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By Knud Sinding

Many industries have established their own systems for self-regulation. They often do so when companies operate in countries where financial, technical, environmental and social regulation is weak and when the industry is challenged by legitimacy issues related to behaviour in one of these areas. Mining is one industry that has progressed unevenly down the road of self-regulation in these areas. This paper examines how the development of self-regulation for mines and mining companies involves difficult questions of scope, rules, membership, assessment criteria and performance evaluation. Using a range of theoretical and empirical results from research on self-regulation, performance rating and corporate strategy, this paper analyses the strategic and operational issues related to the idea of self-regulation in the mining industry. The analysis indicates that while self-regulation may bring benefits to members, they are likely to take a long time coming; but when they do arrive they may be substantial. Using the fact that in relation to technical and financial issues the industry is quite experienced in self-regulation ? not least as it is more reluctant in areas such as environmental and social performance ? the case is made for a comprehensive and innovative approach, that draws on the areas where the industry is experienced and develops new institutional solutions in the areas where the industry is more reluctant.

Aug 1, 2013

By J. Poplawski

In mineral processing plants, cyclones typically perform the classification duty prior to the downstream recovery process. Particle size distribution of the cyclone overflow is an important parameter and can be viewed as the product of the comminution process. Too coarse of a product will likely have poorly liberated valuable minerals and make recovery difficult. Too fine of a product may represent a missed opportunity to increase plant throughput and/or also result in low recovery due to poor kinetics. “Near-line” particle size measurement instrumentation has been in place for several decades, its availability and low measurement frequency have typically been inadequate for reliable use in automatic control. CiDRA Minerals Processing has developed a novel and robust technology that provides a highly reliable and low maintenance system for “on-line” measurement of the particle size in the overflow of individual cyclones. The system is based around a wetted sensor design with no moving parts and provides a real-time trend of the desired target grind size parameter. The system does not require sampling and associated sample transfer piping that is prone to plugging, thus avoiding high maintenance requirements. Plant data and benefits realized from the latest installations of the CYCLONEtrac PST will be presented. INTRODUCTION Impact-based real-time hydrocyclone particle size measurement Acoustic impact-based particle size tracking is a unique method for measuring and controlling the particle size in cyclone overflow streams. The implementation of this technology is centered upon a sensor probe that is inserted into the overflow slurry stream via a two-inch (50 mm) hole in the overflow pipe (Figure 1). Particles within the slurry stream impact the surface of the probe generating travelling stress waves within the probe. A sensor converts these travelling stress waves into an electrical signal and proprietary signal processing techniques convert these signals into a particle size measurement that is output every four seconds. The sensor is constantly in contact with many particles in the slurry stream, thus obtaining information from orders of magnitude more particles than traditional sample-based technologies. The sensor has no impact on cyclone performance because it is located downstream of the hydrocyclone and the presence of an air core ensures there is no change in the back pressure seen by the hydrocyclone.

Jan 1, 2019

By V. I. Lakshmanan, R. Roy

"Zinc is the fourth most widely used metal in the world after iron, aluminum and copper. The primary zinc production is through flotation of zinc concentrate, roasting, leaching and electrowinning. Close to 60% of the metal produced is consumed in galvanizing the steel by making a thin layer of zinc coating on the steel surface by hot dip galvanizing. Process Research ORTECH Inc. has developed an efficient energy-saving sustainable technology for the recovery of zinc from secondary sources such as galvanized steel scrap, dross, dusts etc. The process consists of treating the zinc containing scrap in an alkaline solution to remove the zinc and thereby producing a zinc free steel scrap for recycle. The zinc containing leach liquor is subjected to a solvent extraction process to recover value added zinc oxide as the final product. In this paper, important industrial processes for the recycling of zinc including the PRO process will be discussed. BACKGROUNDZinc is the fourth most widely used metal in the world after iron, aluminum and copper. Global refined zinc output increased by 2.7 per cent to 13.16 million tonnes in 2011 and is expected to increase by an additional 2.4 per cent to 13.48 million tonnes in 2012 [1]. The primary zinc production is through flotation of zinc concentrate, roasting, leaching and electrowinning. Close to 60% of the metal produced is consumed in galvanizing steel by making a thin layer of zinc coating on the steel surface by hot dip galvanizing. Other major usages of zinc are in the production of brass and bronze, die casting and zinc-air batteries. The additional demand for zinc could come from its addition to fertilizers to increase crop yield.While the demand for zinc is increasing, many mines are scheduled to close in near future after being depleted of ore. The mines set to close between now and 2015 are Teck Resources’ Red Dog Mine in Alaska, Minmetals’ Century Mine in Australia and Vedanta Resource’s Skorpion Mine in Namibia [1]. The depletion of resources due to continued use and exploitation is becoming a great concern for the zinc industry. As a result, the sustainability of natural resources for continued societal care has become extremely important. Resource conservation and recovery by recycling with minimal environmental impact is a key element for sustainable development. In this paper, important industrial processes for the recycling of zinc including the PRO process are presented."

Jan 1, 2012

By C. S. Chen, Y. J. Luo, M. W. Gao, B. Li, Z. F. Zhang

"To obtain large-sized billets with fine grains and homogeneous elements distribution, uniform direct chill (UDC) casting process, based on annular electromagnetic stirring coupling with intercooling, was employed to produce 7055 alloy billets with a size of F584 mm in this study. The results indicated that there were the coupled effects of annular electromagnetic stirring and intercooling on grain refinement and element homogenization, and also the billets produced by the UDC casting process showed excellent hot workability in comparison to the normal direct chill casting process.INTRODUCTION The high solute 7055 aluminium alloy has a wonderful combination of high specific strength and hardness, good resistance to stress corrosion cracking and high fracture toughness, which is very useful in aerospace application (Yan et al., 2013; Mondal & Mukhopadhyay, 2005). The production of large-sized 7055 alloy billets with high quality is the basic condition for the subsequent application of 7055 alloy to the aircraft. Inhomogeneous microstructures and performances of 7055 billets result from the high alloying element content and the inhomogeneous cooling condition in different regions of billets during the conventional direct chill casting (Paramatmuni et al., 2004; Lalpoor et al., 2011), which will bring bad influence to processing property, functional performance and utilization rate of materials. To alleviate segregation and obtain fine and uniform grains, some effective treatment methods were proposed including electromagnetic stirring (EMS) (Vives, 1989), ultrasonic vibrating (Zhang et al., 2011) and melt conditioning (Fan et al., 2013), on the melt to obtain fine and uniform grains. However, these methods could not effectively decrease the large temperature difference between central and periphery parts of the billet, because the solidification mainly depends on outside cooling including mould cooling and water spraying cooling. To change the heat extraction pattern of the billet functioned solely from the outer surface, based on annular electromagnetic stirring (A-EMS) invented by Xu et al. (2010), Luo et al. (2017) proposed uniform direct chill (UDC) casting coupling A-EMS with intercooling in the direct chill (DC) casting process. An in-mold cooler was inserted to the melt sump, and thus the alloy melt temperature and concentration at solidification front become more uniform."

Jan 1, 2018

By Claudia Gasparrini

"Silver occurs in about 200 minerals in variable amount s. Silver ores usually have 5 or 6 and in some instances as many as 10 species of silver minerals. All these minerals may have different flotation and leaching properties and should be correctly identified for successful recoveries. Grain size and host minerals which are critical in gold recovery, are not always as important for silver minerals.IntroductionMineralogical factors affecting the metallurgy of silver are , as for other metals: (i) the silver-bearing mineral s ; (ii) their grain size, and when dealing with very fine sizes; (iii) their host minerals; and (iv) the association they form with the silver-bearing minerals. Of these, the silver-bearing minerals are more often the cause of problems during recovery as opposed to gold whose metallurgy is generally more affected by grain size and host minerals. The problems derive mainly from the complexity of the silver mineralogy: over 200 minerals exist bearing the element in major, minor and variable amounts.As a member of group I-B of the periodic table, silver forms extensive so lid solutions with the other two elements in the same group , copper and gold. It combines with sulphur, tellurium and selenium in covalent bonds and with chlorine, bromine and iodine in ionic bonds. Where the fluid composition, temperature and pressure during crystallization allow it, silver also combines with arsenic, antimony, lead, bismuth, tin, mercury, indium, thallium, and germanium in many instances as a minor element in sulphide , sulphosalt and native element minerals. Cations which silver replaces to a lesser extent than copper and gold are iron, manganese, zinc and probably nickel and cobalt."

Jan 1, 1984

By G. A. Gillett, C. F. Bonney

"The Davy McKee combined mixer-settler (CMS), is a liquid-liquid contactor, which has been commercially applied to the recovery of uranium from dilute sulphuric acid-bearing leach liquors. CMS differs from most other solvent extraction systems in that the mixing and separation of the phases is carried out in the same vessel.IntroductionTypical solvent extraction plants for the recovery of uranium operate at organic to aqueous feed flow ratios of 1 : 2 to 1 : 30. Because it is beneficial to mix the organic and aqueous phases at an organic/aqueous (O / A) ratio of between I : 2 and 2 : I there is incompatibility between the over-all and operating O /A ratios.Conventional mixer-settler designs require an external recycle of the minority flow which results in the possibility of over-mixing, increased settling requirements and entrainment losses. Other workers have approached this problem in terms o f enhanced sett ling and this has been partly successful.Davy McKee's approach involved a radical rethink of the principles of liquid-liquid contact and separation.Description of CMSThe CMS has the important advance that the required mixing O/A ratio can be achieved without external recycle and is not affected by the O /A ratio of the feeds. Three zones co-exist within the CMS unit-a central mixing zone and upper and lower separation zones. A pump impeller on a draught tube is installed within the mixing zone and baffles are installed above and below the mixing zone. Conventional mixer- settlers have several undesirable features which ca n largely be eliminated using the CMS system:"

Jan 1, 1983

By Ros Taplin

Realizing the potential of cutting greenhouse gases (GHGs) associated with mining, a variety of approaches has been proposed for their mitigation. The Clean Development Mechanism (CDM) under the Kyoto Protocol to the UN Framework Convention on Climate Change (UNFCCC) has been a key mechanism to assist in implementation of mitigation measures. The objectives of CDM are not only to assist Annex I countries in meeting their GHG emissions reduction targets with cost-effective reduction but also to achieve sustainable development in non-Annex I countries. However, apart from China, India, Brazil and Mexico, many developing countries are still in the stages of formulation or realizing CDM strategies. Projects associated with methane capture and flaring are the fourth most prevalent type of CDM project internationally. This research primarily has addressed emissions abatement and sustainable development aims and effectiveness of registered CDM projects associated with coal mining in China. The paper reviews 30 currently registered CDM projects in China on the UNFCCC database and six other non- Chinese projects. Systematic evaluation involving content analysis of documentary evidence regarding coal mining CDM projects is presented in relation to firstly, quantitative reduction of GHG emissions and secondly, sustainable development outcomes. The projects have been assessed via a set sustainability criteria. Overall it was found that sustainable development goals are only briefly referred to in Project Design Documents, Letter of Approvals and validation documents. Varying types of sustainability initiatives have been implemented with weak to strong indications of effectiveness. This has implications for the future effectiveness of CDM projects in the mining sector, the proposed new market mechanism under UNFCCC, and for assessment of projects under mechanisms established outside the UNFCCC.

Aug 1, 2013

By S. Hobo, M. Yagisawa, T. Uchida, C. Tokoro, T. Kato

In this study, quantitative modeling was carried out for the treatment of simulated waste water containing As(V), Zn(II) and Hg(II) as toxic elements, and Fe(III), Na(I) and sulfate as coaxing ions. The objective was to predict the pH and residual concentrations of all the elements in solution after the neutralization/co-precipitation treatment. To accomplish this, the removal mechanism for As(V) and Hg(II) by ferrihydrite precipitation was first investigated for simulated waste water containing only As(V) or Hg(II). From the experimental results, it was confirmed that the removal mechanism involves not only surface complexation but also surface precipitation. However, surface complexation is the main mechanism for As(V) and Hg(II) removal to meet the target levels regulated in Japan. Next, the surface complexation model was constructed for the removal of As(V) and Hg(II) by ferrihydrite. The specific surface area and site density were determined from reference values proposed by Dzombak and Morel (1990). By comparing the experimental and calculated results, it was confirmed that our constructed model could successfully represent the experimental results. Furthermore, the surface complexation model was coupled with chemical equilibrium calculations and applied to the neutralization of simulated waste water containing As(V), Hg(II), Zn(II), Na(I), Fe(III) and sulfate. The constructed model could successfully represent the pH edge for As(V), Hg(II), Zn(II), Fe(III) and SO42- removal. In addition, the constructed model could represent the ion balance. Thus, our constructed model is useful to estimate the amount of neutralizer that is needed to achieve a target pH.

Jan 1, 2016

By G. A. Barclay

"I - INTRODUCTIONSteel castings still comprise the largest volume of wear materials used in crushing and grinding in the Canadian mining industry. The range of impact and wear properties possible with steel castings enables them to be used successfully in both high impact crushing as well as milling where abrasion resistance is the main criterion. Approximately 15,000 tons per year of steel mill liners and crusher castings are used by Canadian mines.The properties of the main steel casting alloys used - manganese, pearlitic chrome-moly and martensitic medium carbon steels will be discussed with reference to their applications. Field data on a new application in primary gyratory crushers for martensitic medium carbon steels is presented. Liner wear life and mill efficiency can be improved through proper liner design.The liner wear pattern can be used as an indication for liner profile changes to improve wear life. Changes in liner configuration can improve through put and use of larger castings can reduce downtime. Casting performance can be improved and foundry production costs reduced by adopting certain design improvements.II - ALLOYS USEDTable I list the most common ferrous liner materials used in relation to their hardness and wear resistance (1). The most wear resistant materials are the irons at the top. In many applications the service impact exceeds the impact strength of the irons and tougher less wear resistant steels must be used. The impact resistance improves from top to bottom with manganese steel the toughest. The hardness of the martensitic steels approaches that of the Ni-Hards however the wear life, because of the absence of carbides, is less."

Jan 1, 1983

The total current inventory of mature fine tailings is estimated to be nearly 850 million m³. Pressure has come to bear on the industry to accelerate its tailings management practices and prevent this inventory from steadily growing. The present paper describes the treatment, management and reclamation of fluid fine tailings. New technologies being evaluated include: i) Thin layered - fines dominated deposits, ii) Deep - fines dominated deposits, iii) Fines enriched sand deposits, and finally iv) water capped disposal in end pit lakes. A brief overview for each of the methods of treatment and disposal for fluid fine tailings is provided.

Aug 1, 2013

By T. G. Phillips

"This paper gives an inside look at a bulk terminal and describes the preparations that must be made by a company in developing such a terminal and its position in today's traffic pattern. The following headings cover the subject material: (a) Traffic pressures, their detection and measurement, (b) position in the traffic flow -selection of site, (c) transportation connections -present and possible future routes, (d) engineering studies and costs, (e) contracts, the basic material for insured traffic, (f) financing, (g) budgetary control, (h) development of new techniques, (i) growth into new cargoes or cargo-handling methods and (j) consolidation."

Jan 1, 1968

By Derrick Hunter, Pat Feighan, Keith Chrystall, David Wells

"Equipment which may be remotely operated, has some degree of on-board intelligence, and which for periods of time may operate autonomously, is referred to as telerobotic. Recent advances in electronics, computers and hydraulic equipment have dramatically reduced the cost and simplified the process of converting standard industrial equipment to telerobotic control. The benefits of telerobotic equipment include improved safety by removing the operator from dangerous situations, reduced maintenance costs and increased productivity. This technology has been proven in various military, nuclear, and police applications.The surface mining industry has expressed an interest in automation and is characterized by a willingness to use remotely operated equipment, however, the majority of telerobotic equipment currently in use is experimental or prototypical. Potential applications of telerobotic equipment for surface mining include remote operation of equipment near dangerous high walls and other unsafe areas, utilization of robotic trucks for routine hauling operations, and control of jointed equipment. In addition, component technologies of telerobotic systems are relevant to various forms of condition monitoring, operator feedback systems, and vehicle positioning.Attention must now be directed toward resolving more complex problems associated with enhancing feedback to the operator, improving the man/machine interface, and ultimately, improving efficiency. Removal of the human operator from the work site introduces significant complications in replacing the sensory inputs that an operator normally uses to efficiently run his machinery. These can be difficult to define and even more difficult to replicate remotely and may include restrictions pertaining to vision, hearing, and touch.In cooperation with Defence Research Establishment Suffield and the Alberta Research Council, Robotech Industries Ltd. is pursuing the development of additional technologies to further enhance an operator’s ability to control remote telerobotic equipment. These developments include a head-mounted display, additional control station displays and improvements to coordinated motion control software. Prototypes of these developments are expected to be completed and tested by the fourth quarter of 1997."

Jan 1, 1996

By A. Vervoort, A. Govaerts

Geostatistical concepts are often difficult for students to understand, even those with a strong mathematical background. One of the main problems is the link between the variation of the parameter value in space or time and the calculated experimental semivariogram. Another challenge is differentiating between directional and omnidirectional semivariograms and their interpretation. For these reasons, interactive tools were developed based on the free public domain software R. The use of these interactive tools is limited to educational situations only (i.e., to visualize basic concepts). The interactive modules can be accessed at www.bwk.kuleuven.be/geostatistics.

Jan 1, 2014

By F. P. Hassani, Jacque Ouellet, M. Hossein

A laboratory investigation was undertaken to evaluate the effectiveness of different binding agents in a paste backfilling operation suitable to be used in a sulphide-rich environment. Different combinations of Portland cement and fly ash type C as well as ferrous slag were used as the binding agents. The unconfined compressive strength of the samples was measured for extended curing periods. The results indicate that the addition of 3% slag in the binding agent mix could produce strengths up to 0.5 MPa in the samples under investigation. For higher binding contents, the addition of Portland cement will lead to higher availability of calcium hydroxide and calcium aluminate, which are susceptible to deterioration from the phenomenon known as sulphate attack. Using slag, on the other hand, will reduce the permeability, availability of calcium hydroxide, and dilute the calcium aluminate ions reducing the susceptibility of the samples to sulphate attack. However, gypsum will form which could have the same detrimental effect on the strength of the treated matrix. Therefore, special attention must be given to the content and properties of agents used to activate the pozzolanic properties of the slag.

Jan 1, 2001

By W. H. White, A. J. Sinclair

"Unaltered biotites from three samples of monzonite and gabbro from the Copper Mountain stock and a single sample from a pegmatic biotite-chalcopyrite vein cutting the Triassic Wolf Creek formation have a mean K-A age of 193±7 m.y. These data support a suggestion based on geological evidence that Copper Mountain ore deposits are related genetically to the Copper Mountain stock.A cogenetic mineral pair (biotite and clinopyroxene) from a sample of sericitized and chloritized monzonite of the Copper Mountain stock have identical K-A ages of 150 m.y., which probably represents a time of wide-spread, post-ore, hydrothermal alteration. This alteration is believed to be related genetically to a group of post-ore intrusions known as the ""mine dykes,"" suggesting that they also have an age of 150 m.y."

Jan 1, 1968

By M. R. Henzinger, G. Lenz, A. Gaich, Pötsch, W. Schubert, P. Wagner

"The better the information on the rock mass and its fracture system, the better is the basis for any rock mechanical decision that is required during the excavation process. While in conventional tunnelling free view to the tunnel face is available, possibilities are limited for mechanised tunnelling using a tunnel boring machine (TBM). An approach, already formulated in 2005, is used that produces digital photographs through openings in the cutting wheel of a TBM and merges them into a circular three-dimensional image. The 3D image is then used for geometric rock mass characterisation purposes including geological mapping, for example to measure spatial orientations or determine joint spacing. In the paper the basic concept is described together with first results from a pilot test.INTRODUCTIONA three-dimensional image unites digital photographs with spatial information on the objects/surfaces it shows. Since they combine geometric and visual information they are a straightforward source for geometric rock mass analysis and geological mapping. Their obvious benefits among others are: (i) they allow spatial measurements even in inaccessible regions, (ii) they provide objective and reproducible records of the rock mass conditions, and (iii) they increase working safety (Gaich et al. 2004).Pre-requisite for the generation of 3D images is the acquisition of at least two photographs from the region of interest. From the photographs the imaged object surfaces are reconstructed by means of image analysis using methods from photogrammetry (Slama, 1980) and computer vision (Hartley & Zisserman, 2001). See also Figure 1."

Jan 1, 2015

By L. K. Daneshmend

Key issues in managing information systems in the minerals industry will likely continue to be those relating to the integration and interoperability of disparate systems. This paper argues that, in order to harness the promised benefits of information technologies, the mining industry should adopt a set of open systems standards to define data formats and protocols for seamless data exchange. This is in direct contrast to the present situation where mining equipment, software and instrument suppliers rigidly adhere to proprietary standards for fear of losing competitive advantage. Benefits to the mining sector resulting from the adoption of such standards would be: the provision of near-time data for executive decision support, and the freedom to choose best technologies. The principal benefits to the leading mining software suppliers will be increased market share as a result of “captive sites” converting to open systems standards. Examples are given of open systems standards developed for related industries such as the Petroleum Open Systems Corporation (POSC) and the Machinery Information Management Open Systems Alliance (MIMOSA).

Jan 1, 2000

By Fernando Canales

In the last decade a great dealt of attention has been paid to the chemistry of polynuclear gold derivatives with a central heteroatom, not only from the experimental and structural but also from the theoretical standpoint (1). Interesting hypercoordinated species of the type [C(AuPR3)5]+, [C(AuPR3)6]2+, [N(AuPR3)5]2+, [P(AuPR3)5]2+ and [P(AuPR3)6]3+ have been described (2), apart from other complexes with more conventional stoichiometry, and all have in common the presence of gold-gold interactions of ca. 3 Å. Usually, the chemistry of the first row elements of the p-block is known to follow classical rules of bonding, and only in cases of extreme electron-deficiency has the traditional electron count to be reconsidered to account for special types of molecular or solid state structures. Many of these heteroatomcentered complexes are electron-deficient and the gold-gold interactions provide a significant contribution to their stability. The attraction between these closed-shell systems has recently captured the attention in inorganic and organometallic chemistry (1). P. Pyykkö has summarized the available theoretical and experimental evidence of intra- and inter-molecular interactions between heavy metal atoms, such as Au(I) (3). In general, when heavy metals are involved in such interaction, the closed-shell attractions are of metallophilic or van der Waals type, as has been found for d8, d10 coinage-metals, and d10s2 centers. Experimental evidence for the aurophilic Au(I)???Au(I) attraction is available from crystallography, NMR and Raman spectroscopies, and optical spectroscopic measurements of the interaction strength (4). It is manifested in molecular conformations with relatively close Au???Au interactions of ca. 3 Å, whose strength has been estimated at ca. 25-50 kJ/mol (5). These attractions are weaker than most covalent or ionic bonds, but stronger than other van der Waals bonds and comparable in strength to typical hydrogen bonds. The phenomenon cannot be satisfactorily explained by classical theories such as hybridization (3). From a theoretical point of view, the attractions close to equilibrium distances are caused by dispersive interactions together with relativistic effects (6). The attractive contributions are dominated by pair-excitations from the heavy metal, such as gold, strengthened by relativistic effects. In all the cases where there are inter- or intramolecular metal-metal attractions, the correlation effects are essential; if they are omitted, at the Hartree-Fock (HF) level, repulsive interactions are obtained (6). Hence, it is necessary to use at least second-order Møller-Plesset level (MP2) methods for the dispersive forces, which are included in the electronic correlation effects (7).

Oct 1, 2003

By A. de Ville d’Avray, G. Guezennec, P. Wavrer, E. Braak

The aim of the European CEReS project was to develop an innovative copper recycling route based on the coprocessing of coal production waste by bioleaching and printed circuit boards (PCBs) from Wastes of Electrical and Electronic Equipment (WEEE). Coal waste is processed by bioleaching in stirred tank reactors, and the resulting bio-lixiviant solution is used to extract copper from PCBs pre-treated by catalytic cracking. Copper is then extracted using solvent extraction, stripping and electrowinning. The whole process flowsheet combines thermal, biotechnological, physical and hydrometallurgical operations. Once the process concept has been validated at laboratory scale, a simulator of the whole process has been built in the USIM PAC software platform. The tool enables to improve the analysis of the results of the lab-scale experiments and to design industrial-scale scenarios by simulation. The results of such simulations allow to estimate the economical interest and to perform environmental impact assessment. After presentation of the CEReS project objectives and main results, the paper describes the methodology used to build the simulator and define the scenarios corresponding to feasible process routes. The main results of the simulations are then presented with technical, economic and environmental point of views. INTRODUCTION Because of rapid technological innovations in the electronics industry, electronic waste represents the fastest growing waste stream in the world, especially in developing countries (Işildar et al., 2018). Meanwhile, the global copper demand is expected to go on rising in the future. As significant amounts of copper are present in end-of-life printed circuit boards (PCBs), it becomes a necessity to develop efficient copper recycling routes. Metal refining from e-waste is traditionally performed by pyrometallurgical processes. However, the hydrometallurgical processing of PCBs, which has been shown to be technically feasible at laboratory scale with a wide range of leaching reagents, could be a less energy intensive and more flexible alternative (Tuncuk et al., 2012). However, a large amount of leaching reagent is required to leach the metals from PCBs.

Jan 1, 2019

By T. H. Chuang, Y. Y. Shiue

"Rapid whisker growth was significantly alleviated in a Sn-58Bi alloy doped with 0.5 wt.% La. Experimental results showed that many thin, plate-form intermetallic phases appeared in the solder matrix. The absence of tin whiskers was correlated to the shape effect of RE-containing intermetallic plates. After reflowing, Cu6Sn5 intermetallic compounds appeared at the solder/pad interfaces of Sn-58Bi and Sn-58Bi- 0.5La packages with OSP pads, which grow linearly during the aging at 75 and 100? for various times ranging from 100 to 1000 h. In addition, the interfacial intermetallics layers in Sn-58Bi-0.5La solder joints were also observed thinner than those in undoped Sn-58Bi joints. However, RE-containing interfacial intermetallic compounds in Sn-58Bi-0.5La solder joints led to lower bonding strengths in both ball shear tests (0.4 mm/s) and high speed ball shear tests (2000 mm/s). All the reflowed and aged solder joints of both packages were ruptured through the solder balls indicating brittle characteristic INTRODUCTIONIt has been widely reported that solder alloys doped with rare earth (RE) elements reveal many beneficial effects, such as higher strength, lower melting point, improved wettability, and longer creep life (Wu et al., 2004; Ma et al., 2002; Chen et al., 2002). In addition, Dudek et al. reported that the alloying with 0.5 wt.% La in Sn-3.8Ag-0.7Cu solders resulted in an increase of rupture strain, up to 150% over undoped solders (Dudek et al., 2006). However, Chuang and Yen observed that a large amount of long, fiber-shaped tin whiskers were extruded out of the oxidized CeSn3 intermetallic clusters in the matrix of a Sn-3Ag-0.5Cu-0.5Ce solder air-stored at room temperature for several days (Chuang & Yen, 2006). Furthermore, many coarse hillocks appeared around the CeSn3 clusters in the RE-doped alloy after storage in an air furnace at 150? for several minutes. Chuang proposed a mechanism for the phenomenon of rapid whisker growth, which the predominate oxidation of CeSn3 intermetallics in Sn-3Ag-0.5Cu-0.5Ce solders induced compressive stress and extruded the tin atoms out of the specimen in the form of tin whiskers (Chuang, 2007). However, further investigation showed that Sn-9Zn-0.5Ce solders, after long term exposure at room temperature and 150?, were immune to the whisker growth; the immunity was attributed to the refining of the CeSn3 intermetallic phase in the alloy (Chuang & Lin, 2008). The inhibition of tin whiskers through the refining of rare earth containing intermetallics was further observed in Sn-3Ag- 0.5Cu-0.5Ce solders doped with 0.5 wt. Zn (Chuang & Lin, 2009). In addition to the size effect, the thin plate shape of intermetallic compounds was also shown in this study to inhibit the whisker growth on the surface of Sn-58Bi-0.5La solders."

Jan 1, 2012