Characterizing Frothers Using Gas Holdup

A possible way to characterize (classify) frothers using gas holdup as a surrogate for bubble size was explored. Nine surfactants with a range in chemical structures were selected and tested in a bubble column instrumented to measure gas holdup and superficial gas velocity. A correlation between frother type and gas holdup was observed: for alcohols, gas holdup increases with hydrocarbon chain length and the effect is the same whether the chain is branched or straight; for polyglycols, gas holdup increased with number of propoxy groups. The ranking by gas holdup gave the same result as other frother characterization techniques.