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By J J. McNee and, J Crusius, T F. Pedersen

The use of water covers is a globally-applied method for minimising acid rock drainage (ARD) and metal leaching. Although the subaqueous disposal of potentially acid-generating materials has been shown to effectively limit ARD, under certain scenarios, metal remobilisation can occur at circum-neutral pH. The following paper presents data from four case studies in which metal mobility from submerged mine waste resulted in degradation to water quality in the overlying water cover. Subcentimetre resolution profiling of dissolved constituents across the tailings-water interface (dialysis arrays), in conjunction with mineralogical information, were used to elucidate the controls governing metal mobility. The data illustrate four pathways of metal remobilisation, including: the release of zinc via the oxidative remineralisation of metal-rich organics at the tailings-water interface; enhanced remobilisation of arsenic as a result of anthropogenic eutrophication; the release of copper resulting from the pH-driven dissolution of treatment sludges; and the release of radium from uranium mill tailings due to the dissolution of radiobarite [(Ra,Ba)SO4] by sulfate-reducing bacteria. The results highlight the conclusion that the chemical stability of submerged tailings reflects both: the solid-phase characteristics of the tailings material; and the physical, chemical and biological characteristics of the depositional environment. In particular, the data illustrate that rigorous characterisation of both the waste solids and receiving environment must be performed in order to assess their compatibility. The results have relevance to the management of tailings repositories including constructed impoundments, pit lakes and natural lakes.

Jan 1, 2003

By R. F. Hüttl

World-wide Germany is the leading lignite mining nation. Most of the lignite is produced in opencast operations. However, opencast mining causes enormous impacts on natural ecosystems and even on entire landscapes. The extensive production of lignite particularly in eastern Germany results in large devastated areas, which so far have been reclaimed only to some part. For the restoration of the post-mining area of more than 80,000 ha the major land use option is the reestablishment of forest ecosystems. However, adverse site conditions of the post-mining landscape such as extreme soil acidification and salt concentrations call for specific recultivation practices. Therefore, after the German reunification new reclamation and reforestation concepts have been developed for these brown coal areas of eastern Germany by the Collaborative Research Center (SFB 565) at the Brandenburg University of Technology at Cottbus (Germany). As a case study our comprehensive investigations into forest ecosystem development on terra nova in the Lusatian lignite mining district, south-east of Berlin, will be presented.

Jan 1, 2003

By Yoshihiko Maeda

It is said that the 21 st century will be an era of the remedy of the global environment. In order to reserve natural resources for the future and to avoid the dispersion of heavy metals after usage and to avoid pollution problems, it is extremely important to recycle heavy metals as much as possible by reasonable recovery procedures. The nonferrous metal industry is expected to play a important role in the recycling of heavy metals that are originally their products. From the depressed metal price experienced in Japan in 1980th due to the sudden change in current exchange rate between US dollar and Japanese yen, one of major nonferrous metal company, Dowa Mining, has diversified its business area not only to the so-called down stream, but also to the environmental business including metal recycling, industrial waste treatment and soil remediation by utilizing technologies and facilities once used or still used for mining and smelting of copper, zinc, lead and precious metals. In this paper some of these applications will be presented.

Jan 1, 2003

By P Waters, S Miller

BHPBilliton operates the Mt Whaleback Mine located in the semi-arid Pilbara Region of Western Australia. Approximately 200 Mt of net acid generating (NAG) material still remains to be mined. Acid Rock Drainage (ARD) was first identified at the site in 1995 following cyclonic storms. This resulted in the development of strategies that have allowed the mine to successfully manage ARD whilst continuing to operate. BHPBilliton Iron Ore is working toward prevention of ARD in its operations, however, historical practices have left residual areas that must be considered. Three significant sources of ARD have been identified that must be managed: stormwater run-off from exposed pyritic shales in pit surfaces; basal flows beneath overburden storage areas following rainfall events; and contaminated water from pit dewatering. The mine contains all ARD water onsite. This is achieved by: storage of all affected water in the ARD dam; evaporation of affected water from the ARD dam and the adjacent evaporation ponds; pumping from upstream dams to prevent stormwater from being affected; and emergency storage and treatment in-pit as a contingency. The site ARD management strategy is approved by senior management and endorsed by State Government regulatory authorities and relevant external stakeholders. Additional strategies are also under evaluation to effect long-term closure of the operation. Record rainfalls from 1998 - 2001 have tested the capabilities of the ARD strategy and management plan. Learnings from these events, coupled with recommendations from an extensive technical audit in 2000, have been incorporated into the strategy for ARD management. This paper presents the strategy and an overview of the ARD management plan that can be considered and applied by other affected sites in the management of ARD.

Jan 1, 2003

By P. James, L. J. Steiner, F. Turin

NIOSH researchers and an industry partner conducted an investigation to study the effectiveness of ergonomic interventions in mining. The study required a significant commitment of time and resources from the cooperating site, Bridger Coal Company. This paper focuses on some of the challenges faced by the researchers and their cooperator. Challenges included the need to redesign methods of identifying and prioritizing injuries, and the need to train the workforce in ergonomics while still maintaining progress and interest in the process. The authors discuss some practical interventions implemented by Bridger Coal to date, and discuss future research implications brought about by PacifiCorp’s Generation Business Unit, who monitored the project to determine whether an employee-owned ergonomic process could be implemented throughout their operations.

Jan 1, 2003

By D. Dunbar

The flooding of open pits is now receiving considerable attention from the mining industry as an option that may minimize environmental impacts, particularly when anoxia in pit-lake deep waters can effectively eliminate oxidation of pit-wall sulfides. This paper describes a state-of-the-art, coupled physical-geochemical pit-lake model. The model is used to verify that a controlled, two-stage infilling of the open pit at the Kori Kollo gold mine, southeast of La Paz, Bolivia, would result in a cost-effective, environmentally responsible closure strategy. By filling the pit initially with highly saline surface waters and naturally saline deep groundwater and then capping with fresh river water, a very stable and strongly stratified pit lake will be developed. In addition, the stratification will result in the isolation of metal-rich saline bottom waters from surface waters of good quality. Results of this model provide defensible predictions of the physical stability and evolution of water quality in the Kori Kollo pit lake over time. The model results indicate that anoxic conditions will develop below the fresh-saline water boundary within one to two years, followed by the rapid onset of sulfate-reducing conditions in the bottom waters. Hydrogen sulfide produced by sulfate reduction will readily react with dissolved metals to form highly insoluble metal sulfides. The process results in the gradual removal of metals from the water column and the concomitant improvement of water quality over time. A notable benefit of this strategy is that it can be fully integrated with other mine site closure options as well as future environmental-management strategies. The proposed plan allows for the safe isolation of saline waters, the potential for passive treatment in anoxic bottom waters of ARD seepage from other mine site operations, should they arise, and a repository for future reactive wastes that could be effectively isolated in a physically and chemically stable environment.

Jan 1, 2003

By J. C. Yingling, R. J. Sweigard, P. W. Conrad, J. M. Ringe, D. H. Graves

Much of the land reclaimed since enactment of the 1977 Surface Mining Control and Reclamation Act is overcompacted. Research has shown that excessive compaction in replaced growing media is detrimental to the establishment of trees. If trees are to be grown on reclaimed surface mined sites, something must be done to alleviate this excessive compaction. Dry bulk density and penetration resistance are two soil parameters that can be used to indicate the level of compaction in reclaimed growing media. The University of Kentucky developed test cells on reclaimed areas at a surface mine in eastern Kentucky to determine the impact of tillage (ripping) on soil compaction and tree survival rate. The ripping methods being evaluated include shallow tillage using conventional farm equipment and deep tillage using a dozer with a ripping arm. Each test cell was planted with various species of trees, and for the first two years of tree growth, data were collected at these test cells for soil dry bulk density, penetration depth and resistance, and survival rate of trees. These data were statistically correlated to determine how ripping affects the relationship between soil compaction and tree survival rate.

Jan 1, 2003

Transport Canada (Federal Government) constructed the Halifax International Airport (HIA) near Halifax, Nova Scotia, Canada in the late-1950s. Site location criteria were primarily; direct access to the city and a raised flat topography. Unfortunately, the site chosen was located on shallow Meguma group pyritic slate bedrock. In 1982, during the construction of an airport taxiway, it became very apparent that acidic run-off from excavated bedrock at the site was having a negative impact on adjacent aquatic habitat. The ensuing 20 years involved many efforts to rectify the acidic drainage problem with mixed results. Some of the techniques which have been implemented at HIA to address the acid rock drainage (ARD) issue include: dry covers, wet covers, wetlands, electrochemical treatment, open limestone channels, limestone gravel polishing beds, agricultural limestone application, and two hydrated lime [Ca(OH)2] addition treatment plants, the first producing low density sludge and the new one that creates high-density sludge. Based on over 20 years of water quality monitoring data it is apparent that only certain acid drainage mitigation methods have been effective at HIA. In 2000 when the Halifax International Airport Authority (the Authority) took control of the operation and management of the airport, including the ARD issue, it was decided to construct a modern, highdensity sludge, hydrated lime treatment system. This new $CAN 7 million system is now in operation and is achieving compliance with water quality guidelines. Due to high operating cost, a review of methods to optimise the system is being carried out. The HIA ARD problem, though minor by comparison to most mine sites, has provided unique challenges and may provide valuable insights into this urgent environmental and financial issue.

Jan 1, 2003

By Syd Peng

It is necessary to fully understand roof geological features in order to design a proper roof support system for underground coal mines. These geological features include: rock type, rock strength. rock layer interfaces, voids, cracks, and bed separations. Traditionally, engineers have relied heavily on the use of surface borehole log data to identify geological features. Since surface boreholes very expensive to be drilled in close spacing, log data are often insufficient to provide detailed information on the roof geology. Recent advances in control technology have made a large amount of roof bolter drilling data available to mine personnel. These data can be obtained during normal roof bolt installation cycle with little or no interruption in mining operations. This research project has developed several methods to identify geological features in a mine roof from measured drilling parameters. Power trend line analysis can be used to locate discontinuities and interfaces in mine roof. Power averaging can be applied to determine the relative strength of roof strata. Thrust trend line analysis can be used to locate fractures in mine roof. The results of these methods are combined to produce a mapped roof geology In a production environment, manually interpreting and managing collected drilling parameters is not practical since hundreds of holes will be drilled during a production day. A new software package, MRGIS, has been developed to allow mine engineers to make use of the large amount of roof drilling parameters for roof support design. An actual underground test site is presented to demonstrate the analysis and display capabilities of MRGIS.

Jan 1, 2003

By S. Z. Pethö, H. Yilmaz

South Deep Mine is currently undertaking numerous voidfilling projects using low strength aerated cement products. Representative samples from one such site, were taken and tested for the load deformation behaviour under uniaxial loading conditions. The process of sample collection, laboratory preparation and testing are explained in detail. The results of testing were analyzed and the critical aspects pointed out as a design consideration to be implemented as part of the quality control and assurance program. Design aspects and underground application of the aerated cement product are discussed for the particular site on 58 level SV1. A simple instrumentation has been designed and installed to enable monitoring of any future movements in this area. A quality control and assurance process has been formulated enabling all aspects of the support installation in this excavation to be signed off.

Jan 1, 2003

By T. A. Grammatikopoulos, B. Vasily, A. H. Clark

"The St. Lawrence deposit is a large wollastonite skarn (ca. 9 Mt @ 41.3% wollastonite) adjoining the gabbroic-to-syenitic Leo Lake pluton in the granulite facies Frontenac Terrane of the Grenvillian Central Metasedimentary Belt. It occurs within a horseshoeshaped horizon of quartzite, open to the east. The skarn extends over 1.2 km2, and comprises wollastonite-dominant, wollastonite-clinopyroxene, and diverse quartz-feldspar-sulphide (-titanite) layers, interbanded with, and strongly folded within, the quartzite. As in the world-class wollastonite deposits of the Willsboro district, New York, no carbonate protolith is preserved, and calcite is a negligible constituent of the mineralized zones. Wollastonite development is nonetheless ascribed to metasomatism of a metacarbonate unit by magmatogene, silica-rich, CO2-poor (XCO2 < 0.05) fluids, at P = 350 MPa and ca. 560°C, or, alternatively, 550 MPa and ca. 630°C.Several high-grade zones, averaging >40% but locally exceeding 80%, of translucent, white, tabular wollastonite grains, with lengths of 0.2 cm to 5 cm, have been delimited by drilling. Preliminary beneficiation studies yield high aspect-ratio and high-purity (low Fe and Mn) concentrates.St. Lawrence compares favourably to other known prospects and operating wollastonite deposits: having good chemical and physical properties, low iron content, and high aspect ratios (>20:1). In addition, the deposit has a favourable size and location, and will benefit from a low Canadian dollar. Canada currently has no wollastonite production."

Jan 1, 2003

By Gary L. Seider

Helical screw piles are used in various applications including the underpinning of distressed foundations and as deep foundations for new structures. At present, maximum design loads range between 12.5 and 50 tons. Helical piles installed with in-situ grouting of the central steel shaft are a relatively new type of deep foundation, which have extended the present maximum design loads to the 100-ton range. Vickars & Clemence discussed this new foundation system in a paper presented at GEO-Denver 2000 in Denver, CO. Over the past three years, grouted shaft helicals have been used successfully on remedial and new construction projects all across North America. The authors have studied several construction projects in a variety of soil conditions to compile a list of practical design guidelines. Those guidelines include installability of grouted shaft helicals based on soil type, equipment requirements, grout selection, and theoretical vs. actual load capacity. In a number of cases, full-scale, field load tests were conducted in both granular and cohesive soils and the results broken down between tip resistance on the helix bearing plates and friction resistance on the grouted shaft. Data is presented which will further efforts to develop a design model and method to accurately predict the axial and lateral capacity of grouted shaft helicals.

Jan 1, 2003

By Jia Muxin

The adsorption behaviors of metal ions on a silicate mineral and the flotability of a metalized silicate mineral with sodium oleate as collector are closely related to the structure of the silicate mineral. The adsorption isothermals of the metal ions on different silicate minerals are studied, the parameters of the isothermal give the information how many surface oxygen anions a metal ions is attached to, from this information and the structure of the mineral the site where a metal ion is attached can be guessed (The adsorption isothermals and adsorption behaviors with pH are fitted with Temkin, Frenudlich and Kurbatov equations respectively). Metal ions as Cu2+, Ni2+, Zn2+ are attached to the oxygen anions of surface species –Si-O– on the quartz surface, most of them coordinate to only one surface oxygen, their adsorption ability on quartz is low, but this metal ions on quartz surface protrude out of the surface perfectly, so their ability to combine with oleate acid radical is excellent. Quartz can be activated well by such metal ions. The isothermal of Fe3+ on quartz indicates these cations coordinates with more than two surface oxygen anions. This means the Fe3+ nucleates on quartz surface in the form of Fe(OH)3 colloid particles. The isothermals of Cu2+, Ni2+, Zn2+ Fe3+ on spodumene shows such ions coordinate with more than two surface oxygen anions, it indicate these ions may attach to the position where Li+ is formerly exists, such metal ions stay in a cave on the mineral surface, their adsorption abilities on spodumene are quite well, but they are affect by the oxygen anions of the two Si tetrahedron chains, the can almost not activate this mineral. These cations may attach on the site where Al3+ exists on the muscovite surface, just like spodumene, muscovite can not be activated well by such cations. Pt2+ has a large ion radius, as Pauling’s rules depicts polyhedron can not attach to Si tetrahedron well, the adsorption ability of Pt2+ on quartz is low and quartz is activated badly by Pt2+. On the other Pt2+ can adsorb well on spodumene and muscovite well and activated them well because it is not affected so bad by the tetrahedron oxygen anions of the minerals for their its large radius. The isothermal of Ca2+ on quartz indicates a Ca2+ coordinates with less than one surface oxygen anion, this means Ca2+ attaches on quartz mainly by physical adsorption. The adsorption abilities on mineral surface and the interaction abilities with oleate acid radical of the transition metal ions with the same valence are guessed to be determined by their d electron number, the rules should be d1<d2<d3<d4>d5<d6<d7<d8<d9>d10. Hydrogen bond may play an important rule in the activation of the mineral by HF and the interaction of the HF activated silicate mineral with collectors. The general rule is high bond valence and small metal ion radius surface species –Me-O can be activated well by HF with sodium oleate as collector. For example – SiIV-OH is neutral while –SiIV-FH+ and –SiVI-FH+0.33 are positively charged, the positively charged surface species are more likely to connect oleate acid radical via hydrogen bonds.

Jan 1, 2003

By U. Dillon, G. Blackwell

"Geographic information systems (GIS) provide an efficient means for the recording, manipulation, revision, display and analysis of spatially referenced data. GIS are widely used at the exploration stage of mine development, and are increasingly used for reclamation planning. The ability of a GIS to perform spatial searches and query spatially referenced data make it a powerful tool for use at all stages of mine development. As the amount of data available for analysis increases, so does the power and flexibility of GIS as a planning tool.Starting from the exploration database, this paper describes how a GIS can be used for the development of mining plans based on topography, geology and mineralization information stored in a relational database. Planning decisions approaching the optimal can then be made for a wide range of parameters, including stockpile and waste dump locations, the location of potentially acid generating and neutralizing material for dump design, profitable and risk-controlled mine extraction sequencing, and haul road locations. This is made possible by the overlay and buffer analysis capabilities of a GIS which are explored and exploited to produce a continuous mine production planning program, as well as site remediation and reclamation using a successful case study. The Ore and ProductsThe mines in the Saskatoon area — Agrium, PCS-Cory, PCS-Allan, PCS-Patience Lake, PCS-Lanigan and IMC-Colonsay — extract the ore from the Patience Lake member. The mines in the southeast corner of Saskatchewan — IMC-K1 and K2, PCSRocanville — extract from the Esterhazy member, while IMC-Belle Plaine, near Regina, solution mines potassium chloride from both potash-bearing members.Ore from the Patience Lake member is a medium-grained mixture of sylvite and halite, with a KCl content of 36%, insolubles averaging up to 5.5%, and little or no carnallite.The ore from the Esterhazy member is a coarse-grained mixture of sylvite (KCl) and halite (NaCl) with a small amount of water insolubles, and some carnallite (a K-Mg chloride). Average run-of-mine grades are about 30% KCl."

Jan 1, 2003

By A. Fredriksson, R. Christiansson, I. Staub

A theoretical model based on DFN models and 2D DEM numerical modelling has been developed for evaluating the rock mass mechanical properties. The description of the methodology is non-site related and can be applied in any site for this type of characterisation. The methodology was developed in the frame of the Site Investigation programmes for a Deep Repository for spent fuel in Sweden, and validated on sets of data coming from the Äspö Hard Rock Laboratory. Un modèle théorique base sur des modèles probabilistiques de réseaux de fractures et sur un modèle numérique DEM 2D a été développé dans le but de déterminer les propriétés mécaniques de la masse rocheuse. La méthodologie développée peut être appliquée à tout type de site pour ce genre de caractérisation. Le modèle a été élaboré dans le cadre des programmes de recherche d’un site d’enfouissement des déchets nucléaires en Suède, et validé par une application au laboratoire de recherche souterrain à Äspö. Ausgehend von DFN-Modellen und 2D DEM numerischen Modellierungen wurde ein theoretisches Modell für die Auswertung von mechanischen Eigenschaften von Fels entwickelt. Die Methodikbeschreibung ist nicht standortspecifisch sondern kan überall für diesen Typ von Standordkarakteriserung angewendet werden. Die Methodik wurde in Schweden im Rahmen der Standortuntersuchungsprogramme für die Endlagerung von verbrauchten Brennelementen entwickelt und ist mit Hilfe von Daten des Äspö Hard Rock Laboratory validiert worden

Jan 1, 2003

By P. Trudel, É. Cabot, L. Cabot

"A modular gold processing unit (MGPU) was designed, installed and operated over an eight-month period by RSW-Béroma at the Granada mine located near Rouyn-Noranda, Quebec. A description of the project geology, plant set up, as well as exploitation results, including productivity and profitability curves, are given for a small-scale mining operation in comparison with larger ones. IntroductionSmall-scale mining (SSM) is a widespread activity in Africa, Mexico, Central America and South America, where numerous small mineral deposits are exploited manually or by semimechanized methods. On the other hand, SSM is almost absent in Canada, where the mining industry traditionally exploits large deposits, using concentration plants with capacities of many thousands of tonnes per day. However, many small gold (and other metallic or industrial mineral) deposits are known in Canada. Their reserves are too small to justify the cost related to the construction of a standard mill and, if they are remote from a custom milling facility, they remain unexploited. With this in mind, RSW-Béroma has developed the modular gold processing unit (MGPU) that allows the profitable exploitation of small mineral deposits. The MGPU is the perfect tool for SSM and its main advantages are a much lower capital cost than a standard mill and its portability, which makes it easy to transport and reinstall on another site, once the exploitation of a small deposit is terminated. The denomination MGPU will be used hereafter in the text as it was primarily designed for gold deposits, although it must be kept in mind that this portable plant can be adapted to other mineral substances."

Jan 1, 2003

By J. -P. Gisiger

On the basis of laboratory test results a comparison of various parameters (unconfined compressive strength, CERCHAR and LCPC abrasivity indexes, mineralogy) is presented and discussed in order to outline certain correlations between them. Samples cover a wide range of lithological types coming from various sites of tunnels. A partir de résultats d’essais de laboratoire, une comparaison de divers paramètres (résistance à la compression simple, indices d’abrasivité CERCHAR et LCPC, minéralogie) est présentée et discutée dans le but d’en tirer certaines corrélations. Les échantillons couvrent un large éventail de types lithologiques provenant de plusieurs sites de tunnels. Basierend auf Laborversuchen, werden verschiedene Gesteinseigenschaften (Druckfestigkeit, CERCHAR und LCPC Abrasionsindexe) präsentiert und Korrelationen aufgezeigt. Die untersuchten Proben verschiedenster Lithologien stammen aus mehreren Tunnelprojekten.

Jan 1, 2003

By K. Grossauer, W. Schubert

For tunnelling in poor and heterogeneous ground a reliable on-site short-term prediction is required to allow a safe and economical construction. With the use of absolute displacement monitoring data and advanced software for evaluation of the data in combination with a routine update of the geological model a considerable increase in the reliability of the short-term prediction could be achieved. The paper deals with theoretical considerations, numerical studies and case histories from alpine tunnels in heterogeneous rock. Tunnelbau in schlechtem und heterogenem Gebirge erfordert auf der Baustelle eine verlaessliche Kurzzeitprognose, um ein sicheres und wirtschaftliches Bauwerk gewaehrleisten zu können. Die Verwendung von absoluten Verschiebungsmessdaten und deren Auswertung mit Hilfe von hoch entwickelten Softwareprogrammen in Kombination mit einer laufenden Aktualisierung des Gebirgsmodells ermöglicht eine erhebliche Erhöhung der Verlässlichkeit von Kurzzeitprognosen. Dieser Beitrag beschäftigt sich mit theoretischen Ansätzen, numerischen Modellen und Fallstudien von Tunnelvortrieben in heterogenem Gebirge. La construction de tunnels dans la montagne hétérogène de faible résistance exige un pronostic fiable à court terme sur le chantier, afin de pouvoir garantir un ouvrage sûr et économique. L&apos;utilisation des données de mesure de décalage absolues et de leur évaluation à l&apos;aide de logiciels sophistiqués en combinaison avec une mise à jour courante du modèle de la montagne permet une augmentation considérable de la fiabilité des pronostics à court terme. Cette contribution présente des approches théoriques, des modèles numériques et de cas pratiques de progressions de tunnels dans des montagnes hétérogènes.

Jan 1, 2003

By A Gerson, S Miller, R Smart, J Thomas

Environmental Geochemistry International (EGi) and the Ian Wark Research Institute (IWRI) collaborated in a three-year Australian Minerals Industry Research Association (AMIRA) research project (Project Number P387A) focussed on the prediction and kinetic control of acid mine drainage. As part of this project, single addition, and sequential net acid generation (NAG) testing was carried out on sulfide mineral samples. The test samples comprised a range of synthetic waste materials prepared using a quartz bulk and controlled quantities of the commonly occurring sulfide minerals; pyrite (FeS2), pyrrhotite (Fe7S8), arsenopyrite (AsFeS), chalcopyrite (CuFeS2), chalcocite (Cu2S), covellite (CuS), bornite (Cu5FeS4), galena (PbS) and sphalerite (ZnS). NAG test results clearly show that there are significant differences between the acid forming potential of sulfide minerals. The NAG test results for each mineral were compared with theoretical acidity values (NAPP*). The NAPP* calculation was based on stoichiometric oxidation reactions assumed for each of the sulfide minerals. Sequential NAG values for pyrite corresponds closely to predicted NAPP* values, confirming the assumption that pyrite oxidation occurs according to the stoichiometry assumed. For the pyrite sample with 5 wt per cent S, two NAG stages were sufficient for all of the sulfur to be released to solution. Since sulfides in waste materials will generally be dominated by pyrite, results also confirm the validity of including NAG testing for ARD evaluation of most waste rock. NAG testing confirms that of the sulfide minerals examined, only pyrite, pyrrhotite, arsenopyrite and chalcopyrite are acid producing, ie able to produce leachate with a pH less than 4.5. In the case of sphalerite, galena, bornite, chalcocite and covellite the pH of the final NAG solution was greater than 4.5. The significant differences between the acid forming potential of different sulfide minerals could lead to overestimation of acid producing potentials based on NAPP values calculated from total per cent S alone, ie assuming all S is present as pyrite. The oxidation of galena during the NAG test resulted in the consumption of acid. The examination of the galena surface by X-ray photoelectron spectroscopy (XPS) after oxidation in peroxide solution indicated the presence of polysulfide. The reaction of sulfide to polysulfide is acid consuming, thus explaining the net acid consuming behaviour of galena in the NAG test. This reaction pathway may provide a possible explanation for the lower than expected acid production observed for some of the other sulfide minerals examined.

Jan 1, 2003

By Herman D. Mendoza

A rapid recovery/recycling process was introduced utilizing the surface-chemical properties of finely dispersed mercury and alumina (Al2O3) fibers in aqueous environment. The conventional method of amalgamation or .ball milling. involves the mixing of a substantial amount of mercury to collect free gold during the grinding stage. In effect, a portion of the mercury is transformed into minute droplets that readily float and disperse in the amalgamation effluent. The fine droplets of mercury in the dispersion readily attached onto the positively charged macroscopic alumina fibers (i.e. = pH 9.8) at conditions pH 3 to 10. When an effluent from settling procedure after an amalgamation-grinding stage is passed through a column-bed packed with alumina fibers, maximum collection of negatively charged finely dispersed mercury occurred at pH 3 to 6. The collection/attachment efficiency was 99.5%. The collected droplets of mercury, which are left in the column-bed of alumina fibers, were subsequently rinsed with alkaline solution at pH 10 to 11.5. At these conditions, both mercury and alumina fibers carry negative surface potentials and resulted in the partial detachment of mercury from the alumina fibers. The detachment efficiency was only 30-35%. The attachment/detachment mechanisms in this study were analyzed using the DLVO theory.

Jan 1, 2003