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By I. Dymov

"The extractive metallurgy of precious metal ores involves gravity concentration, flotation and cyanide leaching. Pre-oxidation, such as roasting, autoclaving, bacterial oxidation and other techniques, is required for processing refractory ores. Selection of the process is mainly driven by the grade, reserve and mineralogy of the target elements. The concentrations of precious metals in the crust are extremely low and highly variable, resulting in ore variability in many gold, silver and PGE deposits. More importantly, precious metals in an ore may occur in two or three forms (i.e. microscopic, submicroscopic and surface-bound), making ore processing of precious metals extremely challenging. The objective of geometallurgy and process mineralogy is to reduce and minimize the technical risk in project evaluation, process selection, mine planning and production forecasting through geometallurgical modelling, representative sampling and subsequent systematic mineralogical characterization and metallurgical testwork. Geometallurgy is a technique to document variability within an orebody and quantify and evaluate the impact of many factors including geology and mineralogy on grinding, flotation, leaching and metal recovery processes, while mineralogy is one of the major predictive and trouble-shooting tools for many new mineral projects and operating mines. This paper presents an overview of fundamentals, methodologies and techniques applied in geometallurgy and process mineralogy and highlights the importance of both disciplines in process selection and plant optimization with applicable case studies. INTRODUCTION Precious metals, including gold, silver and platinum group elements (PGE) occur in various geological settings and ore types. The concentrations of these metals in the crust are extremely low and highly variable, resulting in ore variability in many gold, silver and PGE deposits. More importantly, precious metals in an ore may occur in two or three forms (i.e. microscopic, submicroscopic and surface-bound), making ore processing of precious metals extremely challenging. Process selection is most important in any precious metals project and is mainly driven by the grade, reserve and mineralogy of the target elements. Free-milling ores, such as Kupol in Russia, Hemlo in Canada, Grasburg in Indonesia, UG-2 in South Africa, Lac des Iles in Canada, and Noril’sk in Russia, can be processed using flotation or cyanidation with or without gravity. B2Gold Corp, a Canadian gold company, just started a number of new and under construction free-milling gold operations such as Fekola mill in Mali, Mastbati mine in Philippins and Otjikoto mine in Nambia. However, refractory ores (particularly gold ores), such as the Carlin and Goldstrike mines in the USA, Giant in Canada, Pueblo Viejo in Dominican Republic, Porgera and Lihire in PNG, Kittilla in Finland, Fairview in South Africa and Shuiyindong in China, must be processed using pre-oxidation prior to cyanide leaching. In some mildly refractory gold ores, such as Kumtor mine in Kyrgyzstan and KCGM in Australia, ultrafine grinding is required to liberate fine-grained gold particles. For some gold ores containing both free-milling and refractory components (such as Cripple Creek mine in Colorado, USA), two or more recovery processes may be required. The variability of grade, metal deportment, ore hardness and other parameters is one of the risks that encountered in development and operation of many precious metals projects. To minimize and reduce the technical risk caused by ore variability, geometallurgy and process mineralogy have been used by mining companies in the last two decades to measure and quantify the spatial variability of the deposits that are being developed. This paper presents an overview of fundamentals, methodologies and techniques applied in geometallurgy and process mineralogy, it highlights the importance of both disciplines in process selection and plant optimizat"

Jan 1, 2018

By H. Pearce, A. E. Lewis, A. Ochieng

Hydrodynamics and mixing are fundamental to the operation of mineral process systems such as flotation cells and metal precipitation reactors. The computational fluid dynamics (CFD) technique has been employed in the present work to study the hydrodynamics in a mixing vessel stirred with either a Rushton turbine or a pitched blade impeller. The multiple frame of reference (MFR) approach has been used to model both impellers. A draft tube was used only in the Rushton turbine stirred vessel. The flow profiles for the pitched blade impeller have been studied in three regions; below the impeller tip, at the middle of the tank, and near the liquid surface. The simulation results were compared with literature data obtained using a laser Doppler velocimetry in the three regions of the vessel, and it was found that the model predictions were better in the impeller region. There was a poor prediction of the experimental results in the region closer to the liquid surface; however, this was improved when the turbulence parameter (C2) in the k-e model was set to a higher value. The value of the impeller clearance at which the Rushton turbine generates an axial impeller type flow has been determined and it has been shown that, at this clearance, a draft tube can be used to enhance axial flow in a Rushton turbine stirred reactor.

Jan 1, 2003

The concept of the Unified Comminution Model (UCM) was presented at the 23rdIMPC. The model utilises computational techniques to calculate the mechanical environment in any comminution device, and then incorporates the outcomes from rock breakage tests to predict the product from a device. The model is fully mechanistic, and incorporates the capability to simulate novel equipment. This paper presents the progress on the first application of this concept to applied comminution equipment. This novel comminution model aims to integrate all comminution models within a single struc-ture. This will provide a step change in the predictive power of comminution models, and include a wide range of particle properties that will enable it to be linked to the upstream and downstream process of mining and recovery. Major advances over current models will be the capability to predict liberation, preferential grinding, performance of new and novel devices, and to have power as an integral driver of the comminution simulation process. The methodology and model structure have been developed. An equation within a population balance framework has been derived as the basis for the UCM. A set of SAG mill pilot has been used as the first test case. The breakage characteristics of the ore have been extensively tested utilising a new range of breakage tests required by the rigorous UCM structure. The mill was simulated with the EDEM - DEM software. A partial test simulation of the pilot SAG mill has been conducted. This serves to demonstrate the feasibility of this modelling technique, but still lacks important ore characterisation components that are under development. The study has raised a number of significant challenges to the accepted understanding of the comminution process. Through addressing these challenges considerable insight has been gained into the energy environment in mills and the requirements of breakage testing. The ore characterisation methods and energy transmission derived from DEM simulations remain as major research items.

Jan 1, 2014

The multiphase reactive flow in process equipments, e.g., fluidized beds, involves complex coupling among flow, heat/mass transfer and reaction kinetics over scales ranging from molecules, sub-particle eddies up to equipments. Conventional two-fluid model (TFM) ignores the effects of meso-scale structures, and hence is not suitable for describing the intrinsically multi-scale heterogeneity within multiphase systems. To be consistent with the meso-scale structures, we proposed a structure-dependent multi-fluid model (SFM), and closed its drag force by invoking the stability condition defined in the energy-minimization multi-scale (EMMS) model. The SFM reduces to the conventional TFM if homogeneous distribution is assumed within each grid, and reverts to the original EMMS model if it is used to describe steady state, global behavior of a fluidized bed. The multi-scale computational fluid dynamics (CFD), which is characterized by coupling of TFM and EMMS drag coefficient, can then be viewed as a simplified solution of the SFM. We demonstrate that the SFM significantly improves the accuracy and at the same time enables higher efficiency by allowing for much coarser grid used than in TFM. Recent application of it in 3D, full-loop, transient simulation of industrial processes, e.g., fluid catalytic cracking, coal combustion, gasification, kaolinite clay calcinations, shows its advantages in helping design and troubleshoot multiphase process equipments. Keywords: meso-scale, SFM, multiscale, CFD, simulation, structure, EMMS, multiphase

Sep 1, 2012

By Cagri Emer

In conventional mechanical flotation cells, when the size of particles exceed a particular value, that is of the order of 100 µm for metal sulphides, the recovery of particles decline rapidly. It appears that the turbulence in the agitated vessel is sufficiently intense to rupture the forces of attraction between the particles and the bubbles, so the large particles are flung off the bubbles in the turbulent field. It has recently been suggested, that a fluidized bed would be a very favorable environment in which to contact bubbles and the particles. In a fluidized bed, particles are supported by rising flow of fluid, which separates them from each other and allows them to move freely while remaining close together. In this novel method, bubbles injected into the fluidized bed are able to rise through it, colliding with hydrophobic particles, transporting them to the top of the column where they can form a froth layer that overflows into a launder. The flow in a fluidized bed is generally slow and nonturbulent, and preliminary experiments have shown, that it is possible to collect mineral particles as large as 1 mm and coal particles as large as 5.5 mm. If the upper particle size limit can be extended, there could be significant reductions in the overall energy consumption in concentrators. Calculations show for example that if the top size for flotation could be increased from 100 µm to 400 µm, there would be a reduction in grinding energy of the order of 40%. It is therefore, important to study the mechanism of coarse particle capture in fluidized beds. In this work, the factors governing the capture rate of particles, particularly the particle and bubble size, the fluidization velocity and the superficial gas velocity have been investigated, and the results will be presented.

Sep 1, 2012

By A. Mainza, H. Hill, L. Bbosa

"The main objective of ore breakage characterization is to quantify the relationship between the energy supplied for breakage and the size of the resultant progeny. In this study, the ore breakage characteristics of drill core particles and crushed particles were compared. Single impact breakage tests were conducted on a basalt ore sample using the JK rotary breakage tester. The size-dependent model by Shi and Kojovic was used to fit the breakage data because the effect of initial particle size is accounted for in the model. It was found that crushed particles consistently gave a higher degree of brokenness than drill core particles and the differences were attributed to the internal structure of the particle. Drill core particles contain a lower crack density (paths of weakness) than crushed particles which have been pre-weakened during the crushing process. An increase in crack density is directly related to a decrease in the minimum threshold energy. Upon application of a stressing force above the stress threshold, particles with a higher crack density will fracture more easily because of a higher rate of crack propagation due the numerous paths of weakness available. It was therefore concluded that under the same conditions, drill core particles are more competent than crushed particles. INTRODUCTION Comminution devices have commonly been reported as being the largest energy consumers in mineral processing circuits (Napier-Munn, 2015). Cleary (1998) reported that the inefficiency of comminution devices is a result of less than 5% of the supplied energy being utilized for breakage, with the majority being expended as heat and noise. With steadily declining fossil fuel supplies and a looming global energy crisis, the mineral processing industry has increased its focus on energy reduction measures. Ore breakage characterization plays a critical role in the design and optimization of comminution circuits (Tavares and King, 1998). The main objective of ore breakage characterization is to empirically quantify the relationship between the energy supplied for breakage (specific input energy) and the size of the resultant progeny through laboratory particle breakage tests (Napier-Munn, 1996). Commonly used laboratory breakage devices include the Drop Weight Tester (DWT), Split Hopkinson Pressure Bar (SHPB) and more recently, the JK Rotary Breakage Tester (JKRBT). Typically, a standard single impact breakage test procedure consists of a matrix of experiments on particles in four to five narrow size fractions each tested at low, medium and high energy levels. The resultant progeny of each test is sized to obtain a particle size distribution (PSD) from which the degree of breakage, usually in the form of a t10 value (percentage of the progeny material that passes 1/10 of the feed size) can be obtained for each size fraction and energy level (Napier-Munn, 1996)."

Jan 1, 2018

By Jacek Kolacz

A new sensor based sorting system related to complex image analysis has been developed at Comex AS - Norway. It makes it possible to separate different mineral particles regarding their color, shape, texture, size, density and indirectly their composition. The sorting system has been successfully tested and applied for sorting minerals providing high separation efficiency in the range of 95-99.9 %. The main advantage of this system is connected with its universality where many material parameters are analyzed in the same processing unit by a single passage.

Sep 1, 2012

By Q. R. Chen

Wet processes are commonly used in coal preparation field home and abroad. Dry coal cleaning technology is very necessary in China because more than 2/3 of coal resources deposited in arid areas, which are difficult to separate coal with wet processes. A particular interest of this article is the discussion of separation research development of dry coal cleaning in China, such as an air dense medium fluidized bed (ADMFB) beneficiation technology, a compound dry (pneumatic) separation technology and a triboelectrostatic separation technology. The fundament and importance of dry coal cleaning methods above were introduced. On the basis of analyzing parameters which influence the performance of separators, including that of structure, technologic and operating, the separation research status of dry coal cleaning methods, especially the ADMFB beneficiation technology, were discussed and reviewed. The recent developments, especially the fluidized bed beneficiation for <6mm fine coal with an external energy assisted, including a vibrated fluidized bed and a magnetically fluidized bed, and the triboelectrostatic separation for <1mm fine coal are also introduced. The study and application results in China show that dry coal cleaning technologies can efficiently beneficiate different coals with different sizes. The ADMFB can separate >6mm coarse coal with an E value of 0.05~0.08, the external energy assisted fluidized bed can separate <6mm fine coal with an E value of 0.07~0.09, the triboelectrostatic technology can efficiently separate <1mm fine coal, and the compound dry separation technology can efficiently separate >3mm coal with a easy washability. The dry coal cleaning provides an efficient and lower cost clean approach for coals distributed in arid areas.

Jan 1, 2014

By M. Karamoozian

Modelling and optimisation of the power draw of large SAG mills are important due to the large power draw which modern mills require (5~10 MW). The cost of grinding is the single biggest cost within the entire process of mineral processing. Traditionally, modelling of the mill power draw has been done using empirical models. Although these models are reliable, they cannot model mills and operating conditions, which are not within the model database boundaries. Also, due to their static nature, the impact of the changing conditions on the power draw, within the mill, cannot be deter-mined using such models. Despite advances in computing power, on-line modelling of large plant scale mills could be a time consuming task. On the other hand, using on-line parameters for model-ling, result in more reliable control of SAG mill without performing any more costly tests. In this paper, SAG mill power draw is modelled using neural network approach. Six inputs, namely: solid percent, two bearing pressures, noise, recycle and feed rate were used to model the power draw. The produced model shows an acceptable correlation coefficient, R2 =0.9623.

Jan 1, 2014

By Manisha Singh, Manikanchan Sarkar

"Presently the global steel production is mainly based on iron ore sourced from high grade hematite deposits. India has large deposits of good quality hematite ore but with the prevailing practice, such deposits are depleting fast and getting exhausted. However, apart from such high grade iron ores, India is also endowed with large reserves of low grade iron ore, such as BHQ (Banded Hematite Quartzite), BHJ (Banded Hematite Jasper), BMQ (Banded Magnetite Quartzite) and Magnetite. In the present situation, it has become necessary to focus attention on upgradation of these low grade ores to produce useable concentrate. It augurs well that already substantial investigation work has been carried out in this respect and a few plants have been set up in India and abroad. One important aspect in this regard is the process route options with optimum yield and grade. Some of these low grade ores, particularly magnetite, are found to contain high phosphorous level, removal of which poses a major challenge. Since the grade is low, substantial upgradation necessitates fine grinding for appropriate liberation. Fine grinding is energy intensive and needs attention to achieve economy in this regard. Large quantity of tailings is generated in the process, wet disposal of which gives rise to a lot of hassles and hence, possibility of dry disposal of the same needs to be explored. The experience of the authors, with regard to aforesaid aspects which has been gained in course of carrying out relevant assignments is presented in this paper."

Jan 1, 2014

By Kazutoshi Haga, Ryo Kawarabuki, Atsushi Shibayama, Masato Kosugi, Masanobu Kawata, Refilwe S. Magwaneng, Kohei Mitsuhashi, Altansukh Batnasan

"The recovery of copper and iron from carbonaceous sulfide ore is of economic and environmental interest despite its processing difficulty. Hydrometallurgical methods can be used to concentrate sulfide metals of these hard-to treat ores in a simple and eco-friendly manner. In this study, high pressure acid leaching process was comprehensively studied to dissolve metals from an ore with organic carbon and carbonaceous gangue material using autoclave equipment. The sample used for the experiment was reduced to an average particle size of 75 µm after undergoing flotation to reduce carbonaceous gangue minerals. A comparative study on two leaching reagents of sulfuric acid and iron sulfate and their dosage was used to observe dissolution of copper and iron. Other parameters of temperature (90-170 0C), solid-liquid ratio (1:10, 1:5, 1:3 and 1:1) were investigated through kinetic studies to access the influence of organic carbon and carbonaceous material on recovery of copper and iron. Materials balancing analysis was used to evaluate the efficiency of metal dissolution. The effects of parameters on leaching rate and concentration was demonstrated. Results obtained from the experiment indicated low concentrations of copper and iron in pregnant leached solutions, which was attributed to acid consumption by organic carbon and carbonaceous material in feed. However, the high efficiency rates of 92.4% and 86.3 % for copper and iron respectively in sulfuric acid can be concluded that leaching of concentrates of carbonaceous ore is possible provided system control on type of acid, pH and temperature. The purpose of this research is important in understanding mechanism involved in dissolution of copper and iron in concentrates of carbonaceous ore and marks an improvement in leaching of highly contaminated ores."

Jan 1, 2018

By G. S. Hansford, G. E. Searby

The rate of bioleaching of pyrite at 70ºC by a thermophilic archaeal culture was measured as a function of the solution redox potential by the staged addition of pyrite to a batch system. The results were compared to the rate of ferrous iron oxidation over the same potential range to determine the applicability of the multi-sub-process leaching mechanism developed for mesophilic bioleach systems.

Jan 1, 2003

By John A. Herbst, Ming Song, Xiangjun Qiu

"It has been known for sometime that as wear occurs in tumbling mills there is an associated change in mill throughput. These changes have traditionally been simplistically, attributed to “mill volume effects”. New high fidelity simulation (HFS) tools (involving DEM, CFD and Breakage models) are now giving new “microscale” insights into the complex interactions that occur between evolving lifter/liner profiles and breakage. An illustration of this analysis is shown in Figure 1 below.Here we see that after a new lining is installed (Region I) the wearing process reduces the liner thickness resulting in a larger power draw and an associated higher throughput until Region II is reached. By this point the lifter height is reduced significantly changing charge motion (less cataracting) the power begins to decline, but the comminution efficiency increases with this type of “calmer” breakage environment therefore the throughput continues to increase. In Region III the lifter is no longer providing the minimum required charge lifting action, the power and the throughput both drop off significantly. In the last two stages the behavior is especially complex because throughput is not linearly related to power since grinding efficiency is changing.The study described here shows that these new HFS tools allow the design of wear part profiles which will maximize mill productivity over the entire life of liner/lifter systems. A simple example of such a design procedure is shown involving the selection of a sinusoidal profile for a 34 ft diameter SAG mill.The paper discusses how the principles exposed in this simple example can be applied to search for an optimal profile in which non-standard modifications are allowed to compensate for throughput or wear shortcomings of standard profiles."

Jan 1, 2003

By Remmerswaal, U. Boin, M. B. G. Castro

"To design sustainable products that can be recycled with high resource efficiency, low environmental impact and economic feasibility, the choice of materials and materials combinations, made in the design stage, is fundamental. The products we design, manufacture and use now will be the resources of the future. Designers are able to select materials for a product according to the many functional requirements they must fulfil. But they have a limited knowledge of the recycling processes and its requirements regarding quality of the secondary material streams. Resource Engineers have to manage the processing of these streams, that are becoming more complex with the increasing variety of materials and decreasing size of components. After mechanical separation of the materials streams resulting from shredding of EOL (endof- life) products, there is always a degree of contamination, from two possible causes:Incomplete liberation: the bonds between different materials combined in a component are not completely destroyed by shredding, resulting in some particles containing two or more materials attached;Separation efficiency: the mechanical separation processes are not able to separate perfectly the many material particles; there are always a number of foreign particles in the recovered streams.Sometimes, those contaminants cannot be removed by the industrial metallurgic recycling processes, and a more serious problem occurs when the contamination levels compromise the recycling of the material stream by lowering its quality (i.e. the properties of the recycled material will be lower due to the contamination). As a consequence, the material must be diluted in virgin raw material and/or used in a less demanding application (downgrading), causing resource depletion and increased energy use, waste production and recycling costs. In order to make the best choice of materials combinations for a product, a systematic approach is necessary, that can close the gap between the knowledge areas of Product Design and Recycling Technology."

Jan 1, 2003

By Fernando Concha

"Thickening development and innovation in the 20th Century occurred in two decades periods. From 1900 to 1920, Dorr invented the continuous thickener and the first method of thickener design was proposed by Coe & Clevenger. From 1920 to 1940, the operating variables of continuous thickening were discovered by Comings at the University of Illinois. From 1940 to 1960, the first theory of sedimentation was proposed by Kynch and several authors, Talmage and Fitch, Ysioka and Hasset used this theory to develop new thickener design methods. From 1960 to 1980 Shannon and Tory demonstrated that this theory applied exactly for the sedimentation for small rigid spheres in water and Scott showed that it is not valid for flocculated suspensions. From 1970 to 1990 the phenomenological theory of thickening was developed based on the theory of mixtures. Papers by Kos, Bascur, Thacker and Lavelle, Concha and Bascur, Concha and Barrientos, Auzeris, Buscal and White, Landman, White and Buscal show the application of this theory to thickening and Adorjan presented the first thickener design method based on this theory. In 1980s the mathematical analysis and solutions of Kynch’s model for batch and continuous thickeners was obtained by Bustos. The new Century brought solution to the phenomenological thickening model which was applied to thickener design, simulation and control. The method of thickener parameter determination was improved by designing new laboratory and on-line instruments and advanced control strategies was designed and validated in plants. Structural thickener design produced improved feedwells and feed dilution mechanism, stronger raking mechanism and different thickener shapes according to new ambient requirements, such as high rate thickener and paste thickeners that increase the water recovery. New challenges include better flocculation and advanced control strategies."

Jan 1, 2014

By D. Chakraborty, Neeraj Kumar

"The study provides the comparative analysis of the performance of water only cyclones and hydrocyclone for iron ore fines processing at Joda Iron ore processing plant, Tata Steel. Joda iron ore deposits have higher proportion of kaolinite in the finer fractions and are meant to be separated with cyclones. The iron processing flowsheet of Joda comprises of water only cyclone for beneficiation of iron ore fines. Water only cyclones are used for the beneficiation of fines in the iron ore processing industry and have a larger cone angle compared to that of conventional hydrocyclones to enhance the density effect in the separation. They are aimed to achieve better product quality of underflow however; the desired result could not be achieved at the Joda processing plant. The water only cyclones were operating at the corrected cut-size of about 60 micron with an imperfection of 0.40 and water split to underflow was approximately 10%. The overall Fe recovery from the water only cyclones were 60%. Since the quality of fines produced from the water only cyclone couldn’t be improved, an attempt was made to process the fraction in the conventional hydrocyclone to achieve the desired product quality. The trial results indicated better product quality with the Fe recovery of 72% at corrected cut-size of 70 microns and imperfection of around 0.29. In view of above results it was recommended to replace the water only cyclones with hydrocyclones to achieve higher product quality of about 60% Fe content.INTRODUCTION Water only cyclones were installed at wet plant, Joda to process the classifier fines where the cyclone underflow is considered as concentrate and overflow is discarded as slime. Because of the lower capacity of the cyclones 30% of the classifier overflow was bypassed directly to thickener. Apart from this the quality of fines produced from the water only cyclone couldn’t be improved further hence an attempt was made to process the fraction in the conventional hydrocyclone to achieve the desired product quality and quantity. Hydrocyclone was installed at Joda after replacing stub-cyclone and came into operation on 23rd Aug’ 2017.The process variables of water only cyclones and hydrocyclones are tabulated below:"

Jan 1, 2018

By A. F. Usov

A potential of electric pulse disintegration in benification used for primary deposits ores containing precious metals is shown. Of special significance is that PGM and gold grains, being highly plastic, are easily liberated and are not smeared on the disintegrated rock fragments surface. It al-lows gravity separation, which is less expensive and more efficient, to be used instead of chemical processing, which is expensive and environmentally faulty.

Jan 1, 2014

By C. L. Xiao

With reference to the test report carried out by Guangzhou Nonferrous Metal Research Institute in 1983, the mineral process flow sheet of Yichun Tantalum-niobium mine is determined based on the characters of ores and successful experiences in light of the problems in the existing flowsheet: The ore is desilted before crushing; the primary slime is separately treated; the staged grinding process used while the fine slime is collectedly treated with tantalum and niobium as the main recoveries and lepidolite and feldspar powder as the secondary. The flowsheet is featured by comprehensive recovery, low investment and low energy cost.

Jan 1, 2014

By Gerke Gilian, Pretz Thomas, Pehlken Alexandra

"The evaluation of health hazards within the treatment of mineral and waste materials is gaining more and more importance in industrial countries. The need to control occupational health and safety has been recognised, and regulations which describe general protective measurements for personnel provide a tool to protect their health. It is the aim of the paper to give an outlook for practical approaches to risk assessment and to present measures for exposure reduction in accordance with the state of the art in Germany.Both the treatment of minerals and of waste materials are described in relation to the risk assessment. The method of evaluating health hazards in the two industries is similar and therefore both examples are presented next to each other.The example presented in the paper is the German “Biostoffverordnung” (the regulation for biological materials) which is important for the waste treatment industry. All kinds of waste treatment facilities (like composting facilities, waste dumps, sorting facilities for packaging materials) are obliged to carry out an assessment of health hazards for a variety of working areas and working places. The possible safety requirements deriving from this regulation are presented and discussed under the aspect of biological hazards."

Jan 1, 2003

By N. T. Beukes, W. Banda

Recovery of Co from slag is a recent advancement in the extractive metallurgy of nonferrous metals. In this study a DC arc technology at laboratory scale has been applied to investigate the selective recovery of Co from slag, under three different flux types with an emphasis on influencing the activity of FeOx, SiO2 and CoO in the slag. It is known that reduction of slag by carbon is only up to a certain level after which, the recovery will depend on the chemistry of the slag, hence the need to modify the slag chemistry. Two power settings were employed to induce higher temperatures and aggressive agitation. The results were interpreted by comparing how much Co and Fe was in the slag and alloy. TiO2 reduced the amount of Fe in the product alloy compared to when CaO and CaF2 were used. The change in power did not seem to have had a major effect on the recovery although the amount of material lost to flue dust was more at a higher power rate.

Jan 1, 2003