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By C. A. C. Sequeira, G. N. Anastassakis

Electrochemical processes occur on nano-, micro- and macro- scale in numerous applications such as fuel cells, batteries, hydrogen production, mineral extraction, water treatment, electrotherapy, sensors and many others. In most of these applications, gases evolve either at one or both electrodes due to electrolysis. These gases form bubbles play a crucial role in electrochemical systems. For example, in electrowinning (EW) that is used to extract and refine metals such as Cu, Zn, Ni, Mn, and Cd from their solutions, in most cases the solution is acidic and oxidation of water molecules at the anode is the common counter reaction, which results in the liberation of oxygen bubbles. This generally requires a high overpotential and accounts for a considerable percentage of the energy consumed in metal EW electrolytic cells, apart from producing acid mist that is very corrosive for other cell equipment and building structures. The behaviour of bubbles in electrochemical systems is still a complex challenging topic which requires a better understanding of gas bubbles hydrodynamics and their interactions with electrode surface and bulk liquid, as well as between the bubbles themselves. The objective of the current paper is to briefly review the fundamental hydrodynamics of both gas bubbles on the electrode surface and gas bubbles interaction with the liquid bulk solution. The current work also investigates the impact of gas bubbling and some operating parameters in copper EW, such as current density (100-500 A/m2), temperature (25-75ºC), acidity (50-300 g/L) and a typical chemical mist suppressant (<50 ppm). The results clearly show that both suppressant and temperature reduced the overall surface tension of the solution. Also, chloride concentration and applied current improved electrolyte flow and copper quality at higher current densities. The current paper contributes to the development of mineral processing (specifically to copper hydrometallurgy), as it deals with fundamental hydrodynamics and interactions of gas bubbles that formed during copper EW and play a crucial role in copper electrochemical systems.

Jan 1, 2018

By M. Etelapaa

A new approach to controlling the process of selective flotation of sulphide minerals from pyrite in a lime environment is covered in the presentation. Advantages of process control based on the electrochemical potential of slurry controlled by ?? ? electrode are proved and compared to conventional methods of ?? ? metering and conductometry. Keywords: flotation, electrochemical potential, automation dosing system, neural network

Sep 1, 2012

By M. Zolghadri

MIBC and sodium metasilicate are used as a frother and a dispersant in coal flotation respectively. In order to study interaction between them, flotation experiments were performed on fine coal (<150 microns). It was found that if the frother (MIBC) dosage is in excess of a certain limit, it has an activation effect on the gangue minerals associated with coal. In addition, it was found that however sodium metasilicate can disperse clay slimes eliminating slime coating, but in the case of excess dosage, could intensify activation effect of MIBC, which is undesirable in coal flotation. Keywords: coal flotation, sodium silicate, frother, dispersion, activation

Sep 1, 2012

By Sergey Gudkov, Yuri Yemelianov, Stanislav Balikov, Andrey Boldyrev, Andrey Bogorodsky

"The results of POX of refractory gold-bearing concentrates using halide-ion as a lixiviant for precious metals and activated carbon as an adsorbent are given. It was found that gold did not recover to the solution when halide was added during POX. Silver partially dissolved in the solution. When halide-based reagents and activated carbon were added during POX, gold dissolved and loaded onto the activated carbon. The degree of sulfides oxidation was 99.3-99.6%. The recovery of gold onto granulated carbon was 94.7-94.8% when using chlorine-bearing lixiviants: NaCL, CaCL and carnalite and 98-99% when using KJ and KBr. This treatment process of refractory gold-bearing concentrates combines sulfide oxidation, dissolution and adsorption of precious metals. The results of the metals recovery achieved using this process can be compared with the recovery during POX-cyanidation. In this case, sodium cyanide was not used. This allows the reduction of capital and operational costs due to the absence of cyanidation, CIL and detoxification of leaching tailings circuits."

Jan 1, 2014

By G. Aguilera

The mineral suspensions do not present a newtonian behavior as their continuous phase; they can be pseudoplastic, dilatant, or both. The viscosity becomes as the most important rheological variable because the different industrial processes involve a wide variety of rheological scenes, with a specific rheological behavior for each one. Some authors have tried to model the viscosity of suspensions considering the volumetric fraction of solids and others have also kept in mind the size of the particles (Einstein, 1906; Batchelor, 1977; Jinescu, 1974; Krieger and Dougherty, 1959; Tangsathitkulchai and Austin, 1988). Others consider the shear rate (Cross, 1965; Hershel-Bulckley, 1926; Bingham, 1916, etc). However, none of the models is able to simulate the viscosity involving the physical, chemical and mechanic factors at the same time for crowded suspensions. A new model based on Neural Networks is presented, taking into account all the variables of ceramic clay suspensions and chemical additives. Keywords: viscosity, clay minerals, neural networks, simulation, mathematical function

Sep 1, 2012

By G. M. Savov

Copper recovery via Solvent Extraction (SX) process is a well-known technique, which is practiced commercially for approximately 40 years. The main advantages of the SX process are: an absence of using high temperatures (not more than 50oC), complete recycling of barren solutions, very high selectivity at removal and purification of metals, metal conversion to a form, suitable for easy subsequent recovery. Despite the wide acceptance of Solvent Extraction, it does have some shortcomings, namely SX employs large quantities of volatile organic substances. This leads to huge plant ?footprint? of SX circuits. The SX is very sensitive to low temperatures and quantity of total suspended solids in feed solutions and this causes bad phase disengagement times and therefore poor process performance. And most important ? low grade solutions (with copper concentrations below 1 gram per litre) are very unattractive for treatment via Solvent Extraction process, because capital costs for SX plants are not a direct function of copper tenor in the feed. The combined process with Ion Exchange (IX) and Solvent Extraction ? further called IX/SX by IONTECH Engineering was developed. This combination eliminates SX negative characteristics shown above. The key findings of the IX/SX process are; (1) recovery of copper from pregnant leach solutions with metal concentrations, varying on a broad range; (2) can be operate effectively with very low-graded copper pregnant leach solutions; (3) the construction of large ponds for pre-filtration of the pregnant leach solutions is not necessary; (4) working with turbid solutions and solutions containing large quantities of suspended solids; (5) winter operation without troubles; (6) strongly reduces organic losses; (7) technological approach lead to plant sizes reducing. This paper reviews the main stages of the combined IX/SX process, the applications for metal recovery and introduces projects where the process is applied. Key findings of the process are also presented. A comprehensive technical comparison between processes has been carried out. This paper also evaluates the advantages of using combined IX/SX technology as a purification and separation step in copper production process, with the aim of further increasing the overall copper recovery and to ensure that a suitable copper concentration in the advanced electrolyte is achieved. The implementation of a Ion Exchange (IX) process in the classic Solvent Extraction-Electrowinning process(SX/EW) is found to be beneficial for processing of pregnant leach solutions both from spent and new copper heaps and dumps, acid mine drainage and other industrial streams without any preconditioning as well as in terms of achieving improved recoveries and copper cathode quality.

Sep 1, 2012

By M. Lundström, J. Aromaa, S. Seisko

"Gold dissolution was investigated in ferric chloride media, promoted as one of the most promising alternatives for cyanide-free gold leaching. The characteristics of gold open circuit potential (OCP) and its relation to gold dissolution rate was investigated. Furthermore, the reaction mechanism of gold dissolution in ferric chloride leaching was discussed. The effect of solution variables, [Fe3+] = 0.02–1.0 M, [Cl–] = 2–5 M, T = 25–95 °C and pH = 0–1.0, on OCP and dissolution rate were studied electrochemically using rotating disk electrode (RDE) and linear polarization resistance (LPR) method with ?cyc = 1000 RPM. The investigated gold OCPs in ferric chloride solutions were found to vary between 597 and 688 mV vs. saturated calomel electrode (SCE) and gold dissolution rates between 1.2·10–5–5.0·10–4 mol s–1 m–2. Increase in temperature (25–55 °C) and ferric concentration (0.02–1.0 M) changed OCP into more positive values, while increase in chloride concentration (2–5 M) decreased it. The logarithm of gold dissolution rate was shown to increase linearly with increasing OCP at the temperature range 25–95 °C, ferric concentration range 0.02–0.5 M and chloride concentration range 2–4 M. A notable increase in the gold dissolution reaction rate was evident at T > 55 °C. INTRODUCTION Currently cyanide leaching is the predominant method used in gold production from primary raw materials (Marsden and House, 2006). However, since the Baia Mare disaster in Romania in 2000, the use of cyanide has been the subject of international concern due to the toxic nature of the chemical posing a significant health threat if exposed to the ecological entities (Hilson and Monhenius, 2006; UNEP/OCHA, 2000). Therefore, several countries e.g., Costa Rica, Czech Republic, Germany, Hungary, Turkey, many states of the USA and provinces of Argentina, have started to ban or limit cyanidation via legislation (Laitos, 2012). Thus, alternative solutions, such as thiourea, thiosulphate, oil-coal agglomerates as well as halides have been investigated in order to replace cyanide as lixiviant (Adams, 2016; Aromaa et al., 2014; Aylmore, 2005; Hilson and Monhemius, 2006; Lampinen et al., 2015). Ferric and cupric chloride leaching have been reported to have advantage over cyanidation being capable to dissolve refractory gold minerals, without pre-treatment such as pressure oxidation or roasting (Angelidis et al., 1993; Lundström et al., 2014; Marsden and House, 2006; van Meersbergen et al., 1993). According to Aylmore (2005), 4% of publications for alternative lixiviants to cyanide in gold leaching were within category oxidative chloride processes including aqua regia and acid ferric chloride leaching. Further, some patents have been granted for ferric chloride leaching of gold (Abe and Hosaka, 2010; Lundström et al., 2016)"

Jan 1, 2018

By W. H. Cheung

Nickel and cobalt production relies heavily on the processing of nickel laterite ores; these ores contain the majority of known Ni and Co reserves, 80% and 90% ~ 95%, respectively. The Caron process is used to extract Ni and Co metals from low-grade nickel laterite ores (1% Ni and 0.1% Co). It involves selective reduction of NiO and CoO minerals followed by ammoniacal leaching. Despite low metal recoveries, this process continues to be technically and economically reliable and thus commercially important globally. However, keeping the Caron process cost-effective has been a challenge for industries because of increasing economic and environmental pressures. Although studies of the Caron process have been extensive, significant improvements in recoveries of industrial processes have not been forthcoming. Reported industrial metal recovery from high iron content ore is only 80% ~ 85% for Ni and only 40% ~ 45% for Co; recovery is even lower for ores rich in magnesium. The real difficulty here is that there is no complete understanding of and control over the complex series of reactions in the ore and in the leaching solution during processing. Achieving effective metal recoveries from the Caron will require control of the mineral transformations, which affect the activation of minerals by reduction. In this study, the effect of over-reduction was investigated, which superseded the effect of activation by lowering the activity of the minerals and thus metal dissolution. Reduction was carried out in a batch reduction apparatus with 1:1 and 1:2.5 CO/CO2 gas mixtures from temperatures of 500 ~ 700°C and residence times up to 60 minutes. The pre-reduced ores were leached using a standard ammoniacal leaching test. Thermodynamic analysis and possible effects of stable phase field on leaching was examined. The results suggest that control of over reduction effects are directly related to the mineral transformation and reduction conditions.

Jan 1, 2014

By G. H. Li

Preparation strontium carbonate with celestite concentrate by flotation is studied by agglomeration-reduction roasting process. It is shown that, the drop strength of green pellet is greater than 4 times?(0.5m) -1 under the balling conditions of moisture of 9% and time of 18~20min. Lignin xanthate obviously improves the ballability of the celestite concentrate due to the increase of surface hydrophilicity, therefore, the balling rate is increased, as well as green ball strength. The drop strength of 7 times?(0.5m) -1 can be obtained when the lignin xanthate dosage is 0.5%~1%. Reduction roasting with anthracite shows that the SrSO4 conversion is 82%~83% for celestite concentrate pellet, under the optimal conditions of roasting temperature of 1100~1150? and time of 30min, and it is 10% higher than conversion of celestite lump under the same conditions. The strontium carbonate are prepared after roasted pellets are leached, purified and carbonated, and the SrCO3 content is higher than 97% , while the content of CaCO3 is less than 0.3%.

Jan 1, 2014

The ball level and pulp load play a key role in the operation of industrial scale ball mills. These two operating variables have a significant influence on the performance of the ball mill and any attempts to optimize these devices require manipulating either one or both of these variables. There are several models that can be employed to perform simulations to optimize the performance of industrial ball mills. However, most of these models require ball load and pulp load measurements as inputs to calibrate the model. The changes suggested by the simulator also provide operating regimes that involve moving either the ball level or pulp load and sometimes both of these variables. A ball mill model coded in JKSimMet was used in conjunction with the Sensomag to optimize the secondary ball mill at Waterval concentrator in South Africa. The results show that the perfect mixing ball mill model can be used in conjunction with the Sensomag to optimize the performance of the secondary ball mill.

Sep 1, 2012

Cenospheres is a sandlike hollow sphere component of the fly ash that is collected in coal-burning electric power generating plants. Metal coated particles have been widely used in industries. Magnetron sputtering method which was used to coat copper film on the surface of the cenospheres is a widely used coating technique in large surface metal coating. A newly designed equipment is used to make the fine particle coating can be carried out because the fine particle is hard to disperse and it must make the particle keep moving to let every direction of the particle be coated. The copper film coated is compact, smooth, even and without uncoated spots under the optical microscopy and SEM. The film has good affinity to the cenosphere surface. The film does not separate with cenoshpere surface even when the cenosphere is crushed. The XRD, SEM, XPS, SPM was used to study the copper film characteristic. It is shown that using this newly designed magnetic sputtering equipment can coat high quality copper nanofilm on the cenoshpere surface.

Jan 1, 2014

By X. Tong

Flotation researches of indium-beard marmatite from the Dulong multi-metallic ore in the Yunnan Province of China has been studied in order to improve the grades and recoveries of zinc and indium of the zinc concentrate in the Dulong concentration plant. The experimental results have shown that copper sulfate mixed with a chemical reagent X-1 as the activator in the marmatite flotation produced a much better beneficiation than copper sulfate alone, increasing the zinc and indium recoveries of 10% and 6%, respectively, while the concentrate grades were unchanged. Also, the new activator acted well around pH 10, allowing large savings on lime consumption in the marmatite flotation. In addition, it has been found that a sufficient activated time of activator with ore slur-ry in the flotation is needed to achieve good beneficiation of the marmatite ore.

Jan 1, 2014

By Janne Kytökari

Controlling a wide range of minerals processes with single control system is an ordinary way to operate in mines all over the world these days. However the potential of these systems is not yet fully recognized nor utilized. The key issue is to manage the information in a way that enables automating the day-to-day tasks, quality control and safety functions. At the same time it provides means for optimization and constant improvement of processes creating a working environment where the system helps employees to do their key tasks instead of searching, modifying, and transmitting the huge number of information arising every day. The distribution of control system nodes enables the other processes to run heedless of a problem occurring in one of the sub-processes. Also the control room can be in remote location such as in large city removing the need to travel substantially long distances to plant sites every day. When all essential information is brought to the same place there is less risk for a mishap to happen due to information breaks that are often the cause of them. One of the biggest single reasons that result in production losses are break downs of machinery usually caused by normal wear, misuse, incorrect utilization rate etc. For this reason it is important to measure the condition of machines using vibration measurement and diagnostics. By moving from failure or time-based maintenance towards predictive or performance maintenance generates eventually a steady and predictable process but also results in significant long term savings. The mineral process at Talvivaara mine is based on bioheapleaching, whereby metals are leached from ore as a result of bacterial action. Bioleaching is a fairly new technology used in metals recovery. Therefore it is important for the mine to collect and analyze data from different stages of the minerals process. Talvivaara mine?s Metso DNA system has integrated machine condition monitoring and information management. These are not only necessary but also crucial in environmental conditions where the outside temperature can drop below -35°C, where ice and snow dominate the landscape and impact the equipment for four months a year and where distances between equipment can be up to 7.5 kilometers. Keywords: DCS, analyzer, machine condition monitoring, automation, remote communications, optimization, mining, metso DNA, Talvivaara

Sep 1, 2012

By Luis Bergh, Iván Rojas, Juan Yianatos, Luis Vinnett

"At present, flotation rate characterization follows standard measurements to identify the overall flotation performance looking at the feed, tailings and concentrate in flotation cells or banks. This classical approach does not take into account the evolution of the true collection rate down the flotation banks explicitly. The potential for identifying the impact of the mineral characteristics (size and liberation) as well as the effect of different manipulated variables (reagents, froth depth, gas dispersion) on the true flotation process remains hindered. Top-of-froth (TOF) measurements, which consist of sampling the first layer on the froth surface, have been used to characterize the mineral collected by true flotation in rougher banks. The information provided by TOF samples allows evaluating the floatable mineral evolution (grade, particle size, liberation) down the bank. In this work, an indirect approach to estimate the flotation rate along rougher flotation banks is proposed. The new approach is based on the decreasing of collected mineral grades (on top of froth) and the feed characteristics. Flotation rates per liberation classes were used to reconstruct the TOF grades from the feed information. This approach requires a simple froth surface sampling, without constraints typically observed during mass balance surveys and uncertainties on the mineral recovery estimation. The proposed methodology was successfully applied at industrial scale using TOF measurements together with QEMSCAN information."

Jan 1, 2014

By B. McFadzean, J. Taguta

The enthalpy of immersion is the heat change arising from the replacement of the solid-gas interface with the solid-liquid interface when a solid surface is immersed in a liquid. Although immersion calorimetry has been established as a valuable and reliable means of determining solid surface properties such as wettability, it has seldom been applied in mineral processing research. In this study, precision solution calorimetry was employed to measure the enthalpies of immersion of different minerals in water. The enthalpies of immersion were then related to the first-order flotation rate constant as determined by the microflotation technique. The same measurements were also made on sulphide minerals whose surfaces were modified to different degrees of hydrophobicity using different percentage coverages of amyl xanthate collector. The enthalpy of immersion technique was capable of distinguishing and ranking minerals according to their wettability. All mineral types and collector-treated minerals conformed to the same relationship that was found between the enthalpy of immersion and the flotation rate constant. This conformed, empirically, to a power law equation. As the enthalpy of immersion decreased, there were large increases in flotation response for very small changes in hydrophobicity. In addition, a critical enthalpy of immersion (CEI) was found, above which no flotation could occur. The scatter in the data points could be corrected for by adjusting the rate constant using the density of the minerals to produce a robust relationship between the rate constant and enthalpy of immersion. These results have shown that the enthalpy of immersion is able to indicate both the natural mineral hydrophobicity and the extent to which collectors can render a mineral hydrophobic. This technique has considerable potential to be used as a sensitive and accurate measure of mineral surface wettability in order to predict flotation performance.

Jan 1, 2018

By T. J. Chen

Vanadium-beard bone coal is one of important vanadium resources in China.To extract vanadium tailings from Stone coal is produced after extracted vanadium from stone coal through the roasting, leaching and other processes. About 120-150 tons of tailings will be produced in extracting 1 ton of vanadium pentoxide. A lot of tailings that are willfully piled up have caused serious environmental pollution and wasting of resources; it is therefore necessary to realize its resource utilization. This study increases the activity of vanadium tailings by means of alkali fusion, and then uses different alkali activators to react with vanadium tailings so that geopolymer with high value added is produced. Sample of geopolymer is acquired from a mixture containing vanadium tailings, alkali activators, water and a little sodium aluminate through compression-molding process under 20MPa pressure. After cured in room temperature for three days, the maximum compressive strength of the sample can reach 36.2MPa. XRD analysis indicates quartz, the major crystal phase in vanadium tailings is decomposed,and the activity of vanadium tailings is heightened. FTIR and SEM analyses show: structural change having an important impact on the mechanical strength of geopolymer occurred during the process of vanadium tailings generating geopolymer.

Sep 1, 2012

By Leming Ou, Qiming Feng, Yiping Lu, Pengyu Zhang, Qing Shi, Kun Liu, Guofan Zhang

"This paper introduces the mineralogical analysis of certain polymetallic copper-zinc ore in China with the aim of improving the flotation process. The main valuable elements, mineral phases and compositions of run-of-mine ore were inspected by the X-ray Fluorescence (XRF) and chemical analysis. For a deep known of the old process defects, Mineral Liberation Analysis system (MLAs) was employed to investigate the minerals liberation degree of selected key slurry points. Analysis results show that the run-of-mine ore belongs to the original copper-zinc polymetallic symbiotic ore at low oxidative level, which mainly contains 0.16% Cu, 4.43% Zn and 0.88% Sn. Gangue minerals are mainly silicate minerals, and zinc mineral is sphalerite. MLAs test illustrates that about 86% sphalerite has been dissociated in zinc flotation feed. In the current flotation process, over grinding of sphalerite monomer and insufficient liberation of intergrowths are the key problems need to be solved imminently. Up to this point, a new process consisted of two steps roughing unit is submitted in this research. It contributes two positive effects on zinc flotation performance: (i) separating sphalerite monomer timely to decrease overgrinding; (ii) improving zinc minerals intergrowths liberation efficiency. Flotation results indicate that the zinc concentrate grade increased 0.90% and the recovery improved 0.96% in the new flotation processINTRODUCTION Mineralogical analysis mainly focusses on solving mineralogy problems in minerals processing, assisting in minerals behaviors prediction and control for separation engineering (Falkovich, et al., 2001; Hillier, et al., 2003; Schouwstra and Smit, 2011). Process defects searching becomes its ordinary work, and flotation optimization appears to be its targets gradually. For example, Lucky Friday mine company (Idaho America) fails to obtain qualified lead concentrate as the change of ore properties (Nadoll, et al., 2011). Mineralogical analysis ascertains that there are too many dissociated sphalerite, pyrite and gangue particles exist in lead concentrate. According to this, more cleaning units are added to solve problems effectively. Kanowna Belle mine (Australia) takes a flash circuit in operation successfully with the aim of optimize flotation process, under the helps of mineralogical analysis and industrial test (Newcombe, et al., 2013). Lotter N.O. (2011) gives a deep description on how mineralogical data assisting mineral processing engineers to design and optimize flowsheet. For decades, quantitative and automated mineralogy techniques (Andersen, et al., 2009; Gu, et al., 2012; Oghazi, et al., 2009; Yu, et al., 2007) get well developed and hugely improve the veracity and repeatability of minerals properties measurement. Among these, MLAs (Gu, 2003) provided by JKMRC (Julius Kruttschnitt Mineral Research Center) is critically acclaimed all over the world. This analysis system can measure mineral phases composition and content, particles size, minerals occurrence and liberation degree directly."

Jan 1, 2018

By A. Akcil, O. Celep, C. Erust, E. Y. Yazici1, H. Deveci1

"Recycling of WEEE has already gain prime importance from both environmental and economic point of view. For the recovery of metals from e-waste, many conventional physical, bio/hydrometallurgical and pyrometallurgical processes are proposed. Economic potential of e-waste is mainly driven by its precious metal content. Physical separation methods (e.g. electrostatic, magnetic, eddy current and gravity separation) exploit the differences in the physical properties of metals and non-metals. Physical separation methods are simple and economically sound but they suffer from metal losses and ineffectiveness at fine sizes. Hydrometallurgical processes are promising owing to their relatively low cost, reduced environmental impact, potential for high metal recoveries and suitability for small scale applications. Hydrometallurgical processes can be developed for selective extraction of base/precious metals using suitable reagent systems. Sulphate-based leaching with a suitable oxidant (e.g. H2O2, O2, Fe3+) is effective for copper and other base metals. After removal/recovery of base metals, precious metals can be easily extracted using various lixiviants including thiosulphate, thiourea, cyanide and chloride. However, further research is required to develop new, cost effective and environmentally friendly processes and/or refine existing ones for leaching and, in particular, downstream processes. INTRODUCTION Electrical and electronic equipments are indispensable to modern societies with numerous applications in the field of medicine, transport, communication, education, security and environmental protection. With technological developments and innovations, the replacement of old equipment leads to ever fast accumulation of waste materials such as waste electrical and electronic equipment (WEEE or e-waste). People are upgrading their mobile phones, computers, televisions, audio equipment and printers more frequently than ever before (Babu et al., 2007; Lee et al., 2007). With the rapid growth in technology today, the life span and utilisation period of most electronic and electrical equipment has been reduced considerably with concomitant generation of huge amounts of WEEE over the past several decades. According to statistics presented by Balde et al. (2015), total WEEE produced around the world was 41.8 million tonnes in 2014 and expected to rise to approximately 50 million tonnes by 2018. Kumar et al. (2017) estimated that annual growth rate for the WEEE stream is 3–5% (Singh et al., 2016). The aim of this paper is to provide an overview of physical separation and hydrometallurgical methods available for the treatment of WEEE."

Jan 1, 2018

By Paul W. Weiblen, Louis J. Cabri, Rolando Lastra

"Preliminary tests were done to determine whether comminution by electric-pulse disaggregation, or E-PD (cf. Rudashevsky et al; 1995), was more effective than using conventional crushing for Merensky Reef ore. A hand sample of the Merensky Reef was sawn in two: then one sub-sample was comminuted to .2 mm using E-PD at the University of Minnesota, and the other sub-sample was crushed to .2 mm using a conventional jaw crusher at CANMET.The products of the electric-pulse disaggregation and jaw crusher were fractionated by sieving and by a separation using a heavy liquid with a specific gravity of 3.3, because the proportion of platinum-group minerals (PGM) and sulphides to silicate minerals is very low. Thus, four mineral separates were produced: .2000 + 833 µm, -833 +208 µm, -208-µm float and -208-µm sink. All the mineral separates were studied by image analysis (Lastra et al; 1998). The main objective was to determine the liberation of gangue (silicate minerals), chromite, pyrrhotite, chalcopyrite, pentlandite and PGM. In the case of the PGM, a specific image analysis program was written to search and measure these minerals.The results show that the liberation obtained for gangue was similar (~99%) using either method of comminution. However, the liberation obtained for chromite (~89% vs. ~38%), pentlandite (~50% vs. 1%), pyrrhotite (~56% vs. ~38%), and PGM (~56% vs. ~1%) by E-PD was higher than that obtained by conventional jaw crusher, whereas the liberation obtained for chalcopyrite (~20% vs. ~71%) by E-PD was lower. Nevertheless, the image analysis of the products also showed that the PGM are strongly associated with pentlandite. Thus, for the Merensky Reef, liberation of pentlandite from the gangue minerals and chromite is important to recover more of the PGM. This maybe be significant because, in addition to increased recovery of platinum-group minerals (PGM), Merensky Reef pentlandite also contains significant quantities of valuable platinum-group elements like Pd and Rh (Cabri, 1981; Cabri 1988, Kinloch 1982, Peyerl 1983). Hence, the results indicate that for the Merensky Reef, electric-pulse disaggregation would represent a better comminution operation than a conventional jaw crusher would. In addition, the greatly improved liberation for chromite may find application for the PGM-rich UG2 chromitite."

Jan 1, 2003

By K. Amano, K. Haga, Y. Watanabe, A. Shibayama, A. Batnasan, A. Battsengel

"Apatite is an important host mineral in igneous and metamorphic rocks for production of phosphate fertilizers and phosphoric acid, and a potential source of rare earth elements (REE) production. For dissolution of REEs, sulfuric acid is better leaching reagent to develop the economical viable process for recovering of rare earth elements from apatite ore. However, the efficiency of rare earth elements dissolution in H2SO4 is about 30 % due to the formation of calcium phosphate or calcium sulfate as precipitate. On the other hands, phosphorus is mainly produced from phosphate ore. However, when treating rare earth elements containing phosphate ore, rare earth elements were discharged. Hence, development of novel apatite ore treatment process is required for effective utilization of natural resources. In this study, apatite deposit associated with REE was treated with sulfuric acid leaching and two stage precipitation by oxalic acid (C2H2O4) and magnesium chloride (MgCl2) for recovering REE and phosphorus, individually. Results showed that it can be seen the vast majority of La (87.5%), Ce (87.3 %), Pr (86.1 %), Nd (85.2 %) and Y (90.9 %) were dissolved in 1 mol/L diluted H2SO4 solution from the apatite ore. As average leaching rate of REE, over 85% of REE were leached by the condition. In the first stage precipitation using the obtained pregnant leach solution from leaching, over 90% of REE was precipitated by oxalic acid addition after controlling pH to 1 by NH4OH solution. After pH changed to 8.5, over 90% of phosphorus was recovered as precipitate by magnesium chloride addition in second stage precipitation"

Jan 1, 2018