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By D. R. Boyle

"The basal type uranium deposits in south central British Columbia occur within unconsolidated, late Miocene fluvial paleochannel sediments that overlie major fault zones within the Okanagan Highlands Intrusive Complex. Prior to the formation of mineralization, paleovalleys containing host sediments were flooded by Pliocene valley basalts of the Plateau Basalt Formation. Five uranium deposits have been outlined to date, of which the Blizzard (4020 tonnes U) and TYee (650 tonnes U) are the largest. The basement intrusive complex underlying the deposits varies in age from early Cretaceous to Eocene and is comprised of quartz monzonite, granodiorite, Coryell monzonite, porphyritic granite and pegmatite.The mineralized host sediments comprise a complex sequence of interfingering conglomerates, arkosic sandstones and mudstones. Organic material is abundant in many, but not all, mineralized beds. Uranium mineralization is present in the form of uranous (ningyoite) or uranyl (saleeite, autunite) phosphates coating clastic grains and filling voids. Because of very strong reducing conditions related to large concentrations of marcasite and organic material, ningyoite is the only uranium mineral in the Tyee deposit, whereas the Blizzard deposit contains a more complex assemblage of minerals (saleeite, autunite, ningyoite). The observed paragenetic sequence of mineral precipitation in the Blizzard deposit (autunite-saleeite-ningyoite) indicates that the uranyl minerals, saleeite and autunite, are primary. Small amounts of Zn, Ni, Co and Mo have been introduced into the Blizzard deposit whereas Mo is the only non ore-forming element enriched in the Tyee deposit. Mn is the only depleted element in both deposits."

Jan 1, 1986

By O. A. Carson

"IntroductionTHE ZINC-BASE die casting alloys in common usage contain approximately 4 per cent aluminum as the major alloy element. In addition, they contain about 0.05 per cent Mg .and may• have a small amount .of copper. These are usually the only •elements intentionally present.Small amounts of some impurities have been shown to have a deleterious effect on the properties of these alloys and therefore the impurities are kept low by starting with '99.99%' zinc.The reasons for holding the aluminum content at 4 per cent are not clear. Some statements appear in the literature that higher aluminum increases the brittleness, but probably the chief reason was the relative price of zinc and of aluminum when 4% alloys became firmly established. At that time, aluminum was three to four times the price •of zinc on a weight •basis. Recent prices, roughly equivalent per lb., make aluminum considerably cheaper than zinc on a volume basis and suggest that increased aluminum content would result in a decrease in the cost per piece due to the lower density of the alloy.Little information could be found in the literature and, therefore, it was decided to determine some physical properties of the higher aluminum zinc-base alloys made from high-purity zinc."

Jan 1, 1953

By L. V. Chugaev, Y. M. Shneerson, P. V. Zaytsev, I. V. Fomenko, M. A. Pleshkov

"Pressure oxidation (POX) is one of the most common and reliable methods of processing gold-bearing sulfide concentrates. However, when processing concentrates that contain natural carbonaceous matter, substantial gold losses occur due to autoclave preg-robbing. The latter involves formation of gold chloride complexes under typical POX conditions (high temperatures, high acidity and high ORP) and subsequent sorption of these complexes by carbonaceous matter. Naturally, chloride ion plays a significant role in the process of autoclave preg-robbing; its concentration in POX solution has a well-marked effect on subsequent gold recovery during cyanidation of POX residue. The previous research done by SRC Hydrometallurgy showed that autoclave preg-robbing of gold could be significantly inhibited by the addition of mercury(II) compounds to POX slurry. The positive effect of mercury(II) was well pronounced both at high (>20 mg/L) and low (<5 mg/L) Cl concentrations in POX solution. The successful bench-scale laboratory testing was followed by pilot plant trials at Ore Test Facility in Blagoveshchensk, Russia. The present paper provides the results of these trials. The bench-scale testing results were verified; the optimum oxidizing parameters and reagent dosage were specified. The behavior of mercury (II) at POX pilot plant was found to be in good consistency with industrial practice described in the literature.INTRODUCTION Pressure oxidation (POX) is one of the most common, reliable, and commercially proven methods of processing gold-bearing sulfide ores and concentrates. However, when processing double refractory materials that contain natural carbonaceous matter, POX technology advantages are compromised by autoclave preg-robbing of gold. The latter occurs when natural organic carbon and soluble halides are both present in autoclave feed. Strongly oxidizing conditions of POX (high temperature, oxidation-reduction potential or ORP, and acidity) favor formation of gold-halide (mostly, gold-chloride) complexes, which tend to bond with carbonaceous matter. The exact nature and mechanism of this bonding is unknown, but as the result of this, cyanide is unable to leach gold from POX residue and the precious metal is lost to the tails (Axenov et al., 2014; Dimov, Chryssoulis, & Sodhi, 2003; Fomenko, Zaytsev, Pleshkov, Chugaev, & Shneerson, 2013)."

Jan 1, 2017

By K. Muehlenbachs, J. U. Stemler

"Abstract - The Boston deposit is a recently discovered Archean lode-gold deposit located approximately 700 km northeast of Yellowknife, in the southern portion of the Hope Bay volcanic belt. Primary H2O-CO2-NaCl fluid inclusions associated with gold mineralization at Boston are of low salinity (4.6 ± 1.4 eq. wt.% NaCl, n = 182) and contain pure CO2. Homogenization temperatures of liquid-phase inclusions average 270° ± 33°C (n = 141), but some fluid inclusion assemblages contain coexisting liquid- and vapor-phase inclusions that homogenize near critical conditions, suggesting phase separation. In these groups, liquid-phase inclusions homogenized at 299° ± 25°C (n = 24), and vapor-phase inclusions homogenized at 338° ± 28°C (n = 18). These temperatures overlap within error, and a median temperature of ~320°C is taken as representative of trapping conditions within the veins. An approximate pressure of 2-3 kbar was estimated from fluid inclusion isochores at this temperature. Stable isotopic compositions of carbonate minerals from the mineralized zones range from -4.7‰ to -3.1‰ in d13C, and from 11.2‰ to 12.8‰ in d18O; quartz ranges from d18O = 12.8‰ to 14.9‰; and pyrite ranges from d34S = 2.1‰ to 3.5‰. The d18OH2O, d13CCO2, and d34SH2S values of the fluid calculated from these minerals at 320°C are 6‰-9‰, -2.4‰ ± 0.6‰, and 1.5‰ ± 0.5‰, respectively, and are intermediate between metamorphic and magmatic compositions. A unique source for the fluids cannot, therefore, be constrained from these data. Petrographic and geochemical data for the Boston deposit are consistent with data from other Archean lode-gold deposits worldwide, implying that the Boston deposit formed in a similar environment and from similar types of fluids. These results suggest that the Hope Bay volcanic belt may represent a major new mesothermal gold belt in this part of Nunavut. Sommaire - Le gîte Boston a été récemment découvert à environ 700 km au nord-est de Yellowknife dans la partie sud de la ceinture volcanique de Hope Bay, il s’agit d’un gîte d’or filonien d’âge Archéen. Les inclusions fluides primaires de H2O-CO2-NaCl associées à la minéralisation aurifère du gîte Boston présentent une faible salinité (4.6 ± 1.4 eq. pds.% NaCl, n = 182) et contiennent du CO2 pur. La température d’homogénéisation des inclusions à phase liquide est en moyenne de 270° ± 33°C (n = 141), mais certains assemblages d’inclusions contiennent des phases liquides et gazeuses coexistantes qui s’homogénéisent dans des conditions quasi critiques, suggérant qu’elles résultent d’une séparation de phase. Dans ces groupes, les inclusions de phase liquide s’homogénéisent à 299° ± 25°C (n = 24) et les inclusions de phase gazeuse s’homogénéisent à 338° ± 28°C (n = 18). Ces températures se recoupent à l’intérieur des limites de l&apos;erreur de mesure, et nous considérons qu’une température médiane de ~320°C est représentative des conditions de piégeage dans ces veines. Les isochores permettent d’estimer une pression d’environ 2-3 kbar à cette température. La composition des isotopes stables des carbonates dans les zones minéralisées s’étend de -4.7‰ to -3.1‰ pour d13C et pour de 11.2‰ à 12.8‰ pour d18O; les valeurs de d18O pour le quartz varient de 12.8‰ à 14.9; et les valeurs de d34S dans la pyrite vont de 2.1‰ à 3.5‰. Les valeurs de d18OH2O, d13CCO2, et d34SH2S du fluide calculé à partir de ces minéraux à une température de 320°C est de 6-9‰, -2.4‰ ± 0.6‰, et 1.5‰ ± 0.5‰ respectivement, reflétant des conditions intermédiaires entre des compositions métamorphiques et magmatiques. Il n’est donc pas possible d’identifier une source unique pour ces fluides à partir de ces données. Les données pétrographiques et géochimiques du gîte Boston sont similaires à celles d’autres gîtes d’or filoniens ailleurs dans le monde, ce qui implique que le gîte Boston s’est formé dans un environnement similaire à partir des mêmes types de fluides. Ces résultats suggèrent que la ceinture volcanique de Hope"

Jan 1, 2006

By John Postle, Maureen Jensen, Marcel Vallee, Bernie Haystead, Dan Hora, Graham Clow

The Committee's proposed standards establish definitions and guidelines for the reporting of Exploration Information, Mineral Resources and Mineral Reserves in Canada and are identified as the "CIM Standards" and referred to as such hereafter in this document. To provide additional clarification to Qualified Persons (QPs), guidelines have been included with the respective definitions. The CIM Standards are applicable to all minerals including industrial minerals, diamonds and other gemstones. Reserve definitions for bitumen, natural gas and oil are not included in these Standards. The CIM Standards are not intended to cover mineral inventory estimates that will be reported to government agencies.

Jan 1, 2001

By D. W. Hayley

The rapid expansion of exploration drilling with anticipated production facilities for oil and gas in the Mackenzie Delta region of the Northwest Territories has created a demand for granular construction materials. This paper discusses the technique adopted and experience gained by the authors from several major resource evaluation programs in this remote area. The first part of the paper describes a methodology for deposit identification, logistics of helicopter and ground-based drilling operations and the sampling difficulties which are unique to permafrost: soils. The second part describes the exploitation of a large glaciofluvial deposit at YaYa Lake on Richards Island. Granular construction material is sparse in the delta region relative to projected demand. Exploitable sources of granular materials for aggregates or construction borrow are found in glaciofluvial deposits of Pleistocene age or in outcrops of Paleozoic bedrock. Glaciofluvial landforms can be located by reference to published surficial geology maps coupled with airphoto interpretation. Preliminary assessment of these features in a large region is most economically carried out during the summer months with a drill that is transportable by helicopter. Once prospective borrow pit sites are identified, a detailed ground-based winter drilling program must be undertaken to establish aggregate quality and quantity, and to provide information on natural features which could affect development. The glaciofluvial terrain has been highly modified by the formation of massive ground ice within the gravel deposits. This presents some unique pit development problems which are not encountered in a normal bedrock quarry operation.

Jan 1, 1977

By W. Holdsworth

The flotation mill of Dentonia Mines, Limited, at Greenwood, B.C., went into operation on April 20th, 1934, and by October 11th a total of 15,000 tons of ore had been treated. It is intended in this paper to describe briefly the operation and to give some of the operating data which have been gathered. The metallic minerals in the Dentonia ore are pyrite, chalcopyrite, galena, and, occasionally, native gold, and the gangue includes chloritic material, vein quartz, and calcite. Pyrite makes up about 90 per cent of the metallic content of the ore, in which it is disseminated as irregular grains and well-formed cubes. An average analysis of the ore is: gold, 0.27 oz. per ton; silver, 1.73 oz. per ton; copper, 0.12 per cent; lead, 0.31 per cent; and zinc, trace. From the mine ore-bin, situated near the portal of the tunnel at the mine, the ore is hauled by motor truck to the mill, a distance of three-quarters of a mile, and there dumped into the receiving bin, which has a capacity of fifty tons. The hauling is done during one eight-hour shift, commencing at 7 a.m. The maximum size of the ore fed to the mill-bin is ten inches. Lumps larger than this are broken by sledge hammer to pass through grizzly bars, spaced ten inches apart, installed above the bin. The ore is drawn from the bin by a 30-inch, 6-ply conveyor belt, 18 feet 6 inches long. In the near future, when the cross-cut tunnel is completed, the ore will be trammed to the receiving bin. This will effect a considerable saving in cost. At the same time, the bin will be set back several feet, so that the length of the conveyor belt may be doubled. This will make efficient ore-sorting possible, and so ensure a minimum of waste rock in the mill feed.

Jan 1, 1935

By D. M. Hendrick, D. K. Fountain

Since the discovery by conventional prospecting of the Horne deposit in 1920, the Noranda area has produced 82 million tons of copper-zinc-gold-silver ore from sixteen massive sulphide bodies. Recent exploration in the area has consisted of systematic studies employing geology, geophysics and geochemistry. Due to the depth of the deposits being sought, surface geo-physical surveys are limited in their effectiveness as DIRECT indicators. However, because of the geological environment, surface geophysical methods, and the Induced Polarization method in particular, can be success-fully employed as INDIRECT indicators of ore deposits. Examples of survey results from various properties in the Noranda area illustrate the advantages and limitations of the Induced Polarization method as an exploration tool in this area.

Jan 1, 1971

By D. N. Madge

The use and development of industrial process control computers in the mineral industry during the 1970&apos;s has been sluggish. This cautious approach is due to lack of commitment by senior management. The lack of commitment is due to several reasons: variable mineral processes and technologies, market fluctuations, and excessive costs and inadequacies of applicable products supplied by computer vendors.

Jan 1, 1979

By N Robb

This paper gives an account of the laboratory testing, plant testing and final inclusion of the two-stage sulphuric acid leaching process in the Milliken mill. Operational results for September, 1962, are presented, showing a uranium extraction of 95.5 per cent, with a saving of some 16 lbs. of 100 per cent H~S04 and some 9 lbs. of lime per ton milled. Methods for effecting further improvements in the process are indicated. HISTORY P RIOR to the incorporation of two-stage leaching, the process for the treatment of uranium ores at Milliken consisted of a single-stage sulphuric acid leach, followed by a solution recovery step involving washing in thickeners and two-stage filtration. The thickener overflow solution was subsequently concentrated and purified by ion exchange, and the uranium was recovered, by two-stage precipitation, as ammonium diuranate. Figure I illustrates this flowsheet. For satisfactory extraction of uranium from the. Milliken ore, a high residual acidity, of the order of 40 grams per litre of free acid in the discharge solution, must be

Jan 1, 1963

By K. K. Mamyrbayeva, G. Z. Guseinova, V. A. Luganov

This paper presents the results of theoretical and technological studies on leaching ore of Bozshakol deposit. The major oxidized copper mineral of Bozshakol ore is atacamite, and the content of malachite, azurite, cuprite, copper sulfide minerals is insignificant. The chemical composition of the test sample, with mass, %: 0.9 Cu; 55.00 SiO2; 22.40 AI2O3; 9.00 Fe2O3; 2.24 CaO; 3.56 MgO. Technological studies on leaching the ore were carried out with sulfuric acid 5, 15, 25 and 50 g/dm3 in one and multistage (up to 4 stages) countercurrents. Size of ore 1 mm, the ratio S : L 1: 4. It was found that with increasing of acid concentration from 5 to 50 at one-mode leaching the copper extraction reaches 55 %. At multistage leaching the copper recovery reaches 73 %, a productive solution containing g/dm3: Cu - 4; Fe – 1.2; Al – 1.1 at a pH of 2.8. When leaching the cinders obtained by ore roasting in an atmosphere with limited value of oxygen, with increasing of the roasting temperature from 650 up to 750 °? the extraction of copper from the Bozshakol ores reduced from 31.5% down to 24.4%. The rate of filtration is markedly increased compared with the crude ore. When leaching the cinders obtained by roasting in a nitrogen atmosphere a marked increase up to 87.2-88 % of copper extraction from Bozshakol ores is observed. As an extractant for the extraction of copper from the pregnant solution used LIX984N extractant in kerosene. On the basis of the calculations it was built extraction isotherm and modeled processes of copper recovery with the circuit 2E + 1P, allowing up to 93 and 96% extraction. The through extraction of copper from the ore in the electrolyte was 67 %. Technology is recommended for semi test.

Jan 1, 2016

By E. Krause

The oxidation of Fe(II) with S(IV) and oxygen can be used advantageously in leaching systems requiring both Fe(III) and sulfuric acid; e.g., heap leaching of sulfide-containing ores or concentrates. The oxidation of Fe(II) with SO2/air is several orders of magnitude faster than with air alone; rates of up to ?20 g/L&apos;h were observed at 25°C. The reaction proceeds via an intermediate orange-red mixed-valence Fe(II)/Fe(III) sulfite complex, which is present at an essentially constant concentration throughout most of the oxidation process. The oxidation rate of Fe(II) is approximated by the formula -d[Fe(II)]/dt = k [S(IV)] [02]0&apos;3. The concentration of the mixed-valence complex, and thus the iron oxidation rate, decreases with increasing acidity. Certain impurities, such as SCN- and thiourea, negatively affect the rate. The oxidation reaction 2Fe2 + SO2 + 02 4 2Fe3+ + S042- is accompanied by the side reaction H20 + SO2 + 1/202 4 H2SO4. The side reaction becomes particularly important at low temperatures and whenever the oxygen mass transfer is insufficient with respect to the rate of addition of S(IV). Thus, effective oxygen mass transfer is essential for achieving high oxidation rates with minimal acid formation. The activation energy was estimated as 141 kJ/mol over the temperature range 10-35°C.

Jan 1, 2006

By M. D. Vance, G. R. Corbett, S. D. Butt

Surface wave imaging is a relatively new seismic technique that generates subsurface depth images without having to drill boreholes into the ground, and is rapidly becoming a standard tool in non-destructive geotechnical characterization. This paper presents a case study of the application of these surface wave techniques to image shallow abandoned mine workings at the Montague Gold Mines district near Dartmouth, Nova Scotia. This district has numerous steeply dipping narrow vein workings from historical mining activity, and has actively subsiding and collapsing crown pillars. Due to the rugged conditions at the site and the relative narrowness of the openings (often less than 1 m), a surface seismic system was developed that had improved portability and lateral resolution over other available seismic imaging systems. Seismic surveys were conducted over two sites where independent evidence indicated the presence of shallow mine workings. At one site, a comparative gravity survey was also conducted. The seismic data was processed to generate velocity vs depth images. Overall, the velocity images show vertical zones of zero velocity in the same lateral positions where historical mapping, current subsidence and gravity surveys indicate the presence of steeply dipping workings. Further, the velocity sections are consistent with the thickness of the till cover at each site and the possible weakening of crown pillars at one of the sites.

Jan 1, 2005

By K. W. Edwards

The formulation of a theoretical basis for the evaluation of in-situ coal through the use of geophysical logs is outlined. This involved the development of an approach to the interpretation of resistivity in environments having multiple conductive and non-conductive components. Utilizing this approach and other conventional interpretation techniques, a program was developed yielding accurate determinations of the in-situ percentages of coal, water and ash for the evaluation of coal deposits. Basic information obtained from the CWA program can be utilized in numerous aspects of total mine planning . Some examples of the practical application of this method are included.

Jan 1, 1978

By W. J. Farley

Location and History The Sherritt Gordon mine is in northern Manitoba, one hundred miles north of The Pas and forty miles northeast of Flin Flon. The original discovery was made by a Cree indian, Philip Sherlett, in 1922. The claims lapsed in 1924 to be re-staked and optioned by various mining groups who carried out a certain amount of development work before relinquishing their options. In 1927 the present Company, Sherritt Gordon Mines, Limited, was formed to take over the property. Production commenced in 1931, but in the following year operations were suspended and it was not until 1937 that the prevailing price of copper pemitted resumption as an economic operation. The mine has operated continuously from that time to the present. Total production to the end of 1947 has been: Copper . . . . . . . . . 301,813 . .,345 pounds Zinc . . . . . . . . . . . 112,636 tons of concentrat (50% zinc) Gold . . . . . . . . . . 83,070 ounces Silver . . . . . . . . . 2,651,317 ounces General Geology The consolidated rocks in the vicinity of the mine, all of Precambrian age, are a series of gneisses and form a part of a great area of what are known as the Kisseynew gneisses. The Sherritt is the only known economic base-metal deposit to occur within the Kisseynew series. Extreme metamorphism has produced recrystallization that has imparted a decided igneous-like texture to many of the units. However, the gneisses are predominantly of sedimentary original although the most basic member, a hornblendegarnet gneiss, is considered to be an altered basic flow. Figure 1 illustrates the intricately folded structure and the succession of roe types. The footwall enclosing members are of sedimentary origin and represent quartzite and arkosic and greywacke derivatives. The contact footwall member is gneissic quartzite, a medium to coarse grained rock composed mainly of quartz with minor altered feldspar (orthoclase and plagioclase), muscovite, chloritized biotite, and magnetite. Most phases of this unit show varying degrees of granitization.

Jan 1, 1949

By E. L. Bruce

Introduction The Outokumpu copper mine is situated in eastern Finland, 50 kilometers west of the city of Joensuu or 225 kilometers directly north of the city of Viborg (Viipuri), which is situated at the eastern end of the gulf of Finland (Figure 1). The ore-body was discovered in 1910 by Dr. Otto Trüstedt after two years of careful, scientifically-directed, search. During the early period of development of the mine, the ore was treated locally and the copper re-covered by an electrolytic process. Now the ore is concentrated by tables and by flotation. The concentrates are shipped to Germany for refining. In 1929 the mine produced 150,000 tons of ore from which between 20,000 and 25,000 tons of flotation concentrates containing 20 per cent copper were produced. Profits in 1929 were approximately half a million dollars, but the present price of copper will affect very seriously the profits for 1930. The ore reserves are given as between 7 and 8 million tons (1). The grade of ore is stated to be 4 percent to 6 percent copper, with a little zinc.

Jan 1, 1931

By J. Defreyne

CESL has developed a proprietary hydrometallurgical process for base metal concentrates, notably those of copper and nickel. The process is based on pressure oxidation (PO) of the sulphide minerals, which is done at elevated temperatures in mixed sulphate-chloride liquor at about pH 2 ? 3. The process achieves maximum oxidation of the metals whilst minimizing sulphur oxidation to sulphate. Almost all base metal sulphide minerals are efficiently treated under these conditions. In the case of copper minerals, pressure oxidation does not generally put the copper into solution, because of the relatively high pH prevailing in this process. Therefore, PO is followed by an acidic leaching stage, which specifically aims at maximum copper dissolution with minimal leaching of iron. The overall copper recovery is largely determined by the efficiency of this stage. The process has low capital and operating costs, partly because there is minimal use of acid or neutralizing agents for iron dissolution or precipitation, respectively; this is achieved by minimizing iron leaching during both the oxidation and leaching stages. Iron sulphides in the feed concentrate deport almost entirely to the solid leach residue as hematite, which has superior handling characteristics for filtering and washing. Iron minerals play a key role in the process, with pyrrhotite and pyrite having very different responses to the oxidation process. Acid management for the whole process is affected by the iron mineralogy, and the flowsheet is therefore tuned to the specific concentrate.

Jan 1, 2006

By T E. Tibbetts

This paper deals with coal sampling in general and with mechanical coal sampling in particular. The necessity of obtaining representative samples is emphasized. Other sections of the paper are devoted to the design and selection of automatic samplers, with a consideration of the three main types, and the testing, operation and maintenance of these samplers. The cost of the installation of an automated sampling system must be related to the value of the material to be sampled, to the volume of coal involved, and to the savings in labour and economy which can be achieved. Introduction T HE Committee?:; on Coal Sampling of the Coal Study Subsection, Thermal Power Section (Eastern Zone), Canadian Electrical Association, was established in November, 1963, to "study the various problem areas of coal sampling." The first undertaking of the Committee was to at-tempt to survey the problem areas of coal sampling through an evaluation of coal sampling difficulties as experienced at both the plant design and operational levels within the electric utilities represented on the Committee. The results of this enquiry indicated that satisfactory answers to almost any conceivable

Jan 1, 1965

By M. Epiney, A. Ghahreman, R. Kim1and

"Pre-oxidation and cyanide leaching behavior of gold in the presence of sulfide minerals were reviewed, focused on the effects of oxygen injection in the gold leaching process. Generally, pre-oxidation and gold leaching kinetics from iron sulfide refractory minerals, such as pyrite, pyrrhotite, marcasite, pentlandite and arsenopyrite, can be enhanced with higher dissolved oxygen (DO) concentration. However, most of copper sulfide minerals dissolved well both in water and cyanide solutions, and copper from the minerals consumed DO and cyanide to oxidize and leach. Only in the presence of chalcopyrite, gold leaching was effectively occurred with increasing DO. However, chalcocite and covellite severely retarded gold leaching. Stibnite, an antimony mineral, formed a passive film on the gold surface under any DO conditions, and it slowed gold leaching. This impeding effect can be alleviated by leaching at low pH or adding lead salt. Using oxygen and lead together can make synergistic effect in oxidation of sulfide minerals and can enhance gold extraction. Depending on the mineralogical characteristics of the ore, the optimum DO and lead concentrations can be optimized. However, lead can cause environmental problems, and so its dosage should be minimized or eliminated by substituting it with oxygen injection.INTRODUCTIONGold ores containing sulfide minerals are becoming more significant as high grade gold oxide deposits are continuously becoming difficult to find. In light of this situation, to produce more gold, recovery methods from refractory gold ore containing various sulfide minerals should be investigated. Generally, sulfide minerals have impeding effects on gold leaching: formation of a passive film on the gold surface, high consumption of chemicalssuch as cyanide and oxygenduring leaching, reduction of gold cyanide by sulfide ions, etc. (Senanayake, 2008). Therefore, sulfides must be properly treated for better gold recovery. Pre-oxidation of sulfide minerals by injecting pure oxygen can decrease the impeding effects in gold leaching. Prior to cyanidation, sulfide minerals can be oxidized to metal hydroxide and sulfate form, which consume negligible cyanide in the following cyanidation circuit (Bodnaras et al., 1993). Moreover, gold cyanidation can be enhanced by increasing concentration of the dissolved oxygen (DO). In general, the optimum concentration ratio of [CN-]/[O2] is calculated as 6, but it goes higher in the real system (Marsden &House, 2006), which means that the reaction is typically controlled by DO concentration."

Jan 1, 2017

By S. Power Warren

Introduction It is generally conceded by flotation men that the condition at the surface of a particle of mineral or gangue is the most important factor controlling its behaviour in a flotation cell. Much research work has been devoted to the study of the forces that are active at the surface of the particle and of the effect of the surrounding solution upon these forces. Study of the relationship between mineral or gangue particles and gas bubbles indicates that, in the main at least, flotation is a physical phenomenon. The important factor, that of mineral-gas-bubble attachment, is unquestionably physical; however, modifications may be effected by chemical means, whereby the nature either of the surface of the particle or of the surrounding solution may be changed. For example, the coating of lead sulphide that forms on lead-carbonate ore particles when sodium sulphide is added greatly aids the flotation of the carbonate particles. Without going into the question as to why, under certain surface conditions, mineral particles will attach themselves to gas bubbles whereas under other conditions they will remain unaffected, it may be stated that there are three general conditions in a flotation pulp which control the attachment of the particle and the gas bubble.

Jan 1, 1933