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By Krishna Parameswaran

In this paper, we attempt to answer an often asked question, how can metal mining be compatible with the principles of sustainable development. Starting with the classic Brundtland Commission definition of sustainable development as "development that meets the needs of the present without compromising the ability of future generations to meet their own needs," we make the case that mining is or should be sustainable, using examples of sustainable practices at ASARCO LLC, an integrated U.S primary copper producer. These examples cover the entire mining cycle starting with exploration, mining, beneficiation, smelting, refining, closure and post-closure and post-mining land use. It is hoped that the presentation will challenge the mining industry to even greater innovation as future mineral development projects are planned.

Jan 1, 2015

By J. Fellowes, V. Landais, J. Robson, J. Carr

"Aerospace Al-Zn-Mg-Cu (7xxx) alloys are known to be susceptible to environmentally assisted cracking (EAC). This phenomenon has been studied intensively for many decades, leading to empirically adopted methods to mitigate this problem through overaging and composition design. In parallel, many theories have been developed to explain EAC in 7xxx, but none is yet universally accepted. Today, a number of emerging techniques offer potential to shed new light on EAC in 7xxx. The purpose of the present paper is to demonstrate how X-ray tomography (XCT) combined with electron microscopy can be used to identify the true crack path in 3-dimensions, and hence identify material for site specific electron microscopy analysis. Composition mapping over large areas to high accuracy has been performed using a modern electron microprobe analysis system. This has been combined with transmission electron microscopy to investigate local composition in matrix and precipitates at high resolution. This combination of techniques across length scales offers the potential to provide new insights into the links between local composition, microstructure, and EAC resistance.INTRODUCTION Environmentally-assisted cracking (EAC) is a phenomenon which dramatically decreases the performance of metals and can cause premature failure of large structures. Observed in situations where components were not subjected to critical loads and no widespread corrosion was involved, this type of brittle failure is extremely difficult to predict. The EAC designation covers a number of phenomena, e.g. stress corrosion cracking (SCC), hydrogen embrittlement (HE), corrosion fatigue (CF), etc. Initially identified in steels, EAC can also affect other metals such as high-performance aerospace aluminium alloys, and this phenomenon has been a concern for industries for decades. Extensive research has been conducted on the effects of various environments (moist air, saline water, dry hydrogen gas, etc.) on microstructures and crack propagation, however no consensus has been reached and the exact nature of the mechanisms that control EAC is still being debated (Birnbaum & Sofronis, 1994; Gangloff, 2007; Holroyd & Scamans, 2013; Lynch, 2012; Oriani, 1972; Scamans, Alani & Swann, 1976, Young & Scully, 2002)."

Jan 1, 2018

By S. J. Laskowski

In potash ore flotation, carried out in NaCI-KCI saturated brine (about 6-7 molar KC1 and NaCI solution), long-chain primary amines are used as flotation collectors. Long-chain primary amines are poorly soluble in water and their solubility further decreases at high electrolyte concentration. For ionic surfactants there is a characteristic temperature (Krafft Point, KP) below which their solubility is too low for micellization. In a previous study, the effect of pH on the KP of dodecylammonium chloride in water was determined [Q. Dai and J.S. Laskowski, Langmuir, 7, 1361-1365 (1991)]. This paper deals with the effect of electrolyte concentration on the KP of dodecylammonium chloride. The derived theoretical relationship between the KP and the critical micelle concentration (CMC) for dodecylamine can be used to calculate the KP for electrolyte concentrations of up to 0.5 mol/L (about 8% NaCI-KCI brine). A simple experimental procedure for the determination of the KP for higher electrolyte concentrations is also described. The results show that the Krafft point of dodecylamine increases from about 17-18°C (in distilled water) to about 80°C at 16% brine saturation.

Jan 1, 2006

By M. E. Wilson

"The property of McWatters Gold Mines, Limited, is in the east-central part of Rouyn township and about 6 miles east-southeast of the town of Rouyn. It includes 35 claims, the group of 5, staked originally, and 30 claims acquired in later years. The Rouyn-Val d'Or road and the Noranda Senneterre branch of the Canadian National railway both pass within a few hundred feet of the mine.The group of claims in which the mine occurs was first staked in 1922, but gold was not discovered until August 1932 when a schistose zone including veins of quartz carrying considerable free gold was laid bare in a stripped area in the northeastern part of claim R.11604. Diamond drilling undertaken in 1932, and continued into 1933, shouwd that the gold extended for at least 1,000 feet along the strike. A 3-compartment shaft was sunk to 418 feet in 1933. A mill having a capacity of 50 tons a day was constructed in 1934, and enlarged to 150 tons in 1935. Production began in 1934 and continued without interruption to June 1944. Except for a few diamond drill holes, there have been no operations on the property since that time. The maximum depth of the mine workings is 1,50) feet. A total of 368,013 tons of ore having a value of $3,946,752 and an average grade of $11.04 was mined during the years of operation.GEOLOGYThe ore mined from the property occurred within the south limb of an eastward plunging syncline of volcanics and sediments cut off on the north by the Cadillac-Bouzan Lake fault. Because the rock formations within the syncline have been severed from those outside with which they were originally continuous, their correlation is based almost wholly on lithological similarity. They include an irregular middle zone of conglomerate and greywacke underlain by north and south bands of andesite agglomerate and andesite tuff, in which lenticular bands of pillowed andesite are included."

Jan 1, 1954

By George A. Guess

The making of contracts for the purchase of ores is a business which the metallurgist usually understands better than the miner. Companies in the custom ore business often employ an ore buyer who is aware of the class of ore which the smelter needs, and is thoroughly conversant with the business. The miner on the other hand makes ore contracts but seldom, and it is often only after a settlement has been made that he realizes the meaning of the terms of the contract under which he has sold his ores. He has expectations usually greatly in excess of the amount 'net proceeds' shown at the bottom of the settlement sheet. Seldom does the occasional shipper really know his contract. A somewhat similar parallel is to be found in insurance policies. We all have insurance policies; we never know the conditions contained in them until after the fire. The clauses in the policy are for the protection of the Insurance Company. An Insurance Company has no friends.

Jan 1, 1926

By R. I. Grauch, Michael D. Glascock, Chen Nansheng, Jr Coveney, James B. Murowchick

"Unusually rich molybdenum ores (cutoff grade = 4.10/0 Mo) hosted by Lower Cambrian black shales have been mined since 1985 near Zunyi in the province of Guizhou in China. Similar ores were once worked for Mo and Ni near Dayong in the province of Hunan. In both mining areas, mineralization occurs in Lower Cambrian black shale (Niutitang Formation and stratigraphic equivalents) as a single sulfide bed or lens with exposed thicknesses up to 15 cm and reported thicknesses up to 35 cm. In addition to high Mo values (4% to 7%), ore samples contain up to 7% Ni, 2% Zn, 2.5% As, and several hundred ppb Au and Pt-group elements, but the precious metals have never been recovered from the ores. Sporadic occurrences of Mo-Ni sulfide ore beds are found in at least five provinces stretching approximately 1600 Ian from Yunnan to Zhejiang. None of the Mo-Ni ore-bed occurrences has any obvious connection with mafic or ultramafic source rocks. Similar occurrences containing elevated values for Ni, Mo, and PGE exist in Devonian black shale in the Yukon. Future exploration for Pt, Au, Mo, and Ni deposits should consider this previously unknown type of sediment-hosted mineral deposit.Sommaire - Des minerais anormalement riches en molybdène (teneur-limite = 4.1% Mo) provenant de schistes argileux noirs du Cambrien Inferieur ont été exploites depuis 1985 près de Zunyi dans la province de Guizhou en Chine. Des minerais semblables ont déjà été traire pour Mo et Ni près de Dayong dans la province de Hunan. Dans ces deux régions minières, la minéralisation se présente dans le schiste argileux noir du Cambrien Inferieur (Formation Niutitang et équivalents stratigraphiques) sous forme de couche ou lentille unique de sulfures avec des épaisseurs exposées de plus de 15 cm et des épaisseurs rapport6es de plus de 35 cm. En plus des fortes teneurs en Mo (4%-7%), des échantillons du minerai contiennent jusqu’ à 7% de Ni, 2% de Zn, 2.5% d'As, et plusieurs centaines de ppb d'or et d'éléments du groupe du platine; toutefois, les métaux précieux n'ont jamais été récupérés des minerais. Des présences sporadiques sous forme de couches de minerai sulfure de Mo-Ni se retrouvent dans pas moins de cinq provinces s'etendant sur 1600 km de Yunnan a Zhijiang. Aucune de ces présences de minerais, sous forme de couches, ne semble associée a des roches du type mafique ou ultramafique. Des présences similaires contenant des teneurs élevées en Ni, Mo et EOP se retrouvent dans le schiste argileux noir Devonien du Yukon. L'exploration future pour des gisements de Pt, Au, Mo et Ni doit prendre en considération ce type de gisement encore inconnu précédemment."

Jan 1, 1992

By K. Halada

Current trend of the global flow of strategic metals are analyzed to discuss the strategy of the development of recycling technology and alternative technology. In many cases, each global flow of metal is changing from the trilateral structure of U.S., EU and Japan in the later 20th century into the convergence to China as the factory of the world. Scrap flows are also changing dynamically. A long term change of prices of metal has gotten changed since the entrance of this century. The estimation of metal consumption up to 2050, in which the author estimated that many kinds of metal will overshoot the reserve base line, is revised considering these change of current trends.

Jan 1, 2014

By Jean-François Doyon

Les aspects environnementaux des activités minières d?exploitation réalisées sur le territoire québécois sont encadrés par divers cadres légaux, réglementaires ou autres (directive, politique, guide) tant au niveau provincial que fédéral. Ces cadres s?appliquent à l?un ou l?autre des trois grandes étapes du projet, soit lors de l?étude d?avant projet, pendant l?exploitation ou à la cessation des activités d?exploitation. Comme la réglementation environnementale est de plus en plus nombreuse, ces dernières années, cette présentation vise à exposer les principaux cadres provinciaux et fédéraux actuellement en application au Québec pour le secteur minier et à en dégager les particularités. ABSTRACT The environmental aspects of mining activities carried out across Quebec fall within the scope of various legal, prescribed or other frameworks (directives, policies, guides) at provincial and federal levels. These frameworks apply to one or another of the three major steps of a project: preliminary design, mining and closure. As the number of environmental regulations has greatly increased during the past few years, the object of this presentation is to state the main provincial and federal frameworks currently applicable in Quebec for the mining sector and to identify their special features.

Nov 1, 2002

By Martin Encinas, Jesús L. Valenzuela, Jose R. Parga, Salvador Aguayo, Roy G. Lewis

Continuous laboratory solvent extraction of gold from cyanide solutions using LIX?79 guanidine based extractant has been investigated. Different variables that affected the selectivity and extraction include aqueous pH, extractant concentration, and modifier concentration. The extraction isotherms of the aurocyanide complex with respect to the other cyano anions were compared, and the following order of selectivity Au > Ag > Zn > Cu > Fe was observed. According to the pH isotherms, aurocyanide can be extracted in an alkaline media, and a better separation with respect to the other cyanoanions was obtained in the pH range 10.5-11.2. From the McCabe Thiele diagrams, better recovery was predicted when using LIX?79 extractant and tridecanol modifier at 10 vol.%. Stripping of the gold from the loaded organic was carried out at pH > 12 using NaOH and NaCN solution. The continuous tests indicate that a two-stage extraction followed by a single stage strip is adequate to obtain an overall process efficiency of >90%. Better results were obtained using a copper wash stage before gold stripping.

Jan 1, 2014

By Greg Yuriy

This paper discusses research carried out by the Laurentian University Mining Automation Laboratory (LUMAL) in the field of discrete-event simulation of mine equipment systems and reliability assessment of these machinery using genetic algorithms. The AutoMod simulation package, from Brooks-PRI Automation Inc., is used in this research. It is a 3-D discrete-event simulation/animation software tool for creating realistic depictions of manufacturing and materials handling systems. Discrete-event simulation involves modeling of real-life systems based on variables and events which occur or change at distinct points in time. In our case, a two level, multi-drift sublevel stoping model was created in AutoMod for the simulation of the equipment fleet employed in the development cycle (drilling, explosives loading, blasting, materials hauling, ground support) of a typical underground mine in the nickel mining region of Sudbury in Ontario, Canada. The equipment primarily considered in the simulation is Load-Haul-Dump (LHD) vehicles (scooptrams), drills, explosives-loaders and roof bolters. The purpose of the simulation study is to assess the impact of equipment failures to mine?s production throughput. In more detail, using Mean Time Between Failures (MTBF) data of scooptrams derived from a reliability assessment model based on genetic algorithms, LHD failures are incorporated into the simulation model. These failures cause production interruptions to the development cycle and consequently loss of hauling capacity. This paper will indicate the significance of equipment failures to a mine?s production and suggest a methodology based on the combination of discrete-event simulation and a predictive reliability assessment model using genetic algorithms for the study and analysis of mine equipment systems.

May 1, 2003

By F. Doxey

Introduction In order to improve outputs and to reduce or hold mining costs, many attempts have been made to mechanize the getting and loading of coal in the major coal producing countries, and machines of various kinds and sizes have been designed and manufactured. Some of the most important are: Joy Continuous Miner Joy Coal Auger Goodman Mining Machine Lee-Norse Koal-Master Jeffrey Colmol Cardox Hordsecg Recovery Drill German Coal Plough British Coal Plough with agitated blades M. & C. Samson Stripper AB Meco-Moore Cutter Loader Joy Gloucester Getter The three last named are the chief longwall machines in use and the AB Meco-Moore and the Samson Stripper are doing a good job in their respective applications. It is understood that the Gloucester Getter recently installed in a British colliery also shows reasonable promise. It was felt, however, that to meet the conditions of the mines in Nova Scotia, any machine developed must have certain distinctive characteristics. It must: ( 1) Be able to cut and deliver coal in quantity and of the right sizes ( 2) Be easily manoeuvrable ( 3) Be suitable for longwall operations ( 4) Not interfere with timbers already set ( 5) Cut its own stable (6) Work on reasonably heavy gradients

Jan 1, 1951

By Ronald E. Pike

"PREFACEAt the CIM Annual General Meeting in Quebec City, R.E. Pike of The Toronto-Dominion Bank described how the Canadian banking industry worked with the minerals industry to assemble the large capital requirements for resource projects in Canada and overseas. He developed a profile of the mining industry and Canadian banking, both being important sectors of the Canadian economy and global in context. He also outlined the banking and financing partnership that existed in the past. In looking to the future and challenge that lies ahead f or each industry, Mr. Pike questioned whether the financing practices of the 1970s will be acceptable over the next decade. In that regard, he highlighted the risks that impact on each industry and illustrated how that financing partnership might evolve in response to those forces. The folio wing is a synopsis of his paper.IntroductionThe Canadian mining and metals industry is prominent in the domestic economy and respected internationally. Any measure of its performance illustrates that status-percentage of GNP, employment, exports, capital investment, size relative to other producing nations, etc.Energy, Mines and Resources Canada has forecast that the non-fuel minerals industry will grow in real terms by an average annual rate of 3.0% over the period 1981 to 1991. Using the GNP as reference, that growth in non-fuel mineral production will represent 7.7% of GNP. In translating that growth to capital expenditure, the EMR Canada estimates the aggregate amount at $43.8 billion ('79 dollars) or approximately 12% of total business investment in Canada during the 10-year period.About half of the $43.8 billion will be devoted to the ferrous sector-$8.4 billion in iron ore mining and $12.4 billion in the steel industry. Capital investment in nonferrous s projects is estimated at $13.3 billion, and it is projected at $6.7 billion for industrial minerals. The residual $3.0 .billion is exploration spending."

Jan 1, 1982

By K. Blower

"Since there was no representative from Wesfrob Mines Limited, the information on their infra-red concentrate drying operation, which had been prepared by Mr. K. Blower, was presented by Mr, Dorland. Mr. Blower, in submitting the information, emphasized that their objectives in this operation were (a) to guarantee less than 90%, of flow-moisture in their copper concentrates and thus satisfy marine shipping regulation• and (b) to minimize capital costs, The infra-red dryers have satisfied these objectives.To control final moisture in the copper concentrate, current practice is to preheat the filter cake with steam in the disc filter hood and then conveyor-0r7 the concentrate with infra-red calrod heaters. The application of steam aids the system as follows:1) Improves vacuum pump efficiency.2) Lowers viscosity of filtrate (increased temperature},3) Preheats the cake prior to radiant heating. (150°F)The hot cake discharging from the filter ranges from 10.6 to 10.9% moisture. After radiant heating the moisture level is reduced to 8.5% - 9.7% depending on production rate. Further moisture loss occurs during conveying and transferring to the stockpile for a final shipment moisture ranging from 8.1% to 9.5%. Production rate is frail J to 5 dry short tons per hour.1) #23 Conveyor 18"" flat belt covered from filter discharge to transfer point with 7 heaters end-to-end. Drive - Reeves Vari-Speed, 31:4 ratio, type 332-10-18, class ""D"", driving through a 24:1 ratio Dodge reducer. Speed of Conveyor - 3,9 feet per minute to 19.6 feet per minute. (Speed has been established and is not changed as a rule from the present level of a1:out 15.)2) #23 Conveyor 24"" wide, 20° troughed belt covered with 21 heaters, end-to-end from loading point, Speed - Constant at 54,2 feet per minute."

Jan 1, 1972

By L. Gawlik

Since the beginning of the 20th century, coal has been the world?s main source of primary energy. In the last few decades, consumption of coal has gradually decreased in some European countries and elsewhere due to the introduction of other energy sources. Regardless, industry continues to use solid fuels for energy production despite of their association with carbon dioxide emissions (about 7 billion Mg). For global development going forward, it is important to estimate what level of energy consumption can be expected as far into the future as the next few decades. To answer this question, specialized global institutions such as the International Energy Agency, the World Energy Council, the World Coal Institute, the U.S. Energy Information Administration, the International Institute for Applied Systems Analysis, as well as oil companies (BP, Shell), conduct periodic forecasts of world energy consumption. The development of such forecasts is very complex because their reliability is influenced by many factors that are difficult to estimate, such as economic development, population growth, climate change, and public awareness. We are all aware that the global demand for electricity will rise significantly in the coming years as a result of anticipated population growth, industrial development, rising living standards, and the general development of civilization. The world?s mineable resources in 2010 were as follows: coal 665.6 million Mg, brown coal 195.4 billion Mg, oil 163 million Mg, and natural gas 185.5 billion m3. The annual global primary energy demand in 2008 was more than 12 billion toe (12,267 Mtoe). In 2006, electricity production in the world amounted to 18,921 TW?h. The structure of the primary energy mix in TW?h (2006) was as follows: coal 41.0%; natural gas 20.1%; nuclear fuel 14.8%; hydro energy 16.0%; liquid fuels 5.8%; and other renewable energy sources 2.3%. The European Union (EU) is one of the largest coal consumers in the world. In 2010, the EU-27 produced 396.1 million Mg of brown coal, and 132.9 million Mg of hard coal; 188 million Mg of coal was imported from outside the EU. The largest hard coal producers in the EU-27 are Poland, Great Britain, Germany, the Czech Republic, and Spain; major brown coal producers are Germany, Greece, Poland, the Czech Republic, and Hungary. For many years, the Polish energy sector has been based on domestic fuel sources ? hard coal and brown coal. The characteristic feature of the Polish balance of primary energy resources is a very high share of coal ? much higher than the world average. Pursuing the decarbonisation of the Polish economy may jeopardize Poland?s energy security, leading to a significant increase in electricity prices, which would hamper the country?s economic development. Price volatility and supply uncertainty are now the dominant features of the international markets for oil and natural gas. The high share of these fuels in meeting energy needs is the reason for unrest in many countries, including those in the EU. Under these circumstances, coal may become the stabilizing element of EU energy security.

Aug 1, 2013

By N. Shi, T. G. Joseph

ABSTRACT A revised equilibrium approach to evaluate dipper-ground interactions during the dig cycle of ultra-class mining shovels operating in soft unblasted uniform ground conditions is presented. A review of previous approaches, leading to an outline of the modifications and ground condition considerations, is made in support of the reasoning and basis for the derivation presented. An analytical solution is provided to the scenario of a cable shovel dipper digging in soft ground material such as oil sands.

Jan 1, 2012

By J. A. Hillier

The staff of the Hudson Bay Mining and Smelting concentrator have developed a new type of reagent feeder. Several factors encouraged the development of such a system: varying heads caused by the mixing of ores from several mines, the increasing number of flotation circuits operated and reagent feeding stations remote from the flotation operator's work area. The reagent feeders also had to be compatible with future plans for reagent control from an on-stream X-ray analyzer and computer system. The new feeder is a positive-displacement pump set to deliver a constant volume per stroke. At a remote panel, the feed rate is altered by changing the time between strokes. The feeders have been found to be reasonably trouble-free and accurate to less than 2 per cent error.

Jan 1, 1973

Presentation Topics ? Low and Intermediate Level Waste ? Project Location and Site ? Geological Setting ? Key Features ? Project Overview ? Licensing and EIS ? Next Steps DGR Waste Package Inventory Approximately 50,000 packages over 35 years: ? ~40,000 packages or 80% of inventory are LLW Bins ? ~7,000 ILW Shields (concrete boxes) ? ~2,000 resin liner packages

Oct 1, 2010

By S. Banisi, A. Haji-Zadeh, A. R. Hasankhoei, M. Maleki-Moghaddam

At the concentration plant of the Gol-E-Gohar Iron Ore Company (Iran) three 9m × 2.05m AG (Autogenous) mills (fixed speed) are used in parallel in a dry operation. The test works conducted in a scale down mill with a diameter of 1m indicated that conventionally used "deflector" type liners did not provide efficient environment for grinding. In this research, to improve the grinding efficiency, a new design using low profile end liners incorporating radial ribs of proper height was investigated. In order to determine an appropriate liner design at different operating conditions, a 100cm×10.8cm model mill was used for experimentation. The special design of model mill made it possible to increase the radial ribs height in steps of 6mm up to 18.5mm. The transparent end of the mill enabled accurate trajectory determination by image analysis. The results indicated that the new lower height profile deflectors and 15.5mm-height (14.5cm in industrial scale) radial ribs improved the mill performance while avoiding excessive pressure drop across the mill and wear on the liner. The image analysis showed that the use of new liners increased the distribution of coarse particles across the mill cross section from 28% to 35%. A new liner design was proposed by decreasing the number of liners in each slice from 5 to 4 pieces. The thickness of the inner head liners reduced from 45cm to 30cm and the outer deflector liners replaced by radial ribs. The distance between the feed and discharge inner head liners increased from the original 115cm to 145cm which increased the effective length of the mill by 26%. The new design reduced the weight and volume of end liners by 9% and 23%, respectively. It was predicted that the new liners design increases the mill throughput by 10% and reduces the metal consumption by 20%.

Jan 1, 2016

By Charles G. Kemsley

IN January, 1939, Dome Mines, Limited, purchased a few bars of an alloy drill-steel for the purpose of testing its fatigue resisting qualities as compared with those of a straight carbon-steel then in general use at the mine. A steel of the following analysis was selected: Carbon 1.00% Sulphur 0.022 Chromium 1.26 Silicon 0.17% Phosphorus 0.028 Vanadium 0.1 Manganese 0.32% Molybdenum 0.30 This steel has a tensile strength of 180,000 lb. per square inch and a Brinell hardness of 380, as compared with a tensile strength of 114,000 lb. per square inch and a Brinell hardness of 230 for the standard carbon drill steels, in the as rolled' condition. The result of this test showed that about five times as many runs could be obtained from the alloy steel before failure from fatigue. It was therefore decided to replace gradually the one-inch quarter-octagon carbon steel, then in use, with seven-eighths quarter-octagon alloy steel. In January, 1940, six machines was placed on the seven-eighths steel and this was gradually increased until now (March 15th, 1941) fifty per cent of the steel being used is alloy steel. An O'Donovan furnace is used at the Dome for heat-treating their carbon drill-steel. In this furnace, a magnet withdraws the steel when the critical temperature has been reached, and the operator then places the steel in the quenching tank. Not being able to use this furnace for the alloy steel, the management felt that some means should be developed to determine the quenching temperature without depending upon the operator's judgment of the correct 'colour'. With the assistance of the Canadian General Electric Company, a radiation-type vacuum thermocouple pyrometer was adapted to this purpose, with excellent results; in fact, with this instrument no previous experience in hardening is necessary and results are remarkably uniform.

Jan 1, 1941

By K. Turgeon, D. Larivière, L. Whitty-Léveillé, J. -F. Boulanger, C. Bazin

"The processing of ore containing rare earth elements leads to the production of an impure solution of these elements. The separation of the rare earths from the impurities and the production of individual elements is usually carried out by solvent extraction. The effectiveness of the extraction conditions and of the reagents is generally tested in the laboratory. This paper deals with the processing of results from solvent extraction laboratory tests planned to generate data redundancy. A method is proposed to take advantage of the data redundancy by accounting for the pH variation during the extraction. The parallel processing of several tests also allows estimating the equilibrium constants for the extraction. The proposed method produces equilibrium constants that are more reproducible than values estimated using conventional approaches. The method is illustrated with solvent extraction tests conducted on synthetic solutions of rare earth elements.INTRODUCTIONThe processing of ores containing rare earth elements (REE) usually includes the production of a concentrate of the minerals carrying the REE. These minerals, for instance monazite and bastnäsite, contain the 14 elements from La to Lu plus yttrium and scandium. As an example monazite has the general formula of (La,Ce,Pr,Nd,Sm,Eu,Gd,Tb,Dy…Lu)PO4 with a typical lanthanum content of 20-26%, cerium content of 40-50%, praseodymium of 4-6%, neodymium of 16 to 20%, and decreasing concentrations of heavier elements (Gupta & Krishnamurthy, 2005). During the processing of a REE mineral, it is generally not possible to isolate and separate a single REE from all the rest. The mineral molecules need to be broken (usually via a heat treatment followed by leaching with a base and/or an acid) to produce an aqueous solution of the REE of the ore. After purification of the solution, the REE can be precipitated as a bulk concentrate and sold to a refinery that separates the REE into particular groups of REE such as the light versus heavy REE or into individual elements such as lanthanum, neodymium, or europium oxides to yield value-added products."

Jan 1, 2016