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By Matej Petružálek, Václav Vavrycuk, Tomáš Svitek, Tomáš Lokajícek

The most common type of waves used for probing anisotropy of rocks in laboratory is the direct P wave. Information potential of the measured P-wave velocity, however, is limited. In rocks displaying weak triclinic anisotropy, the P-wave velocity depends just on 15 linear combinations of 21 elastic parameters, called the weak-anisotropy parameters. In strong triclinic anisotropy, the P-wave velocity depends on the whole set of 21 elastic parameters, but inversion for 6 of them is ill-conditioned and these parameters are retrieved with a low accuracy. Therefore, in order to retrieve the complete elastic tensor accurately, velocities of S waves must also be measured and inverted. For this purpose, we developed a lab facility which allows the P- and S-wave ultrasonic sounding of spherical rock samples in 132 directions distributes regularly over the sphere. The velocities are measured using a pair of P-wave sensors with the transmitter and receiver polarized along the radial direction and using two pairs of S-wave sensors with the transmitter and receiver polarized tangentially to the spherical sample in mutually perpendicular directions. We present an inversion method for elastic parameters describing general triclinic anisotropy. We demonstrate on synthetic tests that the inversion becomes more robust and stable if the S-wave velocities are included. This applies even to the case when the velocity of the S waves is measured in a limited number of directions and with a significantly lower accuracy than that of the P wave. Finally, we analyze velocities measured on a rock sample from the Outokumpu deep drill hole, Finland, including the error analysis for several levels of confining pressure.

Jan 1, 2015

By Jim Cooney

Background ?1990s saw massive changes in South African mining industry ?over 100,000 jobs lost as the industry restructured; ?1999 ?Placer Dome purchased a 50% interest in South Deep (WAL), a mine located just outside Johannesburg ?This was the first major post-apartheid foreign investment in the South African mining industry The Situation ?Placer Dome decided to lay off 2560 mineworkers (one third of the workforce) from the South Deep Mine to restore the mine to economic viability. ?Unemployment in South Africa was over 25%, and the retrenched mineworkers had few skills with which to make a living. Policy Context ?Placer Dome was committed to: ?global corporate policy of Sustainable Development, ?demonstrating that its business contributes to the economic and social progress of host jurisdictions. ?Government of South Africa was committed to ?attracting foreign investment to its mining sector with a view to modernizing and enhancing its economic and social viability, ?ameliorating the negative social consequences of structural change without arresting the necessary process of restructuring. ?National Union of Mineworkers was committed to: ?working with the mining industry and the government in implementing a Code of Good Practice on Dismissals and a Social Plan to assist retrenched mineworkers (1999).

May 1, 2006

By B. Chambers, M. Yunovich

"Corrosion monitoring is commonly used in a variety of industries as a means of effective corrosion control programs to extend the life of the asset and ensure safe operation of the facilities. The majority of the monitoring tools have limitations and tradeoffs – e.g., sacrificing the longevity of the probe for higher measurement resolution. Linear polarization resistance (LPR) probes have the advantage of providing the operator with accurate, real-time corrosion rate data; however, the probes can only be deployed in conditions where the measured environment possesses certain minimal conductivity. In many instances, utilization of LPR probes in conditions with intermittent wetting (for example, conditions where the temperature fluctuates above and below the dew point) presents a challenge. To address this limitation, a special-design cooled corrosion probe has been developed, commercialized and integrated into the distributed control system in the plants. In addition to high-accuracy measurement of corrosion rates, the probe allows for monitoring of pitting corrosion. The most innovative feature of the probe is the cooling circuit, which brings the temperature of the sensors below the dew point, forcing precipitation of moisture and thus permitting corrosion measurements. Additionally, the probe was found to be well-suited for monitoring corrosion in crude distillation unit (CDU) overhead space, where condensation of hydrochloric acid may take place at relatively high temperatures, which would require relatively moderate amount of cooling to be imparted to the probe sensors. This paper presents laboratory-based data from a test simulating CDU refinery environment. A case study is presented to demonstrate how the cooling probe can be effectively used in the plants for corrosion monitoring.INTRODUCTIONConventional corrosion-monitoring techniques such as weight-loss coupons to assess corrosion damage are commonly used in plants1. However, the use of coupons is not only labor-intensive, but also does not deliver real-time corrosion data, thus effectively serving as a “backwards-looking” monitoring tool. Linear polarization resistance (LPR) probes have the advantage of providing the operator with accurate, real-time corrosion rate data; however, the probes can only be deployed in conditions where the measured environment possesses certain minimal conductivity."

Jan 1, 2012

In order to avoid impurity problem and enhance absorption/desorption kinetics of Mg-based compounds, nanostructured Mg-based compounds were synthesized from Mg, Ni and other elemental nanoparticles produced by hydrogen plasma-metal reaction. XRD and TEM results demonstrate that homogeneous nanostructured Mg-based compounds with less impurity were successfully synthesized by this method. DSC in hydrogen atmosphere, pressure-composition isotherm and the kinetics of hydrogen adsorption/desorption were investigated at different temperatures. The results show that the nanostructured Mg-based compounds can absorb hydrogen in a high speed at a low temperature.

Jan 1, 2005

By Gordon A. Irons, H. Y. Hwang

An impinging gas jet on a water surface was studied to understand momentum transfer in oxygen steelmaking. Depth, width and oscillation frequency of the jet cavity were measured and the splashes interpreted with Kelvin-Helmholtz instability and combined Rayleigh-Taylor and Kelvin-Helmholtz instability theory. A model to calculate separate gas and liquid velocities, applying the exact momentum boundary condition, is proposed.

Jan 1, 2004

By Madaah Hosseini H. R., P. Abachi, S. Miraghaei

In this study, the effects of milling time, chemical composition and heat treatment on microstructure and magnetic properties of nanocrystalline Fe-Si (6.5-25 at.% Si) alloys prepared by mechanical alloying have been investigated. The results show that increasing the milling time or the Si content, decreases the lattice parameter and increases the internal microstrain. The prepared powders mainly consist of micron-sized particles with an average grain size of less than 20 nm. The specific saturation magnetization values are slightly less than those of single crystal or conventional Fe-Si alloys and decrease as Si content increases. The coercive force values of the nanocrystalline as-milled powders are much higher than those of corresponding Fe-Si bulk alloys with a minimum at 13.5 at.% Si. The values of coercive force decreased after annealing but it seams that the residual strain developed during milling is not the major contributing factor to the higher values of coercive force in the mechanically alloyed powders and nanocrystals behave as single-domain particles without exchange interaction between them.

Jan 1, 2006

By P. Karimi, A. Amini, H. Abdollahi, A. Mirzaeian

Due to detrimental effects of cyanidation process on the environment in gold industry, application of cyanide alternatives such as thiourea are being highly considered in recent projects. In this study, the extraction of gold from poly metal ore, using thiourea was precisely investigated. The representative sample contained 2.5 ppm Au and 160 ppm Ag. The sample was categorized as oxide gold ore, because the main part of its pyrite was changed to iron oxide and hydroxide such as goethite and lepidocrosite. According to mineralogy, the main gangue mineral was quartz. It shows that gold grains are free and interlocked with quartz matrix. Also, the presence of a high amount of silver in free and sulfide forms and also the low content of other sulfide minerals such as base metal sulfides is a remarkable point of these studies. In the gold extraction process with thiourea, there are several parameters that affect the rate of gold dissolution such as concentrations of thiourea as a gold lixiviant and ferric sulfate as an oxidant, pH and size fraction of feed and leaching time. The influence of these parameters on the gold dissolution rate were investigated and optimized. The results showed that the concentration of thiourea is the most influential parameter which could increase the gold recovery to 71% (at 10 g/kg sample). The optimal amount of ferric sulfate was determined as 6 g/kg sample. Also, the optimal levels of size fraction of feed and pH of solution were 88% under 75 micron and 2 as acidity; respectively. Leaching time was 6 hrs. In addition, this sample was leached with cyanide and the optimized values of size fraction of d88=75 microns, pH=10.45, 2500 ppm of sodium cyanide with time leaching of 24 hours were concluded for maximum recovery of gold in solution. Finally, the results of cyanidation tests were compared to the thiourea dissolution after optimizing all affected parameters in cyanidation process.

Jan 1, 2016

By P. Nelson, B. Salt, J. A. Scott, H. Shang

ABSTRACT In a nickel smelting process, large amounts of off-gas emissions are generated, which can cause serious environmental and plant hygiene problems if not properly treated. With increasingly stringent environmental regulations, an enhanced understanding of well-controlled, off-gas cleaning systems is vital. In this paper, dynamic models for an industrial smelter, off-gas system tackling hazardous sulphur dioxide, carbon monoxide, and carbon dioxide are developed using mass continuity, momentum, and energy conservation laws. The effect of air in-leakage is explored under different operating conditions. The developed models provide an enhanced process understanding and a necessary basis for highperformance control analysis of smelter off-gas systems.

Jan 1, 2011

By J. Fellowes, Z. Liang, J. Robson, M. Kenyon

"Dispersoids play a significant role in the recrystallization and texture development for wrought Al-Mg-Si (6xxx series) alloys by inhibiting grain boundary motion. It is therefore important to understand the precipitation kinetics of such particles. It is the additions of Mn and Cr in Al-Mg-Si based systems that can lead to dispersoid phases being formed. These phases are currently thought to nucleate on ß’-Mg2Si via an intermediate semi-coherent precipitate. Scanning transmission electron microscopy (STEM) has been conducted to study the precipitation of a-Al(CrFe)Si and a’-AlCrSi dispersoids. Corresponding electron dispersive spectroscopy (EDS) has been used to distinguish the dispersoids. The volume fraction and size distribution of dispersoids has been measured as a function of distance across a grain. Electron probe microanalysis (EPMA) has been conducted to study the inhomogeneity of elements in the cast structure and the effect on dispersoid precipitation. Dispersoid free regions have been observed in the microstructure correlating to regions depleted in the dispersoid forming elements.INTRODUCTION Al-Mg-Si (6xxx series) based alloys are increasingly being used in the automotive industry. The primary reason is to reduce the weight of vehicles, resulting in a reduction of CO2 emissions and increased fuel efficiency. The demand for 6xxx series is predicted to increase over the coming decade. Due to the high cost and CO2 emissions produced by raw extraction of aluminium, close loop recycling of these alloys becomes a more important process. However recycling of automotive alloys can be difficult due to pick up of impurity elements such as Mn, Cr and Fe. The addition of these elements can form dispersoid particles during early heat treatment processes. Although a controlled population of dispersoids is necessary to control the grain structure during thermo-mechanical processing, a significant change to the dispersoid population due to a composition change could profoundly influence the final microstructure, affecting the final properties of the material. More research is required on the precipitation and effect of additional minor alloying elements; in order to increase the 6xxx series alloys recyclability."

Jan 1, 2018

By C. R. Kerr

"This paper describes the revisions to the heating and ventilating system at the Frood-Stobie mill, which resulted in substantial savings in energy costs.IntroductionInco Metals Company, a unit of Inco Limited, is involved in the mining and processing of nickel-copper ores. The Ontario Division of Inco Metals consists of 10 operating mines, with 5 mines and open pits on a standby basis, and 10 pro- cessing facilities, located in Sudbury, Port Colborne and Shebandowan. In 1980, the Ontario Division's energy expenditures amounted to $87,000,000.Due to the accelerating cost of energy, the Division established an Energy Management Program in 1975 to define, evaluate and implement measures to reduce energy cost and consumption per unit of output by 10% by 1980. This falls in line with the goals set by the mining and metallurgical task force on voluntary energy conservation.To effectively implement the program, Plant Committees were established at each plant and mine area, with an energy management coordinator appointed to coordinate the activities. The Plant Committee's responsibilities include identifying the major areas of energy consumption, isolating areas with large potential losses and determining what action should be taken to improve energy efficiency.Within a five-year period from 1975 to 1980, the Ontario Division has been able to cut its energy consumption by 8.9 trillion BTUs, the equivalent of 1.5 million barrels of oil."

Jan 1, 1981

By D. Bois, P. Keating, J. Lemieux, M. A. Vallée, M. Allard, R. S. Smith, L. Z. Cheng, M. Chouteau, D. K. Fountain

"Abstract - MEGATEMII airborne electromagnetic data collected over the Iso and New Insco massive sulfide deposits have been modeled using three modeling packages. The EMQ package is a quick inversion tool which indicates that the Iso body is a dipping, plate-like body. The New Insco body is inferred to have a geometry somewhere between a dipping plate and a sphere. The Maxwell package was used to refine the properties of the plate-like body at Iso. The EMIGMA package was able to identify which parts of the New Insco orebody were more conductive. It was observed that the most conductive parts correspond to copper-rich zones and the next most conductive to pyrite-rich zones. The EMIGMA package was also used to show that a thick-prism model might be more appropriate for the New Insco orebody. Gravity modeling constrained by the known geology was successful in identifying the denser sulfide zones. The densest zones appear to be pyrite rich. Magnetic modeling identified diabase dikes. Over New Insco, a small magnetic anomaly was attributed to pyrrhotite-rich sulfides. There was only a weak magnetic anomaly over the Iso body, consistent with the nonmagnetic sulfides logged in the holes drilled at that location. Sommaire - Les données MEGATEMII recueillies au-dessus des dépôts d’Iso et de New Insco ont été interprétées en utilisant trois outils de modélisation différents. L’outil EMQ a été utilisé comme un outil d’inversion rapide suggérant que le dépôt Iso peut être considéré comme une plaque inclinée, et que le dépôt de New Insco se situe quelque part entre une plaque et une sphère. L’outil Maxwell a été utilisé pour raffiner les propriétés du dépôt Iso. L’outil EMIGMA nous a permis d’identifier les différences de conductivité à l’intérieur du dépôt Iso. Il a été observé que la partie la plus conductrice correspond à la zone riche en cuivre, suivie par la zone riche en pyrite. L’outil EMIGMA a aussi permis de montrer qu’un modèle de prisme épais pourrait être plus approprié pour décrire le dépôt New Insco. La modélisation des données gravimétriques, contrainte par la géologie connue, définit bien la zone de sulfures massifs. La zone de pyrite semble être la plus dense. La modélisation des données magnétiques identifie bien les dykes de diabase. Au-dessus du dépôt New Insco, on observe une faible anomalie magnétique correspondant aux sulfures non magnétiques observés dans les carottes de forages à cet endroit."

Jan 1, 2006

By Matthew Blecha

The Tribag copper deposit is one of the rare examples of mineralized breccias in the Canadian Shield. The breccia is a pipe-like body, and consists of granitic, diabasic and volcanic fragments embedded in a vuggy, quartz-carbonate matrix. The mineralization is essentially chalcopyrite and pyrite, with minor molybdenite, sphalerite, galena and other sulphides. The main ore zone is saddle-like in shape, and is enveloped in a zone of chloritization, sericitization and clay-mineral alteration. It is suggested that the breccia is of the diatreme type. Introduction T HIS paper is based on eighteen months of field work, including surface and underground geological mapping and core logging, and on the survey of relevant literature. No significant amount of laboratory work has been done as yet. Location and Access The Tribag Batchawana property is located 40 miles north of Sault Ste. Marie, Ontario, about 10 miles east of Lake Superior. A 17-mile, all-weather road connects the property to the Trans-Canada highway to the south, and 4 miles of a 12-mile road remain to be completed to link it to the Algoma Central Railway to the northeast.

Jan 1, 1965

By Saikat Chatterjee, Xintong (Brett) Liu, Kinnor Chattopadhyay

Magnesia carbon bricks are commonly used in BOFs and are generally pre-heated before the BOF goes into service. Owing to very stringent emission regulations, the BOF pre-heating process need to be controlled and optimized so that, the emission standards are met. One of the major concerns in organic emissions are its stringent limits on emission rates and total volatile emissions. In the present work, an attempt has been made to integrate CFD and Thermodynamic models to predict the emission rate of volatile organics during the pre-heating process. A one dimensional heat transfer model was developed using visual basic and then integrated with thermodynamics calculations using FactSage 6.4. The parameters that affected organic emissions were the pre heating procedure, gas composition of the burner, heating rate and type of the burner. Typical composition of MgO-C bricks and binder materials were obtained from literature and vendor data sheets. Chemical reactions between organic materials, refractory and burner gasses were considered. The model predictions indicated that certain burner conditions could destroy all organics before it exits the vessel while other conditions needed the use of an after burner at the mouth of the vessel. The model was also able to predict the organic emission rates based on the chosen pre-heating profile. This kind of predictive model will be very useful for the steel industry and enable them to justify permit limit applications and stick to the limits by fine tuning their pre-heating process.

Jan 1, 2015

By W. R. Smith

Introduction No commercial deposits of silica sand are known to occur in British Columbia, so all requirements for foundry and other uses must be imported. During the war, nearly 5,000 tons per year were used, all originating in Illinois and delivered to local consumers for about $12.00 per ton. Present requirements are somewhat less, but the cost is still of the same order. The relatively high cost of silica sand in British Columbia is not only a serious item for present consumers, but might be a deterrent to the establishment of a glass industry, should this be contemplated at any time. The present investigation was undertaken in an attempt to provide a cheaper source of silica sand within the Province. In 1936, a large number of beach and bank sand deposits in the lower coastal region of British Columbia were examined by the British Columbia Department of Mines, and samples were analyzed chemically and mineralogically. The deposits over the whole area proved remarkably uniform in mineral composition, consisting essentially of quartz, feldspar, ferromagnesian minerals, rock fragments, and various accessory minerals, and differing only in the relative proportions of the various constituents. In no case did the quartz content of any sand exceed about 40 percent and the average was of the order of 20 to 30 percent.

Jan 1, 1947

By Qiling Zhang, Zengqian Hou, Xiaoming Qu

Abstract - The Okinawa trough is an active back-arc-spreading center in which submarine hydrothermal exhalation (black chimneys) and sulfide mineralization are forming. Fluid inclusion composition in minerals of the hydrothermal feeder zones in the JADE field shows that the hydrothermal systems are extremely gas-rich. There are two independent and co-existing fluids, CO2-hydrocarbon and saline fluids. Microthermometry and Laser Raman Microprobe (LRM) analyses on individual fluid inclusions of the CO2-hydrocarbon type, dominated by CO2 and containing minor CH4, C2H4, C2H6, N2 and H2S, are almost equivalent to the fluid inclusion composition of a natural gas field. The saline fluid is mainly composed of H2O and contains minor Na+ and K+. It is close to a H2O-NaCl, or H2O-NaCl-KCl system, with salinities from 3.7% to 7.5% NaCl eq. Before venting on the seafloor, the fluids experienced immiscible separation. One of the end-member fluids is downward circulating seawater that interacted with sub-seafloor rocks. The other was gas (volatile)-rich fluid derived from a shallow magma chamber. The immiscibility separation of fluids resulted from the decrease of temperature and pressure of the hydrothermal system and continuous input of magmatic volatiles. The saline fluids in this system are discharging to form sulfide chimneys and black smoke. Meanwhile, CO2-rich fluid discharges as CO2 bubbles through hydrate pipes. A large amount of CO2-CH4-H2S gas or fluid in the upper part of the hydrothermal system, and reaction of this gas or fluid with saline fluids, finally enables the accumulation of metal sulfides.

Jan 1, 1999

By X. -G. Chen, J. Qin, K. Liu, D. Racine

"Understanding the thermo-mechanical fatigue (TMF) behavior of materials plays a significant role in the safety design of critical components used in aerospace and automotive industries, such as engine blocks and cylinder heads, which undergo the cyclic change of temperature and stress. However, the cyclic changes of temperature, stress and strain make it difficult using the traditional testing methods to accurately simulate the TMF process. In the present work, the Gleeble® 3800 system was successfully applied to develop a reliable procedure to measure the TMF behavior of aluminum alloys. The modified setup together with the new designed program allows the Gleeble system to precisely simulate the cyclic profiles of temperature and mechanical strain. The novel procedure includes the calibration and verification of the TMF setup to ensure the test validity with Young’s modulus measurement, multi-cycle measurement of the thermal strain and zero stress adjustment followed by online monitoring the TMF cycles. The results of the TMF testing of an AA6061 alloy under cyclic temperatures (60–300°C) and various strain amplitudes (0.2–0.6%) were demonstrated. Its TMF behavior was characterized by the typical hysteresis loops and cyclic stress-strain response.INTRODUCTION The thermo-mechanical fatigue (TMF) behaviour becomes increasing important to evaluate the elevated-temperature properties of materials used as the critical components in automotive and aerospace industries, such as the gas turbines (Hu, Shi & Yang, 2016; Moverare, 2007; Segersäll et al., 2015) and engine blocks (Grieb, Christ & Plege, 2010; Javidani & Larouche, 2014). During the cycles of start-up and shutdown of the engines, these components undergo a complex change of loading. Meanwhile, a dramatic temperature gradient exists on the components due to the cooling system. Therefore, the cyclic changes of load and temperature can give rise to the TMF and may limit the use life of such components (Hu, Shi & Yang, 2016; Javidani & Larouche, 2014; Moverare, 2007). Hence, performing the TMF tests to precisely simulate the cyclic changes of load and temperature to understand the TMF behaviours of materials is playing a significant role in the safety design of these components. For TMF tests, two principal types of cycles are generally employed, including the in-phase (IP) cycle where the load and temperature are at the same phase (i.e. maximum load at highest temperature) and out-of-phase (OP) cycle where the maximum load is applied at minimum temperature (Kliemt, 2012; Miller, 2014). The most significant damage mechanisms in engine components are reported to be OP TMF cycles (Javidani & Larouche, 2014; Kliemt, 2012)."

Jan 1, 2018

"A growing public awareness of work-related diseases such as pneumoconiosis and the impact of this awareness on legislative bodies and on the skilled labour market are reasons why the Canadian mining industry must consider dust control of top-drawer importance. Measurements and standards related to the hazard are necessary to control a dust situation and to avoid excessive risk. The author discusses some of the methods of measurement, standards proposed and terminology used in this developing technology. The purpose primarily is to give a better understanding of the basic advances achieved by those who have applied current knowledge with a measure of success."

Jan 1, 1972

By A. Hekmat-Ardakan

Conventional hypereutectic Al-Si alloys such as A390 are used principally for the casting of components used in wear applications requiring abrasive resistance such as in engine or compressor blocks. A comprehensive study was undertaken to investigate the potential of improving the mechanical properties of these alloys by the addition of magnesium. A thorough thermodynamic study of the effect of the addition of Mg to the conventional A390 alloy showed that Mg2Si starts to form as a primary phase at 4.2% Mg as well as in the products of the binary and ternary eutectic reactions forming the matrix. Experiments were carried out in producing castings with different cooling and solidification rates of alloys with up to 10% Mg. Mg additions were found to increase the hardness over the as cast alloy due to solid solution strengthening. Also, T6 heat treatment greatly improved the tensile properties of these alloy compositions due to the strengthening effect of the theta-Al2Cu phase. The elongation of these alloys generally decreases marginally with Mg content. The most significant property improvement of the alloys with higher Mg content is the substantial increase in wear resistance. This is attributed to the dispersion of smaller particles of Mg2Si and their coherence with the matrix as compared to the large Si particles in the conventional alloy. A new rheoforming process for A390 is presented that improves the processing of the semi-solid slurry. Structure modification elements were also added to refine the primary and eutectic silicon greatly improving the processing of the semi-solid slurry.

Jan 1, 2011

By P. Morissette

Passive monitoring of support performance during rockbursts was conducted at three deep underground mines. A comprehensive database was constructed of 172 seismic events and the associated damage to support systems at 266 mine locations from January 2000 to September 2012. The majority of pertinent information was obtained through seismic system records and on-site field assessments. This work assesses the quality of collected information and evaluates the dynamic-load demand on support systems in seismically active mines.

Aug 1, 2013

By V. Barranco, K. Yliniemi, A. Hubin, B. P. Wilson, D. Janas, M. Lundström, P. Hannula

Typical copper electrorefining electrolyte contains tens of grams of copper, some nickel and a wide variety of impurities. Some of these impurities comprise trace amounts of dissolved precious metals like Ag, Pd and Pt that currently are not fully exploited. This study presents an electrochemical method to recover precious metals via a combined electrodeposition-redox replacement (EDRR) process, where energy is used only to deposit copper during the ED-step, while the RR-step relies on the spontaneous replacement of copper by the precious metals (i.e. cementation). In order to conduct the recovery successfully, process parameters such as deposition potential (EDE), deposition time (tDE), redox replacement time (tRR) and the number of cycles (n) was adjusted. Investigations performed in synthetic electrolyte (40 g/L Cu, Ag = 10 ppm) proved the possibility to recover a high purity silver. Short deposition times (tDE) were found to result in small Cu particles that provided a suitably high surface area for silver cementation. In addition, experiments performed in real industrial electrolytes containing 44 g/L Cu and 54 ppb Ag (Boliden Harjavalta, Pori), demonstrated that EDRR could attain Ag recoveries of between 46–67% in an energy efficient, additive-free manner. INTRODUCTION The raw materials used in the state-of-art primary and secondary copper smelters contain mainly base metals, but also notable amounts of Ag, Pt and other precious metals. These valuable metals distribute mostly into the copper matte during the pyrometallurgical treatment (Tirronen et al., 2017) and end up into the cast anodes. During the electrorefining stage, metals more noble than copper such as gold and platinum, are not dissolved but enrich into the anode slimes. In contrast, silver may dissolve slightly and thus, minor chloride addition is used to retain silver in the slime as sparingly soluble AgCl. Moreover, other metals less noble than copper may also dissolve, such as nickel. Therefore the electrolytes used in electrorefining typically contain substantial amounts of copper, nickel and even arsenic as well as minor metals such as antimony and bismuth. In the Boliden electrorefinery these were reported to be in the magnitude of 51.2– 60.4 g/L of Cu, 10.9–15.8 g/L Ni, 7.2–15.9 As, 0.2–0.4 Sb and 0.1–0.4 Bi with an associated sulfuric acid concentration of 139–155 g/L (Lehtiniemi et al., 2018). Copper is the most noble of the dominating base metals in the electrolyte and is thus deposited on the cathode as 99.99% purity LME-A grade. Anode slimes are collected and subjected to precious metals treatment e.g. via pressure leaching—selenium recovery— Doré smelting—Ag refining—Au/Pt/Pd leaching and reduction process (Ludvigsson & Larsson, 2003). The Pori refinery, operating in Finland since 1941, not only produces 133 000 t Cu cathode and 2300 t nickel sulphate annually but also 66 t silver, 4.6 t gold and palladium and platinum (in year 2017).

Jan 1, 2019