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By J. Gray, J. Peck

As the turn of the century approaches, traditional open pit mining methodologies and processes are being modified through the introduction and use of new technologies. As in other industries, the personal computer is dramatically changing the traditionally conservative mining industry by allowing mines of varying size and capacity to increase their productivity and efficiency through the use of easy to use, office software. Computer-based monitoring and control systems are also being used more frequently to measure and optimize, in real-time, the performances of operating equipment. When communicated to an end-user, this information can provide accurate and timely answers to questions of how much, where, when, and by whom. This capability forms the foundation of a more comprehensive, proactive management and planning facility where, ultimately, information acquired from the producing equipment will be used to optimize and control machine and human activities. As these technologies mature and become essential tools in a mine, they will eventually serve as the basis for more robotic and autonomous mining operations.

Jan 1, 1999

By Pravin Mathur

"Praxair's CoJet® technology was introduced in 1997 to effectively inject chemical energy in electric arc furnaces. Coherent jets were invented as a revolutionary means of injecting oxygen and other gases into the EAF and into converters. Today, steel makers have widely accepted this concept in over 70 EAFs worldwide. Indeed, the whole industry has shifted to this new standard for chemical energy input in EAFs. CoJet® technology has also been implemented successfully in BOF converters.This paper will review the principles of coherent jets as applied to steelmaking. The key learnings garnered from several furnaces are also reviewed. In addition, while the CoJet® program has been widely accepted worldwide, based on steady feedback received from customers and the market place, several programs are underway in development and commercialization. These enhancements and new applications of CoJet® technology are also overviewed in the paper."

Jan 1, 2004

By G. D. Bysouth, G. Y. Wong

"The Endako molybdenum deposit is located 160 km west of Prince George, British Columbia. It occurs within the main body of the Francois Lake Intrusions, a composite batholith consisting of early, middle and late intrusive phases. The ore deposit is confined to Endako Quartz Monzonite, a middle phase intrusion, which is bound on the north by Carey Alaskite and on the south by Francois Granite, both late stage intrusions. In the mine aretz, the Endako Quartz Monzonite has been intruded by pre-ore dikes of quartzfeldspar porphyry and porphyritic granite, and by post-ore dikesof basalt.The Endako deposit forms a west-northwest trending body that has a strike length of 3360 m and an apparent width of 370 m. It consists of four structurally distinct zones: Endako East, Endako West, Denak East and Denak West. Principal sulphide minerals of the deposit are pyrite and molybdenite, accompanied by magnetite and minor chalcopyrite. Galena, associated with wulfenite and bismuthinite, occurs in some ores of Endako West and Denak as minute inclusions in molybdenite. The sulphides and associated minerals are hosted by quartz veins which occur principally in vein systems. Hydrothermal alteration accompanying ore mineralization has pervasively kaolinized the quartz monzonite host rock, and has locally produced K-feldspar and quartz-sericite-pyrite envelopes on quartz veins.Primary structural controls of the deposit are southwesterly dipping vein systems which strike 110° in the Endako zones, 110° to 130° in Denak East and 170° in Denak West. Secondary structural controls are northeasterly striking vein systems that dip northwesterly in Endako East and southeasterly in Denak. Domal uplift accompanying the rise of latest stage magma is considered to have caused intense dilatant deformation along older west-northwest trending shear zones, producing an elongated structural host for ore deposition."

Jan 1, 1995

By A. Mitura

The paper presents the initial investigation of possible energetic applications of chosen wastes from groups: 06, 03, 05 and 01, including coal slimes being secondary product of hard coal processing. These categories of wastes are catalogued according to the polish law, where 06 ? wastes from production, preparation, purchasing and application of products of non-organic chemistry; 03 ? wastes from wood processing and from plates and furniture, celluloid mass, paper and card board production; 13 ? oil wastes and wastes from liquid fuels; 01 ? wastes produced by searching, extracting, physical and chemical processing of ores and other mineral raw materials. The change of combustion heat value was evaluated in produced energetic mixtures containing these types of wastes together with the change of their individual components. All combinations of ingredients were taken into consideration giving 256 various mixtures, from which 36 were selected to investigation. This allowed the performance of statistical factor analysis. For such prepared materials the application of regressive method was proposed in purpose of calculating combustion heat value and then the comparison of empirically determined and theoretically calculated heat values was performed. The change of regressive coefficients can be determined by the nature of Hess law (eq. 1) what was investigated and the attempt of its explication and validation was done.

Aug 1, 2013

By J. W. Hohn

The precipitation of Fe(III) to form ferrihydrite in the presence of arsenic is the United States EPA's Best Demonstrated Available Technology for treating arsenic-containing hydrometallurgical solutions and waste streams. This technology has been widely adopted throughout the world and developments have been well reviewed. The adsorption and long-term stability of ferrihydrite can be improved by co-precipitating Fe(III) and Al(III) together to form an aluminum-modified ferrihydrite. Arsenate adsorption into ferrihydrite and modified ferrihydrite as a function of pH, Fe/As or (Al+Fe)/As mole ratio, and the initial As(V) concentration is presented and compared. The results of long-term aging of both adsorbents at 70°C for over a year are also summarized.

Jan 1, 2006

By Jennifer L. Durocher

The speciation of Uranium in silica-rich depositional layers in the proximity to uranium ore deposits was investigated using micro X-ray fluorescence (VESPERS beamline), X-ray Photoelectron Spectroscopy, Laser-Ablation ICP-MS, Scanning Electron Microscopy, X-ray diffraction and micro-Raman Spectroscopy. The heterogeneous Si-rich laminations contain micrometer-size inclusions of secondary uranyl-minerals. The U concentration in these layers range from several ppm to lower weight percent and the U 4f spectra indicate variable U6+ : U4+ ratios. Correlation between the concentrations of U and other metals (M) suggests the presence of M-U-bearing nanoparticles or species within the amorphous silica matrix.

Aug 1, 2010

By L. Vinnett, I. Panire, J. Yianatos, F. Ruiz

"The effect of operating variables on the flotation performance at steady-state has been extensively used for modelling and simulation of separation processes. However, the dynamic characterization of key variables such as gas dispersion (Sauter mean diameter of bubbles, D32, and bubble surface area flux, SB) and froth discharge rate is rather scarce. In this paper, an experimental design allowed identifying the dynamic response of the flotation process in a laboratory scale flotation cell, using a two-phase system, airwater. The installation included automatic control for the superficial gas rate, JG, and the pulp level. Gas dispersion was evaluated in terms of the Sauter mean diameter of a bubble population and the bubble surface area flux, SB = 6·JG/D32. The D32 was measured using the McGill Bubble Size Analyzer (MBSA) along with a semiautomated algorithm. In addition, the froth discharge velocity was measured in real-time using a Visiofroth system. The control variables were the superficial gas rate and the frother concentration (Teefroth). The dynamic characterization of the flotation process is useful to design algorithms that allow the direct or indirect control of metallurgical variables such as flotation rate, concentrate grade and mineral recovery.INTRODUCTIONGas dispersion indicates the way the gas entering a flotation machine is dispersed throughout the volume of the equipment (Schwarz & Alexander, 2006). The gas dispersion is typically characterized in terms of the bubble size (dB), gas holdup (eG), superficial gas rate (JG), and bubble surface area flux (SB =6·JG/dB) (Finch et al., 2000). All these variables have significant impact on the metallurgical performance of flotation machines. For example, Perez-Garibay et al. (2014) investigated the effect of the particle size, bubble size distribution, superficial gas rate and collector dosage on the flotation performance, for the separation of a sphalerite mineral. The authors observed that recovery increased with the superficial gas rate ranging from JG = 0.04 to JG = 0.08 cm/s and also a maximum recovery was obtained for bubble size close to 300 µm. Gorain et al. (1998) reported a strong correlation between the flotation rate constant and the bubble surface area flux in a zinc cleaner circuit. Both variables were directly proportional at three froth depths in the range of hF =7 - 45 cm. Dobby & Finch (1986) incorporated the effect of the superficial gas rate and the bubble size on the flotation efficiency by means of a kinetic model for the rate constants. Yianatos & Contreras (2010) developed a model to estimate the carrying capacity in large flotation cells by including the bubble surface area flux."

Jan 1, 2016

By E. Krause, V. G. Papangelakis, S. Garg, R. Mahadevan, E. Edwards

"Bioleaching uses iron and sulfur-oxidizing bacteria to extract base metals from sulfide minerals. As bioleaching involves breaking the iron-sulfur bonds by ferric attack, the biologically mediated rate of iron oxidation is recognized to play a key role in influencing the overall kinetics. In this study, we investigate the catalytic ability of an indigenous AMD culture for oxidizing Fe(II) in solution. This culture was subsequently adapted on pyrrhotite tailings (0.6% Ni) by gradually increasing the solids loading. Results from this study show that such an adaptation reduces the initial lag phase in the biotic oxidation of Fe(II), thereby allowing for a higher Ni extraction when compared to experiments with an un-adapted culture at a similar solids loading. The use of adapted cultures also helps to reduce the residence time for bioleaching of Ni from pyrrhotite tailings. INTRODUCTIONAs the world demand for pure base metals grows; the mining industry is increasingly faced with the burden of processing lower grade ores and mining waste streams in order to recover the occluded metal VALUES ((Watling, 2006). The extractive metallurgy of nickel from sulfide minerals focuses on using a combination of mineral processing, pyrometallurgical (smelting) and hydrometallurgical techniques to extract Ni from its ore bodies.Pyrrhotite (Fe1-xS) is commonly found in association with pentlandite and chalcopyrite in sulfidic Ni ores, such as those found in Sudbury, Ontario, and in Russia, e.g. Norilsk. The vast majority of this pyrrhotite needs to be removed using mineral processing techniques, in order to minimize the Fe and S contents of the concentrates that proceed on to smelting. If all pyrrhotite were left in the concentrate, much more slag and SO2 would be produced, and the smelter throughput would be limited. Beneficiation of Ni sulfide ores leads to the rejection of unwanted constituents as mining wastes, which may still contain extractable amounts of Ni (Edgar Peek et al., 2010)."

Jan 1, 2012

By R. Q. Honaker

A significant problem in ultrafine particle classification is the significant amount of submicron particle by-pass to the coarse particle stream. In classifying cyclones, submicron particle by-pass to the underflow stream can be reduced by decreasing water recovery. Past studies have shown that a reduction can be realized when the feed solids concentration is increased or the apex diameter is reduced. However, both adjustments tend to increase the particle size cut point and negatively affect classification efficiency due to the impact on slurry rheology. The addition of a viscosity modifier to the feed stream of a classifying cyclone improved the classification performance and decreased the particle size cut point over a range of feed solids concentrations. The detailed test program investigated the use of the modifier in conjunction with varying apex diameters to identify conditions that minimize ultrafine by-pass. With small apex sizes, roping conditions were readily eliminated by the addition of viscosity modifiers. The addition of the modifier had no deleterious effect on froth flotation performance, which commonly serves as a downstream separation process. The fundamental and practical benefits of viscosity modifiers in classification processes are discussed in this publication.

Jan 1, 2006

By G. S. Hume

THE Plains of east-central Alberta herein described embrace an area from Viking east to the Saskatchewan boundary and from North Saskatchewan river south to Coronation and Monitor (Figure 1). By far the greater part of this area is deeply drift-covered, and .outcrops of bedrock are relatively few and often widely separated. Within the area there are large morainal hills and others of considerable extent that superficially have all the characters of morainal hills but contain a core of bedrock. These latter, then, were hills when the ice sheet traversed the country and only have been modified by glacial agencies. In many places on them, the drift is but a thin veneer, as is certainly the case in part of the Neutral hills (Figure 2) northeast of Coronation and north of Monitor. In other cases, however, as in the Blackfoot hills, southwest of Lloydminster, the drift is sufficiently thick to conceal practically all the bedrock and in many places no information is available as to whether a bedrock core, representing a pre-glacial hill, is present. There is no question, however, that the larger river valleys, as for example those of the North Saskatchewan and Battle rivers, are in part at least pre-glacial. Proof of this can be demonstrated in many places, because obviously the valleys must have been present in pre-glacial times to allow glacial deposits to have accumulated in them. It is also known that inter-glacial deposits occur. At one locality in Battle River valley, in sec. 30, tp. 45, range 2, west of the 4th mer., the following section occurs( l ): 15 feet of boulder clay with granite and other boulders. 56 feet of stratified sands, clays, and gravels containing pebbles of Precambrian rocks and fresh-water shells. From this it is apparent that the 56 feet of stratified sands, clays, and gravels must have derived their Precambrian pebbles from a previous glaciation of which the overlying boulder clay represents another ice advance in this area. Thus, although the river valleys contain glacial and interglacial deposits, they have not been filled by them to such an extent that the drainage has been diverted, and in many places, especially in the case of Battle river and some smaller streams, the size of the valley is altogether out of proportion to the size of the stream it now contains.

Jan 1, 1937

By L. P. Chrismas

"IN 1975, Nova Scotia produced 1.8 million tons of coal with a FOB mine value of $47.6 million. Of this total, about 30 per cent or 600,000 tons was coking coal and the remainder was steam and industrial-grade coal. The Nova Scotia Power Corporation consumed 630,000 tons in three generating stations and 570,000 tons were sold to Sydney Steel for making coke for its steel operations. Exports, principally to Great Britain, comprised 370,000 tons in 1975 in addition to the 300,- 000 tons shipped to other provinces for use by cement and pulp and paper companies. In 1975, just over 100,000 tons of coking coal were imported into the province from Alberta. Before 1975, low-volatile coking coal was traditionally obtained from the United States. In 1975, production came from seven individual mines and one project involving reclamation from mine dumps in Pictou County. Of the seven producers, four are owned by the Cape Breton Development Corporation, a federal Crown corporation; the remaining three are small independent mines, but, even though small, they are sizeable contributors to the economies of their local areas. After 101 years of continuous operation, Devco's Princess mine was closed in 1975. The Nova Scotia coal industry, in terms of value, accounted for about half of total mineral production in 1975. The industry provides jobs for 3,000 men and women. It is also significant that in 1975 Nova Scotia produced about 6.5 per cent of Canada's total coal production of 28.3 million tons. Detailed statistics on Nova Scotia's coal industry appear in the Appendix."

Jan 1, 1976

By W. S. Hargratt

THE present era of exploitation of the Little Long Lac and Sturgeon River areas commenced in 1925, when Beardmore Gold Mines started development of what is now the property of Northern Empire Mines. A shaft was sunk in 1927-28 and a very limited amount of underground work was carried out, following which the property was shut down. It remained idle until 1932, when Empire Star Mines, a Delaware Company, optioned the property. This Company formed the Northern Empire Mines Company, Limited, to operate the mine, and immediately instigated an aggressive programme of surface and underground development. By the summer of 1933, sufficient ore was indicated to justify the installation of a small mill. The decision was also reached to bring in electric power. A power-line was built from Hydro, the Ontario Power Commission's development on the Nipigon river, to the mine, a distance of approximately 50 miles. This work was entirely financed by Northern Empire Mines. Mill construction was commenced in October, 1933, and completed by March, 1934, thus making this mine the first producer in this district.

Jan 1, 1940

By B. N. Church, R. H. Seraphim, J. T. Shearer

"The Lexington-Lone Star CU-Au deposits straddle the Canada U. S.A. border, south of Greenwood, British Columbia. This 3 km long linear porphyry system occurs in a northeast dipping belt of sheared quartz porphyry and serpentinite. The best grades of mineralization occur in three principal bodies known as the Pit zone, the Northwest zone and the Lexington Main zone. The Pit zone at the Lone Star mine is the largest of the mineralized bodies and consists of fracture fillings and disseminations of pyrite, chalcopyrite and minor molybdenite, hosted by the Lexington quartz porphyry. The Northwest zone, discovered by drilling through overburden near the 49th Parallel, consists of pyrite-chalcopyrite-gold mineralization in the quartz porphyry and the footwall serpentinite. The Lexington Main zone has the highest grade of gold and occurs near the footwall of the quartz porphyry with the mineralogy and setting similar to the Northwest zone. Alteration of the host quartz porphyry is mostly sericitic and chloritic; alteration in the adjacent serpentinite is mostly talc and carbonates.A weighted average of the drill-indicated reserves is 19.5 million tonnes grading 0.56% CU and 0.55 gl t Au.IntroductionThis paper describes copper-gold mineralization associated with the Lexington quartz porphyry in the Greenwood mining camp of south-central British Columbia and adjacent parts of Washington State (Fig. 1).Access to the property is mainly by a network of farm, logging and old mining roads to the U.S. border, 10 km south of Greenwood, British Columbia."

Jan 1, 1995

By A. W. JR. Whitaker

Introduction Within the last quarter of a century the Lake St. John-Saguenay valley has been converted from a quiet agricultural district to one of the important industrial centres in the Dominion. First there was the expansion -of the pulp and paper industry, and then, starting a little over ten years, ago, the development, in large .blocks, of the enormous hydro-electric power resources of the Saguenay river. Coincident with this power development, the world aluminum industry was rapidly expanding and looking for a new source of cheap power. This was found in the Saguenay valley-and so, in 1925, Arvida was established by the Aluminum Company of Canada as a location for one of the largest aluminum plants in the world. Arvida, an incorporated city comprising an area of some ten square miles, is ideally located on a more or less level plateau about 350 feet above the Saguenay river. Seldom has industry stepped boldly forth and carved out of Nature a community with full city status. The process usually goes through the steps of camp, village, town, and city, involving improper planning or lack of planning; all of which has been avoided at Arvida by starting out in the right way. While this community has only a population of approximately 2,000 at the present time, it is carefully planned for a population many times this figure. Streets, city parks, business and residential sections, have been definitely planned, and, with a City government, proper ordinances were passed at the beginning to ensure the building and maintenance of a model industrial community. As the crow flies, Arvida is about 35 miles due east of lake St. John, and 0 miles west of the St. Lawrence river at Tadoussac. From a shipping standpoint, it is well served by the Canadian National railways, with direct lines to Quebec and Montreal, and by ocean shipping facilities at Port Alfred, which is about 15 miles to the east on the Saguenay river and is served by the Roberval & Saguenay railway. The latter has interchange connections with the Canadian National at Arivda, and also operates a branch line into the city of Chicoutimi.

Jan 1, 1933

By E. O. Lilge

THE USE of the Driessen cone as a heavy-media concentrator involves a mineral dressing process in which many variables inherent in the ore and in the process may have an effect on the efficiency of mineral separation and the operation of the cone. The magnitude of these effects and their possible interrelationships must be known before a full-scale plant can be designed and built. It appears that, among the most important variables, are the following: Ore Variables: The particle size of feed The difference in specific gravity between economic and non-economic minerals The intimacy of mineral association Cone Variables: Cone inlet area Ore to media ratio Cone ratio Size distribution in heavy media Specific gravity of media Viscosity of media Type of media

Jan 1, 1956

By E. Fritz

This paper reviews the history, developments and 10 milestones of the oxygen steelmaking processes, with a special focus on conventional autothermic converters, high-speed converters with a blowing rate up to 5 m3n/t min and allothermic converters with coal addition, post combustion and the possibility to increase the scrap rate up to 50%. Related operating results are introduced. A new process route, which is based on hot metal and chromium ore, is outlined. The cost advantage for the production of 304 stainless steel grade is higher than 100 USS/t. The synthesis of EAF and oxygen converter steelmaking, a comparison of decarburization rates, refining combustion burners for optimized oxygen-management in EAF and an example for a large advanced EAF are outlined. Possibilities of flexible steelmaking and the growth and outlook of worldwide oxygen steelmaking are described.

Jan 1, 2004

By M. Hames, K. Larmour-Ship, B. Grinbaum, E. Buchalter, R. Hackl, B. Wassink

Sodium cyanide continues to be the lixiviant of choice for gold dissolution. Many gold ore-bodies contain a significant amount of cyanide-soluble copper which increases the cost of processing due to high cyanide consumption and high cyanide destruction and disposal costs. Several cyanide destruction processes are in use today, however, there are just a few cyanide recovery plants operating. A solvent extraction process to recover cyanide has been developed which utilizes the organophosphorous extractants Cyanex 923, di-butyl-butyl-phosphonate (DBBP) or tri-n-butyl phosphate (TBP) in Bateman Pulsed Columns. Copper cyanide species are first converted to hydrogen cyanide (HCN) by acidification, with or without sulfide addition. HCN is extracted by the organic and stripped using a suitable base (eg. NaOH) resulting in a high strength cyanide solution (eg. NaCN) for recycle to the gold recovery process. Continuous pilot plant testwork on HCN extraction using a 40 mm diameter Bateman Pulsed Column demonstrated a cyanide recovery of greater than 99% with final levels of cyanide in solution of less than 10 ppm. These results illustrate the potential of this technology to recycle cyanide and to detoxify final effluent streams.

Jan 1, 2005

"Beneficiation of low grade ores is the process of increasing the grade of a mineral through unit operations that remove and separate the waste (or gangue) material from the valuable mineral that can then be used for further processing or direct use. Important factors when deciding upon a beneficiation program are the feed grade, mass yield and the metal recovery. As lower grade ores are being processed beneficiation is a critical process. How predictive is laboratory test work for “as built” operating projects? Beneficiation includes all or some of the available unit operations to produce a beneficiation flow sheet i.e. associated unit operations including but not limited to optical sorting, radiometric sorting, crushing and screening, coarse cobbing, jigging, dense media separation (DMS), spirals, magnetic separation, flotation, thickening, filtering and drying. Reference to specific projects and the approach developed in formulating a beneficiation flow sheet and a comparison of difficult and simple beneficiation flow sheets are cited. INTRODUCTIONReserves of high-grade iron ores are reducing all over the world, at an alarming rate, over the years as a result of the rapid increase in demand for steel particularly from Japan and then China. The recovery of mineral value from the low-grade ores using present technology is more expensive than DSO ores due to high energy and capital costs. Beneficiation is defined as a variety of processes whereby extracted ore from mining is reduced to particles that can be separated into mineral and waste.Various physical properties of an ore can be exploited to separate a low grade fraction including variation in hardness, density, reflectance, conductivity and magnetism.""Beneficiation"" of iron ores includes concentration, generally by physical removal of unwanted gangue. Also considered beneficiation is the regulation of product size, or other steps such as agglomeration to improve its chemical or physical characteristics prior to smelting."

Jan 1, 2012

By Michael Moser, Brighty Dutta, David Dreisinger

"Molybdenum is widely used in the industries as an alloying element in the manufacture of steels and super alloys. The widespread use of the element encourages a growing need to develop extraction processes for recovery from both primary and secondary sources. The Solvay Group has developed a solvent extraction reagent named CYANEX®600 for the recovery of molybdenum from acidic solutions originating from both low grade (e.g. copper solvent extraction raffinates, smelter dusts and slags) and high grade (molybdenite) molybdenum sources. CYANEX®600 is a purified form of CYANEX®272 with the active component bis(2,4,4- trimethylpentyl)phosphinic acid. The extraction behavior of CYANEX®600 towards molybdenum in sulphuric acid medium was evaluated. The uptake of molybdenum increased with the increase in concentration of CYANEX®600. The approximate stoichiometry of the extracted complex was: Mo: CYANEX®600 = 1:2. Efficient back-extraction could be achieved with 0.1 M disodium EDTA and 0.1 M (NH4)2CO3, thus providing the option of recyclability of the extractant. The detailed back-extraction studies are currently under progress to find out the possible option for complete transfer of Mo(VI) to the aqueous phase so that high purity Mo salts could be precipitated from the molybdate solutions.INTRODUCTION Molybdenum (Mo) is one of the world’s valuable metals and is highly sought after by researchers due to its versatile mechanical, thermal, chemical properties. Swedish scientist Carl Wilhelm Scheele demonstrated molybdenite to be a mineral sulfide in 1778. Peter Hjelm successfully isolated dark metal powder from the mineral sulphide and named it as ‘Molybdenum’ in 1782 (Gupta, 1992). Molybdenum is a refractory metal of silver gray appearance and is an important alloying element used in the manufacture of steels and super alloys. Molybdenum compounds are widely used in formulation of catalysts (Gupta, 1992). Molybdenum occurs in nature only in chemical combination with other elements. Several molybdenum bearing minerals have been identified, but the only one of commercial significance is molybdenite (MoS2). As molybdenum is a strategic metal for the industrial sector, its widespread use acts as a factor for depletion of the natural resources. Hence, there is growing need to develop extraction procedures for its recovery from both primary and secondary sources. United States, China, Chile, Canada, Peru, and Mexico are listed as the main producers by the U.S. Geological Survey, 2016 (U.S. Geological Survey, Mineral Commodity Summaries, January 2016)."

Jan 1, 2017

By B. Szpunar

Structural and mechanical changes of urania are investigated when oxidized to U3O8. The CASTEP ab-initio quantum mechanical program, employing density functional theory is used. The total energy technique is implemented to investigate changes in the lattice constants. The ab-initio calculations predict a 36% increase in the volume per uranium atom when transforming from UO2 to U3O8, which agrees very well with experimental data. The implication of this prediction on the linear expansion and fuel fragmentation is discussed. The calculated elastic constants of urania are in good agreement with experiment. The predicted mechanical properties of UO2 and U3O8 are compared.

Aug 1, 2010