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By D. Kong, A. Klyashtorin, L. McGilp, I. Wilson

This work reports on applying iron oxide coated sands media in an experimental permeable reactive barrier to remove uranium species from uranium containing water. A field experiment was conducted at the legacy Gunnar uranium mine & mill site that was abandoned in the 1960s with limited to no decommissioning. The flooded Gunnar mine pit presently contains about 3.2 million m3 of water contaminated by dissolved U (1.2 mg/l), Ra-226 (0.4 Bq/l), and minor concentrations of other contaminants (As, Se, etc.). The water is seeping over the pit rim into Lake Athabasca posing environmental and health concerns. Iron oxide coated sands can be used to immobilize uranium species through an adsorption process. Methods for preparation of hydrous ferric oxide sorbents and their supported forms onto silica sands are described. Fourier transform infrared spectroscopy (FTIR), and powder X-ray diffraction (pXRD) were used to characterize the physical-chemical properties of the sorbent. The monolayer uranium uptake capacity (Qm) was estimated through the Langmuir adsorption isotherm. Adsorption kinetic experiments were performed in a lab environment before moving to a field trial. Based on these lab results and the input on field-scale appropriate geometries, a pilot permeable reactive barrier was fabricated and a field test conducted near the Gunnar pit in June 2019. This pilot test provided technical data and information needed for designing a full-scale permeable barrier based on the iron oxide coated sands, which may be applied for in-situ water treatment at Gunnar and other legacy uranium sites.

Jan 1, 2020

"THE PACIFIC CONTINENTAL MARGIN OF CANADA is de-fined, for the purposes of this paper, as the area sea-ward from the present mainland coast of British Columbia to the foot of the continental slope. It thus coincides with A. Sutherland Brown's Insular Tectonic Belt. The region is limited to the north and south by the political boundary with the U.S.A., the location of which is still in dispute.The region can be subdivided into: (1) an interior trough comprising the Queen Char-lotte, Comox and Nanaimo basins; (2) a medial uplift comprising Vancouver Island and the Queen Charlotte Islands; and (3) a marginal shelf which is extremely narrow (Jess than 5 km) west of the Queen Charlotte Islands, widens to 160 km in Queen Charlotte Sound and is about 35 km wide west of Vancouver Island, where it is underlain by the Tofino sedimentary basin, with its• extension, the Juan de Fuca Basin, at the southern end.The medial uplift consists of a highly disturbed anticlinorium of mainly Mesozoic rocks, with a core of Palaeozoic. The rocks include thick sequences of eugeosynclinal volcanics and sediments. There is strati-graphical evidence of repeated interruption in sedi-mentation. By late Jurassic, the main eugeosynclinal phase was over and a successor basin was initiated in the interior' trough. This became filled, during Cre-taceous and Tertiary time, with sediments ranging in environment from bathyal turbidites to terrestrial conglomerates and coals. West of the medial uplift, another successor basin developed in early Tertiary times and became filled with mainly deep-water marine sediments. A third effusive sequence marks the base of the Tertiary on Graham Island and over most of the Hecate Strait region and Tofino Basin."

Jan 1, 1970

By André Desbiens, Frédéric Flament, Lionel Ryan

"In December 1991, the GRAHM (Groupe de Recherche sur Jes Applications de L'informatique a L'industrie Minerale), of Laval University started a KBAC (Knowledge Based Automatic Control) grinding project with Falconbridge Ltd. The project was shifted to the Kidd Creek concentrator in the summer of 1992, with the first phase involving the collection of data by GRAHM and Falconbridge personnel for the construction and tuning of a dynamic simulator. This grinding circuit dynamic simulator known as DYNAFRAG was used to assess various control strategies, with a PID-based strategy being selected for ease of installation on a Foxboro II A DCS.The ""B"" primary grinding circuit was chosen for the initial strategy development, which is one of three parallel divisions. The KBAC project was successfully completed in November 1994, with subsequent modifications being implemented by Kidd Creek staff.This paper summarizes, the current control strategy, the project costs, and the realized benefits. Some of the problems which were encountered with the initial installation, and the subsequent modifications are also dealt with in this paper.2.0 IntroductionIn the summer of 1992, the GRAHM of Laval University and Falconbridge Ltd. started a project to design a control strategy for the ""B"" grinding circuit at the Kidd Creek Division. Between 1992 and 1994 several papers have been written to describe the control objectives, the methodology followed, and some initial results (Flament, 1994A, 1994B). Since then, however, the control objectives changed, and several improvements were made to the circuit. In particular, maximizing tonnage was no longer a priority, a variable speed drive pump was installed on the cyclone feed, the ball mill power was lowered, and the geometry of the cyclones changed. As a consequence, the control strategy was revised. Table 1 summarizes the historical developments on the ""B"" division grinding control."

Jan 1, 1996

By F. E. Goodwin

Since the last CIM Zinc and Lead Conference ten years ago, significant technical and market forces have influenced how these metals are used, and the geographic distribution of their uses. Unprecedented price fluctuations have opened competitiveness issues, while the rapid growth of the Chinese market has created challenges both inside and outside China. Recent technical developments in battery energy storage, coatings, castings and chemical applications of lead and zinc will be reviewed together with the influence of these trends on end use markets.

Jan 1, 2008

By E. P. Cadwell

"Throughout the years Cyanamid has been a supplier of cyanide and a supplier of information to the mining industry. In general, the knowledge of mineralogy is greatly overlooked. Mineral deposits in the Western hemisphere have been exceedingly rich in the past but now they are becoming poorer. In other words, we will have to use our talents to the utmost to extract the precious metals and base metals from these ores. Modifications of some of the mineralogical equipment displayed here belong in the mill.Cyanidation of copper has been one of the main projects in our labs in recent years. De-rimming or de-filming of copper in order to upgrade copper concentrate was the main aspect investigated. A study was made as to how wide spread was the filming of secondary copper on pyrite, and to what extent it affected the copper industry. It was very wide.Often there is no conception as to what the minerals are. One open pit copper producer with a chalcopyrite ore was producing a copper concentrate with a 5% copper value whereas chalcopyrite contains 35% copper. They used primary and secondary grinding and a regrinding section. The ore contained about 8 parts chalcopyrite to one part of other copper minerals. In tests, a 3 1/ 2% copper rougher concentrate, cleaned without regrinding but conditioned with cyanide for a low contact time of 30 seconds produced a 30% copper concentrate with 90% recovery by removal of the film. It was of utmost importance that some quantitative mineralogical analysis be made before flow sheet changes were made. Every man should be trained to do his own microscopic examination in order to get quick answers. The fundamental thing in all mineral dressing is to first of all know the minerals and the mineral associations."

Jan 1, 1964

By T. Narita

The diffusion barrier coating system (DBC system) was designed to suppress interdiffusion between alloy substrate and coatings in addition to ensuring slow oxide growth at high temperatures. In this report the concept of the DBC system will be introduced, and the results obtained for various heat-resistant alloys are presented. In this DBC system the s-phase of the Re-Cr-Ni system was selected as the barrier and is formed by electroplating Re-Ni and Ni films from aqueous solutions, followed by Cr and/or Al pack cementations. A typical DBC system consists of Ni-base superalloy / triple s-Re based alloy layer / ?’-Ni3Al and/or ß-NiAl (with or without Pt addition) / a-Al2O3. It was found that the DBC system maintained its structure for long time exposures because the s phase has tie-lines with the ? and ?’ alloy substrate and the ?’ and/or ß coating. The s-Re based alloy can suppress both the inward Al diffusion and the outward diffusion of alloying elements. The DBC system was successfully applied to various heat-resistant alloys such as Ni-Mo and Fe-Cr-Al based alloys, and these alloys with the DBC system were creep-deformed slowly under external applied stresses. A simultaneous diffusion coating process for Al and Hf was developed using Hf+NH4Cl+Al2O3 pack cementation. To obtain reliable and long-life coatings the combination of alloy substrate, coating, and external scale should be considered as a total system, to optimize oxidation resistance, structural stability, and mechanical properties.

Jan 1, 2010

By M. E. Moraes Castanho de Almeida, A. Ribeiro Cotri

Recovery of cobalt to produce high grade cobalt sulfate from cobalt concentrate by leaching and solvent extraction was investigated. The PLS typically contains Co 10g/l, Mg 2g/l, Fe < 10ppm, Mn < 200ppm, insolubles <100ppm and is extracted with 20wt% Cyanex??272. The typical strip solution contains Co 60g/l, Mg 0.03g/l, and was sent to the current process for the production of cobalt sulfate heptahydrate. The cobalt yield of the plant with two extraction steps was 92%, with three steps was 97% and with four steps 99%. The extraction stage used the concept of "scrubbing" in a countercurrent system. In the first stage of extraction pH was 4.8, and in the last stage of extraction pH 5.5 to promote the exchange of magnesium in the organic with cobalt contained in the PLS. Following the extraction, when using two scrubbing stages, Co/Mg selectivity between of 2,000-3,000 was obtained, and with three scrubbing stages, selectivity was greater than 6,000. The desired selectivity was reached when using a scrubbing configuration with O/A ratio of 10:1. The typical cobalt sulfate heptahydrate had the following composition: Co 20wt%, Mg < 0.01wt%, Fe < 5ppm, Mn < 0.01wt%, Cu < 0.01wt%, Zn < 0.01wt%.

Jan 1, 2014

By R. B. Nourse, R. Hundermark, B. Masters, H. Joubert

The new 30 MVA slag cleaning furnace at Waterval Smelter, Rustenburg Platinum, South Africa, has been in operation since 10 March 2003. The furnace design and operation face a number of challenges including a wide variety of feed materials and resulting bath conditions. Furnace feed varies in combinations of granulated Waterval Ausmelt Converter Slag (WACS), hot fed Peirce-Smith converter slag, concentrate and reverts. Coke is added as reductant. The resulting slag composition varies considerably and regularly. For the case feeding WACS an almost pure fayalitic slag (60%+ FeO, 30%+ SiO2) with a very low viscosity results. Due to the widely varying slag conditions, including a superheated fayalitic slag with high fluidity, a robust sidewall design is required adjacent to the slag bath. For this reason the furnace sidewall is equipped with Pyromet&apos;s MAXICOOL® high intensity copper cooling system. The design and installation of the copper coolers as well as tap holes are discussed. To cope with the variation in bath conditions and high slag superheat (350°C when tapped at 1650°C), the copper coolers are capable of removing peak sidewall heat fluxes above 500 kW/m2. Feedback is included on the performance of the Pyromet MAXICOO® copper cooling system for the first two years of operation. The paper further includes an overview on the design and performance of the tap holes, furnace shell, furnace roof and copper slag spouts.

Jan 1, 2005

By E. Wusaty

"Fording Coal is a wholly owned subsidiary of Canadian Pacific Limited. The company was founded in 1968 to mine metallurgical coalfor export at the Fording River operations in southeast British Columbia.Today, Fording Coal Limited also operates the Whitewood mine under contract to TransAlta Utilities and the Genesee mine under a joint venture arrangement with Edmonton Power. Both these operations are located just west of Edmonton and produce subbituminous low-sulphur coal which is used for power generation. Fording also owns and operates two industrial mineral mines in the United States and is mining overburden under a lo-year contract with Syncrude Canada at Fort McMurray.As of December 1992, Fording Coal Limited owns and operates the Greenhills mine which was closed due to bankruptcy. This papers deals with the innovations and changes which have been made and those which are currently being implemented to make this operation competitive in the world export coal market. IntroductionOn December 4, 1992, following a tendering process, Fording Coal was awarded 80% controlling interest in the Greenhills mine by Trustee Arthur Andersen Inc. Assets acquired included 100010 of the land and coal leases and 80% of the major joint venture assets including all structures. The remaining 20% is owned by Pohang Steel Canada Ltd., a wholly owned subsidiary of Pohang Iron Steel Co. of Korea. The Greenhills mine had been in continuous operation since 1983 and was finally closed due to bankruptcy of its majority owner on October 31, 1992.A permit to operate the Greenhills mine was issued by the British Columbia government on January 29, 1993, and Fording Coal Limited started mining operations in late February 1993.To return the Greenhills mine to profitability significant changes were required in workforce productivity, mining methods and equipment selection. These mine plan changes are designed to make the Greenhills operation competitive in world markets, provide longterm employment for the company&apos;s workforce and ensure that a secure supply of coal is available."

Jan 1, 1994

By R. W. Boyle, W. Dyck

"Scientists throughout the world have observed radioactive disequilibrium in the uranium decay series. Radiometric and fluorometric determinations of U in plants from the Goldfields district and in sediments and rocks from the Beaverlodge district exhibit marked radioactive disequilibrium. The eU/U ratio in plants rooted in mineralized ground shifts from greater than unity to less than unity for those rooted in background soils. A similar shift is observed in the transition from rocks to stream sediments and to lake sediments in the Beaverlodge district.Results of a Rn-Ra-U survey of lake bottoms in the Key Lake district show that anomalous hydromorphic U from U mineralization is parallelled by anomalous Rn, even though there is much less Ra in the lake-bottom sediments than one would expect from the amount of U present. IntroductionDisequilibrium in the U decay series has been studied for many years and is observed in almost all surficial environments. Rosholt (1959) measured U, 234Pa, 23O&apos;fh, 226Ra, 222Rn, and 210Pb in a large number of U ores and outlined six types of situations to explain disequilibrium. Davy (1974) outlines the geological significance of radioactive disequilibrium situations with respect to exploration. Levinson and Coetzee (1978) discuss possible mechanisms by which separations of parent and daughter elements are affected and suggest analytical pitfalls that may be encountered in the use of radiometric techniques when disequilibrium has occurred. Generally, it is the oxyphile and easily complexed parent 238U (with its associated isotopes 235 U and 234U) that is leached from rocks and soils at a faster rate than are the daughters, 230Th, 226Ra, 2loPb, and 206Pb. This mobilized U is adsorbed on sediments in streams and lakes, or enters groundwaters, where it is eventually precipitated under reducing conditions, occasionally in oregrade concentrations. This surface leaching and"

Jan 1, 1980

By Fathi Habashi

Extraction by organic solvents is a chemical process in which metal species in the aqueous phase react with an organic reagent to form an organometallic com- plex, thus, the metal species leave the aqueous phase and enter the organic phase from which it can be stripped back in the aqueous phase to obtain a pure and a concentrated solution. The metal in the organic phase is not bound to carbon atoms as in organometallic compounds but to oxygen, nitrogen, sulphur, or hydrogen by a co-ordination (dative) bond (Habashi, 1999).Solvent extraction was used for the first time in hydrometallurgy in connec- tion with the special and urgent materials requirements of nuclear energy during World War II. A plant was constructed in the United States for the preparation of high-purity uranyl nitrate solution. In this plant, the yellow cake (a high-grade sodium or ammonium uranate) was dis- solved in HNO,, and uranium was selec- tively extracted by ether then stripped by water to give a concentrated solution of pure uranyl nitrate. This was gradually followed by developing methods for other high-priced metals such as plutonium, thorium, niobium, tantalum, zirconium, hafnium, boron, beryllium, and molybde num. The second step took place in the 1960s when solvent extraction was applied for the first time to extract a rela- tively cheap metal-copper. At present, solvent extraction technology is wide- spread, well accepted, and highly efficient. Solvent extraction had its origin in the discovery, by Christian Friedrich Bucholz (1770-1818) in 1805, that uranyl

Sep 1, 1999

By E. Tulcanaza

Mining companies normally establish exploration and research programs originated with actions in embryonic stage. At their early stages of development, these exploration and technological activities are subject to uncertainties that need, first, to be resolved, deciphered or, at least, mitigated for information reporting; and later, for valuation reporting. Under these circumstances, these exploration activities follow a sequence of development phases that range from exploration work to the profile, conceptual, and finally to basic engineering phases and construction. For information reporting, the International Template for Reporting of Exploration Results, Mineral Resources and Mineral Reserves integrates the minimum standards being adopted by the relevant professional bodies in Australia, Canada, South Africa, Chile, USA, UK, Ireland, and other European countries which set up the Committee for Mineral Reserves International Reporting Standards (CRIRSCO, www.crirsco.com). These standards are based on the progressive collection of relevant information to reduce present and future uncertainties over time under a context of transparency, materiality, and technical competence. For valuation reporting several procedures have been disclosed and applied. However, in the last decades financial instruments such as real options, decision analysis, and games theory have developed into a niche of great potential for mine valuation applications. The objective of this paper is to provide a summary of the information reporting standards prepared by the Chilean National Commission for the Qualification of Competent Persons in Mineral Resources and Mineral Reserves and show a procedure and an application of real options to the valuation of the sequential development phases of a mine asset from the exploration stage through up to full development.

Jan 1, 2007

By E. Fiset, T. Hennebel, F. Verbruggen, A. Prévoteau, K. Rabaey

Arsenic (As), bismuth (Bi) and antimony (Sb) are known to affect the quality of copper deposits in copper electrowinning operations. The codeposition of As was previously believed to occur only at current densities far exceeding the range of typical current densities for copper electrowinning. In this study, we investigate the copper electrodeposition on different pretreated stainless steel (SS) substrates from bleed electrolyte in galvanostatic mode at –45 mA/cm². Scanning electron microscopy (SEM) micrographs illustrate that during the initial phases of copper nucleation and growth, the current density was locally increased due to the pretreatments. It was reasoned that the codepostion of As could possibly occur in normal electrowinning conditions, but the risk can be substantially reduced by good SS substrate handling and maintenance practices. INTRODUCTION The presence of As, Bi and Sb is known to have a deleterious effect on the copper cathode quality in copper electrowinnings (Hiskey & Maeda, 2003; Hoffmann, 2004; Xiao, Cao, Shen, & Volinsky, 2012; Xiao, Cao, Mao, Shen, & Ren, 2014; Jafari et al., 2017). They are known to influence both the chemical and physical quality of the copper as they can contaminate the copper (Jafari et al., 2017) and affect the copper deposit structure (Hiskey & Maeda, 2003; Kim, Kim, & Chung, 2009), which contributes to a degraded market value of the copper (Tuddenham, 1984). The incorporation mechanisms of these impurities are believed to occur mainly through slime inclusion (F. Xiao et al, 2012) and electrolyte inclusion (Hiskey & Maeda, 2003). Other studies suggested that codeposition of these impurities is possible by their standard reduction potential being close to the one of copper (Xiao et al, 2014). Hiskey and Maeda (2003) investigated the copper electrodeposition on a copper electrode substrate in Cu electrolytes with a Cu, H2SO4, As, Bi, Sb composition representative for commercial copper tankhouses. The combination of voltammographic techniques and Auger electron spectroscopy showed that As was the first impurity to be electrodeposited from this electrolyte, yet at potentials where the limiting current density of the copper electrodeposition reaction is exceeded. The copper tankhouses usually operate at a current density ratio of 0.3 to the limiting current density in order to achieve tolerable copper quality deposits. The codeposition of As could be considered impossible in this current density condition. However, it is known that during the initial phases of electrodeposition on foreign substrates, a substantial part of the reaction proceeds by growth of individual nuclei where the current density is locally high and diffusion limited (Radisic, Ross, & Searson, 2006). Furthermore, it was observed that copper nucleation on TiO substrates occurred preferentially in the scratched oxide free areas which could serve as parts with high localized current densities (Chang, Choe, & Lee, 2005).

Jan 1, 2019

By E. Lehtila, J. J. Talja, R. Jahila

Kopar Oy is acknowledged for engineering and manufacturing of robust systems for bulk material handling, especially at power plants and non-ferrous smelters. We have over thirty years of experience with systems specifically designed for hot and abrasive conditions, aiming at low cost of ownership, low operational expenses and high availability. Although Kopar has numerous applications in mechanical conveying, there is an increasing number of pneumatic conveying applications at copper smelters. They relate to conveying of concentrate, and primary and secondary flue dusts. Challenges of pneumatic conveying for concentrate are mechanical and do relate to broad particle size distribution and high abrasivity of the concentrate and the silica. Therefore, special attention shall be paid to system design and ceramically lined bends in the pipeline. Challenges of pneumatic conveying of primary flue dust relate predominantly to material stickiness and poor flowability which are mainly due to fine particle size and formation of sulphates and furthermore, crystalline water. Additional challenges of secondary dust, the white converter dust, are primarily due to the extremely fine 0.1–1.5 µm particle size and problems which come with this. Effect of material characteristics like size distribution, morphology and chemical composition in pneumatic conveying are discussed in detail. INTRODUCTION Fine materials like concentrate, feed mix, flue dusts (from waste heat boiler and electrostatic precipitator) and secondary dusts need to be conveyed at smelters. Both horizontal and vertical conveying and combination of those are used. For the purpose, both mechanical and pneumatic conveying are applied. Most widely used equipment are drag chain conveyors and various combination of pneumatic systems, e.g. air lift, dense-phase and dilute phase pneumatic conveyors. Kopar has 30 years’ experience with multiple material handling systems. Furthermore, acquired companies like Elmomet Oy and SITE Oy (both currently fully merged and integrated into Kopar Oy) have even longer history, especially in pneumatic conveying. It is commonly known that the finer the dust the more difficult it is to be conveyed pneumatically. Sulfates with crystal water makes it all even more difficult, if not ineligible. Challenges related to pneumatic conveying of various fine materials is discussed in detail in the paper.

Jan 1, 2019

By M. S. Moats, C. M. Campbell

Samples of a high impurity (90.05 wt. % Cu, 4076 ppm Pb, 1939 ppm As and 635 ppm Bi) commercial copper anode were characterized and then electrorefined in a laboratory scale cell. Anode inclusions were examined using backscatter mode scanning electron microscopy and energy dispersive spectroscopy. Hundreds of inclusions were measured for size, morphology and composition. Commonly found inclusions were copper oxide (Cu2O), complex oxides (Cu-Pb-Bi-As-O) and copper selenides/tellurides. The weight percent of lead and arsenic increased with increasing inclusion size up to 4- 5 microns. During electrorefining, starter sheet ductility was negatively impacted by thiourea addition. The importance of arsenic (V) concentration on the electrolyte concentration of bismuth was observed. INTRODUCTION Copper electrorefining is a commercial process used to produce the majority of the world’s refined copper. During this process, impure copper anodes are dissolved electrolytically, and high purity copper is deposited on cathodes. As the anodes dissolve, the impurities either accumulate in the electrolyte or report to solids that form on anodes surfaces or at the bottom of the refining cell. These solids are called slimes. Slimes contain precious metals and are collected for further processing. Slimes are also an important outlet for problem impurities such as lead, antimony and bismuth. The electrorefining process is operated in such a way to encourage the deportment of these elements to the slimes. Impurities in copper anodes have been studied extensively by Chen and Dutrizac (1990, 1993 and 2005). The most common impurities found in modern copper anodes include: Ag, As, Au, Bi, Fe, Ni, O, Pb, Sb, Se, Sn and Te. Impure copper anodes are produced by pyrometallurgical methods and have purities ranging from 97.7–99.7% Cu (Moats et al., 2019). The composition ranges of commercial copper anodes from the 2019 worldwide tankhouse survey are given in Table 1. The concentrations of anode impurities vary widely dependent on the source material and prior processing steps. Based on the work of Chen and Dutrizac, both gold and silver are predominantly found in solid solution within the copper grains while a minor amount of Ag can be found in Cu2(Se/Te) inclusions. Nickel is entirely soluble within the copper grains up to anode compositions of 2500–3000 ppm Ni; above which NiO and kupferglimmer phases are formed (Chen & Dutrizac, 1990). As, Bi, Pb and Sb are found in solid solution within copper and within oxide inclusions typically found along grain boundaries. Oxides are formed due to the presence of 0.13-0.18 wt. % O (Chen & Dutrizac, 1990). This is because during solidification of the cast anodes, impurities are enriched in the liquid phase as the copper grains nucleate and grow. The inclusions form from the last liquid to freeze, which is typically along grain boundaries (Wenzl & Filzwieser, 2007; Wenzl, Filzwieser, Mori & Pesl, 2008).

Jan 1, 2019

By G. J. Hawkes

"We all know that every man who works for us should have a thorough knowledge and understanding of his responsibilities. But how about ourselves? Du we have a thorough knowledge and understanding of our own responsibilities as Mill Superintendents?I once had an occasion to say to a Manager that I did not know something was my responsibility and he replied with suitable emphasis ""Everything inside those four walls is your responsibility"". That makes the extent of our responsibilities clear but does not give us a check list to keep an eye on as we do our job from day to day.What are our responsibilities? I suggest they are the following:1. Developing and maintaining efficient operating and maintenance crews.2. Milling the required tonnage.3. Recovering the economical maximum amount of gold.4. Keeping costs at the economical minimum.5. Seeing that the figures are reasonably accurate for tonnages, assays, production, losses, and costs.6. Preventing accidents.7. Preventing fires.8. Maintaining the equipment and building and keeping them clean and tidy.9. Enforcing company rules and regulations."

Jan 1, 1965

By D. Shishin

Continuous integrated experimental and thermodynamic modelling work is conducted in Pyrometallurgy Innovation Center (PYROSEARCH). The target is to develop a tool, which is capable to predict the compositions of phases, phase equilibria and enthalpy balance for pyrometallugical processes with higher accuracy. All these can be achieved by thermodynamic calculations based on Gibbs energy minimization algorithm. Recent developments made it possible to predict important factors, such as the chemical solubility of Cu in slag as a function of matte grade, temperature, P(SO2), Fe/SiO2 ratio in slag, wt% Al2O3, CaO and MgO in slag. In industrial practice, it is not only chemical solubility, but the overall amount of slag, which affects the recovery of copper and other valuable metals. It will also impact the energy balance. The presence of solids in the slag matrix influences the physical entrainment of matte in slag. Oxygen enrichment which is sometimes used to control the temperature of the furnace, may also affect the volatilization of minor elements into the gas phase. Same is true if additional fuel is used to compensate for heat balance. In other words, all key process parameters mentioned above are interrelated. Present study demonstrates the ways thermodynamic modelling can be used to link those process parameters on the example of copper smelting. INTRODUCTION Research methodology involving integrated thermodynamic modelling and experimental approach has been recently reported by the authors (Shishin, Hayes, & Jak, 2018 Shishin, Hidayat, Jak, Decterov, & Belov, 2016). Present paper reviews the updates and discusses challenges in the development of a large self- consistent thermodynamic database. The database covers the Al-Ca-Cu-Fe-Mg-O-Pb-S-Si-Zn-(Ag, As, Au, Bi, Ni, Sb, Sn) chemical system. The database works in the environment of FactSage software Bale et al., 2016 and related family of products: ChemApp (Petersen & Hack, 2007), ChemSheet and SimuSage. A list of phases, and thermodynamic models is shown in Table 1. For the copper industry, most important phases are Gas, Slag, Spinel and Liquid matte/metal/speiss. Black-colored elements represent the base system, elements in green can be considered as slag modifiers (slagging elements), and elements in red are minor. Ni is highlighted because it was included recently, in 2019, and currently under development. In addition to copper, the database covers the conditions typical for lead and zinc pyrometallurgical extraction. It is developed in consistency with the experimental results for high concentrations of Pb and Zn. Examples of applications in the present study include the thermodynamic analysis of fluxing for an agitated copper reactor to show the effect of Fe/SiO2, and calculations of copper slag cleaning using reductant.

Jan 1, 2019

By J. Ga?parík

The optimal selection of machine or machine group for building processes is very important role of building planner during the process of building planning. During this process building planner have to analyze several factors influencing the final effective decision concerning this problem. There are several factors and criteria for effective selection of building machines. In our contribution there are analyzed: ability of machines to realize designed building process (quality aspect), duration of mechanized process (time aspect) and minimizing of energy consumption (cost and environmental aspect). Selected scientific methods and theories of problem solution can be divided into these groups: theory of system (creation of building machine selection method), multi-criteria optimizing method (analysis of mechanized building process from the point of more optimal criteria), queuing theory (application during the mathematical modeling of mechanized soil processes), method of scientific analysis (analysis of factors influencing final decisions), method of scientific synthesis (creation of optimizing method implemented into building processes and possible application in construction sector). Multi-criteria optimizing method were during our research work implemented into soil processes and selected building group machines (excavators and trucks), which are very often used in construction and mining processes. This method can be considered as a multi-level decision making process based on multiple parameters. In our contribution is presented key mathematical models for model example solution and software built in Java, which has been created as a support for method described in this contribution. Application of this method and software will increase the effectiveness of building machine selection from the point of key criteria of optimizing: quality, time and energy consumption.

Aug 1, 2013

By David Meadows, Elmer Palmer, Steve Dixon

As part of the Goldcorp Inc growth plan Minera Peñasquito SA de CV has developed its polymetallic deposit with a large “state of the art” concentrator to process lead and zinc ores. The plant consists of two grinding lines including 38ft diameter SAG mills and 24ft diameter ball mills. During mid to late 2009 concentrator commissioning activities commenced. First concentrates were produced in October 2009 and now the plant is meeting its design basis of 65,000 mtpd per line. This paper describes the design and operational experience to date for its grinding circuit design, together with the recently commissioned HPGR crushing circuit.

Jan 1, 2012

By Hämäläinen M., O. Hyvärinen, E. Jääskeläinen

HydroCopperTM is a new hydrometallurgical process for the treatment of copper sulphide concentrates, which has been developed by Outokumpu. The process includes chloride leaching of copper concentrate, solution purification and precipitation of copper(I) oxide, an intermediate product, which is reduced and cast into copper products. The reduction can be carried out by pyrometallurgical methods or hydrometallurgically in an autoclave. This paper discusses the thermodynamic and kinetic aspects of the hydrogen reduction of copper(I) oxide in an autoclave. The results of the laboratory tests are presented and discussed. Finally, the autoclave method is compared with other options.

Jan 1, 2004