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By C. Suazo, O. Alruiz, A. Hofmann, I. Fernandez, W. Kracht, N. Mora

"Compañía Minera Dona Inés de Collahuasi, CMDIC, has developed a methodology that allows estimating economic benefit taking into account the variability of the ore characteristics (geometallurgical models). Currently, the grinding model allows predicting the treatment capacity, specific power and balls consumption for short, mid and long term planning. An alternative impact test to estimate SAG grinding parameters is presented in order to bring the geometallurgical model from mid and long term to short term planning. The impact test uses either the production bench or geological drill holes. This allows Geologists increasing the density of grinding parameters within the block model improving the geostatistical estimation of the rest of the blocks. The test requires a small amount of sample to obtain the requires grinding parameters for the grinding model in comparison to the well known grinding test and also, it can be performed easily and quickly by the geology team of a mining company. The alternative grinding test is presented in this article. The grinding model using this short grinding test has been successfully used in mining planning and the accuracy of the model is demonstrated using monthly average instantaneous throughput from January 2013 to March 2014, showing an average relative error of 5% and an R2 value of 0.9. Also, 111 individual variability samples were divided into two each, in order to compare the estimated grinding parameters based on this alternative test to the grinding parameters obtained from the conventional grinding test. The comparison shows an average relative error of 4% and an R2 value of 0.9."

Jan 1, 2014

By C. Suazo, N. Mora

"The bubble size distribution plays a fundamental role in flotation kinetics. Nowadays it is possible to measure the bubble size distribution, gas holdup and superficial gas velocity by using specialized equipment developed for this purpose. In this article a methodology is presented for estimating the kinetic rate constant using a known particle and bubble size distributions. The attachment and detachment probabilities were modelled from three matrixes. The first matrix represents particle size distribution, the second was named the probability matrix, and the third is the bubble size distribution. Using laboratory data, it has been possible to estimate the flotation rate constant as a function of operating conditions and both the bubble and particle size distributions. The model tested at laboratory scale achieved a quadratic correlation coefficient equal to 0.97. This methodology could be used in the operation and control of the flotation, when in the near future we have industrial equipment that allows in-line measurement, in real time, of gas dispersion and bubble size distribution. knowing particle size distribution, it will be possible to manipulate the operating flotation cell conditions, in order to modify the bubble size distribution and find the bubble distribution that maximizes flotation kinetics. Furthermore, knowing the bubble size distribution, the grinding operator will be able to look for the particle size distribution that produces the maximum flotation kinetics. In order to do this, the operator will have to modify the solids percentage fed to the hydrocyclone cluster, modify the apex/vortex ratio, etc. Finally, this article shows that the maximum flotation speed is reached when the particle size distibution slope is equal to the bubble size distribution slope."

Jan 1, 2014

By Nicolás Luis, Qi Liu, Gonzalo Montes-Atenas

"The prediction of froth flotation performance is still an unresolved topic. Classic industrial models based on particle size, elemental and mineralogical information provides recovery results with deviations that may become significant. One possible reason for this deviation may be the fact that the current liberation analysis provided by electron microscope based techniques does not take into account the outmost surface layer composition of liberated particles. In order to complete the description provided by the liberation analysis, other spectroscopy techniques measuring the extreme surface of the minerals can be tested. For instance, X-ray Photoelectron Spectroscopy (XPS) is a technique which measures the first tens of nanometers providing elemental composition over the particle surface and allows resolving the elemental associations present at the surface sample. However, this information needs to be statistically robust, reproducible and most importantly representative of what is occurring in the process. The aim of this research work is to develop a statistical model based on particle population to evaluate the feasibility of turning the XPS technique into a metallurgical tool. The model consists of classic statistical population arranged in a bed of heterogeneous particles with a known grade and mineral liberation. The simulations showed that the XPS results statistically followed a well-defined pattern. The statistical results were confronted with pilot plant results obtained from a rougher bank when processing a copper sulfide ore from a Chilean mine site. It was observed that the probability function distribution was in agreement with the experimental data. Further analysis on how the XPS results provide valuable information improve the computation of froth flotation recoveries is also discussed."

Jan 1, 2014

By Tomás Vargas

Treatment of copper sulphides minerals via leaching-solvent extraction-electrowining (lix-sx-ew) have been for years the process scheme proposed from hydrometallurgy as an alternative to the conventional flotation-smelting route. Many different hydrometallurgical technologies of this type have been proposed, investigated and tested over the years, but until today none of them has come close to endanger the predominance of the flotation-smelting route in the copper industry. However, bioleaching introduced an important breakthrough in this context as this technology enabled the alternative hydrometallurgical treatment of secondary copper sulfide ores and low grade ores by applying heap bioleaching processes. Extension of its application to primary copper ores have been limited until now by the nature of chalcopyrite which is very refractory to leaching. However, important improvements are expected by using of improved designs that enable to operate at high temperature ranges where copper is leached faster under the catalytic action of thermophile microorganisms. The present work analyzes future scenarios for the application of this technology either in heaps or in-situ, which can become very attractive as copper can be produced reducing drastically the energy consumption associated to the mining, crushing and grinding stages.

Jan 1, 2014

By Francisco Vicuña, Miguel Becerra, Gonzalo Montes-Atenas

"The optimization of the copper recovery from smelting slag by a process of comminution / flotation has been a widely discussed topic during the last few decades. Several studies covering the characterization of different types of slag, the impact of the slag cooling rate and of different flotation operating conditions on the flotation performance have been widely published. Currently, at El Soldado mine site (Angloamerican), there are large copper bearing slag deposits that can be a profitable alternative for the concentrator with capacity to treat this material. Under this process schema, the optimization of the flotation process to obtain better copper recoveries is a relevant topic of study. The aim of this study is to assess the efficiency of a sulfidation stage of a slag and to correlate that process with copper recoveries results in a flotation circuit. This article presents a detailed examination at both laboratory and plant scales of the slag sulfidation on the recovery of copper in the flotation process. The experimental methodology involves studying the effect of the sulfidation agent dosage, the pH, the particle size distribution of the flotation feed and the conditioning time. Furthermore, the performance of the sulfidation stage was analysed through the XPS analytical technique. It was observed that the sulfidation of particles in floatable size fractions correlated well with the increase in copper recovery. The results indicated that it is possible to increase between 2 to 4 points the total copper recovery with a sulfidation process implemented appropriately."

Jan 1, 2014

By Javier Baladron, Mijail Villar, Brandt Henriksson

"In this presentation an overview will be given of what has been observed by the authors in the copper concentration industry, with a large diversity of tailing thickeners operating under different conditions, although many of them are located in the same neighborhood. A closer look will be taken at the reported performance from different sites and from different thickener designs, either conventional or high rate, including those that were retrofitted, regardless of the thickener brand. An analysis is also made of the generic correlation of the size of the thickener and the performance in terms of solids loading (or unit area) and % solids. The paper envisions a technology development route, makes a brief analysis of the economic impact of the suggested route and points out the need for development in technologies around tailings thickeners, such as automation, yield stress measurement, slurry pumping and construction methods."

Jan 1, 2014

By Daniela Campos, Aldo Casali, Gonzalo Montes-Atenas

The understanding of the effect of the major variables influencing the froth flotation performance may allow both to predict and to identify best operating conditions towards optimizing the process efficiency. The aim of this research work is to model the effect of dissolved oxygen onto froth flotation performance. Experimental pilot plant results were obtained from a continuous circuit consisting of a ball mill and a rougher bank of four flotation cells. A series of flotation experiments were run with different conditions of dissolved oxygen keeping constant most of other operating conditions. Variables difficult to control were measured or estimated. A set of mathematical models suggested in the published literature were tested. It was found that the copper recovery results were highly sensitive to the concentration of dissolved oxygen. The latter confirmed the reactions mechanisms associated to the collecting capabilities of current flotation reagents used in the flotation of copper sulfide ores. On the contrary, the results of molybdenum recovery varied non-linearly with changes in dissolved oxygen which could not be explained directly in terms of the computed specific rate constants. The error analysis confirmed that Klimpel continuous model exhibited the best specific rate constant correlation with molybdenum recovery data. Lastly, the classic particle force balance equations indicated that the adjustments of estimated mineral liberation with experimental data exhibited a turning point when passing from highly liberated to low liberated particles. The values of recovery for such turning point correlated well with the concentration of dissolved oxygen. The results indicated corrections due to changes in the dissolved oxygen must be incorporated in future froth flotation descriptions.

Jan 1, 2014

By K. W. Stöckelhuber, A. Wenger, H. J. Schulze

"An important elementary step of the flotation process is the forming, drainage and rupture of a thin intervening liquid film between bubble and mineral particle.After the encounter of the bubble with the solid surface a wetting film is formed. The initial thinning of this film is driven by the capillary pressure inside the bubble. When the film has reached a certain thickness rupture can take place. There are two possible mechanisms describing this process:(a) Gas nucleation, caused by nano bubbles inside the film.(b) Growing fluctuation waves (spinodal dewetting) on fluid interfaces under the influence of any kind of attractive forces (electrostatic, van der Waals).Metastable wetting films on negatively charged, hydrophobic glass surfaces (gaseous phase methylated), or on hydrophilic, positively charged glass surfaces (with Al3+ ions), have been analysed by means of the kinetics of film thinning according to the Reynolds law. These experiments demonstrate that both mechanisms can be responsible for the rupture of a thin wetting film."

Jan 1, 2003

By R. Imhof, S. E. Sánchez-Pino, H. Sprenger, S. A. Sánchez-Baquedano

"In 1992, Ingeniería de Minerales started with the introduction of pneumatic flotation technology in Chile and South America. This technology consists of vertical cells and gyratory cells, used mainly under actual operational conditions, with pilot units directly installed in the concentrator circuits of the industrial process. Successful industrial applications have been observed at Los Pelambres, in the molybdenum plant; at Codelco Andina in the molybdenum plant as pre-rougher to produce directly a final concentrate; in the copper circuit at Las Luces as pre-rougher producing final concentrate using sea water; at Minera Valle Aconcagua where a full automatic plant produces pre-concentrate from fresh tailings as feed; at the silica and silicate reverse flotation circuit of Compañía Minera del Pacífico; in cleaning the final concentrate of Zn by reverse flotation removing ultrafine carbonate; and in a plant that reprocesses fresh tailings from a copper slag flotation process. Positive operational changes in the design of the flotation circuit have been seen in plants using G-cells and V-cells, improving the performance of flotation circuits and the quality of final products. The high concentration of bubbles and micro turbulence produced by the pneumatic aeration units provide a high probability of collision and attachment, reducing dramatically the residence time. Though it is a pneumatic flotation, no compressed air is needed, and the equipment is characterized by low maintenance costs, full automation, savings in investment and energy."

Jan 1, 2014

By Johan Nell, Paul den Hoed

"Carbochlorination tests were conducted with matched particle-size fractions of rutile, ilmenite and hightitania slag in a small bubbling fluidized-bed reactor. The effects of temperature, the type and proportion of solid reductant in the charge, and the fraction of Cl2 in the fluidizing gas were investigated. Tests confirm the need for solid carbon in the bed if chlorination is to run at high rates. With solid carbon in the bed, CO supplied with the fluidizing gas does not increase significantly the degree of chlorination after 75 minutes.When large proportions (30 wt%) of carbon are added to the charge, then the reactionTiO2 + 2C + 2Cl2 = TiCl4 + 2COis favoured overTiO2 + C + 2Cl2 = TiCl4 + CO2Ilmenite is chlorinated more quickly than titania slag, which in turn is chlorinated more quickly than rutile. Rates of chlorination at 1100°C and 1000°C are much the same and significantly higher than at 900°C. Chlorination is associated with significant increases in particle porosity (even for rutile), which is brought about by the rapid initial chlorination of FeO and MnO (in ilmenite and slag) and (it is argued) by the chlorination of Ti2O3 which forms at high-energy surface sites."

Jan 1, 2003

By Derek Caizergues, Hurman Eric

The principle of carbothermic reduction has been around for many years. In principle it is a simple process, yet with a multitude of problems. The temperature required to affect reduction is in the region of 2200ºC and results in aluminium oxy-carbide formation rather than metallic aluminium. From a thermodynamic point of view, reducing the temperatures of reaction which would suppress oxy-carbide formation would only be possible by lowering the total pressure of the system. A decrease in thermodynamic activity of product aluminium by dissolving it in another phase would also help preventing the formation of oxy-carbides and would also increase the yield of the reduction reaction. Thus experiments have been conducted at around 1700ºC to determine the possibility of carbothermic reduction of alumina under the presence of a metallic solvent. Total pressure of the system was reduced to around 30kPa and metallic nickel, iron, copper and tin were selected as the solvent. The highest recovery of aluminium was achieved with the nickel solvent followed by iron, copper and tin. This ranking for the first three was also in accord with the extent of negative deviation form ideality in the respective binary solutions of these solvents with aluminium. The tin-aluminium system displays positive deviation form ideality. The rate and extent of reduction was found to be highly dependent on temperature and pressure. The pseudo first order reaction rate was found to be applicable to the process in all the solvents used. Rate constants were calculated and it is also suggested that the reduction was controlled primarily by the chemical reaction rate.

Jan 1, 2003

By M. Brennan, A. Majumder

"The mineral processing research community has devoted enormous efforts to the modelling of mineral separators over the last 50 years. While many efforts have been made to use only fundamental physics as a basis for the models, fluid flow patterns in separators are not simple while the motion of particle swarms through fluids is extremely complex.Sluices are the simplest forms of the flowing film concentrators and have been used in the mineral industry since at least the 15th century (Agricola, 1556). Flowing film concentrators, in general, still have widespread applications in the mineral industry and their designs vary according to the specific need.Particle separation in a sluice appears deceptively simple, but the separation mechanism has proven complex and difficult to quantify. Separation in the sluice takes place in a flowing film a few millimetres thick. The particles are suspended by turbulent eddies and motion relative to the fluid takes place in socalled hindered settling mode. The difficulty arises because the presence of the particles influences the flow pattern and when the particles are fully transported by the flow, the flowing slurry may not have the same viscosity as water and does not have the same density. For this reason a universal theory which can explain the behaviour of a suspension in a sluice or any other gravity equipment has still not been developed. Few attempts have been made to analyse the mechanisms involved in the concentrating processes of pinched sluices and Reichert cones.Fluid flow behaviour and slurry transportation characteristics in open channels have, however, been active research topics in the disciplines of fluid mechanics, chemical engineering and civil engineering for many years. As a result, an extensive literature is available, which has led to the development of the model described in this paper.In an effort to test the extent to which fundamental fluid mechanics can provide a prediction of particle separation, a study on a simple parallel-sided sluice has been carried out using glass beads at various particle concentrations and flow rates, and the actual particle separation taking place compared to predictions from modelling.The modelling strategy was divided into two parts; the first was to predict the horizontal slurry flow velocity profile and the second to predict the solid particle concentration over the depth of the flow at different flow conditions. The predictions were then validated with measured data sets. This can easily be done if the slurry flow is split at different fractional flow depths so that the mass flow of solids over different flow heights is measured accurately over a fixed period. Mass flow splits can then be calculated by integrating the product of the predicted slurry velocity profile and the predicted solids concentration profiles from the base of the sluice bed to the slurry free surface."

Jan 1, 2003

By Thomas Pretz, Alexandra Pehlken

Sampling of municipal solid waste is known to be difficult to sample if it has to be representative. When dealing with municipal solid waste, the usual method is to study separately waste material below 40 mm and particles bigger than 40 mm. The material < 40 mm cannot be sorted manual and is termed the “fine fraction”. The particles > 40 mm can be separated manually and are usually sorted into pre-defined groups of materials. These groups can be defined depending on the demand of quality assurance. But standardisation of procedures is not far progressed, even for the widely practised sorting methods.

Jan 1, 2003

By Jussi Liipo, Pertti Lamberg

Image analysis of process samples gives precise data on particles and their composition. The results presented as liberation tables and maximum grade-recovery curves are informative and good for comparing different feed materials, but basing on them it is impossible to predict the results of the mineral separation process (flotation, magnetic separation, gravity separation) in details. The exact and extensive particle data has remained large unused, because there has not been a model nor a modeling program to include particle information in mineral separation processes. This study introduces a method, which incorporates the particle data in the kinetic model of flotation. Similar approach can be used in modeling other separation processes, too.

Jan 1, 2003

By Markus A. Reuter, Antoinette van Schaik

"INTRODUCTIONGoods and products, such as passenger vehicles, are manufactured by using a wide spectrum of different raw materials to meet highest consumer requirements during use. Due to the time-varying composition and complexity of multi-component products such as cars, recycling is complicated. It involves a network of interconnected processes and material and energy flows. Improving the efficiency of the material cycle of the car to comply with the recycling targets as imposed by EU legislation, requires insight into all aspects influencing the closing of the material cycle (dynamics, technology, economy, legislation, etc.) and their mutual relation. In order to define the link between recycling end-of-life products, their changing composition and design a dynamic model was developed for the resource cycle of cars. The model integrates the optimisation of the material cycle with the dynamic behaviour of recycling systems."

Jan 1, 2003

By R. Peter King, Claudio L. Schneider, Reiner Neumann

Predicting the liberation spectra that is produced from breakage of two-phase ores under the random fracture assumption can be accomplished by measuring the conditional, on length, linear grade distribution directly from images obtained from a representative sample of the unbroken texture. The technique tremendously simplifies the prediction problem by avoiding the multiple convolutions that arise from the traditional method based on a description of texture from a measurement of the chord length distributions associated with each phase in the unbroken texture. For a 3-phase system, the phase transition probabilities associated with the textural information make the traditional calculation an almost insurmountable mathematical problem. The direct measurement procedure on the other hand can be expanded to three phases comparatively easily.

Jan 1, 2003

By H. Pearce, A. E. Lewis, A. Ochieng

"Hydrodynamics and mixing are fundamental to the operation of mineral process systems such as flotation cells and metal precipitation reactors. Hydrodynamic conditions influence phase mixing and mass transfer in a multiphase system, and these affect the overall performance of such a system. Detailed information on the effects of the hydrodynamics on the performance of agitated systems is still required for the design and optimal operation of hydrometallurgical systems, which are always multiphase. Computational fluid dynamics (CFD) techniques have been employed to study the hydrodynamics and mixing, most of which have focussed on the performance of axial and radial pumping impellers in agitated tanks. However, very little has been reported on the influence of a draft tube on the flow profile in such systems.CFD simulation of a stirred vessel centres on the way the impeller is modelled. Some of the most recent approaches to modelling an impeller are impeller boundary condition (IBC), snap shot, sliding grid (SG), multiple frame of reference (MFR) and inner outer (IO). The accuracy, with which these models predict experimental results and the corresponding computational demands, form the basis upon which the choice of an approach is made. Most of these approaches (IO, SG and MFR) address the key problem of the stirred tank modelling, namely, the simultaneous meshing of the rotating impellers and the stationary baffles. The MFR is computationally cheap and has been found to give predictions that compare well with experimental data.The CFD technique (code CFX4.4) has been employed in the present work to study the hydrodynamics in a mixing vessel stirred with either a Rushton turbine or a pitched blade impeller. The multiple frame of reference (MFR) approach has been used to model both impellers. A draft tube was used only in the Rushton turbine stirred vessel. The flow profiles for the impellers have been studied in three regions; below the impeller tip, at the middle of the tank, and near the liquid surface. The simulation results were compared with literature data obtained using a laser Doppler velocimetry in the three regions of the vessel, and it was found that the model predictions were better in the impeller region. There was a poor prediction of the experimental results in the region closer to the liquid surface; however, this was improved when the turbulence parameter (C2) in the k-e model was set to a higher value. The value of the impeller clearance at which the Rushton turbine generates an axial impeller type flow has been determined and it has been shown that, at this clearance, a draft tube can be used to enhance axial flow in a Rushton turbine stirred reactor."

Jan 1, 2003

By D. P. Hatfield, G. de Jager

"Recent developments in image analysis techniques and the power of computer hardware have spurred international interest in the potential uses of image analysis techniques in a range of industrial applications. One of these applications is the control of the complex flotation process. Despite years of work, the flotation process is still poorly understood. Current attempts to control flotation cells focus on consistently duplicating the control achieved by human operators.In human control of flotation two of the dominant visual cues are the froth flow speed and the froth stability. These two factors can be measured and inferred respectively from image analysis of video of the froth surface. Two important hydrodynamic variables for control of the flotation process are the air addition rate and the level of the froth pulp interface.The current work focuses on the relationship between froth flow speed and the rate of recovery of concentrate from a flotation cell. Results are presented that show a strong relationship between flow speed and concentrate yield. These results include tests where the conditions in the cell were not changed, as well as tests involving changes to the cell level and air addition rate. Preliminary results are presented which show a correlation between froth stability and froth percent solids.Future developments of the system will include comprehensive froth texture typing, colour space and stability analyses."

Jan 1, 2003

By Dingwu Feng, Jannie S. J. van Deventer

"The effect of ultrasonication on reactions at solid/liquid interfaces was investigated by using an ultrasonic probe in two slurry systems, i.e. cyanidation of a refractory sulphide ore and geopolymerisation of metakaolinite. The surfactant dithiophosphate was used to render the gold bearing sulphide particles hydrophobic, in an attempt to induce the formation of cavitation bubbles directly at the desired surfaces. Oxygen was injected into the cyanidation system to improve the attachment of oxygen bubbles to the hydrophobic sulphide surfaces. Geopolymerisation occurs in highly alkaline solution with waste aluminosilicate oxides and silicates as the reactants. The process of geopolymerisation is believed to involve dissolution of Al-Si oxides from solid particles, diffusion of dissolved Al-Si complex from the solid surface into the gel phase, condensation of gel phase and hardening of the gel phase. It has never been investigated how ultrasonication affects the above steps in synthesising geopolymers, despite a number of papers dealing with sonochemical synthesis of materials. The introduction of power ultrasound into such slurry systems is expected to result in advanced geopolymer materials.In the cyanidation of the pyrite concentrate, the kinetics of gold extraction were significantly enhanced in the presence of ultrasound, due to the prevention of passivation and the enhanced dissolution of sulphides. Cyanide consumption was significantly reduced with ultrasonication, owing to the oxidation of soluble sulphides to sulphate, minimising the cyanide consumption by sulphides. With oxygen injection, ultrasound significantly enhanced the leaching of gold from the pyrite concentrate, as oxygen could enhance the formation of the oxidation radicals by ultrasonic cavitation. In the presence of dithiophosphate, ultrasound further improved gold leaching in the oxygen-aerated system. Dithiophosphate could selectively adsorb at gold host sulphide surfaces, and make the surfaces hydrophobic. As a result, the ultrasonication effectiveness could be enhanced through forming cavitation bubbles directly at the interfaces."

Jan 1, 2003

By Katarina Theander, Robert J. Pugh

In the flotation process, control of the stability of the froth is extremely critical. In the case where the froth is too stable then mechanical entrainment of particles can occur but in the opposite case, where the froth is too unstable and difficult to skimm-off, then a reduction in recovery can result. In minerals and deinking flotation, commercial fatty acids are used and may act as both both collectors and frothers. However, frequently the fatty acids are mixed with nonionic ethoxylated surfactants to give more effective froth control and increase the flotation performance. It is of interest to note from the surface chemistry literature, that such mixtures may cause synergistic effects in surface activity which may explain changes in bubble size, foaming and carry over of particles. In the present study, we have carried out foaming and drainage experiment with oleic acid and model nonionic surfactants; hexa(ethylene glycol) mono-dodecyl ether, C12E6 and tetra (ethylene glycol) mono-dodecyl ether, C12E4 both in separate and mixed systems. Frothing was carried out in a column, equipped with a series of conductivity electrodes which enabled the water content of the froth to be measured along the length of the column, during various stages of the drainage process. The variation in water content of the froth enabled the process to be characterised by distinct three stages; (a) an entrainment state where the water transfer from the bulk phase to the froth was dominant (b) a steady state when entrainment and drainage are balanced and no water is transferred to or from the froth and (c) the drainage step when drainage predominates and the volume of the bulk phase increases. We also carried out surface tension measurements on the oleic acid/ nonionic systems and related the results to the frothing and drainage performance. From the surface tension data, the adsorption interaction parameter of the mixed systems at the air/solution interface could be calculated and was found to depend on the oleate/ nonionic surfactant ratio. This value was related to the frothing performance and the results indicated a positive interaction parameter for the mixed surfactant systems which could explained the synergistic effects in frothing performance.

Jan 1, 2003