Selective Depression Of Pyrrhotite Using Sulphur Dioxide- Diethylenetriamine Reagent Combination

The flotation process developed at Falconbridge laboratories utilizes sulphur dioxide and diethylenetriamine (DETA) reagent combination in the depression of pyrrhotite to allow its separation from pentlandite and chalcopyrite. DETA by itself has failed to produce flotation selectivity with samples from plant and pilot plant streams which showed relatively high redox potentials. However, DETA was found to function effectively on laboratory-generated samples under certain conditions. The results of poor depression are in keeping with thermodynamic calculations which indicate that in the presence of sufficient xanthate and DETA, the formation of ferric dihydroxy xanthate and dixanthogen is possible under oxidizing conditions. The use of sulphur dioxide alone has also resulted in a rather poor depression of pyrrhotite. However, the combined use of these reagents has resulted in an efficient and consistent separation of pyrhotite from pentlandite and chalcopyrite. Various aspects of this selective flotation system are presented along with a discussion on possible operating mechanisms.