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By Francis Church Linxoln

"This property was explored as part of a general investigation of zinc-prodccing areas of southwestern Wisconsin at a time when an effort was being made to increase the production metals important to the Nation's war program. This report describes the work that was done and presents the data obtained.ACKNOWLEDGEMENTSIn its program of exploration of mineral deposits, the Bureau of Mines has as its primary objective the more effective utilization of our mineral resources to the and that they make the greatest possible contribution to national security and economy. It is the policy of the bureau to publish the facts developed by each exploratory protect as soon as practicable after its conclusion. The Mining Branch, Lowell B. Moon, chief, conducts preliminary examinations, performs the actual exploratory work, and prepares the final report. The Metallurgical Branch, P., G. Knickerbocker, chief, analyzes samples and performs beneficiation tests. Both these branches are under the supervision of Dr. R. S. Dean, assistant director. Special acknowledgment is due Professor G. H. Pett, of the Wisconsin Institute of Technology at Platteville, Wis., Jack Tracy, manager of the Mifflin Mining Co., and J. M VanMatre, representative of the Defense Property, for their assistance in the work. Acknowledgment is also due to A. F. Agnew and A. V. Heyl, geologists of the Federal Geological Survey, for furnishing geologic interpretations and lithologic studies of the drill-hole sections. All drilling was done under the immediate supervision of Francis C. Lincoln and M. Howard Berliner, project engineers, Edward P. Barrett, district engineer, Minneapolis, and E. D. Gardner, regional engineer, of the Bureau of Mines."

Sep 1, 1946

By Edward D. Thimons

As U.S. mines go to greater depths, the high temperatures and humidities characteristic of such depths make it difficult to maintain a comfortable environment in working areas. Better techniques for cooling these deep working areas are needed. At the Homestake gold mine in South Dakota the Bureau of Mines has tested a water spray cooler inserted into the fresh air vent tube entering a warm stope. The cooler supplied more than 6 tons of refrigeration to the stope air, which dropped from an inlet temperature of 83° F dry bulb and 75° F wet bulb to 73.5° F dry bulb and 71.5° F wet bulb. These preliminary results show the water spray cooler to be a feasible concept. However, there is a need for substantial refinement and further testing, and work on the concept will be continued under contract to the Bureau.

Jan 1, 1979

By X. Shi, K. S. Kaspnak

"The generation of free radicals from reactions of nickel (Il)-thiol complexes with molecular oxygen and model lipid hydroperoxides was investigated by electron spin resonance (ESR) utilizing 5,5-dimethyl-1-pyrroline-N-oxide (DMPO) as a spin trap. Incubation of nickel (II) [Ni(II)) with cysteine in an aerobic environment generated hydroxyl (·OH) radical, which then reacted with cysteine to generate a carbon-centered alkyl ( · R) radical. Radical generation was inhibited under a nitrogen atmosphere. Model lipid hydroperoxides, cumene hydroperoxide, and I-butyl hydroperoxide enhanced the yield of these radicals and also generated an alkoxyl (·OR) radical. Radical yield decreased by approximately half under a nitrogen atmosphere. Although histidine did not cause radical formation in the reaction between Ni(II) and cumene hydroperoxide under aerobic conditions, the addition of histidine to a mixture containing Ni(ll), cysteine, and cumene hydroperoxide under the same experimental conditions increased the yield of · R radical but lowered the yield of ·OR and ·OH radical adducts. It thus appears that histidine caused the ·OH attack to be more site-specific. Similar results were obtained utilizing 1-butyl hydroperoxide. Penicillamine or N-acetylcysteine yielded similar results except that under aerobic conditions, reaction between Ni(ll) and N-acetylcysteine without hydroperoxide did not generate a significant concentration of free radicals. Under the same experimental conditions, cystine did not generate any detectable free radicals, suggesting an important role of the -SH group in Ni(II)-mediated free radical generation. The results indicate that free radical generation from the reaction of Ni(Il)-thiol complexes and molecular oxygen, and/or lipid hydroperoxides, may play an important role in the mechanism(s) of Ni(II) toxicity and carcinogenesis. INTRODUCTIONWhile nickel is a well-recognized carcinogen [l, 2]. the underlying biochemical mechanisms remain unclear (3, 4). Recent studies suggest that these mechanisms may involve oxidative DNA damage through free radicals, especially the hydroxyl (•OH) radical [5-13]. The mechanisms of nickel carcinogenicity and toxicity may also involve lipid peroxidation [14-21]. Unlike ferrous ion [Fe(II)], the Ni(II) cation itself does not directly react with 02, H2O2, or lipid hydroperoxides to generate free radicals [12, 21]. However, it has been reported that Ni(II) complexes with certain synthetic oligopeptides, e.g., tetraglycine or glycylglycylhistidine, make Ni(II) reactive with 02. This reaction results in transitory formation of Ni(III) and degradation of the organic ligand via free radical reactions [22]. Such Ni(II)-peptide complexes are also capable of reacting with H2O2 to produce oxygen free radicals [11, 12]. Although the cellular environ¬ment may not contain these particular peptide ligands that are known to render Ni(II) redox active in vitro, it does contain a variety of oligopeptides that are capable of forming Ni(II) complexes at physiological pH, and thus may facilitate Ni(II) redox activity in vivo. These oligopeptides include glutathione (y-L glutamylycysteinylglycine), carnosine (homocarnosine (y aminobutyryl-L-histidine), and anserine ( B-alany1-3-methyl-L-histidine)."

Nov 1, 1995

By N. N. Moelbs

The U.S. Bureau of Mines is conducting research on many topics relating to the hazards of coal mining, increased production, and protection of the environment. One area of research that has received scant attention in recent years is that of water inflows, probably because few fatalities in the United States have been attributed to them. As mining goes deeper, the problem of water in 1ow could increase dramatically because of adjacent or overlying mines in which huge water pools are impounded. Inaccurate mine maps and ineffective barriers can constitute a serious problem for operators both from gradual inflows and sudden inrushes of water. This report describes a wide but ineffective barrier that permitted an average 240-gpm inflow to a developing mine from an adjacent mine. The anomalous geologic structure that facilitated this leakage is described, demonstrating that size, alone, is no assurance against serious leakage. Some recommendations for managing serious water inflow are included.

Jan 1, 1989

By W. R. Moorehead

This paper, describing the mining methods and colt at the New Indria quicksilver mine, is one of a series of similar papers being prepared by the Bureau of Mines on various mines in the United States. The New Idria mine lies at an elevation of 3,500 to 4,200 feet in the Coast Range of San Benito County, Calif. The property is accessible by automobile stages from Gilroy or Hollister via Tres Pinos. Tres Pinos, 65 miles northwest of the mine, is the nearest railroad point.

Jan 1, 1931

By Will H. Coghill

[The supply of gravel spar and of acid spar is not well balanced. Gravel spar -- 85 per cent flourspar, 5 per cent silica -- gluts the market, whereas acid spar -- 98 per cent fluorspar, 1 per cent silica -- is somewhat scarce. Hence it is desirable to convert some of the gravel spar into acid spar. Knowledge of this condition prompted the Franklin. Fluorsrar Co. at Paducah. Ky., to enter into cooperation with the U. S. Bureau of Mines and the Missouri School of Mines and Metallurgy to improve the methods of fluorspar, milling so that morn acid spar would be available. The fluorspar company detailed Mr. Omar Greeman for the work. During the course of the investigation, while Mr. Greeman was also doing work for a master's degree in the School of Mines? an extensive study was made of gravity concentration of fluorspar ores. Decrepitation by heat treatment was also given a laboratory try-out. A part of tie time was spent on flotation; these notes relate only to the flotation. The results of one of the flotation runs is appended. The test was made in a 500-gram mechanical-agitation machine. The sample was ground to 100-mesh in a pebble mill.]

Jan 1, 1928

By Charles B. Kenahan

The chemical and galvanic corrosion properties of commercially pure titanium, a titanium-manganese alloy, a titanium-aluminum-tin alloy, 2 titanium-copper alloys, and 2 titanium-aluminum alloys were studied. Tests were conducted in synthetic ocean water, tapwater, 1-percent sodium hydroxide, 5-percent ferric chloride, and 5-percent ammonium sulfate solutions, various concentrations of sulfuric and hydro-chloric acids, and 1-percent oxalic acid. All tests were carried out at 35° or 60° C., with a flow of air or helium. Dissimilar metals involved in galvanic-couples experiments were aluminum, magnesium, and stainless steel. Electrode-potential measurements on single (uncoupled) specimens were also measured. Commercially pure titanium and the titanium-base alloys were generally quite similar in their resistance to corrosion, whether alone or in. contact with a dissimilar metal. Contact with the titanium metals caused aluminum and magnesium to corrode by galvanic action. Coupling with stainless steel in sulfuric acid solutions decreased the normal corrosion rate of the titanium metals. Contact with aluminum in air-aerated oxalic acid and 0.1N sulfuric acid solutions resulted in cathodic corrosion of titanium and the titanium-base alloys; however, there were a few exceptions. The copper alloys showed better corrosion characteristics than titanium in certain sulfuric acid solutions but were more susceptible to chemical attack in some hydrochloric acid solutions.

Jan 1, 1958

By C. H. Schack, A. O. Ipsen, H. G. Poole

"INTRODUCTION In the course of the investigation of manganese mineral occurrences in continental United States, the Bureau of Mines has collected several lots of ore from properties in the vicinity of Long Valley, Ariz. The ore occurs as irregular and random pockets in a brecciated zone. As only high-grade portions of the deposits obtained by selective mining would be acceptable as commercial-grade manganese ores, an investigation was made to determine amenability of the ores to concentration by ore-dressing methods. Several types of ores, differing in grade and mineral associations, were studied.Ores from the Vaiazza property are of special interest, owing to the successful application of silica flotation for their concentration. Ores from the Shroup and Conner-Hough properties are very similar but differ somewhat in their response to ore-dressing Method's. In all instances, the man¬ganese minerals are psilomelane and pyrolusite, with minor amounts of other manganese oxides. The country rook is a brecciated limestone; the diluent in the high-grade ore pockets is chiefly silica. The low-grade manganese ores are limestone replacements, and the chief gangue material, of course, is limestone."

Nov 1, 1947

By J. A. McAllister

In the course of a study of domestic Manganese resources, 2-ton representative samples of ore were taken by Bureau of Mines' engineers from the Payday claim, Weber County, and the Newcomb-claims, Rich County, Utah. The Payday No. 1 deposit is situated 13 miles northeast of Huntsville, Weber County, Utah. The manganese ore is a. replacement deposit in limestone and consists of manganese oxides imbedded 'in clay and also as the cementing agent consolidating small pebbles and pieces of quartz and limestone.

Jan 1, 1949

By Timothy Y. Yen

This Bureau of Mines report evaluates audio dosimeters, 3 sample units from each of 10 currently marketed brands. Each dosimeter was treated as a "black box" with the acoustic stimulus as the input and the accumulated dosage as the output. The dosimeter microphones were exposed to a sound field gener¬ated in an anechoic chamber. Characteristics evaluated include frequency response (100 to 8,000 Hz), level-time trade-off rate (88 to 117 db), status of calibration, crest-handling capability, and power consumption rate. Experi¬mental errors revealed by replication of the tests were found to be generally much smaller than variations in performance among the samples of any brand, and possibilities of further reducing the magnitude of these errors are discussed.

Jan 1, 1977

By Maria I. De Rosa

The U. S. Bureau of Mines performed experiments to determine if the primary gas toxicities evolved during the early (~300° C) and later (~400° C) combustion stages of chlorinated polyester-reinforced mine ventilation ducts could be predicted by a smoke particle characteristic, for the development of a test parameter. The experiments were conducted in an approximately 20-L furnace, at 14-min durations at set furnace temperatures of 2500 and 1,000° C, with an airflow through the furnace of 10 L/min. The variables studied, as a function of time, were the hydrogen chloride (HCI), carbon monoxide (CO), carbon dioxide (C02), and oxygen (02) concentrations, furnace temperatures, the sample mass weight loss, the average smoke particle diameter (dg and average number and concentration (no), and the product of the average smoke particle diameter and concentration (dgno). Results show that the inverse of the smoke particle diameter-concentration product [(l/dgn0)], correlates directly and significantly with the primary gas toxicities evolved during both early (HCI) and later (CO) stages of combustion.

Jan 1, 1989

By A. U. Miller

Since coal -mining records have been kept , reports of all mining States show that each year the lives of many workers have been sacrificed in the production of coal , and Illinois has contributed its share , Illinois reports for the 50 years 1882 to 1932 , inclusive , show that 6,673 men were killed -- 6,121 underground , 340 in the shaft , and 212 on the surface . Of the fatalities underground , 3,116 were caused by falls of roof or sides , 1,111 by haulage , 630 by explosives , 577 by gas explosions , 139 by electricity, and 548 by other causes ; 166 of the shaft fatalities were caused by falling down the shaft , 143 by the cage , and 31 by other causes ; 108 of the surface fatalities were caused by railroad cars , 46 by machinery , and 58 by other causes . Most of those engaged in mining are still of the opinion that it is an extremely hazardous occupation and that it is practically impossible to operate without accidents ; however , students of safety in mining now believe that with the proper attention to accident prevention mining may be conducted with little , if any , greater accident rate than that of other supposedly hazardous industries . There is no mystery connected with accidents in mining ; reports show that the majority are due to two main causes , falls of roof and sides and haulage . Mining companies in Illinois , as well as in other States , have proved in the past few years that the hazards of mining , like those of other industries , can be controlled to a large extent and the mines operated with few if any accidents , provided a great enough effort is made by employer and worker . Although the past accident rate of Illinois may compare favorably with that of other mining States it is higher than it should be ; the fact that 6,673 men (an average of 133.46 per year) were killed in and around the mines of the State between 1882- and 1932 indicates that accident prevention should receive more consideration in the future than in the past .

Nov 1, 1934

By H. G. Iverson

Solid state reactions of manganese with silica were investigated in high-temperature tests. Reactions of 0.5 to 4.0 moles manganese (Mn) with 1 mole silica (SiO2) at 1,100° C and of 2.0 Mn:SiO2 mole-ratio mixtures at 1,000° to 1,150° C yielded products consisting of a slag phase and a metallic phase. At 1,100° C, the slag phase from reactions of the low Mn:SiO2 mole-ratio mixtures was composed of SiO2 and rhodonite (MnSiO3), and the slag phase from the high Mn:SiO2 mixtures was composed of MnSiOs and tephroite (Mn2SiO4). The metallic phase from the corresponding low Mn:SiO2 mole-ratio reactants consisted of two manganese silicides, Mn5Si3 and Mn3Si; from the high Mn:SiOg mixtures, it was Mn and the manganese silicide (Mn5Si). For the higher mole ratios of MnSiO2 the manganese content in the metallic phase increased, while the manganese and silica contents of the slag phase remained nearly constant. The slags did not contain free or uncombined manganese oxide (MuO). For the 2.5 to 4.0 Mn:SiO2 mole-ratio mixtures reacted at 1,100° C, the maximum quantities of silica reduced and of the manganese in the slag appeared to become asymptotical at about 41 and 48 percent, respectively. A brominating procedure was developed that was highly selective in removing the metallic constituents from the reaction product, leaving the slag phase as residue. X-ray diffraction patterns were obtained on prepared silicides Mn5Si, Mn3Si, and MnSi.

Jan 1, 1967

By Ivan F. Avery

DOMESTIC production of carbon black increased 4 percent in 1962 to 2,056 million pounds. Furnace black output was 8 percent, or 132 million pounds, above that in 1961 and accounted for 90 percent of total carbon black production. Channel black output continued to decline and was 55 million pounds less than in 1961. Carbon black shipments during the year totaled 2,082 million pounds and were 5 percent above those of 1961. About one-fifth of these shipments were exported; the balance were sold domestically. An increase of 180 million pounds in domestic sales was partially offset by a decline of 80 million pounds in exports. Total value of carbon black production in 1962 was $145 million. The average value per pound of 7.06 cents was 0.24 cent per pound less than in 1961. Producers' stocks declined 26 million pounds during the year.

Jan 1, 1963

By Martin J. Gavin

During the recent study of lubricating oils carried on in the San Francisco laboratory of the United States Bureau of Mines, it became desirable to distill the oils used in the experimental work at pressures as low as 10 millimeters (mercury column) absolute. In the effort to Overcome difficulties and eliminate sources of error, certain changes were made in the apparatus for vacuum distillation used by the Bureau of Mines for crude petroleum.4 These changes were described in R.I. 2819, issued in July, 1927. Subsequent to the publication of R.I. 2819 several other changes have been made, and the present form of the apparatus for vacuum distillation of lubricating oils is described in this revision of R.I. 2819. These changes were found to give more accurate checks on duplicate distillations. The major part of the credit for the laboratory work which developed the changes in the apparatus and method revised herein is due to Boyd Guthrie, assistant petroleum chemist, and R. V. Higgins, junior chemist, o the San Francisco laboratory, United States Bureau of Mines. DESCRIPTION OF APPARATUS The distilling flask employed is essentially the Hempel flask as used by the United States Bureau of Mines for the analytical distillation of petroleum.5 he complete apparatus is shown in Figure 1. The fractionating column and exposed portion of the flask is wrapped with 4 inch asbestos rope and then surrounded by a cylindrical hood of 1/8 inch pliable asbestos sheet with a narrow air space between the wrapping and the cylindrical hood. This was found necessary to prevent any radiation or convection heat losses from the column, and resulted in obtaining a more even and constant fractionation by eliminating any dephlegmating action caused by temperature changes around the column.

Jan 1, 1930

By Robert J. Anderso

Few elements have received more attention and developed greater interest in the last ten years than titanium. The substantially pure metal has been din...ie. cult to isolate, and so far has been little employed oommercially, but the use af alloys and chemical compounds of titanium has increased markedly in recent years. The earlier attempts at preparing pure titanium resulted in various impure forme which, from their metallic appearance, were always mistaken for the metal. Hunter in 1910 isolated pure titanium by the reduction of titanium tetrachloride with sodium. This brief statement is issued by the Bureau of Mines in response to numerous inquiries which have been received concerning titanium. More complete in. formation on the metal may be had by consulting the referenpes appended. The Literature is voluminous and only the more important references are Riven. It has been drawn upon freely in preparing this report; also information was supplied by M. g. Hunter, Arthur Braid, M 1. Schmid, C. M. Johnson, N. B. Hoffman, and de Courny Browne. The pioneer investigator in titanium is A. IL Rossi.

Oct 1, 1922

By C. Watson Owings

"The mining Industry in the United States is becoming fully cognizant of the hazards of dust in underground mining as well as in surface plants. The dust problem in metal mines has been brought to focus through knowledge of the harmful effects of dust, especially silica, and through adoption of more or less stringent legislation classifying certain types of pneumoconiosis as occupational diseases. The coal-mining industry is aroused principally by the apparently great increase in the dust-explosion hazard resulting from the rapid growth of mechanized mining. The United States Department of the Interior, through the Safety. Division of the Bureau of Mines, has been requested repeatedly to recommend methods of allaying dust in both coal and metal mines. Methods adequate under hand-mining conditions fail to effect satisfactory reduction of dust in more rapid extraction with modern equipment. Studies of methods and equipment for allaying dust are being conducted in both metal and coal mines. Results of these studies are discussed, and indications of possible means of reducing dust concentrations are presented in the hope that the health and 'safety of men employed in the mining industry may be increasingly safeguarded.DUSTThe term ""dust"" is a common one, and yet the meaning is applied to widely different particle sizes. The general term means ""earth or other matter reduced to fine, dry, and powdery particles."" The root from which the word is derived means ""something that can be blown about by the wind."" As a result of tests on the explosibility of coal, the Federal Bureau of Mines has arbitrarily defined dust as being. ""that which will pass through a 20-mesh screen,"" based upon the fact that particles coarser than 20-mesh have little influence on the development of an explosion of Pittsburgh coal-bed dust. The study of dust, from a health standpoint, has given rise to still another definition of dust, namely,- according to Drinker3/, ""solid particles ranging in size from less than 1 micron to about 150 microns."" A micron is 1/25,400 inch, and 150 microns are approximately 1/1,700 inch. Atmospheric dust usually is considered as 10 microns or less, larger particles not being counted under the microscope in determination of dust concentrations."

Apr 1, 1942

By Robert E. Barieau

This report gives the principles of the method used by the Helium Research Center of the Bureau of Mines when solving nonlinear-regression problems and contains the mathematical equations necessary to accomplish the following objectives: the evaluation of the parameters in such a way that the sum of the weighted squares of the residuals of an experimental observable is a true minimum, regardless of the functional relationship between the variables and these parameters; and the evaluation of all variances and covariances of the parameters by means of the usual approximation of the law for the propagation of errors.

Jan 1, 1967

By Aldo L. Furno

Sufficient quantities of combustible vapors are released by some sulfurs to produce flammable atmospheres under prolonged storage. Hydrogen sulfide and carbon disulfide appear to be the principal flammable constituents in the vapor space above molten sulfur. If sufficient carbon disulfide is present, ignition of the vapor-air mixtures can occur spontaneously on contact with the heated surfaces found within storage tanks.

Jan 1, 1963

By T. J. Ballard

The Conrad Hill mine vas first opened as a gold mine about 182 and has been operated at various times since then. The Bureau of Mines, as part of the strategic minerals program, mapped and sampled the accessible mine workings. The work failed to reveal appreciable copper values or evidence of additional ore deposits.

Jan 1, 1948