Search Documents

By A. Chaisantikulwat

Most solid-oxide fuel cell (SOFC) modeling emphasizes steady state cell operation. However, understanding the dynamic behavior is essential to predict the performance and limitations of SOFC power systems. In this work, we demonstrate a dynamic model of a SOFC, and we simulate a feedback control scheme that can maintain output voltage despite load changes. Dynamic response is determined as the solution of coupled partial differential equations derived from conservation laws for energy, mass and electric charge. From such a model, the step responses to system input variables can be determined. Low order dynamic models that are sufficient for feedback control design can be derived from the step responses. The development of the partial differential equation model is outlined, and the limitations of the control system are discussed.

Jan 1, 2005

Commercial SOFC systems will likely utilize hydrocarbons or hydrogen produced from hydrocarbon fuels and therefore will likely be exposed to sulfur impurities. Conducting-Atomic Force Microscopy (C-AFM) is a scanning probe microscopy technique which maps both sample topography and conductivity with tens of nanometers resolution. In Ni-YSZ, C-AFM measures the resistance of the metallic network at scanned locations, with the ability to differentiate between interconnected and isolated metallic particles. We have applied C-AFM to Ni-YSZ SOFC anode materials, with the goal of monitoring changes in the conductivity of the Ni anode network resulting from SOFC degradation processes, such as H2S poisoning.

Jan 1, 2005

By E. Dernedde

Industrial plants located in the province of Quebec, Canada, are subjected to large variations of the ambient air temperature, Building ventilation systems of these plants must have some flexibility in order to meet industrial hygiene standards (TLV for chemical substances, heat stress and cold stress) at any time of the year, The building ventilation of a bath treatment plant of an aluminium smelter in Quebec was examined under summer and winter conditions, Part of the plant has periodic emissions of hydrogen fluoride gas and heat from hot anode butts, CFD modeling was used to optimise the building ventilation of the bath treatment plant, The present study proposes a modified building ventilation system, which improves the internal environment, complies with industrial hygiene standards and also reduces heating costs by 20 % during winter.

Jan 1, 2005

By L. Sun

A numerical model has been developed to study the air flow in the flow plate and gas diffusion layer assembly on the cathode side of a PEM fuel cell. The flow plate in this type of fuel cell often has serpentine channels and the porous layer is adjacent to the flow plate to diffuse the air to the catalyst layer. Flow cross-over of air through the porous diffusion layer from one part of the channel to another can occur. This flow cross¬over is a result of the pressure differences between different parts of the channel, and it causes the flow rate through the channel to vary with the distance along the channel. A numerical study of pressure distribution and flow cross-over through the gas diffusion layer (GDL) in PEMFC flow field using a serpentine channel system has therefore been undertaken to compare the cases of a single channel and two parallel channels, with the channels having a trapezoidal cross-sectional shape. The purpose of the present work was to study the effect of the flow plate geometry on the basic fluid flow through the plate. The flow here has been assumed to be three-dimensional, steady, incompressible, isothermal and single-phase. The flow through the porous diffusion layer has been described using the Darcy model. The dimensionless governing equations have been solved by using the commercial CFD solver, FIDAP. From the results obtained, it can be found that the single channel systems have greater maximum flow rate difference than the parallel channel systems under the conditions considered in the present study. Also, the size ratio R of trapezoidal cross-sectional shape has a significant effect on the flow cross-over and pressure variation in the flow field.

Jan 1, 2005

By D. Bois, P. Poirier, B. Bussière

Environmental desulphurization is an attractive alternative for the management of acid generating tailings. Bulk sulphide flotation is the most commonly used method to produce desulphurized tailings, as shown from many previous works. This process can reduce the volume of problematic tailings to manage by making a sulphide fraction concentrate. The desulphurized tailings can then be used as construction material for an engineered cover to prevent acid mine drainage. In this paper, the results from different laboratory and pilot scale flotation tests are presented. These results confirm that low sulphide non-acid generating tailings can be produced by froth flotation. It is also demonstrated that sulphide concentrates obtained from desulphurization mixed with the appropriate binders can be used as feed material for paste backfill. From previous work on the evaluation of operating and capital costs of the desulphurization process for different ore types, the use of desulphurization as a tailings management approach was studied for several scenarios. The desulphurization process was then compared with other technologies (underwater disposal, engineered soil cover) currently used to prevent acidic drainage (AD) for a new mining operation. Results show that partial or total desulphurization are technically and economically viable options to manage tailings during mine operation. Mine waste managers should consider desulphurization as an efficient technology.

Jan 1, 2005

Advanced high temperature electrochemical systems such as fuel cells, electrolyzers and ionic transport membranes are currently being developed for a wide variety of energy conversion, storage and gas cleanup applications. These systems offer high electrical efficiency, multi fuel capability, modular construction, no/negligible emissions (SOx, NOx, VOC, particulate matters) with capability to sequester green house gas emissions (GHG). Electrochemical processes and electrode reactions will be discussed. Cell and stack component materials and fabrication processes will be presented. Bulk, surface and interface degradation processes responsible for cell and stack performance degradation will be examined.

Jan 1, 2005

By Waldbillig. D.

A baseline of the poisoning effect of hydrogen sulfide (H2S) fuel impurities on solid oxide fuel cell (SOFC) anodes was developed using polarization testing. After the baseline behaviour was characterized, tests to study the effect of various H2S concentrations on the rate and amount of cell voltage degradation and recovery were performed. Attempts were made to improve the rate and amount of recovery by various methods. Testing was very reproducible, but significant electrochemical performance degradation was seen after all H2S poisoning tests even at an H2S concentration of 0.1 ppm. Degradation is initially quite rapid, but after a period of time the rate of degradation levels off. After poisoning was complete, the H2S flow was stopped and the cells were allowed to recover. Some recovery was seen after poisoning, but cell performance was never fully recovered.

Jan 1, 2005

By W. Mirihange

Considerable mechanical property decline is always observed at the Heat Affected Zone (HAZ) of AA 5083, This occurred as a result of the thermal effect on the hardened material, It is highly beneficial to have a prospective metallurgical procedure to overcome this decline of properties. Therefore, experiments were set to evaluate the effectiveness of a quick post weld heat treatment process with the AA 5083, Optimum results were obtained at 473K and with approximately 600 seconds time, The interplay between the time, temperature and mechanical properties are possible to explain by the Lifshitz-Slyozov-Wagner (LSW) theory and by considering the composition of the material.

Jan 1, 2005

By T. ?kre, O. M. Dotterud, S. Haarberg, J. Thonstad, G. M. Haarberg

An electrowinning pilot plant has been constructed at Falconbridge Nikkelverk A/S, Kristiansand, Norway. The equipment consists of a mixing tank where the electrolyte composition and temperature are controlled, an electrowinning tank equipped with five cathodes and six anodes of commercial size and design and a dechlorination facility. Electrowinning experiments were carried out in this pilot plant using acid cobalt chloride solution from the cobalt tankhouse. Key parameters were varied to obtain an improved understanding of the cobalt electrowinning process, focusing on the detrimental deposition of cobalt oxide on dimensionally stable anodes. The extent of anode scaling was found to be dependent on the electrowinning conditions. Low pH, temperature and cobalt concentration resulted in less scale being formed, however at the expense of cobalt current efficiency and cell voltage, adversely affecting electrowinning production capacity and energy consumption. When operating at high acidity, pH in the anolyte was higher than in the catholyte, which is believed to be due to H+ ions taking part in the current transport across the diaphragm, migrating out of the bags surrounding each anode.

Jan 1, 2005

By Paul Laframboise, Nigel MacDonald, Mike Hallewell, Robert Thorpe

"Galmoy Mine, owned by Arcon Mines Limited, has operated since 1997, and is one of three operating lead/zinc mines in Ireland. Changes in ore type starting in mid 2002 created challenges to metallurgical operations at Galmoy. This resulted in unacceptable lead and zinc flotation performance, which prompted initiation of a formal plant review and a subsequent stabilization programme. This involved a structured review of operational practices, development of a new Standard Operating Procedure (SOP) which in turn led to significant changes in process control equipment needs in conjunction with extension of zinc flotation cell residence time.This paper will describe the metallurgy of the Galmoy operation. Reasons for the poor metallurgy experienced in 2002 will be described, as well as the solutions identified to overcome these problems. By the second quarter of 2003, these solutions had been implemented and recoveries had risen to record levels.INTRODUCTIONGeneralGalmoy Concentrator is located in County Kilkenny (Refer to Figure 1 below) and was constructed during 1996 and commissioned in 1997.The concentrator at Galmoy had been designed initially to treat 650,000 tonnes per annum of primarily CW ore type. The main mineral of economic significance was sphalerite (Typically 10 to 11% Zn) with some minor galena (0.7%Pb) in a dolomite (Magnesium Carbonate) host rock.The only other competing sulphide mineral was pyrite (Circa 3 to 5% Fe in Mill Feed. This CW ore type predominated the first 6 years of production, but in August 2002, the ore mineralogy changed due to significantly higher levels of pyrite rich G ore body being blended in with CW ore."

Jan 1, 2005

By K. Poorhaydari, B. M. Patchett, D. G. Ivey

In this paper, some applications of carbon extraction replicas, as samples for transmission electron microscopy (TEM), are discussed. Modern high strength microalloyed (HSMA) steels, used as structural or pipeline materials, have very small grains with substructures. Replicas used in TEM can resolve the grain boundaries and can be used for grain size measurements in cases where the small size of the grains pushes the resolution of conventional optical microscopes. The grain size variations obtained from replicas correlated very well with mechanical property variations, indicated by hardness, in the fine-grained heat-affected zone and base metal of some welded HSMA steels. Replicas are also very suitable samples for precipitate examination with analytical TEM. Advantages and limitations of the application of replicas, as well as some corrections for the estimation of the volume fraction of fine precipitates, are discussed.

Jan 1, 2005

By K. Adham, C. Lee

The demand for nickel is continuing to exceed inventories, and producers are working vigorously to increase capacity. Many nickel processes utilize the fluidized bed technology for its fast heat and mass transfer, excellent temperature control and low maintenance. The following four nickel applications of the fluidized bed technology have been commercialized: I) Sulfide ore roasting; II) Nickel sulfide (matte) roasting; III) Nickel oxide reduction; IV) Nickel chloride pyrohydrolysis. This paper examines the issues surrounding the application of fluidization technology to the above processes, from the stand point of the engineer modeling the process and designing the key equipment, based on the historical success stories and the fundamental principles of flow sheet synthesis. Using the available data in open literature, typical flow diagrams (with convenient bases of 1 t/h feed or product) are developed to illustrate the relative flow rates and to highlight the key features of each application. In addition, some historical background information is provided for each process with supplemental notes with regards to our company's involvements.

Jan 1, 2005

By J. E. Amadi-Echendu, F. Stober, J. Ndlovu, L. R. Nelson

The Polokwane Smelter Complex (PSC) relies on a single 68MW high-intensity six-in-line furnace to smelt a planned 650 000 t/a dry concentrate to produce a platinum group metals (PGM)-bearing matte. As typical of a greenfields venture, considerable attention was paid to the project development and implementation stages of design, engineering, construction and commissioning. Somewhat unusual though, was the role of a dedicated multi-disciplinary "Operational Readiness" and support team, comprising the owners team and specialists from the furnace designer, HATCH, to effect a safe and rapid ramp-up to the design smelter capacity of 68MW. The challenges encountered in developing an effective partnership will be discussed. The modus operandi and roles of the "Operational Readiness" team during the design, procurement, construction and commissioning stages as well as that of the operational support team within the overall ramp-up objective will be presented. The "Operational Readiness" team was responsible for:

Jan 1, 2005

By G. P. Gu, B. Fang, R. W. Revie, M. Elboujdaini

Stress-corrosion cracking (SCC) tests were conducted in the near-neutral pH standard solution, NS4, and in an actual soil solution, using four-point bending at high a stress ratio and low frequency conditions very similar to those of operational pipelines. Pitting incubation appeared first and then pitting initiated and grew in both solutions although there were many more pits on the specimen tested in soil purged with 5% CO2 + 95% N2 than in the specimen tested in NS4 solution purged with the same gas. These observations show that samples in soil solution are more susceptible to pitting than those in NS4 solution. When the pit reached a critical size, the increased stress concentration around the pits, resulted in the transition to a crack.

Jan 1, 2005

By M. Dupuis

It has been previously demonstrated [1,2] that using selective collector bar rodding has a big impact on the uniformity of the current density at the top surface of the cathode block and hence on the intensity of the horizontal current in the metal pad, The present study investigates the impact of using selective collector bar rodding on the MHD stability of a 500 kA aluminium electrolysis cell, For this purpose the recently developed MHD package for the aluminium reduction cell time dependent behavior is used.

Jan 1, 2005

By D. Want

In titanium-lined autoclave design the most critical point of its mechanical reliability is its titanium batten strips present at the circumferential and longitudinal barrel-weld seams. Recently an Australian Company, W.E. Smith Hudson (WESH) P/L, has developed a fully flush batten strip and is building autoclaves with this design. Significant research and development has been performed in the process. In this presentation, design aspects of these batten strips are presented that cover topics such as residual-stress magnitudes during fabrication, affect of preheat during batten-strip welding and residual stress in respect to fatigue life. There has been little research done regarding the affects of residual batten stress in relation to fatigue life. Considerations of this 'grey' area of design will be discussed based on the author's research data and finite element analysis.

Jan 1, 2005

By H. Abdollahi

Cold rolling is one of the most important techniques in metal forming since the cold rolling products are almost finished product, The product quality of this process is widely influenced by friction in the roll gap; therefore, controlling the friction and other parameters affecting the cold rolling is very important in order to have a product with high quality, Among the cold rolling parameters, the pressure distribution or friction hill within the roll gap is known as the most significant one, In this study, a new software (Matroll), is introduced which can determine the coefficient of friction (COF) and plot the friction hills for an industrial mill, Besides, based on rolling equations, it offers about 25 rolling parameters as outputs. To verify the software operation, the real industrial rolling data was used as inputs, The results (outputs) are in good agreements with the findings of other researchers, The COF values are very reasonable, The friction hill shows that COF is not constant over the whole arc of contact.

Jan 1, 2005

By F. Khomamizadeh

In this study, deep cryogenic treatment was applied to A319 cast aluminum samples. Although the cryogenic treatment didn't have any significant effect on mechanical properties of the well degassed and fluxed samples, but the tensile strength of the samples containing a considerable amount of gas and shrinkage defects was improved surprisingly, This improvement was attributed to the strengthening of the a-aluminum matrix which slows down the propagation of the existing defects. There was no significant increase in the hardness after cryogenic treatment, The abrasion resistance of the alloy was improved after cryogenic treatment, by developing a homogeneous protector shield, composed of abrasive grains penetrated into the soft aluminum matrix and kept tight.

Jan 1, 2005

By P. C. Sui

Numerical investigation and parametric simulations of the coupled electrical conduction and mass diffusion in the GDL of a PEMFC are reported. The coupled transport is solved using a 2D, "under-the-rib" computational domain for the cathode GDL. The current density on the GDL/catalyst layer interface, which constitutes one of the boundary conditions for the GDL domain and reflects the activation overpotential in the catalyst layer and the ohmic loss in the membrane, is solved iteratively using a novel numerical algorithm. A parametric study is performed to investigate the effects on current density distribution of various operating conditions such as oxygen concentration and membrane resistance, and of design factors such as GDL geometry, anisotropic transport properties, and deformation under the land area. The results show that the current density distribution under the land area can be dominated by either electron transport or mass transport, depending on the operating regime.

Jan 1, 2005

By P. Harvey

"Following initial discovery in 1991, BHP Billiton Diamonds Inc. opened Canada’s first diamond mine, the EKATI Diamond Mine (EKATI) in the Northwest Territories on October 14, 1998. Four short years later, on November 29, 2002, saw the opening of North America’s first underground diamond mine, the Koala North mine. Nestled between the original Panda open pit and the new Koala pit, which is in the early stages of production, Koala North represents the only underground kimberlite mining venture in Arctic conditions outside the new underground mines being developed by ALROSA in the Yakutsk region of eastern Russia. Extensive underground kimberlite mining has been practiced in the Republic of South Africa for much of the 20th century and continues today.Underground mining represents a key component of the long-term business plan for EKATI. As various open pits reach their economic limit, continued recovery of high-value ore at depth is dependent upon the ability to productively mine the kimberlite pipes by underground methods. As a function of its location, size, and value, the Koala North pipe is ideally positioned to host the first underground mine at EKATI. Koala North is designed and approved as a learning mine, from which to gain valuable experience in preparation for the potential mining of other larger, higher value pipes by underground methods in the development, the Koala North mine is well into its production ramp-up phase and currently producing at around 1,200 t/day from the first two production levels."

Jan 1, 2005