Ultrasound Enhanced Reactions at Solid-Liquid Interfaces

"The effect of ultrasonication on reactions at solid/liquid interfaces was investigated by using an ultrasonic probe in two slurry systems, i.e. cyanidation of a refractory sulphide ore and geopolymerisation of metakaolinite. The surfactant dithiophosphate was used to render the gold bearing sulphide particles hydrophobic, in an attempt to induce the formation of cavitation bubbles directly at the desired surfaces. Oxygen was injected into the cyanidation system to improve the attachment of oxygen bubbles to the hydrophobic sulphide surfaces. Geopolymerisation occurs in highly alkaline solution with waste aluminosilicate oxides and silicates as the reactants. The process of geopolymerisation is believed to involve dissolution of Al-Si oxides from solid particles, diffusion of dissolved Al-Si complex from the solid surface into the gel phase, condensation of gel phase and hardening of the gel phase. It has never been investigated how ultrasonication affects the above steps in synthesising geopolymers, despite a number of papers dealing with sonochemical synthesis of materials. The introduction of power ultrasound into such slurry systems is expected to result in advanced geopolymer materials.In the cyanidation of the pyrite concentrate, the kinetics of gold extraction were significantly enhanced in the presence of ultrasound, due to the prevention of passivation and the enhanced dissolution of sulphides. Cyanide consumption was significantly reduced with ultrasonication, owing to the oxidation of soluble sulphides to sulphate, minimising the cyanide consumption by sulphides. With oxygen injection, ultrasound significantly enhanced the leaching of gold from the pyrite concentrate, as oxygen could enhance the formation of the oxidation radicals by ultrasonic cavitation. In the presence of dithiophosphate, ultrasound further improved gold leaching in the oxygen-aerated system. Dithiophosphate could selectively adsorb at gold host sulphide surfaces, and make the surfaces hydrophobic. As a result, the ultrasonication effectiveness could be enhanced through forming cavitation bubbles directly at the interfaces."