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By R. Cooper, K. De Wet, A. Janwong

"Horsehead Metal Products is a zinc refinery in Mooresboro, NC, treating crude Waelz oxide (WOX) to produce special high-grade zinc by a hydrometallurgical process comprising leaching, zinc solvent extraction/electrowinning, melting and casting and bleed treatment. Cadmium removal by zinc-dust cementation plays an essential role in the bleed treatment circuit to prevent cadmium buildup in the circuit. Silica, though present at a low level of approximately 0.3 percent in the WOX feed material, had a significant impact on the efficiency of cadmium cementation with zinc dust, most likely due to the passivation of zinc dust particles with silica gel. Solid/liquid separation efficiency by filter press was also affected. To identify the source of the silica issues, silica levels were mapped throughout the circuit, and adjustments, including using pregnant leach solution as the feed to cementation, and pH control in the WOX leaching and neutralization were introduced to mitigate the issues created by silica gel in the circuit. IntroductionLocated in Mooresboro, NC, Horsehead Metal Products Inc. is a hydrometallurgical zinc refinery processing Waelz oxide (WOX) to produce special high-grade (SHG) zinc. The flowsheet, known as the Modified Zincex process, consists of leaching, solvent extraction (SX), electrowinning (EW), melting and casting and bleed treatment (Fig. 1). Cadmium cementation, part of the bleed treatment process, provides an essential bleed of cadmium from the circuit, as metallic cement. The cadmium cementation circuit consists of agitated cementation reactors, a zinc dust addition system, filter presses, agitated purification (releach) reactors and a cadmium concentrate filter press.At the refinery, WOX pulp is leached at a controlled pH to achieve the maximum zinc extraction, according to the main reaction:"

Jan 1, 2016

By A. L. Miller, A. J. Chambers, P. R. Griffiths, D. A. Parks

"Diesel engines are one of the primary contributors to the presence of nano and ultrafine aerosols in ambient air and occupational environments. Exposure to diesel emissions has been shown to contribute to various adverse health outcomes of the pulmonary system and cardiovascular system. Currently diesel emissions in the workplace are monitored by way of collecting the aerosol onto filters, which are then sent to a lab for thermal-optical analysis using the NIOSH 5040 method, which measures elemental and organic carbon explicitly. This process can take days or even weeks, and workers can potentially be exposed to excessive levels of diesel particulate matter (DPM) before the problem is identified. To remedy this, researchers from the National Institute for Occupational Safety and Health (NIOSH) are seeking to develop a field-portable method for measuring elemental and organic carbon in DPM aerosols. In the current study, we investigated the use of Fourier transform mid-infrared (FT-IR) spectrometry, which lends itself more readily to implementation in a real-time system than do the thermal-optical analysis methods. We have demonstrated a method for measuring organic and elemental carbon in DPM for a broad range of organic carbon (OC) to elemental carbon (EC) ratios (from 50.3 to 0.8). The ability to handle a wide range of OC to EC ratios is critical given the evolving diesel technology. INTRODUCTION Respiratory illnesses are common in mining industry workers [1] and exposures to toxic aerosols such as DPM can result in serious respiratory illness [2]. Health studies show a correlation between workplace exposure to diesel exhaust and an increased risk of lung cancer [3-8]. The International Agency for Research on Cancer (IARC) has characterized diesel exhaust as a human carcinogen [9], and similar classifications have been made by the World Health Organization and the California Air Resource Board. A recent study [10] suggests that the risk of lung cancer is approximately three times greater for heavily exposed workers. When compared to other aerosols in the mine environment, the settling time of DPM is significantly longer than that of dust due to their small particle size (typically < 1 µm) [11]. Additionally, submicron particles (such as DPM) are deposited in the lungs much more efficiently than their larger counterparts such as dust [12]. Previous studies focusing on particle morphology [13] show that the largest mass contributor to lung disease in mining is elemental carbon, which provides a solid core onto which hydrocarbons are adsorbed. In accord with those findings the Mine Safety and Health Administration (MSHA) decided on submicron total carbon as a surrogate for monitoring diesel particulate matter in the mining environment."

Jan 1, 2018

By Yuri L. Nikolaev

The treatment of placer gold with fine gold, associated with gold-bearing sulfide minerals, heavy minerals and oxidized minerals such as manganowolframite (gubnerite) is not an easy task. In this case, this complex material cannot be treated using physical separation methods such as deep concentration and finishing, magnetic separation and solvent extraction. This technology is usually employed in gold washings finishing plant. The easiest way to recover precious metals in the form of an easy-to-sample saleable product is metallurgical treatment. This paper describes the application of pyrometallurgical processes with oxidative roasting, re-cleaning of cinders (if required) and ore-thermal smelting for producing gold bullion. Hydrometallurgical treatment of slags as an additional operation is recommended in order to maximize recovery of valuable metals. After this treatment, a barren leaching cake rich in PGM can be sold in the market. PGM can be collected as gold-silver alloy during smelting which allows the phase formation of polymetallic matte due to specific composition of fluxes. The PGM are then in the form of saleable gold bullions in the refinery.

Sep 1, 2012

The methods employed for the addition of uranium to steels and cast iron in the Physical Metallurgy Division are outlined. It has been found that the segregation of? uranium is a major problem in aluminum and/or silicon killed steels and that the cooling rate is important in al-lowing the segregate to settle to one area, which can subsequently be discarded. The unsegregated areas were found to be extremely low in total oxygen, acid insoluble aluminum (AizOg) and, in some cases, slightly lower in nitrogen. Uranium recoveries, based on analyses of the unsegregated areas, were quite constant, at about 45 per cent, regardless of the type of uranium master alloy used for the addition. No segregation of carbon, manganese, silicon, sulphur, phosphorous, chromium or copper was observed in these steels. In commercial heats, the recoveries ranged from 7 to? 29 per cent for ladle additions to oxygen converted steel. When the steel was fully deoxidized prior to the uranium addition, recoveries ranged from 49 to 66 per cent, regardless of the steelmaking process.

Jan 1, 1964

By David F. Gearhart, Khaled M. Mohamed

"Trusses are primarily used as passive roof supports in coal mines. They are constructed of three main parts: two grouted bolts installed at opposing forty-five degree angles into the roof so that they are anchored over the ribs and a cross member that ties the angled bolts together. There is also hardware used to assemble these components. The capacities of the angled bolts are typically 30 to 40 tons and the tensile capacity of the cross member is also 30 to 40 tons. Importantly, the direction of the immediate roof loading on the cross member is unlike the direction of the loading on the angled bolts. The load on the cross member is transverse to the longitudinal axis instead of along it, and therefore the cross member is loaded in the weakest direction.Previous tests conducted on truss systems applied loads such that the increasing tension in the two diagonal bolts increased the tension in the horizontal cross member, resulting in a stiff response. By contrast, if the load is applied directly to the cross member, which then transmits those forces to the diagonal bolts, it results in a much softer response.Based on this difference, laboratory tests to apply transverse loads and measure the vertical load capacity of three different types of cross members were conducted using the Mine Roof Simulator (MRS) located at the National Institute for Occupational Safety and Health (NIOSH) in Pittsburgh. The length of the samples was about 16 feet. Single-point load tests, with the load applied in the center of the specimen were conducted to verify the performance of the test arrangement and the finite element models. Double-point load tests, with a span of eight feet, were also conducted. This arrangement replicates the performance of the cross members with a distributed load. Both of these test arrangements were conducted on one-inch-diameter threaded steel bars and 0.7-inch-diameter cable and 0.6-inch-diameter cable cross members.For the single-point load configuration, the yield of the one-inch bar was nominally 22 kips of vertical load, achieved at 17 inches of deflection. For both sizes of the cable cross members, yield was not achieved even after 18 inches of deflection. Peak vertical loads were about 20 kips for the 0.7-inch cables and 15 kips for the 0.6- inch cables. For the double-point load configurations, the one-inch bar cross members yielded at 33 kips of vertical load and 10 inches of deflection. The 0.7-inch-diameter cable cross members broke strands at 30 kips of vertical load and 10 inches of closure, and the 0.6-inch-diameter cable cross members broke strands at 25 kips of vertical load and 10 inches of closure. Finite element models of each of the six different configurations were developed and show the variation of the vertical capacity of the cross members and the difference of the behavior of the bar versus the cables."

Jan 1, 2015

By R. Hammen

Processes are needed to rapidly and cost-effectively produce highly pure lithium salts for the rechargeable battery sector. Lithium purification is a chemical engineering challenge, due to the low concentration of lithium compared to sodium, potassium, magnesium, calcium, and transition metal ions commonly occurring in lithium brine resources. We describe a Solid Phase Extraction (SPE) process that rejects sodium and potassium, while binding lithium and other higher valent ions. Lithium is then harvested by selective displacement from the SPE column. The rapid equilibration kinetics of SPE composites enables these ion separations to occur in a small SPE column and in one column stage. The chemical parameters of the process are described.

By Faruk Oksuz, Dave Schiemann, Matt Trotter, Mike Padilla, Carmen Scalise, Miquel Sanchez

"The McCook Main Tunnel system consists of a 10-m (33-ft) finished diameter, 490-m (1,600-ft) long, hard rock tunnel constructed from a 27.5-m (90- ft) diameter and 92-m (300-ft) deep main gate and tunnel construction access shaft. The gate shaft houses six, high-head 4.4 m by 9 m (14.5 ft by 29.5 ft) wheel gates to be installed in the bifurcated and steellined section of the tunnel. The tunnel also includes portal and energy dissipation structures as it daylights into the reservoir.The construction of the tunnel system has been divided into two contracts. The gate and construction access shaft was completed in August 2011. The tunnel excavation and concrete and steel lining was completed in September 2014. The remaining and undergoing construction include the tunnel connections to the reservoir and the Mainstream Tunnel and installation of gates and hydraulic cylinders. This article focuses on the live connection of the McCook Main Tunnel to the Mainstream Tunnel that was initiated in November 2014 and will continue through the seasonal drier weather conditions in Chicago approximately from October through April. Chicago TARP systemThe MWRD has been addressing combined sewer overflows (CSO) and flooding in Chicagoland since the late 1960s and formally adopted the tunnel and reservoir plan in 1972 to protect the region’s most precious drinking water supply, Lake Michigan. Phase I of TARP, which included construction of 175 km (109 miles) of deep storage and conveyance tunnels with diameters up to 10 m (33 ft), was completed in 2006. In addition to protection of Lake Michigan from CSO discharges, Phase I resulted in substantial improvements in surface water quality as well as the quality of life for lake and riverfront communities in Chicago. Water quality improvements and flooding mitigation will be further enhanced as Phase II reservoirs are placed in service, including the three large reservoir systems, McCook, Thornton and Majewski (Fig. 1).The McCook Reservoir is the largest reservoir in the TARP system. Once completed, this $700-million reservoir facility will receive 38 billion L (10 billion gal) of CSO and flood water via the McCook Main Tunnel, which connects the TARP Mainstream Tunnel to the McCook Reservoir, and from distribution and Des Plaines inflow tunnels which will bring flow from the Des Plaines Tunnel of TARP."

Sep 1, 2016

By Takahiko Okura

Japanese non-ferrous industry introduced large-scale smelting plants along seashores for overseas concentrates with increasing demand of metals around 1970s. Although serious environmental pollution became obvious, with economic growth, the industry got rid of pollution by installing new processes and improving operation technologies. At present, over 99.8% of sulfur input to smelters is fixed as stable compounds. Through those decades Japan had steep rises of oil prices, sudden change of exchange rate, and inadequate treating charges, we were faced to consider the closure of smelters. The industry has survived by increasing productivity, saving energy and reducing manpower. Furthermore the industry made great effort to recycle valued metals from scraps and wastes for the resources-recycling society. Academic research also contributes to support these individual technologies. Thus the industry has fostered world-acclaimed technologies in terms of efficiency and energy conservation. This paper presents technology development and environmentally-benign sulfide smelting processes.

By Robert D. Irvine

"Enhanced concern for protection of the environment and attendant actions by environ-mental regulatory authorities in support of this concern are influencing, to varying degrees, the demand and supply of a range of industrial minerals in a number of jurisdictions. These influences take a variety of forms.In this paper, the author seeks to delineate certain broad trends which are occurring relative to industrial minerals and the environment and then, through a series of examples, to outline opportunities, developments, and impacts respecting a number of industrial minerals produced and consumed in Canada and the United States."

Jan 1, 1996

By Dr. Jagdish C. Agarwal

Kennecott Copper Corporation has developed a new hydrometallurgical process for extracting nickel, copper, cobalt and molybdenum from maganese nodules. This process (KCC Cuprion Process) utilizes a reduction leach operating at atmospheric pressure in the temperature range of 45 C to 50 C and has been successfully demonstrated in a continuous pilot plant processing 800 lbs of nodule ore per day. The chemistry, basic flow sheet and operating characteristics are presented and discussed.

Jan 1, 1978

By J. L. Coburn

The Huari-Huari ore body is located in Southern Bolivia, at an elevation of approximately 3,800 meters above sea level. The ore is a complex massive sulfide, slightly marmatitic sphalerite, in a fault fissure filled hypo- thermal vein in Paleozoic shales and quartzite-altered sandstone. The sphalerite has common associations with pyrite and quartz and is frequently intricately intergrown with stannite, chalcopyrite, and pyrrhotite. The sphalerite also contains numerous inclusions of pyrite, marcasite, galena, boulangerite, jamesonite, quartz, arsenopyrite, and cassiterite. A research program was undertaken to develop a flowsheet for the recovery of separate silver, zinc, and tin concentrates by selective flotation. Based on this experimental work and subsequent flowsheet development, engineering and construction of a 500 metric ton per day concentrator was undertaken. This paper describes the process that was developed for the Huari-Huari ore and the unique aspects of the Huari-Huari concentrator.

Jan 1, 1977

By C. T. Aimone-Martin

Time-domain reflectometry (TDR) laboratory experiments have been conducted using cylindrical salt cores from the Waste Isolation Pilot Project (WIPP). TDR has been used as an instrumentation technique to quantify the type and magnitude of rock mass deformation. Laboratory shear and tensile tests were conducted to calibrate measured deformation versus changes in reflected waveforms. Coaxial cables grouted within rock cores were crimped to produce localized reference defects. The evaluation of waveform characteristics produced during rock deformation experiments shows a good correlation of cable response to both shear and extension of the salt

Jan 1, 1994

By N. S. Dalal, B. Jafari, F. H. Y. Green, M. M. Suryan, V. Vallyathan

"Freshly ground and aged anthracite and bituminous coal samples were investigated by electron spin resonance (ESR) spectroscopy to detect the presence, concentration and reactivity of free radicals. Freshly ground anthracite coal produced greater concentration of free radicals than the bituminous coal, and the radical reactivity was also greater for the anthracite. The reactivity of the newly produced free radicals in the anthracite dust correlated with the dust's toxicity. Furthermore similar coal-based free radicals were detected in the lung tissue of autopsied coal miners, suggestive of persistent reactivity by the embedded coal dust leading to the progressive disease process. Results of the studies on the severity of coal workers' pneumoconiosis (CWP) and free radical concentration m lung tissue support this hypothesis.INTRODUCTIONCOAL WORKERS' PNEUMOCONIOSIS (CWP) has been an important topic of concern to miners, mining engineers, epidemiologists and medical researchers for decades. It is well known that the prevalence and severity of CWP differ markedly between different regions and mines despite comparable exposures to respirable dust (REISNER and RoBOCK, 1977; HURLEY et al., 1979). These variations in pathogenicity of coal mine dusts can only partially be explained by differences in the mineral composition and by rank of coal (CHRISTIAN and NELSON, 1978; CHRISTIAN et al., 1979; HATCH et al., 1980). Cytotoxity studies on mammalian cells do not correspond well with the human disease pattern (CHRISTIAN and NELSON, 1978; CHRISTIAN et al., 1979; HATCH et al.,1980; VALL YA THAN et al., 1988). For example, while epidemiological studies of coal miners (REISNER and ROBECK, 1977; HURLEY et al., 1979) indicate that the prevalence of CWP correlates roughly with the rank of coal, such correlation has not yet been established in biological studies, despite considerable effort (CHRISTIAN and NELSON, 1978; CHRISTIAN et al., 1979; HATCH et al., 1980). In order to help resolve this apparent paradox we have undertaken a systematic study to evaluate whether any correlation exists between the concentration of free radicals present in fresh or aged coal dusts from two well-characterized U.S. coals. This study was also prompted in part by observations reported in the literature that organic free radicals can be formed on the surface of freshly fractured coals (LEBEDEV et al., 1978; DULIBA and CLARKSON, 1984). In particular, ARTEMOV and REZNIK (1980) noted that the decay lifetimes and, hence, the reactivity of the organic free radicals formed on crushing Russian coals, .depended"

Jan 1, 1989

By C. Dragusanu, J. Sims, J. Connolly

Based on a statistical analysis of the categorical and numerical data from the established geological model, a geochemical classification of mineralization has been shown to be objective in nature and correlated to the envisioned metal extraction process. Multivariate chemical classification has the potential to discriminate within a combined response from different types of alteration and metal abundances. Distinct domains of chemical response determined by clustering analysis were used as a validating criterion for a geologically driven metallurgical testing program. The groups established are spatially linked to the geological process responsible for their genesis, providing clarity in geometallurgical and resource modeling.

Jan 1, 2011

By P. A. Christopher, R. H. Pinsent

"The Adanac molybdenum porphyry deposit near Atlin, in northwestern British Columbia, was discovered in 1905. It was explored extensively between 1967 and 1980.The deposit is within a complex, multi-phase, quartz monzonite stock that is a satellite of the post-accretionary, Surprise Lake Batholith. Biotite K-Ar dates range from 703 ± 2.4 Ma to 71.6 ± 2.1 Ma, indicating a Late Cretaceous age of emplacement.The deposit comprises an irregular-shaped ring or halo peripheral to a quartz monzonite porphyry dome, or ""cupola': The shape of the ring, and of a smal~ fine-grained quartz monzonite intrusion, and the presence of higher-grade mineralimtion on the eastern flank of the cupola, suggest partial control by a preminera/ structure. The deposit is truncated by a steep, northwesterly dipping, normal fault (Adera Fault) that down-dropped the northern half of the deposit by a minimum of 100 mThe deposit lacks strong zonal alteration but there are narrow envelopes of potassic alteration around some veins and local zones of intense wall-rock silicification. There is considerable retrograde alteration along postminera/ faults and fractures.Molybdenite occurs in veins and fractures, many of which are relatively flat-lying. They occur in all phases of quartz monzonite. Molybdenum is the only element of economic significance. There are vein and skarn occurrences with tungsten, tin, lead, zinc and precious metals peripheral to the deposit.In 1981, Placer Development Limited reported an ""undiluted mineable mineral reserve"" of 151 971 000 tonnes grading 0.063% Mo at a cutoff grade of 0.04% Mo and a strip ratio of 1.5:1."

Jan 1, 1995

By R. M. Lamya

A considerable part of gold encapsulated in some refractory sulphides can be dissolved during sulphide matrix decomposition in non-complexing aqueous media. This has been concluded from laboratory results of gold extraction from pyritic and arsenopyritic concentrate containing 172.8ppm Au, into 10% hydrochloric, sulphuric and nitric acids. The degree of sulphides decomposition in the non-oxidative acids limits the gold extraction from this specific concentrate to about 10%. In the case of nitric acid, the gold dissolution follows the rapid decomposition of sulphides, reaching 32 to 42% of extraction at almost total decomposition of the sulphidic minerals. Accumulation of gold in this acidic and non-complexing solution to several ppm was not affected by the soluble products of the sulphides decomposition. An attempt to explain this gold behaviour is undertaken and some practical implications are discussed. In the investigated concentrate the "soluble gold" is mostly associated with arsenopyrite. This is consistent with the latest findings of other authors that gold disseminated in arsenopyrite can occur as cation Au3+. In a comparative test the gold extraction into highly concentrated chloride solution, in the same oxidative conditions, amounted to 92.34%.

Jan 1, 1995

By L. Alagha, M. Khodakarami

"This work focuses on the extraction of rare earth metals (REE) from aqueous solutions using stimuli-responsive polymers. Various parameters affecting the adsorption capacity of the polymer, including pH, polymer concentration and REE concentration were studied. The interfacial behavior of REE in aqueous phase before and after polymer addition and the mechanism of the formation of metal-polymer complexes and their properties were investigated using UV/VIS spectroscopy. Results obtained would help to test the feasibility of employing stimuli responsive polymers in pre-concentration of rare earth elements associated with other elements in mineral aqueous streams prior to solvent extraction. The pre-concentration step would reduce the amount of organic solvents used for extraction and striping compared to conventional extraction processes. INTRODUCTION Rare earth elements (REEs) have become the foundation for several technologies and have been used extensively in many industries such as modern electronics, green energy, health care and transportation and defense [1-4]. As these industry sectors are growing, the global consumption of REEs is going to increase dramatically. The current global REEs demand is estimated to be 105,000 tons of rare earth oxides per annum with an expected annual growth of 5.6% [5-6]. Rare earth elements are produced from different sources (primary and secondary). China is considered as the largest producer of REE in the world, providing about 90% of the world’s mine production while the United States is second with 4% of the mine production [7]. High global demand for rare earth materials results in shortage of such materials in the near future. It should be considered that the term ‘‘rare’’ earth is not an accurate term, since they are abundant in some extent in the Earth’s crust, but are typically finely dispersed. Thus, nowadays looking for more efficient and cheaper methods for extraction, separation and purification of low concentrated REE ores and exploring secondary sources are essential. Rare earth materials are found in raw condition and require treatment that involves several processes, which can consume money and time. Recent improvements in extraction and recycling technology have made the extraction of rare earth elements from rare earth sources more feasible in terms of cost and time [8-10]. Physical and pyrometallurgical methods require high-energy and thus high costs. Moreover, due to environmental problems, environmental protection systems are required, and they are not as adaptable as chemical processes [11, 12]."

Jan 1, 2016

By Andrew Theobald, Peter Dare-Bryan, Trevor Byers

The use of advanced modelling techniques and the timing flexibility of electronic initiation systems allows for unprecedented control over blast outcomes as shown in several complex blasting problems experienced by the open pit operation Xstrata Ernest Henry Mine (EHM) in north-west Queensland, Australia.

Jan 1, 2010

By R. Singh, C. Gong, J. Chaudhry

"Metalorganic chemical vapor deposition (MOCVD) is an ideal technique for the deposition of conducting and non-conducting oxide based thin film materials. In this paper we have presented a study of photo assisted MOCVD for the low temperature deposition of a number of oxide based advanced materials. We have used incoherent light sources as the source of optical and thermal energy in our MOCVD system. The vacuum ultraviolet (VUV) and ultraviolet (UV) photons can enhance the surface reaction of the absorbed molecules through the perturbation of the electronic state of binding between the absorbed molecules and the solid surface. Unlike plasma process, no surface damage is expected and high quality materials have been deposited. At a given substrate temperature, the performance of deposited film depends on the lamp configuration.INTRODUCTIONMetalorganic chemical vapor deposition (MOCVD) has become the standard manufacturing technique for the deposition of large area thin films of compound semiconductors. l.(.w-cost, high crystalline quality, atomically clean and sharp interfaces, atomic layer epitaxy, high throughput rates and potential for direct writing are some attractive features of MOCVD. Due to a number of potential advantages mentioned above, MOCVD is considered as an ideal technique for the deposition of various electronic and optical materials for a wide variety of applications. Rapid isothermal processing based on incoherent radiation as the source of optical and thermal energy is emerging as the key low thermal budget (integral of processing time and temperature) processing technique for the fabrication of current and next generation of microelectronic and optoelectronic devices and circuits [1]. In this paper we have demonstrated that the design of the lamp assembly plays an important role in determining the properties of the materials deposited by RIP assisted MOCVD. We have studied the growth rates, structural properties and electrical properties of Y2O3/Si structure. At a given substrate temperature, best results are obtained for the lamp assembly that provides maximum number of VUV and UV photons."

Jan 1, 1994

By D. L. Babbitt, Sniezek

"This paper deals with the varions methods for the rapid Joading of unit trains which are being: used by ore procossors to move their product to dock-s1de storage facilities or their ultimate customer. Some of the techniques that have been used include (1) volumetrie loading, both in motion and static, (2) batch weighing into moving cars and (3) batch weighing into cars that have been stopped. Particular emphasis shall be placed on the two systems now in use at the Adams Mine facility of Jones and Laughlin Steel Corporation and at Cliffs of Canada's Sherman Mine. Typical ""turnaround"" times, loading rates, types of cars, weighing accuracies, material handling concepts and maintenance considerations shall be discussed."

Jan 1, 1969