many gold and other mineral processing plants are situated in arid regions where the cost of water is high and the quantity often very restricted. Ultra high density thickened underflow results in increased recycle of tailings process water to the plant. In Countercurrent Decantation circuits, the wash efficiency is very dependent on the degree of liquid-solid separation in each thickener stage and the benefits ofultra high density underflow are either increased efficiency or decreased equipment costs as it may be possible to reduce the number of stages in the circuit.

Jan 1, 1995

By David Wright, Colin Burns

Successful leaching of gold depends on appropriate chemical conditions; contact between leach solution and the gold particles; separation of the leach solution from the solids and extraction of the valuable ion from the solution. Irrespective of the leaching method employed the chemical conditions required are similar as is the dependence of solu­tion/gold contact on liberation. The various leaching methods available vary in the means by which gold/solution contact and solid/liquid separation are achieved. The essential difference between heap or vat leaching techniques and those involving agitation of a slurry is dependence on percolation for effective gold/solution contact. The most significant factor preventing uniform percolation is the presence of fines or clays. The quantity and character of the fines fraction is ore type dependent and may result from crushing, degradation during stacking or leaching, or the natural size distribution of the ore. The problems associated with fines can be aggravated during stacking and preparation of the heap. Segregation during stacking can result in concentration of fine particles at the centre of heaps. Further concentration of fines may also occur during irrigation by the movement of the fine particles with the solution. The end result is that the areas in which fines are concentrated become areas of low permeability. The contact between leach solution and the ore in such areas is, at best, slowed down dramatically and, in some cases, prevented altogether. The consequences of this phenomena are slow leaching and a reduction in recovery. The conventional solution to this problem is well known. Agglomeration of ore prior to heap leaching is practised widely. The effect of agglomeration is to immobilise the fines by causing them to adhere either to each other or to larger ore particles. The net effect is that the ore behaves as if no fines were present. The use of agglomeration is limited only by its cost, the most significant components of which are the cost of binding agent, commonly cement, and the capital cost of the agglomerating equipment.

Jan 1, 1995

By A. H. Reitsema, Hans E. van Dam

In CIP, CIL, and Heap Leach gold recovery operations, a sub-optimal activated carbon performance invariably causes a significant loss of revenues. In this paper it is shown, how dedicated analyses of carbon samples can be used as a guide in plant performance optimiza­tion. Firstly, a brief outline is given of the most important methods of analyses, including the specialized methods not normally used by mining operations, but provided by carbon manufacturers. Then, a number of practical cases are discussed in which carbon sample analyses provided insight which allowed significant improvements.

Jan 1, 1995

By H. G. Linge

The Australian gold industry currently contributes some $4bpa to the national economy [l]. Some 40% of the total gold is produced in the region centred on Kalgoorlie known as the Eastern Goldfields of Western Australia. This region is the largest single centre of production with an output of some 100 tpa of gold [2]. In the Eastern Goldfields, refractory arseno­pyritic gold ore is an increasingly significant source of gold, feeding several operations utilizing bio-oxidation as the pre­carbon in pulp/leach (CIP/L) treatment process [1]. This paper desribes an alternative pre-CIP/L treatment option for use in the Eastern Goldfields based on the chlorination of arsenopyrite by chlor-alkali technology [3] using the salt resources available from saline water present in abundance in the region.

Jan 1, 1995

By Ian J. Corrans, Gary Johnson, John E. Angove

Activox® is a hydrometallurgical process used to oxidise sulphide concentrates. The process is based on two relatively simple, established unit operations; i.e. fine or ultra-fine milling (UFM) and pressure oxidation under mild conditions. An under-standing of, and ability to control the pulp chemistry during oxidation has resulted in the successful Activox® treatment ( on a batch scale) of a wide variety of sulphide flotation concentrates; • pyrite/arsenopyrite + gold • pyrite/chalcopyrite + gold • pyrite/chalcocite + gold • pyrite/enargite/tetrahedrite + gold Oxidation rates are rapid (1-2 hours retention time) and gold

Jan 1, 1995

By Kevin Phelan, Gary Johnson, Peter Sperring

The vast majority of tailings in the Western Australian Goldfields are deposited in purpose-built storage facilities. At mine-sites with open-pit mining operations there is also the requirement to mine and stack large volumes of waste rock, usually into surface waste dumps. As these dumps have typically 30% of their gross volume present as voids, there is the potential to use this void space for the storage of tailings. The concept of co-disposal is to store the tailings material in the void space of the waste dumps, eliminating the need for a separate tailings storage facility. Dominion Mining Limited have been investigating the possibility of using co-disposal as a means of tailings storage. Laboratory testwork has been used to understand some of the issues associated with the concept, and assist in the design of an on-site demonstration of the concept. Co-disposal offers a number of potential advantages, and despite a number of practical hurdles to overcome, considerable economic and environmental benefits could be realised if this concept can be demonstrated on a commercial scale. The major advantage of such a system is to remove the need to build, operate and rehabilitate a separate tailings storage facility. Rehabilitation can be incremental throughout the mine life as the co-disposal site will be virtually indistinguishable from a current waste dump in both size and form. Other potential advantages include more stable waste dumps, less land area disturbed on the project site, and better water recovery from the tailings.

Jan 1, 1995

By Timo Niitti

Within the minerals industry, flotation is the predominant method when processing sulphide ores. There is hardly any competition in this area because of the high efficiency and low costs of flotation. When processing other ore types magnetic or gravity• methods are commonly used and sometimes leaching methods are selected. The wide variation of the properties of gold (high value, low ore grades, softness, high specific gravity etc.) sets challenging requirements to the processing methods and particu­larly for flotation machines, which should be able to effectively recover free fine gold, coarse gold and gold bearing minerals throughout the full size range. In gold processes the amount of concentrate is usually low, but in some cases large amounts of gold bearing sulphides e.g pyrites has to be recovered. In gold processing seldom does only one method provide the optimum results, but the recovery is usually made using several complementary technologies: gravity separation, leaching and flotation are the most common ones. Mineralogy is the determin­ing factor when selecting the method or methods to be used.

Jan 1, 1995

By P. Gelfi, G. Hill, A. Showell, V. Martins, R. Dunne, R. Jenkins

Carbon attrition losses are not usually a prime consideration for CIP equipment selection and CIP plant design. However, the costs as a result of carbon attrition and associated gold lost with carbon can be high. Recorded carbon losses for Newcrest operating gold plants were shown to vary widely from plant to plant. The Tuckabiana plant recorded an overall loss of only 0.3g carbon /t ore which is very low by industry standards. A comparative carbon management study was undertaken by Newcrest to highlight the reasons for the excellent record of Tuckabiana operation compared to other Newcrest plants. This paper discusses the results of the comparative study and high­lights areas of concern with respect to carbon attrition.

Jan 1, 1995

By Robert J. Storms, David J. Malone, Thomas E. Crandall

Corrosion and abrasion have been present in hydrometallurgical processes for many years. Ceramic lining materials have been used in several applications to protect process vessels from the corrosive and abrasive effects of a wide range of ore slurry processes. This paper reviews the history of ceramic lining systems utilized in hydrometallurgical vessels, the commercial benefits associated with their use, and additional areas of opportunity for the Mining Industry.

Jan 1, 1995

By Stephen Young

The continuous monitoring of free cyanide levels is an important part of gold recovery operations. Accurate and up to the moment knowledge of the free cyanide concentration can result in substantial cost savings by allowing reduced concentra­tions with lower fluctuations, while maintaining or increasing gold recovery. Reduced free cyanide levels also result in lower detoxification costs at the mill discharge which translates into further savings while meeting environmental requirements. As can be seen from the upper curve in Figure 1 (which is based on in-service measurements), without accurate monitoring and control, cyanide concentration fluctuates during the produc­tion cycle, and is maintained at a high level to err on the side of caution. The lower curve illustrates the improved control permitted by the installation of a CY ANCOR, giving a more consistent concentration over the process cycle, and safely allowing use of a lower concentration.

Jan 1, 1995