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By M. Korchynsky

"The key words which characterize vanadium are: unlimited availability, versatility of applications and price stability. The supply of vanadium is assured by diversified sources, distributed all over the globe. The inexhaustible raw materials base is complemented by a strong vanadium industry. Both the fully integrated vanadium producers and converters of vanadium oxide or vanadium-containing slags or residues guarantee an adequate supply, commensurate with the steady growing demand.The major share of the world's vanadium output is being consumed by the steel industry. As an additive to steel, the versatility of vanadium is particularly impressive. A few hundreds of one per cent of vanadium convert plain carbon steel into high-strength, low-alloy steel with more than double strength. On the other extreme, high-speed steels made via the powder metallurgy route show superior performance with vanadium additions as high as 6 or 8 percent. Vanadium is used as a cost-effective alloying addition in steels for high-temperature service, fully alloyed heat-treatable steels, new dual-phase steels for automotive components, rail steels, etc., to mention only a few applications. Vanadium is also an established essential addition for titanium alloys. The chemical industry is relying on vanadium compounds as important catalysts.In spite of a wide diversity of applications and continual growth in consumption, vanadium has exhibited, over the past several decades, a remarkable price stability, free of conjunctural fluctuations. Because of its availability and versatility, it will continue to be one of the key metallic elements for future technologies.Key Features of VanadiumIn attempting to single out the key features of the metallic element vanadium, three descriptive characteristics come to mind: availability, versatility and price stability."

Jan 1, 1982

By D. K. Matlock, D. J. Hamre, J. G. Speer

Ultrafine ferrite (UFF) grains may be produced in surface layers of plate steels using controlled intermediate cooling followed by deformation. Experiments were conducted using a 0.12 C - 1.26 Mn steel on a Gleeble 1500 hot deformation simulator. Taguchi designed experiments were used to evaluate prior austenite grain size, intermediate cooling rate, intermediate cooling temperature, intermediate hold time and amount of reduction in order to observe the effects of variables and their interactions on the final microstructure while minimizing the number of required test runs. Evaluation of resulting microstructures and mechanical properties revealed a preferred thermal and mechanical history for developing ultrafine microstructures in surface layers of plate steels. Application of the fundamental concepts of phase transformations to industrial plate rolling is considered.

Jan 1, 2004

By W. S. (Steve) Vaughan

The Origins of Joint Ventures in Canada?s Mining Industry ? Among the most important financing structures used in our mineral industry today ? Virtually unheard of in the Canadian industry prior to the 1970s ? Borrowed from the U.S. oil and gas sector where it came into prominence in the late 1930s ? The Securities Acts of 1933 and 1934 in effect killed the sale of (equity) shares for financing oil and gas wells and start up mining companies

May 1, 2013

By K. Feindel

The distribution of water in operating fuel cells must be carefully managed to optimize the performance, durability, and functionality of the system. For example, the ionic conductivity of polymer electrolyte membranes decreases as membrane hydration is reduced. Flooding at the cathode inhibits mass transport, and it can lead to failure of materials. Build up of liquid water in the gas flow channels of a fuel cell stack will create a non-uniform distribution of pressure drops across the individual cells. We will discuss the application of 1H NMR microscopy to investigate in situ the production and distribution of water throughout an operating H2/O2 polymer electrolyte membrane fuel cell. Polymer electrolyte direct methanol fuel cells posses high theoretical storage capacities as power systems for portable electronic devices. There are, however, two long-standing hurdles to development of practical methanol fuel cell systems. First, the electro oxidation of methanol at the anode of the fuel cell is poisoned by absorbed carbon monoxide, an intermediate in methanol electro oxidation. Second, methanol readily crosses over from the anode to the cathode of the fuel cell. This methanol crossover wastes fuel, and it poisons the electro reduction of oxygen at the cathode. We are investigating use of 2-propanol as an alternative to methanol as a fuel. 2-Propanol is less toxic than methanol, and it is less prone to crossover from the anode to the cathode. More significant, however, is that the electro oxidation of 2-propanol to acetone is faster than the electro oxidation of methanol because it avoids formation of adsorbed carbon monoxide. We will present active catalyst systems for the electro oxidation of 2¬propanol to acetone in fuel cells. We will also present methods to convert the resulting acetone back into 2-propanol, possibly leading towards rechargeable portable fuel cell systems.

Jan 1, 2005

By Deni Côte, Marcel Vallée

"The Guide to the Evaluation of Gold Deposits reviews the successive evaluation steps in the domains of geology, engineering, and economics. The Guide analyzes, in a systemic perspective, the sequence of exploration, development, and evaluation work required to bring a mineral deposit to production. The aim is to identify the metal/mineralization losses and ore dilution that each work step contributes to the evaluation and mining process. The procedure allows one to maximize the income and profits of a mining operation, and to reduce the risks of financial losses tied to investment decisions in the mining sector. For greater efficiency, the criteria of reserve estimation and classification should be integrated with the evaluation steps and methods. At earlier stages of deposit development, when quantitative knowledge is available mainly on the geological axis, the term ""delimited mineral deposit"" should be used. The term ""reserve"" should be used only in an operating mine or in a mining project, when information in the geological, engineering, and economic domains is adequate to ensure technical and financial feasibility. ""Reserves"" are by definition ""mining reserves"". Each category of proven/probable reserves and measured/indicated deposits should be subdivided into two classes to express better the many steps of mineral valuation. The category of ""possible reserves"" shall be replaced by that of ""inferred mineralization"". This system, derived from the Australasian Code, can easily be integrated into current practices of the exploration and mining industry within a short timeframe. The proposal to develop the use of the margins of error of the estimates at a confidence level of90% should be viewed in a longer timeframe. Establishing the precision of the mineral inventories and distinguishing between categories and classes by means of the margin of error will require more work and a longer break-in period.SOMMAIRELe ""Guide d’évaluation des gisements d'or"" analyse, dans une approche systémique, les travaux d'évaluation et de mise en valeur des gisements minéraux dans l'axe de la géologie, dans l'axée l'ingénierie et dans I ‘axe de l'économique. L’objectif est d'identifier la contribution aux pertes de métal et à la dilution du minerai des diverses étapes de l'évaluation et de l'exploitation du gisement. Ceci aid erra à maximiser les revenus et les profits, et ainsi, à réduire les risques départe financière que comportent les décisions d'investissements dans le secteur minier. Pour atteindre ces objectifs, iI est essentiel de relier les critères d'inventorie et de classification des réserves aux méthodes d'évaluation des gisements. Aux stades antérieurs du développement minéral, lorsque les connaissances quantitatives ne s'étendent qu’à l'axe géologique, le terme ""gisement délimite"" sera utilisé. Le terme ""réserve"" ne sera utilisé que dans une mine en exploitation au dans un projet minier, lorsque l'information dans les axes de la géologie, de l'ingénierie et de l'économique sera appropriée pour en garantir la faisabilité technique et économique. Chaque catégories des réserves, prouvée et probable sera subdivisée en deux classes pour mieux qualifier les niveaux d'évaluation du projet. La catégorie actuelle des réserves possibles sera remplacée par celle des ""minéralisations inférées"". Plusieurs essais démontrent que le système propose, qui s'inspire du Code australasien, peut facilement et rapidement s'intégrer dans les pratiques de l'industrie. II pourrait également contribuer à une standardisation des méthodes et des nomenclatures à l'échelle internationale. La proposition d'utiliser les marges d'erreur des estimes au niveau de confiance de90%pour caractériser les estimations se situe dans une plus longue perspective. Cette application demandera des développement méthodologiques additionnels ainsi qu'une période de rodage."

Jan 1, 1992

By W. M. Goodwin

"IntroductionIN THE preceding paper we have learned about Canada's resources of metallurgical coal. There is an adequate amount in Nova Scotia, a very large reserve on the eastern flank of the Rocky mountains, and a strictly limited supply on the Pacific coast. Added to these is an unknown quantity of coking coal in the Peace River district, at present rather isolated but possibly capable of industrial development in the future.The chief use of metallurgical coal is to make iron and steel. For this, an adequate supply of iron ore is required. So we should now scan the Canadian supply of iron ore, the possibility of its increasing use at home, and the probable markets abroad.Trade in iron ore tends to be international, as is the case with many other raw materials. The present tendency with iron and steel, in contrast, is to keep its manufacture within national boundaries, and there is no evidence that this will change much in the years to come. We should keep these two points clearly in mind when considering the disposal of iron ore from Canadian mines. We should remember, also, that the modern blast furnace and steel plant has such a large output that a correspondingly large population, reasonably compact, is needed to consume its products.Large Ore Supply in East, Small in WestCanada has now four major iron ore fields, well situated to serve adequately the eastern half of the country. Wabana .and Labrador are well placed to serve overseas markets and plants on the eastern seaboard and eastern interior of the United States and Canada."

Jan 1, 1952

By P. W. A. Walker

"The Riviera tungsten occurrence in the Cape Province of South Africa was discovered in October 1979 as a result of stream-sediment panned concentrate sampling. The Cape age granite and late Precambrian Malmesbury Group carbonates and chlorite schists which it intrudes and which host the mineralization are covered by between 10 m and 30 m of Tertiary/Recent alluvium and clay. The scheelite/powellite and molybdenite mineralization occurs in a greisenized granite cupola with an overprint of porphyry-type alteration as well as in minor skarns. The ore reserve is estimated to be 46 million tonnes at an average grade of 0.216% W03 and 0.020070 Mo. The deposit is uneconomic at current tungsten prices. IntroductionDuring the 19705, Union Carbide Corporation was a major producer, processor and supplier of tungsten and derivative products to end-user manufacturing industries. The corporation owned and operated two tungsten mines in the United States, and one in Brazil, and operated a plant in the United States which produced ammonium paratungstate (APT) which is an intermediate product in the production of tungsten wire and tungsten carbide for cutting tool insets and hard facings. In 1975 the three mines were ageing with short-life reserves and high production costs. The world market for tungsten was buoyant and prices, in constant dollar terms, had risen steadily over the past 15 years (Fig. 1).It was against this background that a decision was made to explore for tungsten in North America, South Mrica, Australia and Brazil."

Jan 1, 1994

By Pierre Gratton, Gordon Peeling

The Mining Association of Canada launched the Towards Sustainable Mining initiative in 2004. TSM’s goal is to improve the mining industry’s performance by aligning its actions with the priorities and values of Canadians. The initiative currently includes performance indicators for four areas: tailings management, energy use and greenhouse gas management, external outreach and corporate crisis management planning. Over the past year, the association has been designing a performance assessment and verification system for these performance areas, as its members prepare to move to external verification of their performance in 2006. The presentation will describe the initiative and its evolution, as well as the challenges faced in developing a verification system applicable to an entire sector.

Jan 1, 2006

By Jochen Petersen

This paper gives an overview of the various strands of postgraduate and undergraduate training offered in the Department of Chemical Engineering at UCT. Since 2003 the Department is offering a formal postgraduate MSc programme in hydrometallurgical engineering aimed especially at graduate work-based engineers, with 5 weeks of intensive course work plus a research dissertation on a work-related project. This programme has now run 5 times over the years and produced some 20 degrees. The paper reflects on the experiences with running the course, especially the difficulties experienced with supervising industry-based external students. Furthermore, through the Department a graduate training program is offered for all junior metallurgists at a major South African minerals company. This 2-year program, which is currently on its 12th cohort, offers 1 or 2 week intensive blocks of course work alternating with longer stints where the candidates are based at various operations. Although primarily focussed on minerals processing, it has a significant element of hydrometallurgy in it and in recent years an advanced hydrometallurgy stream has been introduced. The paper reflects on the development of the program over the years, the benefits it has provided to the company as well as some of the challenges that remain. Finally the paper gives an overview of hydrometallurgy related undergraduate and research-only postgraduate MSc and PhD projects at the university. Some emphasis is placed on the recently launched South African Minerals and Metals Research Initiative (SAMMRI), a joint government-industry programme to support university-based research in the area of applied metallurgy.

Jan 1, 2014

By H. R. Manouchehri, A. Weh

"High voltage electric pulse comminution (SELFRAG) relies on inducing electrical breakdown that occurs when the resistivity of a dielectric is insufficient to completely block all transfer of electricity while the conductivity is not high enough to fully accommodate the flow of electricity without considerable changes to the crystal lattice. The technology is based on introducing the electrical discharges into solids immersed in water and placed between two electrodes. The technology has received significant attention since investigations have revealed the potential for fully fragmenting particles or pre-weakening rocks in order to reduce the energy consumption in comminution practices, improve liberation and potentially increase the recovery in mineral processing. Mineralogical analysis of samples showed possible liberation at coarser sizes by high voltage breakage in comparison with conventional mechanical comminution.This study explored the potential of implementing SELFRAG to treat the Sandvik’s Mittersill mine tungsten ore (scheelite) for recovery improvement. Accordingly, standard SELFRAG tests were conducted on four samples from the tungsten process plant to evaluate the energy-breakage relation and potential to liberate the value minerals at coarser size fraction for recovery improvement. The size reduction of the ore after processing with SELFRAG revealed that size deportment occurs at 0.4, 0.2, and 0.1 mm, which indicated potential liberation of gangue and target minerals at respective sizes. In comparison with conventional milling, the difference is the deportment of values into 0.4 mm sizes, which was, to some extent, confirmed by SEM liberation analysis. However, more tests are needed to proof the concept. The study has indicated that, despite consuming more energy in comparison with conventional mechanical comminution, there are promising prospects in liberating the values at coarser fraction and improve recovery by making use of SELFRAG. The energy consumption can be reduced through customized generator and equipment setup, which must be further investigated."

Jan 1, 2016

By Karen Munro

Importance of Aquatic Studies for Mining ?Aquatic habitat is usually the first area where a mine interacts with the ?real world? outside the mine footprint ?Water management is a key consideration for a mine?Effects on the aquatic environment often extend to wildlife and human uses ?There is a lot of regulatory focus on issues of water quality, fish and fish habitat

May 1, 2011

By E. Esponosa-Gomez, J. A. Finch, A. R. Laplante

"Water quality plays an important role in oxide flotation. The effects on selective flotation of fine (1-16 um) pyrochlore of two types of water used at the Niobec concentrator, potable and plant recycle, were assessed. Several pyrochlore collectors and silicate depressants were tested. Water effects were different for each mineral-reagents) combination. In general plant recycle water decreased selectivity and increased reagent consumption. Interpretation of results is given in terms of electrokinetic effects, hydrolysis of cations, and mineral-collector interactions. Two techniques of treatment for plant recycle water, cation precipitation and zeolite adsorption were assessed. The former was found to be more effective under the tested conditions but recycle water continued to give poorer selectivity than the potable.INTRODUCTIONWater quality plays an important role in selective flotation. Specific effects have been reported by many workers (1-6) and in general the better the water quality the more selective is flotation. Water composition depends on origin and the minerals being processed. For example pulp containing salt-type minerals (calcite, apatite, dolomite) will contain more Ca and Mg cations than that from a sulphide deposit. Another source of water contamination is the flotation reagents added to the pulp, particularly if water recycling is practiced."

Jan 1, 1986

By Filipe Beretta

This study investigates geophysical logging capacity to predict coal quality. It was analyzed for possible correlation, some parameters determined via laboratory analysis of coal against results for the same parameter derived from wireline logs recorded by a geophysical probe. These probes detect variations in some rock physical properties, such as their natural gamma ray emissions and electrical resistivity. Results showed a strong correlation between natural gamma and ash content, establishing a linear model to estimate ash content from geophysical logging data with a low estimation error (less than 5%). Besides, results showed that there is no correlation between sulphur content or volatile matter and resistivity, neither with natural gamma of the rocks. Ash content derived from gamma ray values can be used as secondary information to evaluate coal quality during resources estimation, using methods such as soft indicator kriging. The methodology is illustrated using a case study at a coal deposit in south of Brazil.

Oct 1, 2009

By Erica J. Wanless, Ghislain Bournival, Seher Ata, Jose Hamilton Tavares

In froth flotation valuable particles are captured by bubbles and transferred to a froth layer where bubbles are in close proximity. Bubble coalescence frequently occurs in flotation, especially in the froth layer. The coalescence of two bubbles causes a release of energy, which may expel particles from the bubble surface. A series of experiments were carried out to determine the effect of bubble interfacial properties on the detachment of particles upon the coalescence of capillary-held bubbles of 2 mm in size. The interfacial properties of the bubbles were changed by the addition of low molecular weight alcohols, namely 1-pentanol or methyl isobutyl carbinol (MIBC). Using esterified glass particles (? = 43 °) with a 10 % and 90 % cumulative passing diameter of 47.2 and 92.5 µm, respectively, as model particles, it was found a certain concentration of frother, different for each additive, is needed in order to observe a reduction in the detachment of particles. In the presence of frother, the detachment was evaluated at approximately 65 % which was a considerable reduction in the detachment compared with the value of approximately 85 % found in the absence of frother. Frother molecules changed the properties of the airwater interface. Upon the coalescence of two bubbles, the release of energy caused the merged bubble to oscillate; effectively resulting in the detachment of particles. The addition of frothing agents augmented the elasticity of the bubbles, which appeared to be related to the detachment of particles. Whereas frothing agents are generally used to prevent bubble coalescence and stabilise the froth phase, only transient stability is imparted. The results suggested that an additional role of frothers in flotation is to decrease the detachment of particles from bubble surfaces. The type and concentration of frother can be strategically selected to improve metallurgical recovery as an economic incentive.

Jan 1, 2016

By A. Glover

As the demand for natural gas as a prime global energy source continues to grow, the search for new sources of the fuel spreads into geographical areas that are more remote from the marketplace. Along with this comes the need for longer and ever more efficient pipelines. This requirement for higher value in natural gas transportation is satisfied to a large extent through the application of high strength technology and innovative design approaches that support increased design and operating pressures. This paper reviews the latest accomplishments and successes in these technologies for use in gas transmission. It also explores some of the technologies which are targeted for the future to allow the industry to achieve even higher benchmarks in reliability and cost-effectiveness. The central element in the theme of high strength technology for gas pipelines is that of high strength steel. From tensile strengths of Grade 359 a few decades ago, more and more operators are now specifying Grade 550 linepipe for their large diameter projects. As well, Grade 690 steel is operating successfully in limited transmission applications and Grade 825 has recently been installed. With the introduction of the latest high strength pipe comes the need for high strength fittings. The industry's first Grade 550 fittings were recently specified and installed on a project with Grade 825 line pipe. High strength materials can only be implemented successfully if compatible design and construction processes are in place. The latest developments in strain- and reliability based design will be described as well as the corresponding advancements in welding and inspection technology.

Jan 1, 2005

By R. G. Zaripova, N. D. Ryan, H. J. McQueen

The austenitic and ferritic stainless steels do not undergo any phase transformation that induces very fine grains in the product through thermomechanical processing as practiced in most other steels. Considerable grain refinement can be achieved by intense multistage deformation descending through warm to cold working; notably multi-axial forging of bulk material can attain high strains with diminished risk of cracking. Hot working to improve ductility yields finer grain sizes as the T is reduced and strain rate E raised; increased strain has limited effect due to the steady state regime. Ferritic steels develop subgrains with size diminishing as E rises and T falls with the advantage of retained strain hardening; recrystallization delivers grains several times the cell size. In austenitic steels, dynamic recrystallization (DRX) provides finer grains at higher E and lower T with a lower limit due to intergranular cracking. The DRX grains contain a strengthening substructure that can easily be retained by quenching; if static recrystallization is allowed to occur the grain size rises markedly. Multistage rolling with diminishing T is able to provide grain refinement to the same degree as straining at the finishing T yet provides better ductility. grains on recrystallization. As a result of the strain induced transformation to martensite, small subzero deformations of austenitic or duplex steels produce very high dislocation densities that yield marked grain refinement when they revert upon reheating.

Jan 1, 2004

By R. K. Sidhu, N. L. Richards, M. C. Chaturvedi

Nickel base superalloy IN-738LC, strengthened mainly by the precipitation of y' phase, is extensively used in hot sections of land-based and aero gas turbine engines. Fusion welding, which is one of the most commonly used joining techniques for the repair and fabrication of superalloy components, however, finds a very limited application in case of IN-738LC components, as the alloy suffers from HAZ cracking during welding and during subsequent postweld heat treatment (PWHT). The present paper reports on the two methods studied to reduce the HAZ cracking in as-welded and postweld heat treated GTA welded IN-738LC, viz., the use of various fillers during welding, and the use of appropriate heat treatments prior to welding. The results of the microstructural analysis and crack measurements indicated that the HAZ cracking in GTA welds of IN-738LC was significantly reduced by using age-hardenable fillers with Al+Ti concentration less than that in the base metal in conjunction with a preweld heat treatment developed by the authors.

Jan 1, 2006

By Burrows. A.

Temperature profiles in the lead smelter sinter bed at Xstrata Zinc Mount Isa sinter plant have been measured using a wireless temperature probe. Corresponding sinter samples have been collected for characterization. The sinter peak bed temperatures were found to be in the range of 1000 - 1200 °C. Microstructures and softening temperatures of these sinters have been characterised. Strong correlations have been observed between peak bed temperature and peak hood temperature, and between mean sinter softening temperature and peak bed temperature. It was found that higher peak bed temperature results in higher sinter softening temperature. For the feed material used in the trials, to obtain sinters with mean softening temperatures above 1050 °C, peak bed temperatures above 1130 °C are required. There appears to be a direct correlation between granule size distribution in the feed and peak bed temperature attained. High peak bed temperatures are observed in sinters with narrow granule size distribution.

Jan 1, 2008

By B. D. Thompson

Many mines adopt necessarily conservative backfilling strategies due to a lack of understanding of their backfill behaviour. In the past five years, extensive instrumentation campaigns have focused on measuring in-situ cemented paste backfill behaviour. These tests have resulted in optimised backfilling efficiency through elimination or reduction of cure periods where; i) controls on backfill behaviour are understood, and ii) barricade pressures are demonstrated to be within a safe range using routine monitoring as a required QA/QC procedure. Recently, this work has been extended to consider hydraulic backfill operations. Two stopes have been instrumented at Vale?s Coleman and Garson Ramp mines. The instrumentation and deployment methods are discussed, and representative total earth pressure, pore pressure, and temperature data are presented. In one case, pressures in the stope are relatively low as drainage causes strength gain in the fill and so pressures are arched. In a second example, again, drainage causes strength gain in the fill, but increasing temperatures correlate with pressure increases even during downtimes in filling. These pressure increases are thought to be caused by thermal expansion of the backfill in confined locations. Generally, the instrumentation approach has proven successful in measuring hydraulic backfill behaviour and offers good potential for incorporation into a procedure to safely maximise backfilling efficiency through routine barricade pressure monitoring, when combined with safeguards to ensure adequate fill drainage.

Aug 1, 2013

To determine the optimal circuit configuration for gravity gold recovery consideration should be given to a range of factors in addition to the efficiency of the gravity circuit, including capital costs, ease of operation and impact on comminution. The most common gravity gold circuits utilise a centrifugal concentrator treating a portion of the hydrocyclone underflow. This paper will examine this option and alternative circuit configurations to illustrate the effect of various gravity circuit feed and tailings configurations on the equipment sizing, capital costs, operating costs, water balance, comminution efficiency and gravity gold recovery. The optimum circuit configuration can provide reduced capital and operating costs, maximise gravity gold recovery and improve comminution efficiency.

Jan 1, 2011