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The solution mining review did not arrive in time for publication in the May issue. The term solution mining is commonly used to refer to heap leaching, dump leaching, in situ mining and bore hole slurry mining technologies. The US Bureau of Mines is continuing with research in these areas. Commercial application of these technologies is progressing. There is an ongoing cooperative research project between the Bureau of Mines and the Santa Cruz Joint Venture to evaluate in situ copper mining at a field site near Casa Grande, AZ. The project is currently in the environmental permitting stage. The Bureau is preparing an environmental assessment for the project as part of the National Environmental Policy Act. The Bureau is also continuing with laboratory experiments to study the leaching characteristics of atacamite ore from the field test site, as

Jan 1, 1993

By Ann G. Kim

Fires that occur in abandoned coal mines, waste banks, and in coal outcrops constitute a serious health, safety, and environmental hazard. Toxic fumes, the deterioration of air quality, and subsidence constitute the greatest hazards from these fires. Although tires on abandoned mined land (AML) occur in every coal-producing state, the severity of the problem varies. Methods to extinguish or control AML fires, including excavation, fire barriers, and sealing, are generally expensive and have a relatively low probability of success This U.S. Bureau of Mines report includes information from a variety of sources, i.e., agencies of the Federal Government, State agencies, research reports, conference proceedings, product information, and technical literature. This information has been collated into a comprehensive discussion of AML fire problems. Data on past fire control projects and on the estimated extent of the current problem have been compiled. Factors affecting the occurrence, propagation, and extinguishment of AML fires are discussed. Conventional fire control methods are described, and their probable effectiveness is evaluated. Information on the hazards of AML fires and safety considerations is included. The status of current technology, recent improvements in fire control methods, and areas of current research are discussed.

Jan 1, 1993

By Errol D. Sehnke

This U.S. Bureau of Mines report provides detailed information on worldwide alumina production capacity by plant and country. The information was compiled from a variety of domestic and international sources and was based on information available to the Bureau through December 31, 1993. Capacity data represent announced installed and planned capacities and do not necessarily reflect a Bureau of Mines judgment of actual plant operating levels or timing of planned expansions, The year-end capacity is the ?nameplate" capacity or estimated production capacity, whichever is larger.

Jan 1, 1993

By D. M. Larsen

Since start-up in 1985, the Cannon Mine has produced and shipped a 170-g/ton (5 oz/ton) gold flotation concentrate to various smelters for gold and silver recovery. Several processes have been investigated to economically produce done' at the mine site from the refractory concentrate. This paper describes laboratory and pilot scale test work used in the process design and engineering. feasibility study of a 73-t/d (80 stpd) pressure oxidation and carbon-in-leach (CIL) facility. The designed pressure oxidation circuit utilizes a series of verti¬cal autoclave units operating at 170°C (338F) and 1.4 MPa (200 psig). Projected operating costs are discussed.

Jan 1, 1993

By J. H. Corrigan

A series of six papers describing the Falconbridge Dominicana Ferronickel project were presented at the International Laterite Symposium held as a joint project of TMS-AIME in February 1979 at New Orleans. A review of the ore mineralogy, as well as. the processing and environmental practices as they exist today at Falcondo with emphasis on modifications put into practice since 1979 are presented in two papers: Part I.- Mineralogy and Ore Dressing E.W. Lithgow - General Superintendent ? Mines Falconbridge Dominicana, C. por A. Bonao, Dominican Republic Commercial volumes of nickeliferous laterite ores overlie part of a 90 km long belt of peridotites in central Dominican Republic. Protores are serpentinized harzburgites and dunites, with lesser serpentinite. The ore mineralogy consists mostly of goethite, serpentine-group minerals, quartz and poorly crystallized, X- ray amorphous materials. Minor constituents are hematite, gibsite, olivine and enstatite. In the Ore Dressing plant, the mine feed is subjected initially to proper sizing and blending to produce a homogenized mix. Subsequent drying and upgrading, by selective crushing and screening of rock kagments through a Barmac circuit, complete preparation of the ore for pyrometallurgical processing. Part II.- Pyrometallurgy, Fuel and Power Generation J.H. Comgan - Manager ? Production Falconbridge Dominicana, C. por A. Bonao, Dominican Republic Falcondo's energy requirements are based on oil which is refined on site to provide distillate to carry out drying and selective reduction of the nickeliferous ore in the shaft furnaces, plus bunker oil to produce electrical power for process melting, refining and ancillary use. The dryer product at 1.68% Ni is briquetted and passed counter current to hot reducing gas in 12 vertical shaft furnaces. The hot calcine discharge is melted in two high power electric furnaces at very high secondary voltage. The crude ferronickel is ladle refined and cast as 15 kg ingots or 125 gm ferrocones.

Jan 1, 1993

By Richard A. Leiby

The recycling of lead-acid batteries in the United States has become a challenge as to how to balance ever increasing environmental regulation and cost with efficient operations. East Penn's captive secondary lead smelter has developed into a recycling facility producing lead, polypropylene, sulfuric acid, ammonium bisulfite, and non-hazardous discard slag. The emphasis has been to design a facility to comply with environmental regulations, to eliminate wastes, and to produce products, while at the same time, continuing to supply the company's battery manufacturing raw material needs.

Jan 1, 1993

By Yu. A. Polozov, V. A. Lagunov, O. Yu. Lushinkova, Yu. I. Svirskiy, Eh. Ya. Kipko, Roy A. Williams

6.1 PRINCIPLES OF PLANNING GROUTING OPERATIONS FOR SHAFTS, DRIFTS AND TUNNELS The planning of integrated grouting of vertical, inclined or horizontal underground workings in saturated, fractured rock includes the following phases: 1. Planning for the collection and analysis of geological information concerning the characteristics of the struc¬tural deformation(s) that produced the details of the frac¬ture system being studied. 2. Planning for the acquisition of initial hydrogeological information produced by the flowmetric and hydrody¬namic investigations (described in Chapters 2 and 3). 3. Computing the initial engineering calculations of the ex¬pected or planned dimensions of the isolation curtains for each water-producing stratum (fracture zone) and the expected areal spreading pattern of the grout in each of these water-producing horizons. The selection of the lo¬cations, the initial optimal number of holes and the vol¬ume of grout needed to create each isolation curtain also are included in this phase. 4. The selection or development of a grout formula for the specific hydrogeological conditions that exist at the site. 5. Identification of a resource (deposit) required to produce the grouting clay. The planning of grouting operations must be supported by the acquisition of all necessary initial data, which in¬cludes: 1. The geographic location and administrative responsibil¬ity (ownership and regulatory constraints) of the mineral deposit and any peculiar features of the area where ex¬cavation of the underground workings is planned. The surface relief, the hydrographic network of the region, and the local climatic conditions must be evaluated prior to planning for buildings and waste discharges if any. 2. The economic status of the region, the available trans¬portation, the nature of the energy base, the water and heat supply sources, the location of construction mate¬rials suitable for making the grout all must be deter¬mined. 3. The geological and hydrogeological characterization of the work site must be accomplished. 4. The technical features of the shaft(s) and underground works must be characterized. 5. The organization's principal initial design plan features and the construction sequence of all buildings and struc¬tures must be developed. These must be correlated with the organization and schedule for excavating the under¬ground works. The technical characterization of a shaft or of other un¬derground workings must contain information about the purpose of the workings, the design depth, the planned excavation procedures along with cross-sections, and the parameters of the lining, if a lining is required. The geology of the section to be penetrated must include geological data obtained from existing exploration activities at the mineral deposit and conclusions about the shaft ex¬cavation conditions obtained from drilling technical moni¬toring holes and exploration drillholes. The interpreted stratigraphic regime, including the thickness, strike and dip of each stratum, must be shown in cross-section. The tec¬tonics, including all geologic structures, must be presented by cross-sections. The bedding orientations must be used to identify anticlines, synclines, monoclines and faults. The lithologic composition and the drillability of the rock com¬prising the section must be examined. The character of the rock's fracture pattern must be presented. Finally the per¬meability, porosity and storage characteristics of each aqui¬fer must be determined by in situ hydraulic property testing (injection tests or pumping tests, as described in Chapter 3). The fracture pattern of the indurated rock is presented in reports derived from geo-exploration borehole studies and from studies of outcrops on the surface and in all nearby underground workings. The extent of each fracture zone is mapped in three dimensions. The distribution of fracture apertures, the nature of the fractures according to each litho¬logic stratum, and the relationship of bedding planes to each fracture system are all determined. Acoustic logs, downhole cameras, caliper logs, oriented core, and any other appro¬priate geophysical tools available are used to construct the data base for this purpose. The hydrogeological characterization of the geologic section to be penetrated by the workings is based on the analysis of hydrogeological data collected during the drill¬ing and testing of technical monitoring holes and from in¬formation on ground water inflow collected during the ex¬cavation of nearby underground workings, if such workings exist. The hydrogeologic characterization must contain the following information: 1. The identification of all aquifers, their thicknesses and their locations in the section, 2. The distribution of hydrostatic head in the ground water in three dimensions, 3. The coefficient of saturated hydraulic conductivity (per¬ meability) of each aquifer, 4. The porosity and storativity of each aquifer, and 5. The projected rate of water inflow into the shaft, drift or tunnel for each aquifer prior to grouting. This step is used to identify the zones to be grouted.

Jan 1, 1993

By Chris Mark

Successful longwall mining requires a stable tailgate entry. Gate entry performance is influenced by a number of geotechnical and design factors, including: - Pillar size and pillar loading; - Roof quality; - Floor quality; - Entry width; and, - Artificial support (primary and secondary). This paper describes a comprehensive, practical, design methodology, based on statistical analysis of a nationwide data base of longwall ground control experience. Geotechnical surveys were conducted at 44 U.S. longwall mines, and underground observations of site geology, entry conditions, and support design were recorded at each mine. The observations were combined with discussions with mine personnel to identify 69 longwall gate entry designs as satisfactory, unsatisfactory, or borderline. Only conventional longwall designs, in which the pillars are expected to carry the full abutment loads, were included in the data base. Designs which employed yield pillars only were excluded. The case histories were characterized using five descriptive parameters. Pillar design was described by the Analysis of Longwall Pillar Stability Factor (ALPS SF). A major new contribution is the Coal Mine Roof Rating (CMRR), a rock mass classification system that quantifies the structural competence of bolted mine roof. Other quantitative measures were developed for primary support, secondary support, and entry width. Multivariate statistical analyses indicated that in 84% of the case histories the tailgate performance could be correctly predicted using just ALPS and the CMRR. Most of the misclassified cases fell within a very narrow borderline region. The analyses also confirmed that primary support and gate entry width are essential elements in successful gate entry design. The relative importance of the floor and of secondary support could not be determined from the data. Based on these results, a simple equation was developed to guide the design of longwall pillars and gate entries: ALPS SF,, = 1.76 - 0.014 CMRR Where: ALPS SF, = ALPS SF suggested for design. Guidelines for entry width and primary support density, as related to the CMRR, are also provided.

Jan 1, 1993

By J. F. Childs

Montana consists of an Archean crystalline basement overlain by Proterozoic through Cenozoic sedimentary rocks. Igneous rocks range in age from Archean to Pleistocene; the most voluminous magmatism and volcanism occurred during the Late Cretaceous and early Tertiary. The state can be divided into three tectonic provinces whose deformational styles are a function of different bedrock responses to Late Cretaceous-early Eocene compressional tectonism. Several long-lived structural zones have been periodically reactivated since the Precambrian, and were the sites of recurrent magmatism. Regional gold distributions are strongly influenced by the tectonic provinces and structural zones. Lode gold systems in Montana occur in diverse geologic settings resulting from a complex interaction between structure, magmatism, and sedimentary depositional processes. Reserves or resources are known for 19 significant lode gold systems, and additional unannounced discoveries have been made recently. Mineralization ranges in age from Archean to Tertiary. The influence of long-lived structures is apparent at both the regional and deposit scale, and in some cases multiple mineralizing events have been superimposed upon one another. Most Montana gold systems have a direct spatial and genetic association with Late Cretaceous through Oligocene igneous rocks. However, the importance of sedimentary rocks and associated depositional processes should not be underestimated.

Jan 1, 1993

By A. G. Fonseca

The effects of coal cleaning, coal combustion and flue gas particulate removal systems on the partitioning of 12 trace elements were investigated. This study was prepared to help document the fate of trace elements in modern coal preparation plants and coal-fired utility boilers. The coal cleaning data were obtained from several coal preparation plant operations. The CONSOL 1. 5 MM Btu/hr pilot combustion and electrostatic precipitator (particulate removal system) test facility was used to develop the combustion systems data. A comparison with the very limited amount of published data from utility boilers is presented.

Jan 1, 1993

By I. Gaballah

Decontamination of synthetic solutions of copper acetate, chloride, nitrate and sulfate containing 10, 100 and 1000 ppm of copper, using chemically treated barks has been studied. Metal percent removal from solutions depends on the pH and the initial concentration and to some extent on the salt used. It varies from 40 to 99 % of the solution initial metallic ion's content. The maximum retention capacity of the treated bark varies from 31 to 43 mg of Cu per gram of dry modified bark. Bark loaded with copper had been analysed by Scanning Electron Microscopy and lnfra Red spectroscopy. Cu is uniformally distributed in the bulk of the bark. No copper segregation is observed. It seems that copper is bound to the acidic sites of the bark. Anions are not detected on the copper loaded bark neither with the SEM or with the IR spectroscopy.

Jan 1, 1993

By N. D. Jagger

In order to maximize the benefits obtained from flocculating agents when used as settling aids in high rate and conventional thickeners, it is often necessary to dilute the thickener feed prior to flocculant addition. In some cases, no flocculation at all is possible unless dilution water is used. The most common method of diluting thickener feed has been to recirculate some of the thickener overflow by means of a centrifugal pumping system. This represents a significant capital and operating cost. Supaflo Technologies of Australia has developed and patented an internal recirculation method known as Auto Dilution (or "Autodil") which is based on the principle that an hydraulic head differential exists between the inside and outside of the feedwell because of the higher S. G. of the pulp inside the feedwell, By installing non-return ports in the feedwell wall at the appropriate level, supernatant solution flows into the feedwell at a calculated rate and dilutes the feed without any need for external recirculation of overflow.

Jan 1, 1993

By R. W. Waytulonis

This paper is an update of the activities of the U.S. Bureau of Mines, other government agencies, and the automotive and truck industry concerning diesel emission control. Enacted and proposed regulations from the U.S. Mine Safety and Health Administration (MSHA) and developments in diesel emission control are presented in terms of their impact on underground coal, metal, and nonmetal mines. Mine air quality regulations proposed by MSHA may require the underground mining industry to comply with new standards. Some mines may be required to take additional actions to meet new diesel particulate and lower nitrogen dioxide exposure standards; however, the mining industry is in a position to benefit from emission controls developed for the on-highway diesel engine market. The U.S. Environmental Protection Agency (EPA) has enacted regulations to reduce emissions from on-highway diesel trucks and buses. Engine manufacturers have responded by developing cleaner burning engines. Fuel producers have responded by providing cleaner burning reformulated diesel fuel, and exhaust aftertreatment devices have been developed to provide additional emissions reductions. Bureau research and development projects seek to determine the advantages of using modern engines and fuels, and to evaluate the efficacy of new exhaust control devices on mining machines. It appears that the diesel engine will continue to be a practical power source for use in confined environments because no other available power source is as mobile and efficient.

Jan 1, 1993

The Bureau of Mines has studied 260 underground coal mine fires which occurred from 1970 through 1989. Every fire had the capacity to be hazardous to life and property, however upon closer examination some were found to be inherently more dangerous than others. Our research involved reviewing and recording specific information contained in published Mine Safety and Health Administration fire accident reports. The objective was to determine if degrees of hazard relative to fire source or location could be construed from information contained in the reports. We specifically looked at the propensity for fires to cause injuries and fatalities as well as the need to seal the area in order to extinguish the fire. Relative to all underground locations, this review found that fires occurring in main haulage-ways were most likely to cause injuries and fatalities as well as require sealing of at least the immediate area to extinguish.

Jan 1, 1993

By Robert A. Jankowski

The U.S. Bureau of Mines, in cooperation with the Mine Safety and Health Administration (MSHA) and the mining industry, has identified and demonstrated the effectiveness of several improved face ventilation techniques for longwall mining systems. These include the following: identifying improved techniques for measuring face ventilation parameters on longwall sections, installing curtains at the intake end of the longwall face to maximize usage of the primary airflow, identifying optimum face airflow rates for maximizing dilution effects, and coursing the primary face intake from tailgate to headgate to minimize outby airflow contamination. Application of these techniques throughout the mining industry should reduce the health hazard associated with excessive exposure to respirable coal mine dust.

Jan 1, 1993

By C. J. Newman

Production levels at the Kidd Creek copper operation increased during the 1980's by expansion of both the smelter and refinery and by major modifications to equipment which was causing bottlenecks. As a result, there was a significant reduction in the unit cost, some manpower reductions and hence a significant increase in productivity. In the last two or three years, there have been no major expansion projects leading to unit cost reductions and yet these have still been attained. This has been achieved by the development and implementation of various techniques designed to maximize the inherent potential of the operators and maintenance employees. This paper will initially describe the operation but will then place emphasis on employee involvement through such methods as idea awards, incentive schemes, loss control and continuous improvement programs. Organizational changes are discussed, particularly with reference to changes from the traditional operator role to one which encompasses maintenance skills and to cross-training of maintenance employees into multi-discipline fields. The effect of these changes are discussed by a review of the salient plant parameters of safety, production levels, cost and quality.

Jan 1, 1993

A major high grade zinc deposit, Dugald River has fine-grained and complex mineral associations which provide considerable metallurgical challenges for both mineral dressers and downstream processors. A long history of metallurgical testing focusing on mineralogy and flotation concentrate production has shown that while separate lead and zinc concentrates can be produced at saleable grades, high levels of iron, and particularly manganese, are likely to place constraints on the marketing of zinc concentrate produced from deeper zones where coincidentally lode development is at its maximum. Testwork has focused on characterising the flotation response of ore types ranging from banded and stringer sulphides to brecciated ores in a variety of sulphide matrices. A high level of variability with lower than expected metal recoveries has been indicated across some of the higher grade brecciated ores. However, the dominant slatey breccia has generally provided the best results. Heavy media preconcentration testwork has been moderately encouraging and at this stage, although value adding downstream of concentrate production on-site is not seen as an economic option processing developments are being monitored on a broad front. Providing satisfactory means can be developed for handling manganese during downstream processing of the concentrate, it is not difficult to see a world-class operation emerging from the resource in the medium-term Future.

Jan 1, 1993

By Bret E. Leisemann

The geomechanical environment in which highwall mining must operate represents a hybrid between surface and underground operations. Mine design must take into consideration the complexities associated with unsupported spans, pillars with extreme aspect ratios and the instability related to the interaction between coal extraction and the highwall stability. The rock mass adjacent to the highwall, and for a significant distance in, is affected by lateral stress relief and blast damage. This paper describes a rigorous site investigation program aimed at providing some of the input parameters for the design of highwall mining layouts at the Moura Mine and focuses upon defining the nature and extent of the relaxed zone behind the highwall. The combination of borehole imaging and C factor analysis allows delineation of blast damage and relaxation of the rock mass immediately adjacent to the highwall excavation, as well as the more subtle relaxation effects deeper into the rock mass. This has led to the formulation of a proposed geomechanical model for the relaxed zone for direct input into highwall instability analysis and mine design.

Jan 1, 1993

By Ronald T. Mayerle

In-1992, the U.S. Bureau of Mines conducted a mineral investigation of the Anderson Mountain study area, including RARE II area 4-942, in Lemhi County, Idaho. The 7,340-ha study area lies within the Salmon National Forest about one kilometer north of the old mining town of Gibbonsville (pop.: 100). The eastern boundary of the study area is formed by the crest of the Bitterroot Range. The crest also serves as the continental Divide, and as the border between Idaho and Montana. The study area lies within the Gibbonsville Mining District, an important past producer of gold from lode and placer deposits. Since the 1870's, several hundred claims for both types have been located in the study area. Thirty-six current (1992) lode claims and two patented claim groups (one lode and one placer) are wholly or partially in the study area. No placer claims are current. In all, twenty-seven lode and five placer properties in and adjacent to the study area were investigated. Workings on the properties included 2 caved shafts; 36 caved adits; 8 open adits; 120 small pits, cuts, and trenches; and 4 large dozed cuts.

Jan 1, 1993

By W. K. Collins

Engineered Scavenger Compounds (ESCs), developed by the U.S. Bureau of Mines, are a novel class of compounds that can selectively recover a desired element from a solid or molten alloy. Lithium titanate (Li2Ti3O7 or L'20-3T'02) is being used as an ESC to recover lithium (Li) from Aluminum-Lithium (Al-Li) alloys. X-ray diffraction measurements have shown that lithium titanate undergoes a phase change from an orthorhombic structure to a hexagonal structure. This change is due to the incorporation of Li in the matrix of the material and the effect of temperature. Although both are metastable, the hexagonal phase that forms during the scavenging of Li from Al-Li alloys appears to be the more stable phase. Recovering Li from the ESC by electrodeposition does not cause the structure to revert to the orthorhombic phase. Both the orthorhombic and the hexagonal structures of Li2Ti3O7 have similar scavenging capacities for Li. This paper proposes a new mechanism for the phase transformation.

Jan 1, 1993