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By Phillip J. Mackey, Susumu Okabe

Copper mining and smelting has been carried out in Japan for over 13 centuries and in fact stretching back into antiquity. In 1889, the first electrolytic copper refinery in Japan based on Elkington’s principles was started by Furukawa Mining at Honjyo in downtown Tokyo based on the multiple or parallel system. Within two decades, a number of other copper refineries had begun operation. Interestingly, but perhaps not surprising given Japan’s long history of copper production, this first refinery in Japan commenced just ten years after the first refinery in the USA (1879), and not long after the first plants in Europe. By 1935, as a result of growth in copper demand, there were six domestic copper electro-refineries in Japan with an installed capacity of 97,800 tonnes/a, while actual production was 71,200 tonnes/a. Since about 1932, the majority of these plants were based on the more common parallel or multiple system. In 1946, just after World War II, domestic production capacity had dropped considerably to 29,000 tonnes/a, however with reconstruction, capacity and production expanded rapidly, with production reaching 81,000 tonnes/a in 1955, 187,000 tonnes/a in 1960 and 307,000 tonnes/a in 1965. The introduction of the first refinery and the early ones that followed and subsequent developments are discussed in this paper. The major technical achievements during the high growth period from 1945 to 1963 included: the use of fire- refined anodes; the introduction of newly-developed rectifiers; the introduction of lead-lined or vinyl-lined concrete cells; improvements in the electrolyte heating system; application of improved anti-corrosion materials and the introduction of heat-insulating surface coverings. In 2018, Japan’s refined copper production totaled 1,595,000 tonnes of copper, with Japan ranking third in the world after China and Chile. INTRODUCTION In 2018, Japan’s refined copper production totalled 1,595,000 tonnes of copper and Japan ranked third in the world for refined copper after China and Chile (Wood Mackenzie, 2019). There are now eight copper refineries in Japan which provide Japan’s production of refined copper. These plants are listed in Table 1 (Wood Mackenzie, 2019), also showing the production trend since 2013; in general, production over this period has been relatively steady. The Toyo plant is now the 7th largest copper refinery in the world after several large plants as rated by capacity in China, Russia and India (ICSG, 2019).

Jan 1, 2019

By B. K. Choi, S. H. Kang, G. E. Kim, K. B. Kim, S. Noh, T. K. Kim, H. J. Jin

Oxide dispersion strengthened (ODS) steel is being considered as an in-core structural material of future nuclear reactor systems because of its excellent creep and irradiation resistance on the basis of uniformly distributed nano-oxide particles with a high density, which is extremely stable at high temperature in a ferritic/martensitic matrix. Up to now, ODS steels have been intensively studied and developed to apply these materials to the in-core structural component of future nuclear systems. The primary activity is to develop high strength advanced ODS steel, fabrication technology for the structural components and key joining technology for the component fabrication. As a result, a Fe-10Cr-1Mo alloy with a superior creep resistance at high temperatures has been developed. An optimized fabrication process of this alloy system has been established through various process conditions in mechanical alloying, hot/cold working, and heat treatment processes. Joining technology for the ODS steel components is also being developed using solid-state welding such as magnetic pulse welding, friction stir welding and diffusion boding. These R&D activities will contribute to the realization of ODS materials for future nuclear reactor system applications.

Jan 1, 2015

By D. P. Bishop, G. J. Kipouros, R. L. Hexemer Jr., I. W. Donaldson, W. F. Caley

Aluminum powder metallurgy (APM) is an advanced metal forming technology frequently employed to fabricate complex structural components in a near-net-shape fashion. Exhibiting nearly 100% material utilization, APM continues to rise in popularity. Recent research initiatives in this field have emphasized the development and processing of advanced 2xxx and 7xxx series alloys. In particular, APM equivalents to wrought 7075 and 2024 have been sought. An overview of work completed in this area is presented. Included are data on the various production stages (powder compaction, sintering, forging, and heat treatment) as well as the microstructure and mechanical properties of the finished products.

Jan 1, 2010

By Guy Demers

"This paper defines the responsibilities and functions of the Maintenance Department, and its organization, physical and human assets, highlighting the unique operating problems. Due to the self-sufficient aspect of the Asbestos Hill Deception Bay project, the Maintenance Department cover-s fields that are numerous and very dissimilar: production, mobile, processing, service, power generation, fire protection, heating, water and sewage disposal equipment. Added to this, buildings, plant and camps, wharves and communications equipment all demand versatility, adaptability and expertise from maintenance personnel. Good maintenance practices are a necessity in this environment and are more critical than at southern locations; that is, high-quality replacement material, complete and well-controlled preventive maintenance, major repairs on a component-replacement basis, updated inventory, efficient training and permanent contacts with suppliers, combined with an equipment improvement program, updated specifications on lubricants, hoses, seals, filters, etc., are mandatory. The seasonal aspect of the operations applies a great deal of pressure on the maintenance team, as the production months do not permit major repairs. Short- and medium range planning and accurate evaluation of equipment conditions highly influence production efficiency. Maintenance control, planning and scheduling do not follow the accepted standard routines, as personnel turnover normally does not permit an accumulation of knowledge of the equipment history and condition by the •individual tradesman."

Jan 1, 1976

By K. E. Prince, S. Burling, R. J. Ring, M. K. Maley, W. R. Taylor

Vanadium occurs as a component of carnotite, which commonly occurs in calcrete type ores, and in association with uranium in some sandstone-hosted deposits. Increasing demand for vanadium, which is used in high-strength steel and Vanadium Redox Flow Batteries (VRFBs), is offering some uranium producers a potential option for by-product vanadium recovery to improve project economics at a time when uranium prices are low. This paper presents the results of recent optimisation studies on the Bigrlyi deposit for the recovery of both uranium and vanadium. The impact of carbonate leaching conditions on uranium and vanadium extraction from a range of carnotite-in-calcrete ores is also examined, with vanadium extraction limited by the proportion of non-carnotite vanadium present in the ores. The findings are particularly relevant to developing projects as results show that elevated vanadium content in ore does not necessarily equate to a high vanadium extraction in leach.

Jan 1, 2020

By M. Maldonado

This work details the application of a decentralized control strategy to a pilot flotation column working with a two-phase system (water-air). The process is represented by a multivariable system composed of three inputs and three outputs. The selected control variables are the froth depth, the air hold-up and the bias rate, whereas the corresponding manipulated variables are the set-points of the local flow controllers of tailings, air and wash water. All controlled variables are estimated using electrical conductivity based techniques. In particular, the results of a new method for estimating the bias rate, based on the measurement of the volumetric fraction of wash water under the interface, is presented. This method reduces the coupling problem associated to the bias estimation as a difference between feed and tailing water rates. Moreover, the nominal system transfer matrix can be represented by an upper triangular matrix, in such a way that the closed-loop system stability reduces to the stability of the independent control loops. The experimental results show that the closed-loop system performance, particularly that of the bias rate loop, is strongly dependent on the air flow rate, reaching in some cases the saturation point of the controller.

Jan 1, 2007

By J. D. McFarlane, V. Robinson

"The paper begins with a brief account of the naturarly occurring resources of gypsum and anhydrite and a discussion of their relative value and utility as sources of sulphur. The fundamental chemistry of recovering sul-phur values from calcium sulphate is discussed. (a) Thermal decomposition -discussed as impracticable; (b) Reduction to calcium sulphide; (i) Total Reduction-The chemistry is outlined and the Dorr-Oliver and Bureau of Mines processes mentioned. The Elcor process is mentioned and certain deductions made from available information.(ii) Partial Reduction-This is stated as the basis of the only proven process, namely ""The Cement -Sulphuric Acid Process."" The possibility of recovering lime is mentioned as an aside, but dismissed for lack of commercial application. The history of the cement -sulphuric acid process is covered briefly and a list of plants in commercial operation included. A brief elementary account of the basic chemistry of cement production is followed by a discussion on raw materials and fuels. A short account of the flow scheme of a typical plant, with notes on the operating peculiarities, precedes an account of product quality. The latest developments which enable by-product gypsum to be used as a raw material are discussed, with an indication of how the flow scheme is modified. A statement of feasible plant capacities is followed by requirements of raw materials, services, labour, etc., and finally some indication is given of capital costs."

Jan 1, 1969

By A. Bowles

The process of accumulative roll bonding (ARB) has been applied to wrought magnesium alloy AZ31. Accumulative roll bonding results in severe plastic deformation of sheet material. In AZ31, this process leads to the refinement of the microstructure by dynamic recrystallization. The refinement of the microstructure results in an improvement in mechanical properties with potential for producing materials for superplastic forming. In this work AZ31 was bonded with up to 64 layers and the potential of roll cladding with aluminium was also investigated. The development of microstructure and the mechanical properties are reported here.

Jan 1, 2006

By M. U. Oko

"Monitoring of all the waste streams from Falconbridge's Sudbury Operations to determine whether they meet the required standards, has been performed for many years. By 1969, however, the number of samples being collected had become so large that a complete revision of the existing systemwas necessary. Sites previously designated by name only, were numbered, clearly marked on the ground and on maps which were circulated to all concerned. The types of pollutants analyzed were determined and specified for each sampling location and a chemical analysis report form was designed. The sampling schedule has been computerized to produce a periodic listing of the samples to be taken and the analyses required.An area map showing sampling sites, chemical analysis report form, spill report and a computer print-out example are shown and explained.EVOLUTION OF FALCONBRIDGE'S WASTEWATER. MANAGMENT SYSTEMFalconbridge Nickel Mines employs some 4500 people, operates nine mines, four mills and a smelter in the Sudbury basin. The operations are geographically fragmented into four widely separated locations, the Falconbridge operations east of Sudbury and the Onaping operations in Levack Township being the two largest of the four. The Lockerby area located to the west and the Lindsley Mine just north of Sudbury are now under development. The magnitude, the diversity and nature of the operations are such that constant vigilance is needed to prevent inadvertent damage to the environment. The purpose of this paper is to describe the information system used to monitor and control waste-water disposal on Falconbridge's properties to help ensure the maintenance of effluent standards satisfactory to the Ontario Water Resources Commission (OWRC) and to the Ontario Department of Health."

Jan 1, 1971

By J. Bruce See

INTRODUCTION This symposium at Cu 2019 has been organised to honour and celebrate the career and achievements of Dr Phillip John Mackey, an internationally recognised expert in the production of non-ferrous metals, especially copper and nickel smelting and refining. Phillip was born in Epping, a suburb of Sydney, New South Wales, Australia on 19 April 1941 and is one of 4 children of Gilbert and Philomena (nee Bartlett) Mackey. After completing Primary School in Epping, he attended Marist Brothers High School in Eastwood, Sydney and graduated in 1957 as the Dux of the School. Phillip’s father, being on the staff of the Sydney Technical College, in Ultimo, Sydney had the opportunity in the early 1950s to meet the late Professor Sir Rupert Myers, Foundation Professor of the School of Metallurgy at the New South Wales University of Technology (later called the University of New South Wales or UNSW). Gilbert Mackey was impressed by the new young Professor of Metallurgy and encouraged his son to study metallurgy - at the time an expanding industry in post-war Australia. EDUCATION AT THE UNIVERSITY OF NEW SOUTH WALES Phillip commenced at UNSW in 1958, graduating with honours in 1963. His undergraduate education and training included a few years of part-time study while working at British Motor Corporation on sheet metal forming of car bodies. At University Phillip developed his talent for teamwork. He was a contributing writer to the University newspaper, Secretary of the UNSW Students’ Union and was active in the UNSW Metallurgical Society and co-editor in 1963 of “Metallurgical Review,” the annual journal of the UNSW Metallurgical Society. His diverse interests and curiosity about the world around him were likely nourished while at University. Upon completing his Bachelor’s degree, Phillip was awarded a Commonwealth of Australia Postgraduate Research Scholarship. He began his PhD in 1964 on the thesis topic “Studies in Heat Transfer between Dispersed Liquid Metals and Gaseous Atmospheres” working under the supervision of then Associate Professor Noel Warner, an outstanding Professor at the University. Professor Warner is now an Emeritus Professor at the University of Birmingham and is internationally respected for his pioneering theoretical and practical work on established and innovative smelting processes.

Jan 1, 2019

By P. Diehl, M. David

"As shortage in the supply of mineral commodities become more probable, there is an increasing need for reliable and comparable reserve/resource data. It is therefore necessary to standardize the traditional classification procedure by quantifying the three basic criteria in resource evaluation: economic feasibility, geologic assurance and recovery. For the portion of fairly well documented deposits and as far as their geologic parameters are concerned, geostatistical methods can considerably improve the quality of ore classification. In respect of economic feasibility and recovery, approved geostatistical methods can be introduced directly into the classification procedure. The concept of geologic assurance, however, requires a new interpretation in terms of geostatistical error spread. As the ""risk"" in estimating an ore parameter is also a function of the respective block size, it is reasonable to define not only upper limits for the risk intervals for each class of uncertainty, but also block dimensions which reflect the typical stage of planning associated with the different ore categories. An algorithm has been developed to block out areas inside a mine or a large panel which satisfies the constraints of an ore category in respect of the risk intervals of a parameter and in respect of their size. The method has been computerized and is demonstrated on a massive copper-nickel deposit.IntroductionFacing an uncertain future with respect to the demand and supply of mineral commodities, both governmental authorities and the mining industries show an increasing interest in a useful framework for the assessment and classification of the remaining mineral resources"". This is reflected by the recently published appraisal and classification scheme of the United Nations as well as by the new or revised classification systems of the USA; Canada or Australia. Moreover there are various classification schemes which are currently discussed in major mining companies."

Jan 1, 1982

By K. Adham

Both the dry and the wet fluorination systems require hydrogen fluoride (HF) for the process of uranium conversion to uranium hexafluoride (UF6). The dry methods depend on the electrolysis of HF to generate the fluorine (F2) required for the high temperature pyro-fluorination. The wet methods require aqueous HF in water solutions for the low temperature hydro-fluorination (Argonne, 2019). This paper uses the available HF safety guidelines and industry information to discuss the issues of transportation, storage and utilization. Health effects and environmental considerations are reviewed. Safe practices for handling the HF (both as anhydrous and as aqueous) are considered. Proper selection of different materials of construction are discussed, for both the anhydrous and the aqueous HF.

Jan 1, 2020

By J. Stachulak

In recent years more emphasis has been placed on the control of nitrogen dioxide (NO2) emissions from mining diesel equipment. Worldwide, diesel engine regulations to control emission and protect the environment are also driving the development of the diesel engine technology to reduce oxides of nitrogen NOx (Nitric oxide, NO + NO2). NOx are toxic gases produced in mines during the operation of diesel equipment. Most of the diesel equipment used in underground operations are equipped with Diesel Oxidization Catalysts (DOCs) designed to reduce carbon monoxide (CO) and hydrocarbons (HC). The effects of DOCs on NO2 production from diesel powered equipment is not well understood. DOCs do not alter NOx concentration, but may promote the oxidization of engine exhaust NO to the more toxic NO2, thus increasing the undesirable NO2 exposure of workers in the mine environment. In 2012, the ACGIH reduced the NO2 TLV concentration value from 3 ppm to 0.2 ppm. Vale and CanmetMINING have been involved in several research projects to reduce diesel emissions exposure to workers. One aspect of the current program is to determine the effects of in-use DOCs on NO2 production. Several in-use DOCs taken from mining equipment were selected for testing in the laboratory using ISO 8178-C1 and mine LHD transient test cycles. The paper presents the laboratory test results and effects of DOCs on NO2 production. The results indicate significant reductions in CO concentration, by over 77%, while increases in NO2 varied from 46% to 315% based on the ISO 8178-C1 8-mode steady state test cycle. The mine LHD transient test cycle showed the same pattern, although the magnitude of CO reduction was less. Consequently, it is recommended the use of only those DOCs that have been properly evaluated and shown not to significantly increase NO2 emission in the environment be used on mine equipment.

Aug 1, 2013

By P. E. Fox, R. S. Cameron

"The QR gold deposit lies in the Cariboo plateau region of central British Columbia. The deposit was discovered in 1977 and since then a mineable reserve of 1.3 million tonnes grading 4.7 g/t Au has' been outlined in three separate zones. Soil sampling of glacial tills followed by diamond drilling of favourable host rocks proved to be key exploration techniques.The deposit is situated in the southern Quesnel terrane along the eastern fringe of the Intermontane Belt which here comprises a sequence of basic and intermediate volcanics and a series of stocks of alkaline affinity; generally diorite, monzonite and syenite. Hornfels and epidote-rich ferromagnesian exoskarn and sulphide-rich mantos have developed in a metamorphic aureole formed around a central diorite stock. Gold-rich zones lie along the outer periphery of the aureole where bodies of gold-bearing epidote-rich skarn and auriferous mantos rich in epidote and pyrite have formed in beds of calcareous tuffite lying at the top of a thick basaltic sequence. The deposit is regarded as' a subclass of gold skarn deposits. Diagnostic features are its association with alkalic intrusive rocks in a subvolcanic setting and the presence of oxidized, epidote-rich mineral assemblages.IntroductionThe QR gold deposit lies within the Cariboo plateau region of central British Columbia, 58 km southeast of Quesnel. The deposit, owned by Kinross Gold, was discovered during a regional reconnaissance program by Dome Exploration (Canada) Limited and Newconex Canadian Exploration in 1977. Considerable exploration and development has been done since that time. Mineable reserves of 1.3 million tonnes grading 4.7 g/t Au have been outlined to date in three zones."

Jan 1, 1995

By J. E. Dutrizac, Alba Sunyer

The factors affecting the precipitation of arsenic-free alunite (KAl3(SO4)2(OH)6) were investigated in a series of laboratory experiments. Although the amount of alunite precipitated increased with increasing retention time, temperature, solution pH and the concentrations of Al(SO4)1.5 or K2SO4, the composition of the products remained nearly constant. The preferred conditions identified for the precipitation of arsenic-free alunite were then used to assess the behaviour As(III) and As(V) during alunite precipitation at 98°C. Increasing additions of As(III), as NaAsO2 or As2O3, resulted in a slight increase in the amount of precipitate formed at pH 2.80. However, X-ray diffraction analysis showed all the precipitates to be alunite, and <0.2% As(III) was detected in the products. In contrast, increasing additions of As(V), as KH2AsO4 or As2O5, resulted in significant increases in the amount of precipitate formed at pH 2.80 or 3.00. Furthermore, the arsenate (AsO43-) contents of the precipitates increased up to 15%, and the sulphate contents decreased, as the As(V) concentration of the synthesis solution increased from 0 to 9 g/L. X-ray diffraction analysis of the products detected only alunite, but there was a progressive expansion of the alunite cell with increasing arsenate content. The implication is that arsenate substitutes for sulphate in the alunite structure. Preliminary observations on the environmental stability of the arsenate-bearing alunite using the TCLP protocol gave solubilities <0.4 mg/L from a precipitate containing 8.5% AsO4 and 7.8 mg/L from a product containing 19.5% AsO4. Thus, it appears that alunites containing less than -10% AsO4 would be an acceptable vehicle for the disposal of arsenic from hydrometallurgical processing solutions.

Jan 1, 2011

By F. Azgomi

A possible way to characterize (classify) frothers using gas holdup as a surrogate for bubble size was explored. Nine surfactants with a range in chemical structures were selected and tested in a bubble column instrumented to measure gas holdup and superficial gas velocity. A correlation between frother type and gas holdup was observed: for alcohols, gas holdup increases with hydrocarbon chain length and the effect is the same whether the chain is branched or straight; for polyglycols, gas holdup increased with number of propoxy groups. The ranking by gas holdup gave the same result as other frother characterization techniques.

Jan 1, 2006

By Mosquera. J.

Tailings Storage Facilities (TSFs) are vast structures that respond to site-specific characteristics, rate of production, placement techniques, and the physical and mechanical properties of tailings. As a common denominator, TSFs are in some degree vulnerable to failure due to liquefaction, poor management, slope instability and/or unusual climatic events. In practice, stability of TSFS is determined by calculating a minimum Factor of Safety (FOS) using the Limit Equilibrium Method (LEM). However, it has been proven that relying exclusively on the limit equilibrium approach is not accurate because it is basically a static method that does not take into account the stress-strain distribution and displacement experienced by the constitutive materials of a TSF. In order to overcome these limitations of the LEM, the finite element method - Shear Reduction Technique (SRT) has been used as a more reliable tool for TSFs stability assessment. This paper presents a comparative stability analysis between an upstream tailings storage facility (UTSF), and a water retention tailings dam (WRTD) under static and pseudo-static states using simplified and rigorous LEMs and the SRT. Additionally, and taking into consideration the intrinsic uncertainty of tailings properties, sensitivity and probabilistic analyses in the form of Monte Carlo Simulation (MCS) and the Point Estimate Method (PEM) are applied to determine the Probability of Failure (Pf) and Reliability Index (ß) of each TSF. It is shown that the friction angle of UTSF?s foundation and the core?s cohesion of the WRTD are the main variables that govern stability. Further analysis shows that the WRTD has a higher reliability index and a lower probability of failure than the UTSF.

Aug 1, 2013

By Subagyo, Geoffrey Brooks, Ken Coley

The generation of droplets and their subsequent reaction in the emulsion is critical to the overall kinetics of oxygen steelmaking. High temperature experiments have been performed at McMaster University to study this behavior. The results from this work and other previous studies has formed the basis of a number of physical and chemical models that attempt to describe the critical aspects of droplet behavior in Oxygen Steelmaking. These models include semi-empirical models for predicting droplet generation rate, droplet size distribution and droplet residence time as a function of blowing parameters.

Jan 1, 2004

By Abhinav Karanam, Lukas Bichler

Yttria Stabilized Zirconia (YSZ) is a promising thermal insulator for high temperature environments due to its thermal stability and chemical inertness. As was demonstrated with other technical ceramics (e.g., Alumina), addition of Single-Wall Carbon Nanotubes (CNTs) to a ceramic matrix may significantly enhance the mechanical properties of the composite ceramic. In this work, 8 mol% YSZ with 0.2, 0.5 and 1wt% CNTs composites were prepared via Spark Plasma Sintering process. The densification, Vicker’s microhardness, specific gravity and microstructure evolution of the composites were investigated. The results suggest that the addition of up to 1wt% CNTs to YSZ yielded optimal combination of the studied properties. At higher addition levels, the specific gravity decreased and clustering of CNTs occurred, leading to poor densification and a relative loss of performance.

Jan 1, 2014

By D. J. Wesolowski, D. A. Palmer, P. Bénézeth, S. Hilic

The equilibrium solubilities of gibbsite, Al(OH)3, and boehmite, A1OOH, have been extensively studied in our laboratory from 30 to 90°C, and 100 to 300°C, respectively, to ionic strengths of 5 mol.kg-1 (NaC1) over a wide range of pH. The resulting solubility constants have been treated with consistent empirical models that incorporate appropriate experimental data taken from the literature. These studies were initiated in part to understand and quantify scale formation in geothermal fields as a result of fluid re-injection from electric power generating plants. Most of the experimental results were obtained through application of a unique potentiometric method that allows for rapid, precise measurement of the in situ pH and allows the approach to equilibrium to be monitored from under- and super-saturation. The experimental program was extended to deal with more basic solutions (e.g., five molal NaOH), in which the dissolution of boehmite was measured for application to the refining of bauxite by the Bayer process. More recent results in strong caustic solutions at temperatures below 90°C were obtained to investigate the dissolution of aluminum-containing sludge from holding tanks at the Savannah River waste reprocessing site. In this case the solubility enhancing effects (kinetic and equilibrium) of triethanolamine were also established and quantified. Finally, potentiometric solubility experiments were conducted (50°C in 0.l mol-kg-1, NaCl) on aluminum alloy sheets to identify mainly the nature of the aluminum oxide/hydroxide surface layer formed under these conditions.

Jan 1, 2004