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By Kilian Neubert, Wotruba. Hermann, Lars Weitkämper

Metallurgical slags are produced in large quantities all around the world as a result of smelting, refining or alloying processes applied to metals, ores and recycling material. The slag phase serves different purposes in metallurgical processes. It prevents heat losses and protects the metal phases from contaminations and absorbs gangue and extracted impurities. Due to achievable metallurgical efficiencies certain amounts of valuable metal contents always remain in the residual slag. Recycling of these metallurgical slags has several positive effects, such as optimized ecological and economical compliance of the producing industry. If recycled metal contents can be reintroduced into existing processes, required inputs of raw material can be lowered. High metal prices enable the economic recovery of metal contents in metallurgical slags by applying different non-metallurgical processing methods. Conventional processing of metallurgical slags utilizes processes such as hand picking, selective comminution, screening and magnetic separation. Those state of the art processing techniques have limitations in terms of achievable metal recoveries and required energy demand. The approach for an optimized processing of metallurgical slags targets enhanced metal recoveries in combination with lower specific treatment costs. Processes such as coarse and ultrafine density separation, as well as sensor-based sorting as a pre-concentration stage are used to enable an efficient recovery of metal contents in slags. By applying these methods a completely dry working process is possible. This paper reviews the commonly used methods and describes approaches for innovative processing of metallurgical slags to enhance metal recoveries. Focus of this paper is laid on sensor-based sorting as well as on processes for dry density separation.

Jan 1, 2014

By Tsvetan Damyanov, Nikolay Hristov, Evgeni Kostadinov, Lubomir Kuzev

"The process of grinding in drum mills is directly dependent on the dynamic forces occuring in the free movement of the grinding bodies in the volume. The subject of discussion are the potential impacts between grinding bodies having different shape and equal weight in a drum mill that has a diameter of 1200 mm. The study utilised ball grinding bodies having a diameter of 120 mm and tetraballpebs having a conditional diameter of 120 mm. The study was carried out using the Solid Works Simulation software. The following cases were examined: • Impact between two identical grinding bodies; • Impact between a grinding body and the shell surface. The study provided numerical values for impact force, kinetic energy of impact, linear speed of impact, linear displacment of the center of gravity and duration of impact deformation. The impact force of the balls is approximately 179000 N. The impact force of the tetraballpebs with typical vertices, edges and spherical surfaces depending on the area of impact is 177000 to 185000 N. Upon impact between two spherical surfaces of tetraballpebs, the contact area is 263.55 mm2, which is more than twice the contact area upon impact between two balls, which is 114.39 mm2. This determines better conditions for the transmission of kinetic energy by reducing opportunities for overgrinding."

Jan 1, 2014

By Douglas Fuerstenau

"Comminution not only is the major energy cost in mineral processing but it also can limit the grade of ores that can economically be processed. Rittinger first postulated that the energy for comminution is proportional to the new surface produced. Because most of the strain energy needed to initiate and propagate cracks in particles cannot be recovered, researchers reported woefully low comminution efficiencies. Recognizing this, Schoenert proposed that the baseline for assessing comminution efficiency should be the mechanical energy needed to break single particles. After extensive single-particle studies, Schoenert turned to comminuting beds of particle in piston dies. Finding particle-bed comminution to be energy efficient, he had the brilliant conception of making the process continuous, namely his invention of the choke-fed high-pressure roll mill (HPGR). Practical comminution involves masses of particles, which can lead to energy efficiencies far less than that of single-particle breakage. A three-way classification of grinding modes in terms of the mobility of the particle mass provides the necessary insight into the low efficiency of different comminution machines: namely, single-particle breakage, confined particle-bed grinding (HPGR), and loose-bed grinding (ball mill). Examples are given for determining and comparing comminution efficiencies. The size distribution of comminuted products become self-similar, and a single parameter, the median size, can be used to quantify the extent of comminution. The reduction ratio, expressed in terms of the mean size of the feed and product, varies linearly with expended energy and the slope of such plots is a measure of the grindability of the mineral. This approach clearly gives the order of energy efficiency as single-particle > particle-bed > loose-bed comminution. HPGRs are more efficient at low reduction ratios but lose that advantage at higher reduction ratios. Extensive hybrid grinding experiments carried out with our instrumented ball mill and HPGR showed significant energy savings by first comminuting the material in the HPGR and followed by the ball mill. At Cerro Verde an industrial-scale hybrid HPGR/ball mill system is reported to have a 13 percent energy savings over a SAG mill/ball mill system."

Jan 1, 2014

By Ibrahim Alp, Duygu Dinç, Ersin Yazici, Adularya Energy and Electricity Generation and Mining Inc., Oktay Celep, Haci Deveci

Thiosulfate leaching as an environmentally benign alternative to cyanide leaching has received particular attention in recent years. Most studies have focused on thiosulfate leaching of free milling ores and, to some extent, pregrobbing ores. In this study, leaching of gold from the refractory Kaletas ore (in which gold/silver alloy is the only mode of occurrence detected) in ammoniacal thiosulfate solutions was studied. A two-level full factorial design (23) was adopted to investigate the effects of concentration of thiosulfate (0.2-1 M Na2S2O3), ammonia (0.5-1 M NH3) and copper (0.05-0.1 M CuSO4) on the extraction of gold from a ground ore (-38 µm) over a period of 24 h. Statistical analysis confirmed the leaching of gold improved with increasing concentrations of thiosulfate and ammonia. In contrast, increasing the concentration of copper in the range tested adversely affected the extraction of gold. The magnitude of effects of parameters on the gold extraction was in the order of Na2S2O3 > NH3 > CuSO4. The maximum extraction of gold (69.6%) was obtained in the presence of 1 M Na2S2O3, 1 M NH3 and 0.05 M CuSO4. The negative influence of copper on gold extraction is most likely attributed to the decomposition of thiosulfate catalyzed by copper. Concentration of thiosulfate was also identified to be statistically the most important parameter for its consumption.

Jan 1, 2014

By Rong Fan, Andrea Gerson

"The small recovery of Ag, often in the order of 50%, by traditional flotation and leaching process strategies is closely related to the complicated and heterogeneous nature of Ag-bearing minerals with Ag typically being associated with numerous minerals within any given ore-body. Moreover, grain sizes may be extremely fine with micron-scale common. In order to design cost-effective Ag-bearing mineral flotation and leach recovery strategies it is firstly necessary to characterise the speciation of Ag and its correlation with other elements, e.g., Cu, As and Sb, within the ore matrix and process streams. The traditional QEM-SCAN analytical approach can prove problematic for some mineralogies due to difficulties in recognising degrees of crystallinity, polymorphs, complex solid solution series, high value trace element mineralogy, very fine grained materials; and the requirement for a comprehensive data base. Moreover, there is difficulty ‘seeing’ either surface films or surface contaminants which can both lead to poor flotation performance. There is therefore clearly a need to develop confirmatory and complementary approaches when these uncertainties arise. Synchrotron X-ray microprobe analysis provides a powerful tool for the mineralogical characterisation of finely segregated heterogeneous Ag-containing materials. These measurements enable comprehensive characterisation of the Ag-bearing components using synchrotron microprobe X-ray fluorescence mapping (µ-XFM), X-ray diffraction (µ-XRD) and X-ray absorption spectroscopy (µ-XAS). Further analytical strength is provided by principal component analysis of laboratory ToF-SIMS data which enables the statistical identification of correlated surface species enabling examination of surface chemical characteristics responsible for mis-reporting of Ag containing components within flotation streams. We describe the application of these techniques to a selected Ag-containing feed and tail and demonstrate how these compliment and extend traditional analytical methodologies."

Jan 1, 2014

By D. Szyszka

During passing gas bubbles through mineral suspensions, some mechanical carryover of fine particles to the froth layer always takes place. The entrainment of mineral particles is influenced by many parameters, mostly by the particle size and the concentration of the frother. The paper deals with influence of selected frothers (methylisobutylcarbinol (MIBC), a-terpineol, and hexadecane tricosaethyleneglycol ether (C16E23)), common laboratory flotation frothers, on the mechanical car-ryover of quartz, a typical gangue mineral component of ores. Entrainment tests were carried out in a laboratory Mechanobr flotation machine with quartz particles suspended in aqueous frother solu-tions. The mechanical recovery of quartz in the presence frother was increasing with time and reached plateau after about 20 minutes of flotation. The plateau level of quartz recovery depended on the frother concentration. Initially an increase of the plateau with frother concentration was observed until the plateau reached the highest level called the maximum recovery emax. The emax can be used as a parameter to characterize the ability of frothers to entrainment. In the studied quartz-frother flotation system the maximum entrainment was 32%, 50% and 80% for methylisobu-tylcarbinol (MIBC), a-terpineol, and monohexadecane tricosaethylene glycol ether (C16E23), re-spectively. A comparison of the maximum entrainment factor emax with other, known from literature, indices such as bubble critical coalescence concentration (CCC), dynamic foamability index (DFI), Jw, e =25%revealed, except DFI, their similarity.

Jan 1, 2014

By Xiaodong Jia, Richard A. Williams

"The packing of particles is a fundamental property of a material or system made up of particulates because it underlies many other physical properties of that material or system. Despite being ubiquitous, particle packing has not been an easy subject to study either experimentally or theoretically, except for a few regular shapes.This paper describes the recent developments, arising from research at Leeds, in the computer modelling of packing of complex shaped particles and prediction of physical properties of the structures represented by the packing. The computer model DigiPac, is capable of packing particles of any shapes and sizes in a container of arbitrary geometry. Figure 1 shows a few examples that are relevant to the mining and mineral industry.The ability to predict packing structure of real particle shapes and to compute directly some structuredependent physical properties (such as liquid permeability, mechanical strength/stability, compaction and sintering, dissolution and leaching, etc.) is obviously highly desirable and has significant potential in industrial applications. Examples are presented relating to the packing of granular materials.The mining and mineral engineering industries are well placed to exploit this advance in digital packing and simulation since they deal primarily with asymmetric and complex particulate mixtures. In the future we expect to see a number of developments in this area including:Algorithms that can optimise packing to achieve user-defined propertiesA more rational approach to determining flowability of complex powdersUse of these more realistic packing algorithms linked to blast and crusher design"

Jan 1, 2003

By L. J. Li, Q. Zhang, Z. H. Liu, Q. L. Chen

Phosphogypsum (PG) is an industrial waste from the production of phosphate fertilizer. The utilization of PG is restricted by its containing impurities, and the pretreatment is crucial to eliminating these impurities. The purpose of the research is to recycle pretreatment PG as raw material for preparation of a-calcium sulfate hemihydrate (a-HH) by salt solution method. The effect of pretreatment technologies of lime neutralization and washing on dehydration rate, phase composition and morphology evolution of a-HH were investigated by crystal water content analysis, XRD and SEM. Furthermore, the change of pH in the reaction process was also discussed in detail. The results show that the dehydration rate of conversion PG to a-HH increases and the corresponding induction period, crystal growth period and total time decrease with an increase in CaO dosage from 0.2% to 0.6%. In the presence of 0.4% CaO or 0.6% CaO, the a-HH presents a long hexagon-prism-shaped crystal with a purity of 94%, and the end face of a-HH presents polyhedron. The system pH sharply decreases with the reaction time under different CaO dosage, and the pH variation from the initial alkalinity to acidity. The main reason is that as the co-crystallized phosphorus dissolved and released HPO42-, and with the pH decreasing to 4-5, HPO42- transformed into H2PO4-. The dehydration rate of washing PG is lower than that of original PG. Compared with the original PG, a-HH with the larger width and smaller aspect ratio can be achieved from the pretreatment PG subjected to lime neutralization and washing, meanwhile the crystal surface is more smooth.

Jan 1, 2018

By I. Zh. Bunin, G. K. Khachatryan, N. E. Anashkina

For optimization of diamond processing technology the influence of nanosecond high voltage pulses on mechanical and technological properties of diamond crystals and kimberlite rock-forming minerals (calcite, olivine, serpentine) was investigated. Using methods of Fourier Transform Infrared Spectroscopy (FTIR), X-ray photoelectron spectroscopy (XPS), microscopy and mikrohardness measurement the changes of structural, physic-chemical surface properties, and microhardness of minerals as the result of impacts, was studied. Non-thermal impacts caused a decrease of kimberlite rock-forming minerals microhardness in general to 40-66% as the result of surface microstructure destruction which is caused by formation of micro cracks, traces of surface breakdown and other defects. At the same time, the pulse energy impact on natural diamonds led to formation of B2 type crystal lattice microsift defects, elevated concentration of which increases the hardness properties of crystals. The obtained result indicates possibility of applying pulsed energy effects to improve the softening efficiency of diamond-bearing kimberlites rock-forming minerals without damaging the diamond crystals and ensuring their preservation by the subsequent grinding of ores. By IR and X-ray photoelectron spectroscopy revealed that processing by hight voltage pulses causes a change of natural and synthetic diamonds surface functional cover composition. Short-term exposure (~ 10 - 30) leads to detachment and partial destruction of secondary phases mineral films on the surface of natural technical diamonds, increasing floatability and hydrophobicity of crystals. However, with increasing duration of treatment (~ 30 - 150) occurs surface hydroxylation (found by XPS for synthetic diamonds), as a result of diamond surface layer oxidation. The effect of increasing the natural diamonds flotation activity by 14% (from 47% to 61%) was experimentally established as a result of processing diamond crystals with nanosecond pulses (~ 10-50 sec), which indicates the principal possibility of using pulsed energy impacts to intensify the diamond flotation during processing diamond-bearing kimberlites.

Jan 1, 2018

By S. Mitra1

"This study aims to investigate coarse particle detachment mechanisms (particle diameter > 150 ?m) utilising both experimental and numerical technique. Two mechanisms were studied – (i) interactions of bubbleparticle (BP) aggregate with vortices and (ii) coalescence of bubble-particle aggregates. On the first mechanism, interaction behaviour of coherent vortex structures with a BP aggregate (bubble diameter db = 3 mm, particle diameter dp = 0.3 mm) was studied using a CFD model in the Reynolds number range of 100 to 1000. Effect of surface hydrophobicity on the BP stability was examined using a range of contact angle boundary conditions. To address the second mechanism, interactions of bubble-particle aggregate (db ~ 4 mm, dp ~ 0.4 mm) with both free gas-liquid interface and individual bubbles were investigated using high speed imaging. Both rebound and coalescence outcomes were observed to be responsible for BP instability leading to particle detachment.INTRODUCTIONIt is widely known that flotation process performs excellent mineral recovery for base metal ore particles that are typically in the range of ~ 20 to 150 µm in diameter (Jameson, 2010). More specifically, higher recoveries are usually reported for particles in the size range of ~20 to 70 µm while outside this spectrum, generally the recovery diminishes significantly. It would be highly desirable to improve the recovery of particles at the coarse end of the flotation size range spectrum which has significant economic benefit (Jameson, 2010). However, it is essential that insights to particle detachment phenomenon, the primary impediment in coarse particle flotation caused by the underlying hydrodynamic factors are first obtained at a greater depth.In an ideal quiescent liquid medium, due to inertia, coarse particles deviate substantially from the fluid streamlines and collision efficiency with bubbles decreases which can only be augmented by increasing turbulence level in the medium sufficiently to make random physical contacts with bubbles. Nonetheless, even if successful contacts are made, it is difficult for these large particles to remain attached to bubbles in a turbulent shear flow environment. There are two major mechanisms postulated for particle detachment – interaction of turbulent flow structures (eddies) with BP aggregate and coalescence among surrounding aggregates. Earlier work of Schulze (1982) theorised a vortex acceleration component to characterise turbulence effect on BP aggregate instability in flotation machines. Wang et al. (2015) investigated bubble detachment behaviour from a stationary particle in a nearly homogeneous and isotropic flow field. Using PIV (particle image velocimetry), it was shown that the local maximum energy dissipation rate for the case of bubble detachment was significantly higher than the no detachment case, and was also higher than the critical value for bubble detachment calculated using Schulze’ theory (Schulze, 1982). Later, Wang et al. (2017) also visualised the BP aggregate instability in a cavity flow leading to particle detachment which was attributed to bubble coalescence, bubble surface oscillation and particle deceleration phenomena."

Jan 1, 2018

By Cheng Gan, Gui Xiahui, Li Shulei, Cao Yijun, Liu Jiongtian, Wu Lun

Flotation rate constant is an essential parameter in the flotation process. The fine coal sample utilized in this investigation is anthracite from the Shenhuo mine in eastern China. Fine coal flotation rate tests were conducted to compare the flotation rate constant at constant power input with that at gradually increasing power input. Results indicate that the flotation rate constant decreases with the flotation process and increases as the flotation energy is increased. In addition, the flotation rate constant is close to the maximum value. The increasing trend of the flotation rate constant gradually slows down as the flotation energy input increases.

Jan 1, 2014

By G. K. Nimal Subasinghe

The establishment of grind size that optimally liberates the valuable mineral for efficient down-stream processing is of great importance for most mineral processing operations. Reasonably accurate comminution models as well as models of downstream separation processes may be found in the literature but their use in optimizing grind size is limited without an associated liberation model. In this work, an attempt has been made to address the above shortcoming by demonstrating how the effective parameters of the downstream flotation process may be predicted from the liberation characteristics based on the ore texture data for a disseminated nickel ore. In this regard, the liberation model based on linear intercept distributions of mineral and gangue proposed by King (1979) and its application to predict the flotation performance of an industrial plant demonstrated by Schaap (1979) may be considered useful contributions. However, while the model proposed by Schaap is simplistic enough, it is based on several assumptions due to the non-availability of intercept length measurements on the parent rock, in particular, on the extent of mineral exposure on the surface of comminuted particles. In this work, the linear mineral and gangue intercepts on polished specimens of a binary ore, comprising darker pentlandite as the valuable mineral and lighter barren host rock were measured using an image analyser. The resulting intercept distributions followed negative exponential distributions. Using the mean sizes of mineral and gangue intercepts, the proportion of liberated, compo-site and mineral occluded particles of a given size, the extent of mineral exposure on the surface of particles and their mean mineral contents were calculated using principles of renewal theory. The rock was then crushed and ground and different size fractions were floated. It has been shown that the parameters of observed recovery data based on 1st order kinetics such as the associated rate constant and ultimate recovery agrees well with those predicted from the quantities calculated above. This work has important practical implications since it can indicate variations in flotation performance arising from changes in mineralization within a large ore body.

Jan 1, 2014

By P. Basarova

The attachment of bubbles onto a collecting surface is an ubiquitous natural phenomenon, playing a critical role in numerous practical processes. The goal of the project is to broaden the knowledge about hydrodynamic interactions between small bubbles and large solids that occur in nature and industrial processes. Focusing on collision processes between a single rising bubble (Db<1 mm) and a larger falling spherical particle in stagnant liquid, the theoretical model describing the bubble trajectory is given here. The model is based on analysis of forces acting on the bubble, and utilizes equation for the bubble motion. Mobile and immobile type of bubble surface mobility are considered. The calculated results are compared with the experimental data; here a high-speed video camera was used to capture the bubble motion and bubble-particle interaction. Very good agreement between experimental and calculated data was found. For both types of surface mobilities, the bubble deviation in the horizontal direction is nearly linear. The proportion constant is bigger for immobile bubble surface and increases with the bubble size. Furthermore, particular forces acting on bubble were studied. A similar course of relative bubble velocity and force impact was observed for identical bubble position. For cases when the bubble centre is close to the particle axis, only deflection in one direction is observed. When the bubble is reaching the maximum trajectory, the force ratio is changed. The bubble is firstly pushed away from the particle, but when it is within close distance from the particle, the bubble is pushed towards the particle.

Sep 1, 2012

By B. McFadzean, K. Moller

"The mechanism whereby thiol collectors adsorb onto a mineral surface has been widely studied. Most of these studies examine the mineral surface at equilibrium state and, often, well above monolayer coverage. However, the formation of species at the mineral surface is a complex process that is both kinetically and thermodynamically controlled. In a typical industrial application, the dosage of collector will be around monolayer level. This study uses isothermal titration microcalorimetry to measure the heat evolved during the reaction of sodium ethyl xanthate (SEX) and sodium isobutyl dithiocarbamate (SIBDTC) and their mixtures with galena and chalcopyrite. The sensitivity of the instrument allows heats of reaction of sub-monolayer quantities of thiol collector to be measured.The study found that both the magnitude and kinetics of the reaction between a collector and a mineral surface was dependent on the type of mineral and the type of collector. Proposals are made for the reactions based on literature and the evidence from this investigation. It was found that when collectors were reacted with mixtures of galena and chalcopyrite, that the magnitude of the reaction was lower compared to that measured for the pure minerals alone. This may be due to galvanic interactions between the minerals, resulting in a passivating effect on one or both of the minerals."

Jan 1, 2014

By Tasuma Suzuki

Electrokinetic/permeable reactive barrier system is a promising in situ soil and ground water remediation technique to reduce toxic NO3- into less toxic NH4+. Using granular zero-valent iron (Fe0) as a reductant, the first objective of this study was to investigate the influence of the solid-liquid ratio and aqueouspHon NO3- reduction. The results obtained from a series of batch experiments showed that NO3- reduction was enhanced by either increasing solid-liquid ratio or decreasing aqueous pH. Based on insights obtained from batch experiments, the second objective of this study was set to design the remediation conditions of the electrokinetic/Fe0permeable reactive barrier system to maximize the NO3- reduction efficiency. Experimental results showed that the effectiveness of the system strongly depended on the Fe0 percentage in the reactive barrier, the pH in the anode reservoir, and the applied voltage, which were consistent with the results obtained from batch experiments. Under optimized treatment conditions, nearly 100 % NO3-was reduced into NH4+ in the permeable reactive barrier and collected in the cathode reservoir. Insights obtained from this study provided fundamental information on roles each of remediation design parameters plays, and will be useful to optimize the remediation conditions. Keywords: electrokinetic remediation, permeable reactive barrier, zero-valent iron, nitrate

Sep 1, 2012

Gold thiosulfate complex is difference with gold cyanide complex, which is easily adsorbed on activated carbon while gold thiosulfate complex cannot be satisfactorily recovered by activated car-bon. However, Gold thiosulfate could be recovered by activated carbon if cyanide is added into the thiosulfate solution. To avoid the cyanide solution, this paper will review several possible processes to recover the gold from thiosuldate solution: such as the cementation with metals, ion exchange resin and solvent extraction. The gold cementation with the powders of zinc, copper, iron and aluminium will be discussed. The advantage and disadvantage of each are compared. The consumption of thiosulfate and copper and feasibility of solution recycling will be discussed. The gold recovery by some ion exchange resins will be suggested. The processing conditions, its applications and the resin elution methods will be presented. The gold recovery by using solvent ex-traction will be reviewed. The processing conditions of solvent extraction process are discussed and compared.

Jan 1, 2014

By Jan Cilliers

The demand for minerals has never been higher. Moreover, the rate at which this demand is growing is unprecedented, and expansions and new mines will be required to fulfill these growing needs. This, in turn requires a skilled engineering workforce that can develop and operate minerals extraction processes to utilise effectively more complex ores. The International Mineral Processing Council (IMPC) has established a Commission on Mineral Processing Education to consider the global challenge of ensuring an adequate supply of well-trained mineral processing engineers. The Commission has, for the past four years, been collecting international information of the recent mineral process engineering supply position and with a view into the near future. The data collected by the international Commission members are as follows: ? Undergraduate student numbers in minerals engineering ? A breakdown of their male/female ratio ? The fraction of the students from each course that enter the minerals industry ? Teaching staff numbers and age profile This data has been collated and analysed, and the findings are presented. It is clear from the analysis that the supply situation is very different in different regions of the world, and that great opportunities exist for targeted recruitment into the industry to meet the future talent demand. Further, an attempt at correlate the supply of minerals engineers based on the local mineral production rate is shown, which shows that there are clear outliers.

Sep 1, 2012

By Erico Tabosa, Meng. Jun, Kym Runge, Matthew Brennan, Weiguo Xie, Dee Bradshaw

Turbulence and its distribution are of great importance in flotation cell design as they affect suspension of particles, air dispersion and particle-bubble collision rates, which in turn determine flotation performance. However, there is no mature technique to measure turbulence in three phase (liquid-solid-gas) systems such as in flotation cells. In this article, the authors present two new approaches that are suitable for measuring turbulence distribution in three phase systems and validate their applicability. The first technique uses a piezoelectric vibration sensor (PVS) to measure fluid kinetic energy standard deviation and the second technique applies electrical resistance tomography (ERT) to measure conductivity variation at a measurement position in a flotation cell. For the PVS technique, calibration of the sensor was performed to determine the values of parameters that were needed to calculate the force applied to the sensor. Then measurement was conducted in a 60L batch flotation cell and the results were compared with LDA measurement. This demonstrated that the piezoelectric sensor signal provides a good representation of fluid kinetic energy standard deviation at the position of measurement. For the ERT technique, conductivity distribution data was processed to give conductivity variations, which were then used to calculate fluid kinetic energy standard deviation at the measurement position. The spatial distribution of turbulence obtained by performing multiple measurements at different positions in the 60 litre batch flotation cell was found to agree with the PVS measurement results. These two techniques are potentially powerful tools for turbulence measurement in flotation environments, enabling a clearer understanding of turbulence’s influence on flotation performance to be determined.

Jan 1, 2014

By Johannes Käppeler, Alexander Weh, Harald Giese, Klaas van der Wielen

"High voltage breakage is a novel comminution technology that shows considerable potential for various applications in mineral processing and recycling. It relies on highly energetic electrical pulses to induce electrical explosions in rocks, causing the formation of plasma channels and powerful shockwaves that result in fracturing and fragmentation of particles. There has been considerable interest in this technology for its ability to weaken rocks and preferentially liberate target minerals, as previously demonstrated by other authors. Weakening has the potential to significantly reduce energy consumption during comminution, or alternatively, increase throughput of a circuit. Better liberation may yield an improved concentrate grade and/or recovery, reduce fines losses to tailings or increase the grind size required for liberation, thereby also reducing energy requirements. This review aims to increase general awareness of this technology, and promote further research into it by providing a general summary of the theory underlying high voltage breakage, as well as the envisaged applications of this novel technology. A brief history of the technology is presented before progressing onto the physics underlying the electrical and geomechanical aspects of high voltage breakage. Key results regarding weakening and liberation are discussed, and some mention is made of current challenges and planned developments to increase the throughput of high voltage breakage units to the level where it can be integrated into new and existing processing circuits."

Jan 1, 2014

By Braulio Fernández, Gonzalo Montes-Atenas

The mechanisms taking place during the leaching of chalcopyrite when it is in contact with other sulphide minerals, particularly pyrite, is still a matter not fully solved. The GalvanoxTM process has been suggested as a technical solution to extract copper from chalcopyrite at commercial level inhibiting passivation phenomena widely reported in the field of hydrometallurgy. Although there are some rules of thumb to implement the process in fully flooded stirred conditions such as the optimum pyrite/chalcopyrite mass ratio should range between 2 and 4, among others; not many research studies have been focused on studying the effect of the surface contact area between chalcopyrite and pyrite to reach best copper extraction conditions. The aim of this research work is to determine the effect of the mass and surface area ratio between the minerals and the surface area of each of the mineral species effectively exposed to the leaching solution. Different particle size distributions of pure pyrite and chalcopyrite were contacted in a small column and subjected to leach tests using sulphuric acid in concentrations close those used in industrial leaching processes. The mass and surface area ratios which optimize the extraction of copper were obtained. It was found the best leaching conditions were attained when reducing the particle size distribution of pyrite regardless the particle size distribution of chalcopyrite. Further analysis concerning the impact of this conclusions on large scale operations is presented and discussed.

Jan 1, 2014