Search Documents

By Stanley Lefond

The health of the industrial minerals industry appears to be improving year by year. In fact, preliminary information suggests that only three commodities (asbestos, bromine, and sulfur-other) failed to show a production gain in 1984 over 1983. In 1983, 10 commodities failed to post gains and six remained constant. The total value of industrial mineral production in 1984 was $16.7 billion, up $1.4 billion from 1983. Cement, clays, gypsum, and crushed stone production increased. Since these are used in housing and construction, this suggests these industries are moving out of their recent doldrums. Barite and clay production also improved in 1984. Local US barite production, however, still has a long way to go to attain the 1981 high of 2.6 Mt (2.9 million st). Barite imports remain high. But they are not as high as the 1982 importation of 2 Mt (2.3 million st). Bentonite production in 1984 increased 20% in volume and 25% in value over the previous year. This suggests improvement in the drilling industry and an increase in demand for iron ore pelletizing grades. All in all, the industrial mineral industry is alive and well. And it shows signs of great improvement in the next few years. Many thanks to those industrial mineral technical committee members for their assistance in assembling this industrial minerals review: M. F. Dibble, H. W. Allen, G. H. Gallup, S. G. Ampian, D. W. L. Spry, H. G. Fleshman, and L. J. Czel.

Jan 5, 1985

By L. L. Oden

The Bureau of Mines analyzed vapor-aluminum-diffused stainless steels prior to conducting corrosion measurements in severely sulfidizing environments. These studies were conducted in response to the national need to better control the environmental and economic costs of corrosion. Specimens of a ferritic alloy and austenitic alloys types 316 and 310 were treated by a proprietary vapor-aluminum diffusion process and a dual vapor-aluminum diffusion process. Weights and dimensions were recorded before and after treatment, and comprehensive metallographic, X-ray, and electron micro-probe analyses were conducted for both single-and dual-vapor-aluminum-diffused specimens. Surface aluminum concentrations ranged from 26 to 34 wt-pct for all alloys. Dual treatment increased the quantity of aluminum per unit area by a factor of 2 and increased the depth of penetration by a factor of 3. The aluminum-diffused region of the ferritic alloy was single-phase aFe solid solution that was ordered on the surface, whereas two distinct diffusion layers were ob-served on the austenitic alloys. The outer layer comprised aFe solid solution that was ordered on the surface, and the inner layer was a two-phase mixture of aFe solid solution and the interrnetallic compound AINi.

Jan 1, 1982

"The Antamina orebody is a geologically complex, polymetallic skarn located in the Peruvian Andes. A range of copper and copperzinc ores are campaigned separately through the concentrator producing copper and zinc concentrates as well as lead and molybdenum by-products.Ore type classification at Antamina is based on chemical assays; geological or lithological variations are not considered. Consequently, each ore type demonstrates a wide range of concentrator performance.Antamina is currently implementing a system to track ore movements from the shovel face to the concentrator. Relatively sophisticated models of run-of-mine and coarse ore stockpiles ahead of the mill will be used to account for the variable delay between mining and milling.One of the numerous benefits of ore tracking is the ability to directly associate the measured concentrator performance with a physical location in the orebody. Using existing mine planning software, three-dimensional models can be created of such performance measures as metal recovery, concentrate quality, operating cost, and reagent consumption.Such a database of information allows the true value of different ore sources to be determined. The value of an ore source is conventionally measured as metal content (individual or combined ‘equivalent’) with a cut-off grade applied to indicate some base level operating cost. However, the true value of an ore source should include dynamic factors like haulage cost, reagent use, smelter penalties, and even prevailing metal prices. If an ore source is considered from all perspectives rather than simply its potential to deliver value, the concept of ore becomes more flexible. Any ore source that reveals itself to be unprofitable can be eliminated from the mine plan or possibly blended with others to improve its value. The ability to predict mill performance, and thereby profitability, is a powerful tool.In an operation such as Antamina, where managing ore sources, campaigns, and the delivery of a variety of concentrates in a narrow timeline to customers is a daily challenge, prediction is the key to success and improved efficiency."

Jan 1, 2005

By Wilhelm Borchers

IN all special branches of the chemical and metallurgical industries, in which large electric furnaces became necessary for carrying out new processes or for the improvement of old ones, the development of the electric furnaces took place on much the same lines. The endeavors to make a success of a new idea brought forth many ingenious designs, which, however, almost without exception, furnished the proof that the safest and shortest way to practical success is the utmost simplicity of construction of the necessary apparatus. Our knowledge of the qualities of materials for building electric furnaces and of the constituents of the furnace-charges, especially their electric conductivity and their chemical affinity . towards one another at high temperatures, is still far from being complete, and from this fact we must conclude that the smaller the number of elements in the construction of a furnace, the fewer the number of unreliable factors both in the construction and in the operation of the electric furnace. This conclusion deserves special attention when an electric furnace for making steel has to be chosen from the constantly growing number of inventions, inasmuch as the chief con¬stituent of steel, the element iron, is a substance which in its liquid phase has so great an affinity fir those elements which are to be removed from the charge, that it is very difficult to comply with the following conditions: 1, to beat the refining-slag to the highest point of its chemical activity ; to prevent the iron from entering the slaw, or, where this cannot be done, to make it enter so that it finally appears in the end-product

Jan 1, 1910

The Chamber of Minerals and Energy of Western Australia Inc (CME) is the peak resources sector representative body in Western Australia. The paper gives a summary of the role and objectives of the CME, including its history, structure and key program areas. Particular attention is given to the role of the CME in the Eastern Goldfields of Western Australia. The paper details the types of CME membership that are currently in existence. The paper argues that a strong and vibrant CME is vital to secure the resources sectorÆs growth and development in future years.

Jan 1, 2006

By D. Toporov, R. Abraham

"Gasification is a process of thermal conversion of solid carbonaceous materials into a gaseous fuel called syngas. Coal gasification is an efficient technology for a range of systems for producing low-emission electricity and other high-value products such as chemicals, synthetic fuels, etc.The paper presents the High-Temperature Winkler (HTW) gasification process, which is designed to utilize low-rank feedstock such as coals with high ash content, lignite, biomass etc. The process is characterized by a bubbling fluidized bed, where coal devolatilization and partial oxidation and gasification of coal char and volatiles take place, and by a freeboard where partial combustion and gasification of coal char take place.The recent development of the high-pressure HTW process is reviewed. Gasification of low-rank, high-ash coals with respect to gasification temperatures, conversion rates, and syngas quality is also discussed. The main HTW design steps required for an industrial-scale design are presented. Special attention is given to the process modelling, including global thermodynamic calculation as well as detailed CFD-based simulation of a reacting fluidized bed. Three-dimensional numerical results of the HTW process are also provided and discussed."

Jan 1, 2015

By Malcolm Ross

Fibrous minerals are common in nature but asbestiform minerals are rare. The unique mineralogical characteristic common to all the asbestos minerals is their morphologic form (or habit of crystallization) as polyfilamentous fiber bundles. The individual fibrils within the bundles have a tendency to be very long with a narrow range of diameters and grow with their long fiber axis in parallel orientation to the bundle length. The asbestiform habit imparts to the asbestos minerals sufficient flexibility and tensile strength so that most can be woven into cloth. In the past application has focused on their ability to insulate against the transfer of heat. However, these minerals possess other properties which make them useful in many industrial applications. © 2007 Elsevier Inc. All rights reserved. Keywords: Asbestos; Asbestiform; Fibrous

Jan 1, 2007

By J. Spotts McDowell

Ackowledgments........................... 5 Introduction............................. 5 The Silica Minerals. Stability Relations......................... 6 Optical Properties........................ 9 Density.............................. 10 Melting Points....;..................... 10 Thermal Expansion..................,..... 10 Solubilities............................ 12 Identification of Cristobalite and Tridymite.............. 12. The Silica Refractories. Raw Materia1........................... 13 American Deposits....................... 13 Properties Determining Usability................ 15 Expansion on Heating..................... 16 Texture........................... 17 Silica Brick............................ 17 Manufacture........................... 18 Properties of Silica Brick .................... 19 Analysis ......................... 19 Density......................... 19 Porosity......................... 20 Strength....................... 21 Melting Point....................... 22 Specific Heat....................... 22 Thermal Conductivity................... 23 Expansion........................ 24 Effect of Rapid Temperature Change.........:... 26 Constitution......................... 26

Jan 1, 1918

By Edward Judd

CANADA'S mining industry is rapidly recovering from the depression through which it passed in 1921. Its total output of $183,029,600 in 1922 was 6.4 per cent. greater than that of 1921, and was exceeded by only three previous years, 1917, 1918, and 1920. Table 1 compares the output of a few of 'the more important items selected from preliminary data published' by the Dominion Bureau of Statistics. TABLE 1.-OUTPUT OF CERTAIN MINERAL PRODUCTS IN CANADA PER CENT. 1921 1922 CHANGE Cobalt, metal and in compounds, lb 252,000 443,800 +76.1; Copper contents of blister, matte, and exported ores, lb 47,620,820 43,321,400 - 9.0 Refined copper, lb 4,286,000 730,000 -83.0 Gold, fine oz 926,329 1,230,985 +32.8 Pig iron, sh. tons 665,676 429,024 -35.5 Lead, sh. tons 33,340 47,085 +41.2 Nickel contents of matte, etc., lb. 19,293,060 17,496,490 - 9.3 Silver, including that in base bullion, gold bullion, etc., fine, oz. 13,543,198 17,611,646 +30.0 Zinc (nearly all refined), sh. tons. 26,545 28,199 + 6.2 Asbestos shipments, sh. tons 92,761 136,657 +47.3 Coal, all grades, sh. tons 15,057,500 15,045,300 Gypsum shipments, sh. tons 386,550 441,160 +14.1 Natural gas, M. cu. ft 14,077,600 14,954,100 + 6.2 Petroleum, bbl : 187,540 178,570 - 4.8 Cement, bbl 5,752,885 6,943,968 +21.0 Brick, structural, all kinds, M. , , 109,009 127,137 +17.0 On the basis of estimated market values, the whole output of 1922 was contributed as follows: Metals, 33.4 per cent.; non-metallic minerals, 45.1 per cent.; structural materials and clay products, 21.5 percent.; this distribution indicates a return of the metal mining. industry nearly to the position of relative importance that it occupied. before 1921, in which year metals contributed only 28.7 per cent. to the total value. of output while non-metallics gave 51.1 per cent. Canadian cobalt originates entirely in the ores of the Cobalt district, which are mainly treated at smelters in southern Ontario, although some quantities of residues have been exported to England and Europe. Exports during 1922 increased even more than production, consisting of about four-fifths . cobalt oxides and salts, and one-fifth of cobalt alloys and other metal combinations.

Jan 8, 1923

By WILLARD W. CUTLER

This bulletin reviews, in the light of recent experience, the use of production-decline curves in estimating the future production of oil from wells. It deals with the estimation of the reserves of recoverable oil in properties already producing or in those adjacent to them, takes cognizance of the physical laws governing expulsion of oil from oil sands, and shows how the production-decline curve can be made to utilize these laws in estimating reserves and rates of production. The valuation of oil properties should be based on the total amount of oil recoverable from a property by the methods in use, the rate of recovery, the cost of production, and the selling price. Numerous other curves besides those for reserves and rates of production may be formed from the production-decline curve and will present desired information in a convenient time-saving form. These curves also are described. Methods developed before the production-decline curve method was used are briefly discussed in order that the principles on which estimations of oil reserves are based may be made plain. The construction of curves and tables for estimating future production of individual wells and of average wells in most of the important oil districts of the United States is described and operating problems that may be solved by the use of production-decline curves are discussed. The bulletin does not deal with costs, oil prices, or the methods of evaluating oil properties. Many engineers have amply demonstrated the value of the production- decline curve method by forecasting within reasonable limits the production of many thousands of wells and tracts. The value of similar estimates depends however, on (1) the application of trustworthy methods; (2) the care and judgment of the estimator; and (3) the length and reliability of the records and the accuracy of ofher information used in estimating future production. When adequate records and information are available, experience has shown that It qualified engineer can forecast production far more accurately than has been deemed possible, except where the usual conditions governing the expulsion of oil from a sand have been radically changed by applying compressed air or by flooding with water, or, to a less degree, by using vacuum. In general, the production-decline curve method, though there are limits to its accuracy, is far more trustworthy than any other.

Jan 1, 1924

By S. Bastola, Y. P. Chugh

"This research determines shear strength and stiffness properties of bedding planes and joints in the roof strata rocks within 7.5 to 9 m (25-30 ft.) overlying the Illinois #6 coal seam (within the pressure arch zone). A shear test loading device was designed into a 1.334 kN (150 t) Forney Compression Loading Machine to perform direct shear tests in accordance with ASTM D5607-08 “Standard Test Method for Performing Laboratory Direct Shear Strength Tests of Rock Specimens under Constant Normal Force”. The data were used to determine peak and residual friction angles and the dilation angle. A total of 49 bedding plane samples were tested, out of which 46 (36 intact and 10 relatively weak and loose) samples passed QA/QC procedures in accordance to ASTM D5607. Samples from eight (8) different bedding planes- shale/limestone (SL), shale/sandstone (SSs), shale/bone (SB), laminated sandstone (LS), shale/shale (SS), bone/bone (BB), bone/limestone (BL), and limestone/limestone (LL) were tested. The number of samples tested for each bedding plane were: SL- 11, SSs- 8, SB- 5, BB- 4, LS- 6, SS- 9, BL- 1, and LL- 2. Peak and residual shear strength values at 2.75 MPa normal stress range 1.06 – 6.26 MPa and 0.82 MPa to 0.82 – 4.14 MPa, respectively. The average normal and shear stiffness values are about 11.98 GPa/m and 3.11 GPa/m. Dilation angles are low (<10?) and negative in some cases. Angle of sliding friction values range from 9? to 42?. Joint Roughness Coefficient (JRC) values were less than 10.INTRODUCTIONRock mass may be defined as the total in situ rock medium containing bedding planes, faults, joints, folds and other structural features. Therefore, it is discontinuous and may have heterogeneous and anisotropic engineering properties. Upon creation of an excavation in a rock mass, bedding planes and joints are the most likely points of failure initiation. The failure typically occurs either in tensile or shear mode. Upon failure initiation stresses are transferred to the neighboring rock mass and the failure progresses until stability is achieved through equilibrium of stresses and strength. An example of this mechanism is development of the pressure arch. This study determined the shear strength and stiffness properties in shear and compression of bedding planes and joints in the immediate roof strata rocks within 7.5-9 m ( 25-30 ft.) overlying the Illinois No. 6 coal seam (within the pressure arch zone). Since such data are currently not available for Illinois Coal Basin mines, researchers and engineers have been using estimated values for design purposes. The immediate roof lithology in the proposed mining area consists of shale 0.62 m; Bone 0.09 m (0.3 ft.); Limestone, 0.10 m (0.33 ft.); Shale 2.37 m (7.9 ft.); and sandstone 0.55 m (1.83 ft.). The bedding plane samples were provided by a mine in south-eastern Illinois operating at a depth of about 180 m (600 ft.)."

Jan 1, 2015

By Robert Linton

AT its meeting on May 21, the Board of Directors approved the recommendations submitted by President Lovejoy and named a nominating committee for the year that is especially well distributed as to major technical interest and as to geography. As may be seen from the list published herewith, two come from the East, two from the Midwest, and three from the far West. Mr. Linton, the chairman, has been a valued member of the Institute for 36 years. A memorandum drawn up by Paul D. Merica, representing the A.I.M.E., and W. R. Barclay, representing The Institute of Metals of Great Britain, setting forth a reciprocal plan for special memberships in each Institute for members of the other, was discussed. Both societies already have formally approved the plan in principle and Dr. Merica was clothed with full authority to agree on a few small details that have not been settled, and conclude the arrangement in behalf of the Institute.

Jan 1, 1936

By D Blair, T Scutts, L Fergusson

This paper presents a waste rock treatment and rehabilitation program conducted at a metaliferous mine site in northern New South Wales from 2000–2013. It updates findings from 2005 for Program #1 (which examined acidity, leachable metals and tree growth in a control and three treated areas of waste rock) and includes new results for Program #2 (which examined acidity, plant uptake of metals and trace elements and tree growth in a control and four treated areas compared to undisturbed background levels) and Program?#3 (which examined the treatment and revegetation of submerged mine tailings and an exposed tailings beach).Program #1 showed low soil pH in the control area remained unchanged from years 1–14, and soil pH in the limed and capped areas was initially increased but fell back to starting levels within 12 months and remained low for 14 years. In contrast, soil pH in the Terra B area resulted in soil high pH immediately after treatment and increased in years six and 14 without further treatment. Tree height and density in 2005 and again in 2013 indicated acidity in the control, limed and capped areas suppressed tree height and density; however, in the Terra B area, revegetation in 2013 was comparable to undisturbed forest. Outcomes in the control, biosolids and three Terra B areas in Program #2 were similar to those observed in Program #1.Program #3 showed the submerged and exposed tailings initially had low pH and high concentrations of total and leachable metals before treatment, but these became non-leachable after treatment with Terra B. Revegetation was achieved on the tailings beach, with almost uniform colonisation of bulrush and common reed, along with bottlebrush and golden wattle; a variety of reptiles have also been observed on the revegetated tailings beach, along with migrating ducks, spoonbills and grebes.CITATION:Fergusson, L, Blair, D and Scutts, T, ?2014. Treatment and rehabilitation of acidic waste rock and tailings – a 14-year case study, in Proceedings Life-of-Mine 2014 , pp 247–260 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 16, 2014

By Paul Clark

Generation - Profile l 9,726 megawatts (MW) of capacity l 46,877 gigawatt hours (GWh) produced at an average plant availability of 88.4% l 47 facilities in four geographies: Canada; the U.S.; Mexico; and Australia l Fuel mix of coal (62%), gas (26%), hydro and renewables (12%) l 23.2 million tonnes of coal mined l 47.0 million gigajoules (GJ) of gas consumed

May 1, 2004

By A. V. Roschin, N. V. Malkov, V. N. Karnoukhov, V. E. Roschin

Reduction interactions in solid phases are widespread and occur in most complex metallurgical processes. Among these processes, reactions between oxides and carbon have a special importance. The authors conducted experiments for comparison of reduction by different reducing agents of impregnated chromite ores, in which grains of the reducible chromite spinel are isolated from direct contact with the reducing agent by layers of non-ore material. The results of the experiments have revealed that the beginning of reduction is preceded by thermal and impurity order-disorder transformation of the oxide lattice whilst the transformation of the oxide lattice into the metal lattice takes place as a result of removal of oxygen anions from the zone of metal germ nucleation. Since anions are charge carriers, increase of their mobility can be monitored by changes in electrical conductivity of oxides. Respective measurements of electrical resistance of ores of different metals and a number of pure refractory oxides under heating have indicated that the beginning of reduction coincides with the time of drastic (tens of thousands times) increase of conductivity of the oxides. Besides, the temperature of the beginning of carbon-thermal reduction is in line with the Tammann temperature, i.e. the temperature of transition from the predominantly surface diffusion to volume diffusion. Segregation of metals from the oxide lattice occurs as a result of merging of anion vacancies with defect electrons on defects of the oxide lattice. The transformation of the oxide lattice into the metal lattice requires a certain concentration of anion vacancies and inflow of electrons from the reducing agent to the site of metal segregation. Such inflow has no difficulties due to the mixed anion-electron nature of high-temperature conductivity of oxides. Thus, the reduction is not determined by oxygen diffusion, it is determined by oxygen vacancies diffusion whose speed exceeds the speed of oxygen diffusion by orders of magnitude. This determines that the kinetics of reduction considerably exceeds the kinetics of oxidation at similar temperatures since oxidation proceeds by means of mass transfer of oxygen through the layer of the generated oxide.

Jan 1, 2004

By P B. Hills, R J. Walton

Geotechnical instrumentation has been implemented as a key step for monitoring and optimising an engineered mine design for managing seismicity at the Beaconsfield Gold Mine. Measurements of displacement, stress change, ground control element load and seismic response of the rock mass allow for back analysis and calibration of critical parameters for feedback into the engineering design loop. Instrument clusters are installed in strategic locations prior to the commencement of stoping in order to determine the nature of the response of the rock mass to stoping. A selection of instruments including instrumented cable bolts and rod extensometers, resistance wire extensometers, hollow inclusion stress cells, vibrating wire stress meters and resistance wire extensometers are used to gather data through a data logging system. The rate at which data is recorded is adjusted to provide more information during periods of anticipated rapid change such as around stope firings or during periods of high seismic activity, and less information during periods of anticipated quiescence. The twofold purpose of the instrumentation is to calibrate the numerical modelling output which forms the basis of the engineered mine design, and to provide an alert mechanism where the behaviour of the rock mass is not what was anticipated, or where the impact of that behaviour may compromise the integrity of the engineered ground control system. The paper describes the location of instrument clusters with respect to stoping, the type of instruments employed and the method of data acquisition. It provides examples of results obtained and illustrates the way in which that information is used to optimise the mine design and manage seismicity.

Jan 1, 2008

By Peter Makuvise, Alain M. Bantshi

"The Mazowe Gold Mine is managed by Metallon Gold (Zimbabwe) and is situated in the west-central part of the Harare greenstone belt. Orebodies here generally comprise shear zones which are in-filled with gold-bearing sulphides and quartz. The mineralised zones are up to 1 m in width, have average grades of 4 to 5 g/t, and mostly dip between 10º and 60º to the north.Mazowe Mine is one of the oldest mines in Zimbabwe, and exploration and development in this region dates back to 1890, with over 1.4 million ounces of gold produced to date. Mazowe mine comprises two underground operations, Mazowe and the BSV sections. Ore is processed in a single plant which consists of conventional crushing and milling and carbon-in-leach facility.Baldmin Projects was awarded the contract for the design, construction and commissioning of the 60,000 tonnes per month plant at Mazowe mine in 2014 for the processing of sand and slimes tailings from previous operations at Mazowe mine. The average grade of the tailings is 1.1 g/t. The plant consists of feed preparation, grinding, flotation, thickening of flotation concentrate, and carbon in leach (CIL). A pump station for hydraulic mining of the slimes tailings dam also part of the plant.Key features of the Mazowe sands Plant are described and include:• Hydraulic mining of gold tailings dump.• Feed preparation section that includes a (W x L) 2.4 m wide x 4.8 m trash screen, 250 m3 surge tank, a cluster cyclones with 2 x 500 mm diam. Cyclone.• Comminution circuit designed for a bond work index range of 10-12 kwh/tonne. comminution circuit is constituted with 3 ball mills, 1.83 m diam. X 6.71 m Long, 280 kW.• Flotation circuit comprising rougher bank, scavenger bank and cleaner bank. Rougher Scavenger bank is constituted of 6 x 6m3 flotation cells and 3 x 30 m3 flotation cells and the cleaner is constituted of 3 x 6 m3 flotation cells.• Concentrate Thickening with 6 m diam. Thickener.• Concentrate CIL (carbon in leaching): CIL circuit is comprised of 7 tanks with 2 leach tanks and 5 Carbon in leach."

Jan 1, 2017

By Lijun Xu, Jan M. Mutmansky

"Mutmansky, J.M. and· Lijun Xu, 1989. Some observations on particulates collected in underground coal mines using diesel and non-diesel equipment. Min. Sci. Technol., 9: 207-218.The results obtained when sampling twenty underground coal mine sections, each in a different mine, are outlined. The sampling effort was oriented toward a detailed characterization of coal mine dusts and thus eight-stage Anderson Model 298 impactors were used as the primary collection instrument. This instrument allowed a fairly detailed size distribution for each of the particulates sampled. Because four of the mines used diesel outby equipment and/or diesel shuttle cars at the face, it is possible to make some comparisons of the particulate distributions in diesel versus non-diesel mines.One of the more interesting results is the pattern that exists in mines lising diesels only for outby utility haulage. Particulates in these mines seem to be consistently heavy in the fine size ranges, perhaps being of significant concern to the industry. While no definite conclusions can be drawn from the limited data, a more detailed study of particulates may provide a better picture of particulate loadings.IntroductionThe subject of particulate emiss1ons from underground diesel equipment is currently a very important topic as health concerns and regulation of diesel particulate emissions have created new environmental problems for mine operators. The amount of particulate matter originating from diesels has not been extensively measured and problems of differentiating coal and mineral dust from diesel particulates make existing data questionable.However, it is necessary to make an assessment of the problem in order to solve it. It is known that particulates from diesel engines are solid aerosols formed in the combustion process. Technically, this places the particles in the category of fumes. It is also known from tests where no mineral dust could be a factor in the measurements that about 90% of diesel particles are less than 1 µm in aerodynamic diameter [3]. To measure the diesel component of a coal/diesel particulate to measure, Johnson et al. [2] have developed procedures for utilizing laser Raman spectroscopy. The determination of diesel content in a coal/diesel mixture is difficult due to the chemical similarity of the two organic materials. However, laser Raman spectroscopy, which is often used for identification of organic materials, has potential if the Raman spectra for the two materials are different and unique. The study concluded that an accuracy of ±~% could be achieved for mixtures containing up to 55% diesel particulate. The method is relatively complex and would need further development for routine application."

Jan 1, 1990

By W. S. Holt, E. T. Tkac, R. A. Grange

QUANTITATIVE knowledge of the time element involved in austenite transformation in a particular steel provides a sound basis for understanding and planning heat-treatment. Such knowledge is conveniently obtained by measurement of austenite transformation as it occurs at each of a series of temperature levels. The results of these measurements usually are summarized in the form of the now familiar isothermal transformation diagram (I-T diagram, TTT diagram, or S-curve). Although a considerable number of such diagrams already have appeared in the literature, there remain many compositions of commercial importance for which no I-T diagram is available. The diagram for many such steels may be predicted from published data with sufficient accuracy for most practical purposes, but for others no satisfactory prediction can be made because the effect on austenite transformation of one or more of the important alloying elements present is not well enough known. Such a steel is Nitralloy, Type 135-Modified, which, containing about 1.25 per cent aluminum, differs from any whose I-T diagram has been published. This paper presents results of a study of the isothermal transformation behavior of a sample from a commercial heat of this aluminum-chromium-molybdenum steel, together with pertinent supplementary data including the equilibrium transformation temperatures (Ae3 and Ae1), the temperature range of martensite formation, and the end-quench hardenability. These data are directly applicable to the heat-treatment of this type of steel and are of interest in revealing some of the fundamental effects of aluminum as an alloying element in steel. MATERIAL All specimens were prepared from a 13-in. diam bar forged from a 5 by 5-in. billet from a commercial heat made in an electric arc furnace. The composition of the bar was; C, 0.41 per cent: Mn, 0.57: P, 0.016: S, 0.005: Si, 0.24: Ni, 0.17: Cr, i.57: MO, 0.36: Al, 1.26. The forged bar was normalized from 1750°F (955°C) and then tempered for one hour at 1200°F (650°C), this tempering treatment having been given to facilitate the machining of specimens. EQUILIBRIUM TRANSFORMATION TEMPERATURES In hypoeutectoid steel the minimum temperature at which austenite is completely stable, Ae3, and the maximum temperature at which austenite is completely unstable, Ae1, are of great significance in heat-treatment. Since these temperatures are dependent upon com-

Jan 1, 1946

By F. C. Gennari, D. M. Pasquevich

With the gradual exhaustion of natural rutile, there has been extensive research into its synthesising from lower-grade titanium minerals. The removal of Fe from pseudobrookite (Fe2TiO5) by chlorination was studied, using both isothermal and non-isothermal thermogravimetric measurements. Correlation of the results obtained from element distribution maps, scanning electron microscopy, energy-dispersive X-ray analysis and phases detected by X-ray diffraction in the chlorinated samples showed clearly two associated processes. First, the pseudobrookite particles reacted with chlorine and iron was removed selectively as FeCl3(g), leaving a solid residue rich in the TiO2 phases anatile and rutile, separated from an inner layer of unreacted pseudobrookite by a distinct interphase boundary. Second, chlorine allowed TiCl4(g) to form in the reaction bed, where it removed iron from the Fe2O3 crystals as FeCl3(g) and substituted Ti through a pseudomorphic reaction

Jun 21, 1905