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By J. A. Hurd

Towards the goal of a better understanding of the structure-proton conductivity relationship in PEM materials, this project concerns the design of ordered polymeric solids containing well-defined sulfonate aggregates. The approach employed involves the templation of sulfonated monomers using core principles of crystal engineering. In addition to sulfonate groups, the monomeric units contain crosslinkable functionalities to enable formation of a covalently linked network. The templation strongly directs the construction of well-defined sulfonate clusters and aggregates. Structural, sorption and conductivity data for the networks will be shown.

Jan 1, 2005

By A. Khodadadi, M. Abdolahi, P. Taimory

Cyanide is used by the mining and chemical industries in tremendous quantities without attention being given to its hazardous properties. The use of cyanide compounds in mining is one of the most important environmental issues for the mining industry due to the acutely toxic properties of many cyanide compounds to humans and aquatic life. Cyanide tends to react readily with most other chemical elements, producing a wide variety of toxic, cyanide-related compounds and because cyanide is carbon based an organic compound it reacts readily with other carbon-based matter, including living organisms. This research is aimed at investigating a feasible and economical technique for the removal of cyanide from tailing wastewater of Muteh gold mine. In this research, removal from Muteh factory's waste water, was achieved at Tarbiat Modares University's mineral processing laboratory through the oxidation of cyanide by calcium hypochlorite. Cyanide oxidizes and changes to cyanide (CNO-) which is 1000 times less environmentally hazards than cyanide. Cyanide titration was accomplished using Rhodanine solution and silver Nitrate. Cyanide concentration in the wastewater, was 270 mg/L. Cyanide removal was achieved at an optimum pH of 12.3. However, at higher temperatures, cyanide removal was complete at this pH level. Optimum Dosage for complete removal of cyanide using calcium hypochlorite was 1.43g/L.

Jan 1, 2005

By M. Eikerling

The full competition between mass transport and reaction in PEMFC unfolds in cathode catalyst layers (CCLs). Recently developed models provide vital insights into effects of thickness and composition on effectiveness of catalyst utilization and performance. However, the CCL's key function in liquid water removal is rather unexplored. Studies of water balance in PEMFCs focus mostly on other cell components. Notwithstanding this prioritization, a simple calculation shows that the CCL is the PEMFC's favourite medium for conversion of liquid water into vapor. Porous structure and wetting properties steer the interplay of evaporation, transport and reaction. A model will be presented, that links pore space morphology, composition, distributed properties (concentrations, pressures, reaction rates, potential) with global performance (critical phenomena). It reveals how problems of flooding in the fuel cell could be mitigated by properly adjusting catalyst layer structure and operation conditions and under which conditions all liquid water arriving in the CCL would leave it as water vapour through the CCL/GDL interface. Results for a simple variant of the model emphasize the role of the CCL as a watershed for the whole cell.

Jan 1, 2005

By Tim Edwards, Richard Triglavcanin, Ian Arbuthnot, Darren Colwell, Brad Garraway, Ken Roberts

"In the mineral processing industries, there is an increasing need to design thickeners which are able to produce high density underflows usually referred to as “paste”.The behaviour of a flocculated suspension in compression needs to be well understood in order to arrive at a reliable thickener tank configuration (i.e. diameter, cone angle and depth) for a required paste result.As a suspension approaches paste consistency, it’s fluid characteristics change markedly. It develops a high yield stress, and may have an increased tendency to form agglomerates, which lead to a phenomenon known as “rotating beds”, “donuts”, or “islands”. These characteristics present challenges to the designer of the rake mechanism.The subject paper addresses the requirements for designing a paste thickener, covering the following topics:o Testwork for thickener sizingo Design of rake mechanismso Suspension rheology and effect on designo Case studiesTESTWORK AND SIZING FOR PASTE THICKENERSThickening slurries to the maximum possible density (paste) is becoming increasingly common. Applications such as Autoclave feed thickeners, paste backfill and some counter current washing (CCD) circuits are all examples of potential paste thickening applications. The principle of paste thickeners is that the compression zone is much deeper than on either high rate (HRT) or high compression (HCT) units; generally 3 metres or more. As the compression zone gets deeper, theunderflow density for a given flux rate (tph/m2) increases, as a result of two factors:1. Longer bed settling time. Settling flocs move relative to one another and release interstitial fluid when they are in compression. Increasing bed residence time achieves higher density underflow as more fluid is removed.2. The nett weight of the bed creates a compressive force on the settling flocs. This force increases with depth, so that the flocs at the bottom of the bed experience the highest compressive force. This represents the driving force to expel interstitial fluid and hence increase bed density."

Jan 1, 2005

By J. Fournier, D. Fortin, F. Robichaud

Since milling began in 1988, the Laronde mill has been expanded several times, the most recent, increasing the milling rate from 5 000 to 7 000 mtpd. Laronde uses SAG/ball mill grinding followed by copper and zinc flotation circuits. A cyanidation/Merrill-Crowe process recovers the remaining gold and silver in the flotation tails in order to cope with high silver/gold ratio associated with the discovery of the Penna shaft. Since the commissioning of the Merrill-Crowe refinery in 2000, several modification and expansion projects were performed to reduce health and safety hazards. Remarkably, several of these improvements have contributed at increasing productivity and Net Smelter Return of the refinery while reducing worker's injuries. In 2004, the refinery was audited to evaluate and quantify the circuit performance. Metallurgical and mechanical operating conditions of the refinery are now understood and areas for further improvements are well defined. This paper describes some of the factors that have contributed to this improvement and describes how ergonomics and recovery can further be improved.

Jan 1, 2005

By M. I. Kalashnikova, Y. M. Shneerson, E. E. Zhmarin, Y. V. Degtiarev, E. M. Vigdorchik

Separation of a magnetic fraction from nickel concentrate following matte flotation, and its treatment in a separate circuit enable reduces precious metals losses. The magnetic fraction is treated in two stages of oxidative leaching: atmospheric and pressure leaching. A study of the atmospheric stage, using mathematical modelling, is described in this paper. The mathematical model and experimental data were used to carry out industrial process calculations. The model enabled extrapolation of the results of batch laboratory test to industrial-scale continuous processing and the selection of optimal process conditions and large-scale equipment. In December 2004, commercial oxidative leaching tests were performed on the magnetic fraction at the Severonickel Plant (Monchegorsk, Russia). A comparative analysis of the mathematical modelling results and the actual process parameters is presented.

Jan 1, 2005

By Margarete Kalin

"Difficulties arise in implementing environmental technologies in the mining sector because important fundamental processes, which lead to the environmental degradation, are ignored. Weathering rates, the role of bacteria in the process and the incomplete application of the matching principle of accounting at the time the mining disturbance take place. Mining is a multi-stakeholder activity and the environmental problems have multivariate dimensions also effecting process.The limiting factors in the contaminant generation process are the transport of oxygen by advection, convection or diffusion in air or water and the associated microbial activity. Weathering products are transported from the mineral surface by atmospheric precipitation to surface and groundwater. This contamination takes place at different rates, requiring a long time to evaluate technological choices.Restoration efforts have to focus on slow reaction rates in the contaminant generating processes. Technology, which does not address the reaction rates and is selected based on inappropriate time scales, will not provide long-term solutions. Natural approaches to reduce acid generation, based on Ecological Engineering principles have required decades of research and field testing, but now show promise in addressing the cause of AMD and ameliorating its effects."

Jan 1, 2005

By L. H. Shang

The 319 Al-Si alloy is one of the most prominently used aluminium-based alloys in motor vehicle and engine applications, Microporosity present in 319 alloy castings reduces the load bearing capacity of the castings, The quantitative prediction of microporosity levels in Al-Si castings has been a subject of much interest for several years. In this research a new criteria function, tf 1,98 R13° (tf: local solidification time, R: cooling rate) was developed by multiple regression analyses, correlating thermal data from simulation studies to experimentally obtained microporosity values. This new criteria function gives a general prediction of microporosity in 319 Al-Si castings.

Jan 1, 2005

By A. D. Dalvi

Economics, Resources, Environment and Technology are the major driving forces in the base metals industry. However, these factors are intertwined and together will propel the industry in the future. The demand for metals has grown with economic expansion, between 2 to 4 % p.a. The current growth cycle has been driven by economic expansion in China where the demand for base metals has risen from - 7 % of the world demand in the 90's to - 25 % of world demand today, and rising. Base metals are commodities and their demand and price are cyclical. Historically metal prices have declined in constant dollars, forcing the industry to reduce costs, increase productivity and increase the scale of operation for economies of scale. Due to resource depletion and capacity expansion the industry is driven to expand its reserve and resource base. However, in the case of sulphide deposits of copper and nickel it appears to be a losing battle. For nickel the laterites represent a vast source at this time. Their development requires development of new technologies to make these resources economic. Emission reduction is being increasingly mandated in most jurisdictions with all governments enacting progressively more stringent regulations. The industry has been responding with technological innovation. With the Kyoto protocol there is a push to reduce energy intensity in metal production. Technological innovation is driven by all the other factors and is leading to novel ways of doing exploration, mining and processing, that would maximize resource delineation and utilization, reduce costs, increase productivity, reduce energy consumption, maximize asset utilization and reduce environmental affects. Development of alternative technologies such as Pressure Acid Leach of laterite for nickel, bio-leaching, heap leaching, SX-EW etc are being adopted to achieve the aims of the industry.

Jan 1, 2005

By Polysius AG

"The Lone Tree demonstration was an important milestone in bringing High Pressure Grinding Roll (HPGR) technology into hard rock applications in the mining industry. HPGRs have become standard equipment in the cement, iron ore, and diamond industries over the past fifteen years, but their use in severe duties found in the hard rock mining sector has been restricted due to high roll wear and subsequent low availability. HPGR availability has historically been limited because of frequent downtime for edge weld rebuilding as the rolls wore and short tyre life from high roll surface wear rates.Recent advancements in HPGR wear protection are now being evaluated for commercial applications in the gold and copper mining industry where this technology may offer benefits in comminuting hard and/or abrasive ores and in improving metal recovery in heap leaching applications.Proving the feasibility of HPGRs for processing competent, abrasive gold ore, Newmont Mining Corporation, the world's largest gold producer, operated an HPGR demonstration plant employing a POLYSIUS (POLYCOM) HPGR incorporating some unique wear protection, at their Lone Tree gold mine near Winnemucca, Nevada. Results of the successful demonstration are presented and evaluated in this paper.The Lone Tree HPGR demonstration plant operated for three months, from April through June 2003. The HPGR operated for 1626 hours and processed 141,000 tons of ore. This technology demonstration focused on measuring operating performance, wear characteristics, and availability of today's HPGR technology.Polysius' innovative roll surface wear protection system eliminated edge-welding downtime. Improved surface wear protection extended tyre life to predicted durations acceptable for very abrasive service. The POLYCOM HPGR is now deemed suitable for selected hard rock applications."

Jan 1, 2005

By M. Bozorgtabar

Metal Matrix Composites (MMC) have a ductile matrix containing ceramic particles, Due to their improved wear properties, Al?SiC composites have economical applications in many industrial uses where wear is a problem, One of the most serious difficulties in manufacturing Al-SiC composites is obtaining adequate 'wetting' of the particles by the melt. In this research work, a stir casting system was designed for the improved manufacturing Al-SiC composites, The effect of some production variables such as the addition of SiC particles to the aluminum melt on wettability, was also studied. The results showed that the manual addition of particles would not be successful in manufacturing and that a system of adding silicon carbide particles through controlled temperature, atmosphere and improved mixing was needed.

Jan 1, 2005

By M. J. Merwin

Heat treated seamless tubular products are processed in a fashion that can be easily modified to produce dual phase microstructures, through the implementation of intercritical soaking prior to quenching. Dual phase steels are known to possess low yield strength compared to tensile strength. The steel line pipe market is interested in low yield-tensile ratio materials for application in reel barge pipe laying operations. In the current work compositions of commercially produced material already in use for the line pipe market were examined and dual phase microstructures were successfully developed. The microstructure and properties of the materials were found to be stable over the range of intercritical temperatures employed. Tempering temperature and, somewhat unexpectedly, small chemistry differences were found to have the largest influence on properties. Excellent toughness performance was observed in samples tempered at temperatures in excess of 550°C. Tempering in this temperature regime produced materials with strength suitable for application as API X60 line pipe. A difference in tensile strength between steels of similar chemistry was observed, and is not fully understood at this time. Welding performance was considered through simulation of three regions of the heat-affected zone. Neither intercritical temperature, nor tempering temperature, were found to have a significant influence on the heat-affected zone properties. The peak temperature achieved in the thermal cycle was the only significant factor. The hardness of the heat-affected zone was found to increase continuously with increasing peak temperature. While toughness was found to be low for both partially-transformed and coarse-grain heat-affected zones, the toughness of the fine-grained heat-affected zone was substantially better. Based on the results found in this laboratory study, a limited production trial is expected.

Jan 1, 2005

By K. Nikkhah, N. Dhadli, G. Freeman

Ammoniacal pressure leaching operations have been in commercial use at the Fort Saskatchewan refinery of Sherritt International Corporation since 1954. Recent improvements have significantly increased the capacity of this circuit. The computer modeling of this process has proved to be a valuable tool in facilitating the evaluation of different operating scenarios in an effective manner. Reagent response in the ammonia leach of nickel and cobalt sulphides is examined using the dynamic process simulation capabilities of IDEAS(TM) software. The dynamic simulation enables accurate measurement of the sensitivity of the process to variables such as temperature, feed rate and ammonia concentration as well as compartmental analysis of metals concentration, pulp density, vent gas composition, and the formation of specific complexes. The complexity of the ammonia leach process makes it a logical choice for evaluation by computational analysis. The methodology for dynamic modeling of a pressure leach process is presented.

Jan 1, 2005

By W. R. Tyson

Pipelines for the transport of gas and oil are being designed to operate at increasing pressures in increasingly harsh environments. The steel used to construct these pipelines must have adequate toughness to tolerate weld imperfections (i.e. withstand bending strains) and to arrest running cracks (i.e. to prevent propagation of axial fractures). The problems posed in specifying suitable toughness parameters and the approaches currently being used to measure them are discussed.

Jan 1, 2005

By J. Gao

We present results from our investigation of the concept and practice of using surface-charged latex nanoparticles as building blocks for conductive membranes. Nanoparticles were synthesized by free-radical co-polymerization of two hydrophobic monomers, butyl acrylate (BA) and methyl methacrylate (MMA), a crosslinker, N, N'- methylenebisacrylamide (BIS), and a charged monomer, sulfonate styrene sodium salt (NaSS), in water. The resultant nanospheres were characterized with static and dynamic laser light scattering. Thin films were cast from concentrated particle dispersions, followed by incubation at ?110 °C. Conductivity, water uptake and final charge content were measured. The membranes have higher conductivities than both amorphous films cast from sulfonated BA-MMA-Styrene copolymer chains and BA-BIS-MMA-NaSS gel films. TEM images and neutron scattering spectra confirm the particulate structure of the membranes.

Jan 1, 2005

By Y. Huang

Corrosion of GaAs in aqueous electrolytes is a major limitation in implementing GaAs-based photoelectrochemical solar energy conversion systems, In this work, the corrosion behavior was investigated by electrochemical methods and surface analysis approaches, in both H2SO4 and NH3?H2O solutions, Open-circuit measurements showed that the cleaned GaAs surface was very sensitive to water/air, Impedance measurements for n-GaAs showed that an inductive loop only appeared at a high corrosion rate because a reaction intermediate is the oxidant for a further decomposition step in combination with chemical reaction with water, The results suggest that the same corrosion/decomposition mechanism occurred on n-GaAs in the two solutions, When the surface-hole concentration was low, the hole injection or generation process was the rate-determining step, At large reverse bias on n-GaAs, with high-hole concentration, the corrosion rate was limited by a Faradaic adsorption process, involving an adsorbed intermediate, The different surface compositions after corrosion in the two solutions can be explained by the dissolution of As(0), Further oxidation of As(0) to As(III) in NH3?H2O solution is still slow, as suggested from X-ray photoelectron spectroscopy (XPS) analysis,

Jan 1, 2005

Inco Limited has been evaluating options for streamlining the overall flowsheet at its Sudbury, Ontario operations to improve productivity and to minimize the cost of at¬mospheric emissions reduction. Some of the flowsheets being considered include vari¬ous levels of copper/nickel separation at the Clarabelle Mill where all Inco's Sudbury Basin ores are processed. This paper reports on the laboratory and miniplant studies car¬ried out during the flowsheet development for a commercial Cu/Ni separation plant. There are two potential feed streams for Cu/Ni separation. It was determined that Cu/Ni separation from the rougher concentrate requires no regrind, and a very clean copper concentrate is produced, but the recovery of copper is limited to about 70% from ore. Cu/Ni separation is more difficult from the bulk concentrate because of the presence of excess flotation reagents in the slurry and due to locked particles. By replacing the slurry water with clean process water, and by addition of some hydrogen peroxide, entrainment is minimized and excess reagents are removed from the surface, providing a satisfactory separation of copper from nickel. Fine regrinding is required to increase liberation of the locked particles and to obtain 85% copper recovery with minimal nickel contamination of the concentrate.

Jan 1, 2005

By S. Esmaeili

The yield strength model developed by Esmaeili, Lloyd and Poole [1] has been adapted to model isothermal aging in Cu-containing AA6xxx alloys, with (a) a moderate and (b) a very low Cu content in the solution-treated, as-quenched, condition, Isothermal calorimetry has been used to analyze the kinetics of precipitation in these alloys, While the kinetic parameters for the low Cu alloy has been derived from the present experiments, the previously determined kinetic parameters for the high Cu alloy AA6111 has been used to model the precipitation kinetics in the moderate Cu alloy. The age hardening responses of both alloys have been well predicted by the model.

Jan 1, 2005

By H. J. McQueen

Large-scale industrial production of pipe began with longitudinal hot pressure welding of wrought iron by passage of skelp (narrow strip with beveled edges) through a die or bell that curled it about a longitudinal axis until the edges were forced together. Such small to medium tubes could be reduced by rolling or drawing; with threaded connections, they were excellent for distribution of clean water and of illuminating gas for street, home and industrial lighting. Although steel lacks the fluxing slag for pressure welding it has hot strength similar to iron; hot-pressure bell welding was advantageously transferred to steel in long coiled strip with 50% higher cold strength. For pipe without weld-line defects, hot cupping followed by Pilger mill rolling produced tubing that revolutionized bicycle quality and high-pressure service for boilers and chemical processing. Mannesman hot rotary piercing produced long thick walled tube that permitted reduction or expansion by rolling to provide pipe sections up to 60 cm diameter and 12 m long. During 1910 - 1940, oil and gas pipeline technologies, notably welding evolved markedly as they proliferated in the United States, in response to far-flung petroleum fields, expanding industry consumption and the automobile revolution. In the Second World War combat pipelines were laid rapidly, such as: the Canol line through the Yukon to Alaska, and fuel supply lines across the channel and through liberated France. Perfection of welding techniques for both longitudinal and spiral weld large diameter pipe in combination with controlled-rolling of micro-alloyed steels made possible reliable Arctic pipelines. The development of pipe production and utilization in Canada is recounted. The fabrication techniques and metallurgical controls are explained.

Jan 1, 2005

In order to avoid impurity problem and enhance absorption/desorption kinetics of Mg-based compounds, nanostructured Mg-based compounds were synthesized from Mg, Ni and other elemental nanoparticles produced by hydrogen plasma-metal reaction. XRD and TEM results demonstrate that homogeneous nanostructured Mg-based compounds with less impurity were successfully synthesized by this method. DSC in hydrogen atmosphere, pressure-composition isotherm and the kinetics of hydrogen adsorption/desorption were investigated at different temperatures. The results show that the nanostructured Mg-based compounds can absorb hydrogen in a high speed at a low temperature.

Jan 1, 2005